JPS6031882A - 発色現像主薬の回収装置 - Google Patents
発色現像主薬の回収装置Info
- Publication number
- JPS6031882A JPS6031882A JP14042583A JP14042583A JPS6031882A JP S6031882 A JPS6031882 A JP S6031882A JP 14042583 A JP14042583 A JP 14042583A JP 14042583 A JP14042583 A JP 14042583A JP S6031882 A JPS6031882 A JP S6031882A
- Authority
- JP
- Japan
- Prior art keywords
- color developing
- developing agent
- photographic processing
- tank
- processing waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000011084 recovery Methods 0.000 title claims description 26
- 238000012545 processing Methods 0.000 claims description 76
- 239000002699 waste material Substances 0.000 claims description 63
- 239000007788 liquid Substances 0.000 claims description 61
- 239000003729 cation exchange resin Substances 0.000 claims description 51
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 50
- 239000000243 solution Substances 0.000 claims description 50
- 239000011347 resin Substances 0.000 claims description 47
- 229920005989 resin Polymers 0.000 claims description 47
- 239000012670 alkaline solution Substances 0.000 claims description 22
- 238000010979 pH adjustment Methods 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 description 84
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- 238000000034 method Methods 0.000 description 21
- 238000005406 washing Methods 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 9
- 125000000524 functional group Chemical group 0.000 description 8
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000018109 developmental process Effects 0.000 description 6
- -1 silver halide Chemical class 0.000 description 6
- 238000004061 bleaching Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000003957 anion exchange resin Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 150000002443 hydroxylamines Chemical class 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229940023913 cation exchange resins Drugs 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000000909 electrodialysis Methods 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- NSYCNXOFRPQHGG-UHFFFAOYSA-N 1h-benzimidazole;nitric acid Chemical compound O[N+]([O-])=O.C1=CC=C2NC=NC2=C1 NSYCNXOFRPQHGG-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- HPIVZWOZEIGINZ-UHFFFAOYSA-N 4-n-ethyl-4-n-[2-(2-methoxyethoxy)ethyl]-2-methylbenzene-1,4-diamine Chemical compound COCCOCCN(CC)C1=CC=C(N)C(C)=C1 HPIVZWOZEIGINZ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical group OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229940099427 potassium bisulfite Drugs 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000012089 stop solution Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Landscapes
- Treatment Of Water By Ion Exchange (AREA)
- Photographic Developing Apparatuses (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14042583A JPS6031882A (ja) | 1983-07-30 | 1983-07-30 | 発色現像主薬の回収装置 |
| US06/616,170 US4606827A (en) | 1983-06-03 | 1984-06-01 | Method for separating and recovering color developing agent |
| EP84303746A EP0128720B1 (en) | 1983-06-03 | 1984-06-04 | Method and apparatus for separating and recovering color developing agent |
| DE8484303746T DE3475659D1 (en) | 1983-06-03 | 1984-06-04 | Method and apparatus for separating and recovering color developing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14042583A JPS6031882A (ja) | 1983-07-30 | 1983-07-30 | 発色現像主薬の回収装置 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6031882A true JPS6031882A (ja) | 1985-02-18 |
| JPH0335998B2 JPH0335998B2 (enrdf_load_stackoverflow) | 1991-05-30 |
Family
ID=15268390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14042583A Granted JPS6031882A (ja) | 1983-06-03 | 1983-07-30 | 発色現像主薬の回収装置 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6031882A (enrdf_load_stackoverflow) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4966509A (enrdf_load_stackoverflow) * | 1972-11-07 | 1974-06-27 | ||
| JPS5271861A (en) * | 1975-12-10 | 1977-06-15 | Matsushita Electric Ind Co Ltd | Process for purifying water containing triethanolamine |
| JPS5830387A (ja) * | 1981-08-18 | 1983-02-22 | Asahi Chem Ind Co Ltd | アミン類を含む廃水の処理方法 |
-
1983
- 1983-07-30 JP JP14042583A patent/JPS6031882A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4966509A (enrdf_load_stackoverflow) * | 1972-11-07 | 1974-06-27 | ||
| JPS5271861A (en) * | 1975-12-10 | 1977-06-15 | Matsushita Electric Ind Co Ltd | Process for purifying water containing triethanolamine |
| JPS5830387A (ja) * | 1981-08-18 | 1983-02-22 | Asahi Chem Ind Co Ltd | アミン類を含む廃水の処理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0335998B2 (enrdf_load_stackoverflow) | 1991-05-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS58105150A (ja) | カラ−写真処理装置 | |
| US3253920A (en) | Rejuvenation of photographic developers using ion exchange resins | |
| US3733994A (en) | Apparatus for washing of photographic material | |
| EP0128720B1 (en) | Method and apparatus for separating and recovering color developing agent | |
| US4128464A (en) | Process for regenerating bleaching-fixing solution | |
| US4680123A (en) | Regeneration of spent developers | |
| US6117315A (en) | Process and device for recycling washing water in photographic processing | |
| US4145271A (en) | Method for regenerating oxidized photographic developers | |
| JPS6031882A (ja) | 発色現像主薬の回収装置 | |
| US4311574A (en) | Regeneration of photographic processing solutions | |
| JPS6143749A (ja) | ハロゲン化銀写真感光材料の処理方法 | |
| EP0500592A1 (en) | SLOW EFFLUENT REGENERATION SYSTEM FOR COLOR NEGATIVE DEVELOPERS. | |
| JPS6334461B2 (enrdf_load_stackoverflow) | ||
| JPH0227656B2 (ja) | Hatsushokugenzoshuyakuobunrioyobikaishusuruhoho | |
| Priesthoff et al. | Ion-exchange recovery of Eastman color developers | |
| EP0729066B1 (en) | Removal of tin from seasoned photographic color developers | |
| WO1991017478A1 (en) | Method of processing photographic material | |
| US4010034A (en) | Method for adjusting the bromide ion concentration in a photographic processing solution | |
| Kleppe | Practical Application of an Ion-Exchange Method for Color-Developer Reuse | |
| JPS5814831A (ja) | 現像液中の現像阻害物質の除去方法 | |
| Burger et al. | Recovery of Kodak color developing agent CD-2 from process ECP-2A color developer and stop bath | |
| JPS6155421B2 (enrdf_load_stackoverflow) | ||
| JPH06242560A (ja) | ハロゲン化銀写真材料の処理方法 | |
| JPH01155985A (ja) | 写真現像での洗浄排水の処理法 | |
| JPS60189744A (ja) | カラ−写真現像液の再生方法 |