JPS6028853B2 - 発泡性組成物とその用法 - Google Patents
発泡性組成物とその用法Info
- Publication number
- JPS6028853B2 JPS6028853B2 JP10116676A JP10116676A JPS6028853B2 JP S6028853 B2 JPS6028853 B2 JP S6028853B2 JP 10116676 A JP10116676 A JP 10116676A JP 10116676 A JP10116676 A JP 10116676A JP S6028853 B2 JPS6028853 B2 JP S6028853B2
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- thermoplastic
- composition according
- group
- formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 119
- 238000005187 foaming Methods 0.000 title description 12
- 229920001169 thermoplastic Polymers 0.000 claims description 54
- 239000004604 Blowing Agent Substances 0.000 claims description 42
- 239000004416 thermosoftening plastic Substances 0.000 claims description 41
- 229920000515 polycarbonate Polymers 0.000 claims description 28
- 239000004417 polycarbonate Substances 0.000 claims description 28
- -1 bis(4-hydroxyphenyl) ethylene carbonate units Chemical group 0.000 claims description 25
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 239000008188 pellet Substances 0.000 claims description 15
- 125000002947 alkylene group Chemical group 0.000 claims description 12
- 125000000732 arylene group Chemical group 0.000 claims description 12
- 239000003365 glass fiber Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 125000002723 alicyclic group Chemical group 0.000 claims description 8
- 238000001746 injection moulding Methods 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- 125000004104 aryloxy group Chemical group 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- RUWHMZIBEYGMPG-UHFFFAOYSA-N 5-phenyl-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical group C1OC(=O)NN=C1C1=CC=CC=C1 RUWHMZIBEYGMPG-UHFFFAOYSA-N 0.000 claims description 5
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 5
- 229930185605 Bisphenol Natural products 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- FUGYGGDSWSUORM-UHFFFAOYSA-N para-hydroxystyrene Natural products OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002861 polymer material Substances 0.000 claims 10
- 150000002431 hydrogen Chemical class 0.000 claims 5
- MQXNNWDXHFBFEB-UHFFFAOYSA-N 2,2-bis(2-hydroxyphenyl)propane Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1O MQXNNWDXHFBFEB-UHFFFAOYSA-N 0.000 claims 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims 1
- XSXWYGABGYBZRM-UHFFFAOYSA-N carbonic acid;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical group OC(O)=O.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 XSXWYGABGYBZRM-UHFFFAOYSA-N 0.000 claims 1
- 239000012744 reinforcing agent Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 42
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000004431 polycarbonate resin Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 229920005668 polycarbonate resin Polymers 0.000 description 13
- 229920000620 organic polymer Polymers 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 239000012141 concentrate Substances 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 9
- 229920002223 polystyrene Polymers 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910001868 water Inorganic materials 0.000 description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 239000004793 Polystyrene Substances 0.000 description 8
- 239000004088 foaming agent Substances 0.000 description 8
- 238000012667 polymer degradation Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- MWDQEAAXJLBXLS-UHFFFAOYSA-N (propan-2-yloxycarbonylamino)carbamic acid Chemical compound CC(C)OC(=O)NNC(O)=O MWDQEAAXJLBXLS-UHFFFAOYSA-N 0.000 description 6
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 5
- 238000010097 foam moulding Methods 0.000 description 5
- 229920006258 high performance thermoplastic Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- OWEYKIWAZBBXJK-UHFFFAOYSA-N 1,1-Dichloro-2,2-bis(4-hydroxyphenyl)ethylene Chemical group C1=CC(O)=CC=C1C(=C(Cl)Cl)C1=CC=C(O)C=C1 OWEYKIWAZBBXJK-UHFFFAOYSA-N 0.000 description 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- BNKAEWPBHKDCQE-UHFFFAOYSA-N 5,6-diphenyl-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical compound O1C(=O)NN=C(C=2C=CC=CC=2)C1C1=CC=CC=C1 BNKAEWPBHKDCQE-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- CKJGNIFOQZUIAZ-UHFFFAOYSA-N 1,3,4-oxadiazin-2-one Chemical compound O=C1N=NC=CO1 CKJGNIFOQZUIAZ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 2
- 229940106691 bisphenol a Drugs 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 125000005023 xylyl group Chemical group 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OTJFTLRXGXUHEJ-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)ethenyl]phenol Chemical group C1=CC(O)=CC=C1C(=C)C1=CC=C(O)C=C1 OTJFTLRXGXUHEJ-UHFFFAOYSA-N 0.000 description 1
- HEYIHUTYFWRSPX-UHFFFAOYSA-N 5,6-dimethyl-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical compound CC1OC(=O)NN=C1C HEYIHUTYFWRSPX-UHFFFAOYSA-N 0.000 description 1
- HVOPDHMUBFPTSW-UHFFFAOYSA-N 5-(3-nitrophenyl)-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical compound [O-][N+](=O)C1=CC=CC(C=2COC(=O)NN=2)=C1 HVOPDHMUBFPTSW-UHFFFAOYSA-N 0.000 description 1
- VWPDDHIJKIZLMY-UHFFFAOYSA-N 5-(4-hydroxyphenyl)-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical compound C1=CC(O)=CC=C1C1=NNC(=O)OC1 VWPDDHIJKIZLMY-UHFFFAOYSA-N 0.000 description 1
- PCVMORYFSYKFAJ-UHFFFAOYSA-N 5-ethyl-6-methoxy-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical compound CCC1=NNC(=O)OC1OC PCVMORYFSYKFAJ-UHFFFAOYSA-N 0.000 description 1
- JQWQPZLPPVVJPD-UHFFFAOYSA-N 5-naphthalen-1-yl-3,6-dihydro-1,3,4-oxadiazin-2-one Chemical compound C1OC(=O)NN=C1C1=CC=CC2=CC=CC=C12 JQWQPZLPPVVJPD-UHFFFAOYSA-N 0.000 description 1
- OKMUXIBFKGUFDT-UHFFFAOYSA-N 6-methyl-2-oxo-5-phenyl-3h-1,3,4-oxadiazine-6-carbonitrile Chemical compound N#CC1(C)OC(=O)NN=C1C1=CC=CC=C1 OKMUXIBFKGUFDT-UHFFFAOYSA-N 0.000 description 1
- UKULZRSLLSJFKP-UHFFFAOYSA-N C1(=CC=CC=C1)O.C1(=CC=CC=C1)O.ClC=CCl Chemical compound C1(=CC=CC=C1)O.C1(=CC=CC=C1)O.ClC=CCl UKULZRSLLSJFKP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- 229920011453 Hytrel® 4056 Polymers 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007033 dehydrochlorination reaction Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000003106 haloaryl group Chemical group 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WFJRIDQGVSJLLH-UHFFFAOYSA-N methyl n-aminocarbamate Chemical compound COC(=O)NN WFJRIDQGVSJLLH-UHFFFAOYSA-N 0.000 description 1
- QVRVXSZKCXFBTE-UHFFFAOYSA-N n-[4-(6,7-dimethoxy-3,4-dihydro-1h-isoquinolin-2-yl)butyl]-2-(2-fluoroethoxy)-5-methylbenzamide Chemical compound C1C=2C=C(OC)C(OC)=CC=2CCN1CCCCNC(=O)C1=CC(C)=CC=C1OCCF QVRVXSZKCXFBTE-UHFFFAOYSA-N 0.000 description 1
- 125000004999 nitroaryl group Chemical group 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- FBZULTVJWVCJQV-UHFFFAOYSA-N propan-2-yl n-(propan-2-yloxycarbonylamino)carbamate Chemical compound CC(C)OC(=O)NNC(=O)OC(C)C FBZULTVJWVCJQV-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D273/00—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00
- C07D273/02—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00 having two nitrogen atoms and only one oxygen atom
- C07D273/04—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/108—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond in a heterocyclic ring containing at least one carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60845175A | 1975-08-28 | 1975-08-28 | |
| US608451 | 1975-08-28 | ||
| US669028 | 1976-03-22 | ||
| US05/669,028 US4097425A (en) | 1975-08-28 | 1976-03-22 | Thermoplastic formable blends, a foaming method and products made thereby |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5235264A JPS5235264A (en) | 1977-03-17 |
| JPS6028853B2 true JPS6028853B2 (ja) | 1985-07-06 |
Family
ID=27085772
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10116676A Expired JPS6028853B2 (ja) | 1975-08-28 | 1976-08-26 | 発泡性組成物とその用法 |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS6028853B2 (cg-RX-API-DMAC7.html) |
| AU (1) | AU501566B2 (cg-RX-API-DMAC7.html) |
| DE (1) | DE2637736C2 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2322169A1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1562616A (cg-RX-API-DMAC7.html) |
| IT (1) | IT1064982B (cg-RX-API-DMAC7.html) |
| MX (1) | MX144674A (cg-RX-API-DMAC7.html) |
| NL (1) | NL182732C (cg-RX-API-DMAC7.html) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU509145B2 (en) * | 1976-03-22 | 1980-04-24 | General Electric Company | Flame retardant figid thermoplastic foams |
| US4105848A (en) * | 1976-12-27 | 1978-08-08 | General Electric Company | Process for the production of dihydrooxadiazinone compounds |
| GB2045769B (en) * | 1979-03-27 | 1983-05-11 | Gen Electric | Thermoplastic foamable blends |
| JPS5962578A (ja) * | 1982-10-04 | 1984-04-10 | Mitsui Toatsu Chem Inc | オキサジアジン誘導体およびそれを含有する医薬組成物 |
| US4500653A (en) * | 1983-09-14 | 1985-02-19 | Mobay Chemical Corporation | Blowing agents for thermoplastic compositions |
| US4543368A (en) * | 1984-11-09 | 1985-09-24 | General Electric Company | Foamable polyetherimide resin formulation |
| US7842379B2 (en) | 2007-07-05 | 2010-11-30 | Sabic Innovative Plastics Ip B.V. | Polymeric foams with nanocellular morphology and methods for making them |
| US8908129B2 (en) | 2007-12-28 | 2014-12-09 | Sabic Global Technologies B.V. | Reflective polymeric article and manufacture |
| US8440732B2 (en) | 2008-03-25 | 2013-05-14 | Sabic Innovative Plastics Ip B.V. | Polymeric foams with nanocellular morphology and methods for making them |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2126146A1 (de) * | 1971-05-26 | 1972-12-07 | Bayer | Treibmittel |
-
1976
- 1976-07-30 GB GB3185476A patent/GB1562616A/en not_active Expired
- 1976-08-21 DE DE19762637736 patent/DE2637736C2/de not_active Expired
- 1976-08-24 AU AU17099/76A patent/AU501566B2/en not_active Expired
- 1976-08-25 FR FR7625716A patent/FR2322169A1/fr active Granted
- 1976-08-26 JP JP10116676A patent/JPS6028853B2/ja not_active Expired
- 1976-08-26 IT IT2656876A patent/IT1064982B/it active
- 1976-08-27 NL NL7609535A patent/NL182732C/xx not_active IP Right Cessation
- 1976-08-27 MX MX16607776A patent/MX144674A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL182732C (nl) | 1988-05-02 |
| FR2322169A1 (fr) | 1977-03-25 |
| FR2322169B1 (cg-RX-API-DMAC7.html) | 1979-09-07 |
| NL182732B (nl) | 1987-12-01 |
| IT1064982B (it) | 1985-02-25 |
| GB1562616A (en) | 1980-03-12 |
| MX144674A (es) | 1981-11-10 |
| NL7609535A (nl) | 1977-03-02 |
| DE2637736C2 (de) | 1986-08-21 |
| AU501566B2 (en) | 1979-06-21 |
| JPS5235264A (en) | 1977-03-17 |
| AU1709976A (en) | 1978-03-02 |
| DE2637736A1 (de) | 1977-03-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4163037A (en) | Method for making thermoplastic foams | |
| US4071503A (en) | Polycarbodiimide modification of polyesters for extrusion applications | |
| JPH02294357A (ja) | ポリエステル樹脂組成物及び成形品 | |
| US4334030A (en) | Thermoplastic foamable blends | |
| US4174432A (en) | Flame retardant rigid thermoplastic foams | |
| JPS6028853B2 (ja) | 発泡性組成物とその用法 | |
| US4183822A (en) | Blowing agent composition | |
| GB1600694A (en) | Curable aryloxyphosphazene polymers | |
| EP0505898A1 (en) | Polyester compositions showing a high crystallization rate | |
| JPH02283734A (ja) | 発泡性エンジニアリング熱可塑性組成物 | |
| US4999384A (en) | Foamed blends of nylon 6,I/T and polycarbonate | |
| US3946090A (en) | Flame-resistant polycarbonate molding compositions | |
| US5114983A (en) | Use of polyarylene sulphides for the production of a structural foam resistant to high temperatures, process for the preparation of this foam, and moldings obtainable by this process | |
| US3819545A (en) | Foamable composition comprising a gas-expandable polymeric material and oxalyl carbazate or oligomers thereof, and method of forming same | |
| US4696995A (en) | Poly(ester-carbonates) and blends based on 3-methyl-4-hydroxy-benzoic acid | |
| KR102208407B1 (ko) | 폴리에틸렌 카보네이트 수지 조성물 및 이의 제조 방법 | |
| JPS63152647A (ja) | 発泡性組成物および発泡成形物品の製造方法 | |
| CA1102500A (en) | Thermoplastic foamable blends, a foaming method and products made thereby | |
| TW202006043A (zh) | 聚醯亞胺樹脂組成物及其成形體 | |
| JPH0113496B2 (cg-RX-API-DMAC7.html) | ||
| JPH09176375A (ja) | 亜燐酸エステルで安定化された重合体成形用組成物 | |
| EP0141144B1 (en) | Blowing agents for thermoplastic compositions | |
| CA1242849A (en) | Process for foaming thermoplastic aromatic polycarbonates | |
| US3883474A (en) | Flame resistant thermoplastic polyesters | |
| JPH04132763A (ja) | 熱可塑性ポリエステル樹脂組成物 |