JPS60231420A - コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 - Google Patents
コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法Info
- Publication number
- JPS60231420A JPS60231420A JP24781883A JP24781883A JPS60231420A JP S60231420 A JPS60231420 A JP S60231420A JP 24781883 A JP24781883 A JP 24781883A JP 24781883 A JP24781883 A JP 24781883A JP S60231420 A JPS60231420 A JP S60231420A
- Authority
- JP
- Japan
- Prior art keywords
- cobalt
- nickel
- extraction
- extractant
- branched alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 69
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 132
- 229910017052 cobalt Inorganic materials 0.000 title claims description 111
- 239000010941 cobalt Substances 0.000 title claims description 111
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 111
- 239000007864 aqueous solution Substances 0.000 title claims description 29
- 238000000926 separation method Methods 0.000 title description 21
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 38
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000000605 extraction Methods 0.000 claims description 86
- 238000000034 method Methods 0.000 claims description 32
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 20
- 239000011575 calcium Substances 0.000 claims description 20
- 229910052791 calcium Inorganic materials 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 19
- -1 1-methylheptyl group Chemical group 0.000 claims description 18
- 150000002148 esters Chemical class 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000001424 substituent group Chemical group 0.000 claims 3
- 125000005600 alkyl phosphonate group Chemical group 0.000 abstract 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- XUQLZJVBTGOVPT-UHFFFAOYSA-N octan-2-ylphosphonic acid Chemical compound CCCCCCC(C)P(O)(O)=O XUQLZJVBTGOVPT-UHFFFAOYSA-N 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 description 41
- 239000008346 aqueous phase Substances 0.000 description 30
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 239000000284 extract Substances 0.000 description 8
- 150000007522 mineralic acids Chemical class 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 7
- 238000000638 solvent extraction Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 229910001429 cobalt ion Inorganic materials 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical compound [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910001453 nickel ion Inorganic materials 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- ZDFBXXSHBTVQMB-UHFFFAOYSA-N 2-ethylhexoxy(2-ethylhexyl)phosphinic acid Chemical compound CCCCC(CC)COP(O)(=O)CC(CC)CCCC ZDFBXXSHBTVQMB-UHFFFAOYSA-N 0.000 description 2
- CRLAISPERADHHT-UHFFFAOYSA-N 2-ethylhexyl(octan-2-yloxy)phosphinic acid Chemical compound CCCCCCC(C)OP(O)(=O)CC(CC)CCCC CRLAISPERADHHT-UHFFFAOYSA-N 0.000 description 2
- 239000004808 2-ethylhexylester Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- OGJLPLDTKZHLLH-UHFFFAOYSA-N [Ca].[Co] Chemical compound [Ca].[Co] OGJLPLDTKZHLLH-UHFFFAOYSA-N 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 210000003323 beak Anatomy 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical class [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24781883A JPS60231420A (ja) | 1983-12-28 | 1983-12-28 | コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24781883A JPS60231420A (ja) | 1983-12-28 | 1983-12-28 | コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60231420A true JPS60231420A (ja) | 1985-11-18 |
| JPH0448733B2 JPH0448733B2 (enExample) | 1992-08-07 |
Family
ID=17169114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24781883A Granted JPS60231420A (ja) | 1983-12-28 | 1983-12-28 | コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60231420A (enExample) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5470553A (en) * | 1993-12-07 | 1995-11-28 | Industrial Technology Research Institute | Method for separating cobalt, nickel, and aluminum ions in sulfuric acid aqueous solutions and the extractant compositions used therein |
| JP2008527164A (ja) * | 2004-12-30 | 2008-07-24 | ビーエイチピー・ビリトン・エスエスエム・テクノロジー・ピーティーワイ・リミテッド | 樹脂溶出液流からニッケル及びコバルトを回収する方法 |
| JP2012153546A (ja) * | 2011-01-24 | 2012-08-16 | Sumitomo Metal Mining Co Ltd | 硫酸コバルトの製造方法 |
| WO2013099551A1 (ja) * | 2011-12-26 | 2013-07-04 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| JP2015145820A (ja) * | 2014-02-03 | 2015-08-13 | 住友金属鉱山株式会社 | 脂溶性リン化合物の定量方法 |
| JP2017008407A (ja) * | 2015-06-22 | 2017-01-12 | 住友金属鉱山株式会社 | カルシウムの分離方法 |
| WO2018043703A1 (ja) * | 2016-09-05 | 2018-03-08 | 住友金属鉱山株式会社 | ニッケル、コバルトを含有する溶液の製造方法 |
| WO2022224499A1 (ja) * | 2021-04-22 | 2022-10-27 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| JP2023004393A (ja) * | 2021-06-25 | 2023-01-17 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
-
1983
- 1983-12-28 JP JP24781883A patent/JPS60231420A/ja active Granted
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5470553A (en) * | 1993-12-07 | 1995-11-28 | Industrial Technology Research Institute | Method for separating cobalt, nickel, and aluminum ions in sulfuric acid aqueous solutions and the extractant compositions used therein |
| JP2008527164A (ja) * | 2004-12-30 | 2008-07-24 | ビーエイチピー・ビリトン・エスエスエム・テクノロジー・ピーティーワイ・リミテッド | 樹脂溶出液流からニッケル及びコバルトを回収する方法 |
| JP2012153546A (ja) * | 2011-01-24 | 2012-08-16 | Sumitomo Metal Mining Co Ltd | 硫酸コバルトの製造方法 |
| WO2013099551A1 (ja) * | 2011-12-26 | 2013-07-04 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| US9428820B2 (en) | 2011-12-26 | 2016-08-30 | Sumitomo Metal Mining Co., Ltd. | Method for producing cobalt sulfate |
| JP2015145820A (ja) * | 2014-02-03 | 2015-08-13 | 住友金属鉱山株式会社 | 脂溶性リン化合物の定量方法 |
| JP2017008407A (ja) * | 2015-06-22 | 2017-01-12 | 住友金属鉱山株式会社 | カルシウムの分離方法 |
| WO2018043703A1 (ja) * | 2016-09-05 | 2018-03-08 | 住友金属鉱山株式会社 | ニッケル、コバルトを含有する溶液の製造方法 |
| JP2018039682A (ja) * | 2016-09-05 | 2018-03-15 | 住友金属鉱山株式会社 | ニッケル、コバルトを含有する溶液の製造方法 |
| RU2726618C1 (ru) * | 2016-09-05 | 2020-07-15 | Сумитомо Метал Майнинг Ко., Лтд. | Способ получения растворов, содержащих никель или кобальт |
| WO2022224499A1 (ja) * | 2021-04-22 | 2022-10-27 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| JP2022167760A (ja) * | 2021-04-22 | 2022-11-04 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| JP2023004393A (ja) * | 2021-06-25 | 2023-01-17 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0448733B2 (enExample) | 1992-08-07 |
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