JPS60215613A - Weak-acidity bath preparation - Google Patents

Weak-acidity bath preparation

Info

Publication number
JPS60215613A
JPS60215613A JP7150984A JP7150984A JPS60215613A JP S60215613 A JPS60215613 A JP S60215613A JP 7150984 A JP7150984 A JP 7150984A JP 7150984 A JP7150984 A JP 7150984A JP S60215613 A JPS60215613 A JP S60215613A
Authority
JP
Japan
Prior art keywords
acid
bath
carbonate
weak
acidity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7150984A
Other languages
Japanese (ja)
Inventor
Yasuteru Eguchi
泰輝 江口
Hidenori Yorozu
秀憲 萬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP7150984A priority Critical patent/JPS60215613A/en
Publication of JPS60215613A publication Critical patent/JPS60215613A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22Gas releasing
    • A61K2800/222Effervescent

Abstract

PURPOSE:A weak-acidity bath preparation that is obtained by adding vitamins to a bath preparation which contains a carbonate and an acid and shows a weak- acidity pH in the bath, thus showing enhanced synergism in blood flow stimulation, skin chapping prevention, skin aging prevention and no chill after bathing. CONSTITUTION:The objective bath preparation is formed by adding 0.001-10%, preferably 0.01-2%, based on the total composition, of vitamins such as vitamins A, B2, B6, C, D preferably D2, E, F or H to a weak-acidity bath preparation containing a carbonate such as sodium carbonate or potassium carbonate and an acid such as succinic, fumaric and phosphoric acid. It shows good effect to stimulate blood flow in skins, since carbon dioxide exists in the gas form in the bath.

Description

【発明の詳細な説明】 本発明は新規な弱酸性入浴剤、史に詳細には、炭酸塩と
酸を含有し、使用時の浴場pHが弱酸性を呈する入浴剤
にビタミン類を配合することによシ、血行促進効果及び
肌あれ防止、皮膚老化防止、保温等の効果を相乗的に、
情めた弱酸性入浴剤に関する。
[Detailed Description of the Invention] The present invention is a novel weakly acidic bath additive, and more specifically, the present invention is a novel weakly acidic bath additive, and more specifically, a bath additive that contains carbonate and acid and exhibits a weakly acidic bath pH during use, in which vitamins are blended. synergistically has the effect of promoting health, promoting blood circulation, preventing rough skin, preventing skin aging, and keeping warm.
Concerning weakly acidic bath salts.

入浴剤は一般に芒硝、硼砂、イオウ、食塩、炭酸塩等の
無淡塩禰混合物に香料、着色料、植物エキス、有機酸等
を配合したもので、浴場に香り、色調を与えたり、皮膚
面に適度な刺激を与えることにより血液の循環を活発に
し、疲労回復、新陳代謝を増進させるものでおる。これ
らの浴用剤の中で、炭酸塩と酸を組合せた発泡性入浴剤
があり、これは浴湯中に炭酸ガスの気泡を発生させて、
リラックス感や爽快感を高め、入浴を楽しくする効果を
有する。
Bath additives are generally a mixture of plain salts such as mirabilite, borax, sulfur, salt, carbonate, etc., combined with fragrances, colorants, plant extracts, organic acids, etc., and are used to add scent and color to the bath, and to add color to the skin. By providing moderate stimulation to the body, it activates blood circulation, relieves fatigue, and improves metabolism. Among these bath additives, there are effervescent bath additives that combine carbonate and acid, which generate carbon dioxide bubbles in the bath water.
It has the effect of increasing the feeling of relaxation and refreshment and making bathing more enjoyable.

しかしながら、従来の発泡性入浴剤は、中性ないしは弱
アルカリ性であって、発生した炭酸ガスのほとんど全て
は水中に溶解せず、空気中に揮散してしまうので、この
炭酸ガスの気泡は単に感覚的な機械的作用を奏するのみ
であった。
However, conventional foaming bath additives are neutral or slightly alkaline, and almost all of the carbon dioxide gas generated does not dissolve in the water and evaporates into the air, so the carbon dioxide bubbles are simply a sensation. It only had a mechanical effect.

そこで、本発明者は、種々研究を行い、炭酸塩と酸を含
有し、浴湯のpHが弱酸性を呈する入浴剤とすることに
より、炭酸ガスを浴液中に留め。
Therefore, the inventors of the present invention conducted various studies and created a bath additive that contains carbonate and acid and makes the pH of the bath water slightly acidic, thereby retaining carbon dioxide gas in the bath liquid.

血行を促進し、湯冷めを惹起しない弱酸性入浴剤を開発
した。更に今般、本発明者は、これにビタミン類を配合
すると血行促進効果と肌あれ防IF、皮膚老化防止、保
温効果等が相乗的に・高められることを見出し、本発明
を完成した。
We have developed a weakly acidic bath additive that promotes blood circulation and does not cause the bath to feel cold. Furthermore, the present inventor has now completed the present invention by discovering that when vitamins are added to this product, the blood circulation promotion effect, skin roughness prevention IF, skin aging prevention, heat retention effect, etc. are synergistically enhanced.

すなわち、本発明は、炭酸塩と酸を含有する弱酸性入浴
剤において、ビタミン類を配合した弱酸性入浴剤を提供
するものである。
That is, the present invention provides a weakly acidic bath additive containing a carbonate and an acid, which is blended with vitamins.

本発明の弱酸性入浴剤に配合される炭【酸塩としては、
例えば炭酸水素すl−1)ラム、炭酸ナトリウム、セス
キ炭酸ナトリウム、炭酸水素カリウム、炭酸カリウム、
セスキ炭酸カリウム、炭酸水素アンモニウム塩、炭酸ア
ンモニウム塩、セスキ炭酸アンモニウム塩等が挙げられ
、これらは単独又は2種以上を組合わせて使用できるっ また、酸としては、有機酸及び無機酸の何れも使用でき
るが、水溶性で固体のものが好ましい。
The carbonate salts added to the weakly acidic bath additives of the present invention include:
For example, hydrogen carbonate l-1) Rum, sodium carbonate, sodium sesquicarbonate, potassium hydrogen carbonate, potassium carbonate,
Examples include potassium sesquicarbonate, ammonium bicarbonate, ammonium carbonate, and ammonium sesquicarbonate, and these can be used alone or in combination of two or more.As the acid, both organic acids and inorganic acids can be used. Although it can be used, water-soluble and solid ones are preferred.

有機酸としては、例えばギ酸、酢酸、プロピオン酸、酪
酸、吉草酸等の直鎖脂肪酸;シュウ酸、マロン酸、コハ
ク酸、グルタル酸、アジピン酸、ピメリン酸、フマル酸
、マレイン酸、フタル酸、イソフタル酸、プレフタル酸
等のジカルボン酸;グルタミン酸、アスパラギン酸等の
酸・注アミノ酸;グリコール酸、乳酸、ヒドロキシアク
リル酸、α−オキシ酪酸、グリセリン酸、タルトロン酸
、リンゴ酸、酒石酸、クエン酸、サリチル酸(o、m。
Examples of organic acids include straight chain fatty acids such as formic acid, acetic acid, propionic acid, butyric acid, and valeric acid; oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, fumaric acid, maleic acid, phthalic acid, Dicarboxylic acids such as isophthalic acid and prephthalic acid; acids and amino acids such as glutamic acid and aspartic acid; glycolic acid, lactic acid, hydroxyacrylic acid, α-oxybutyric acid, glyceric acid, tartronic acid, malic acid, tartaric acid, citric acid, and salicylic acid (o, m.

p)、没食子酸、マンデル酸、トロパ酸、アスコルビン
酸、グルコン酸等のオキシ酸;桂皮酸、安息香酸、フェ
ニル酢酸、ニコチン酸、カイニン酸、ソルビン酸、ピロ
リドンカルボン酸、トリメリット酸、ベンゼンスルホン
酸、トルエンスルホン酸並びにこれら有機酸の酸性塩が
挙けられる。無機酸としては、例えば、リン酸、リン酸
二水素カリウム、リン酸二水素ナトリウム、唾硫酸ナト
リウム、面硫酸カリウム、ピロ亜硫酸ナトリウム(メタ
重亜硫酸ナトリウム)、ピロ亜硫酸カリウム(メタ重亜
硫酸カリウム)、酸性へキサメタリン酸ナトリウム、酸
性へキサメタリン酸カリウム、酸性ビロリン酸ナトリウ
ム、酸性ピロリン酸カリウム、スルファミノ酸等が挙げ
られる。就中、コノ・り酸等の脂肪族ジカルボン酸、フ
マル酸、リン酸及びこれらの酸性塩が好ましい。
p), oxyacids such as gallic acid, mandelic acid, tropic acid, ascorbic acid, gluconic acid; cinnamic acid, benzoic acid, phenylacetic acid, nicotinic acid, kainic acid, sorbic acid, pyrrolidonecarboxylic acid, trimellitic acid, benzenesulfone acid, toluenesulfonic acid, and acid salts of these organic acids. Examples of inorganic acids include phosphoric acid, potassium dihydrogen phosphate, sodium dihydrogen phosphate, sodium saliva sulfate, potassium sulfate, sodium pyrosulfite (sodium metabisulfite), potassium pyrosulfite (potassium metabisulfite), Examples include acidic sodium hexametaphosphate, acidic potassium hexametaphosphate, acidic sodium birophosphate, acidic potassium pyrophosphate, and sulfamino acid. Among these, aliphatic dicarboxylic acids such as cono-phosphoric acid, fumaric acid, phosphoric acid, and acid salts thereof are preferred.

更にまた、ビタミン類としては、ビタミンA若しくはそ
のアセテート等の低級脂肪酸エステル、ビタミンB2若
しくはそのテトラブチレート等の低級脂肪酸エステル、
ビタミンB、若しくはそのジアジレート等の低級脂肪酸
エステル、ビタミンC若しくはそのモノ−あるいはジ−
アシレート等の低級脂肪酸エステル又はそのリン酸エス
テル塩、ビタミンD(4寺にビタミンD2)、ビタミン
Eiしくけそのアセテート等の低級脂肪酸エステル、ビ
タミンF1 ビタミンH、パントテン酸、ニコチン酸、
ビタミンEニコチン酸エステル、イノジット等が挙げら
れる。
Furthermore, as vitamins, lower fatty acid esters such as vitamin A or its acetate, lower fatty acid esters such as vitamin B2 or its tetrabutyrate,
Vitamin B or lower fatty acid esters such as its diazilate, vitamin C or its mono- or di-
Lower fatty acid esters such as acylate or their phosphoric acid ester salts, vitamin D (vitamin D2), lower fatty acid esters such as vitamin Ei and sono acetate, vitamin F1, vitamin H, pantothenic acid, nicotinic acid,
Examples include vitamin E nicotinic acid ester and Inosit.

本発明弱酸性入浴剤の炭酸塩と酸の配合量は、入溶剤を
浴湯に加えたとき浴湯が弱酸性を呈するような比率、す
なわち入浴剤の0.01重縫チ水溶液がpH4〜7、特
に好捷しくはpI(6,0〜6.7になるようにするこ
とが必要である。pHが4より低いと肌への刺激が強い
と共に風呂釜等をいためる慣れがあり、甘たpHが7を
超えると本発明の効果が奏芒れないっ 本発明の効果は、pl(が酸性の場合には炭酸ガスは0
02分子として存在して血流促進作用を示すが、pHが
アルカリ性側では炭酸ガスはco、”−イオンあるいは
HCO3−イオンとして存在するため当該効果は全く見
られないという原理に基くものである。
The blending amount of carbonate and acid in the weakly acidic bath additive of the present invention is such that when the solvent is added to the bathwater, the bathwater becomes weakly acidic, i.e., the pH of the 0.01 aqueous solution of the bathant is 4 to 4. 7. In particular, it is necessary to adjust the pI (6.0 to 6.7).If the pH is lower than 4, it will be very irritating to the skin and may damage the bathtub. If the pH exceeds 7, the effect of the present invention cannot be achieved.
This is based on the principle that carbon dioxide exists as 02 molecules and exhibits a blood flow promoting effect, but when the pH is alkaline, carbon dioxide exists as co, ``- ions or HCO3- ions, so no such effect is observed.

斯かる条件を具備するだめの炭酸塩と酸の配合量は、こ
れらの種類によって異なるが、全組成に対し、炭酸塩は
5〜80重tk %、特に10〜50裂、酸は10〜8
0チ、特に15〜50%が好ましい。
The blending amounts of carbonate and acid that meet these conditions vary depending on their type, but the carbonate should be 5 to 80% by weight, especially 10 to 50%, and the acid should be 10 to 8% by weight, based on the total composition.
0%, especially 15 to 50% is preferred.

また、ビタミン類は、広い範囲の址で配合できるが、一
般には全組成に対し0.001〜10チ、特に0.01
〜2チが好ましい。
Vitamins can be added in a wide range of locations, but generally 0.001 to 10% of the total composition, especially 0.01% of the total composition.
~2 inches is preferred.

更に、本発明入浴剤には、一般に配合されている、香料
、色素、あるいは温泉の有効成分、蛋白分解酵素、海草
エキス、7”ルギン酸ナトリウム。
Furthermore, the bath additives of the present invention generally contain fragrances, pigments, active ingredients of hot springs, proteolytic enzymes, seaweed extracts, and 7" sodium ruginate.

ラノリン、シリコン、生薬あるいは七の抽出エキス等を
配合して、効果を一層高めることができる。
The effects can be further enhanced by adding lanolin, silicone, herbal medicines, or extracts of the seven extracts.

本発明の弱酸性入浴剤は、粉末、顆粒、結晶、錠剤等、
特に好ましくは錠剤の形にすることができ、これらの製
剤化のために、必要に応じて賦形剤、結合剤、崩壊剤、
滑沢剤等を添加することもできる。
The weakly acidic bath additives of the present invention include powders, granules, crystals, tablets, etc.
Particularly preferably, they can be in the form of tablets, and for their formulation, excipients, binders, disintegrants,
A lubricant or the like may also be added.

斜上の如く、本発明の弱酸性入浴剤はpHが人の肌と大
略同一であるので肌に好影響を与える。
As shown above, the slightly acidic bath additive of the present invention has a pH that is approximately the same as that of human skin, so it has a favorable effect on the skin.

しかも浴湯に投するとき発生する戻限ガスは、アルカリ
性ではイオンとして存在するため血流促進効果はないか
、不発明の如く酸性領域ではCO2分子として存在して
肌の血行を促進する優れた効果を奏する。
Moreover, the return limit gas generated when pouring into the bath water exists as ions in alkaline conditions, so it has no effect on promoting blood flow, or, as uninvented, in acidic conditions, it exists as CO2 molecules and has an excellent effect on promoting blood circulation in the skin. be effective.

次に実施・例ケ挙げて説明する。Next, implementation and examples will be given.

実施例1 第1表に示す組成の入浴剤を調製し、各入浴剤を0.0
1%水溶液になるように浴湯に投入し、パネラ−30名
に1ケ月間常法に従って使用してもらい、入浴剤として
の全体評価(総合的な使用感)あたたまり感、湯冷めの
有無、肌のしっとり感及び肌荒れ防−止効果を調べた。
Example 1 Bath additives having the compositions shown in Table 1 were prepared, and each bath additive had a concentration of 0.0
A 1% aqueous solution was added to bath water, and 30 panelists used it according to the usual method for one month.The overall evaluation as a bath additive (overall feeling of use), the feeling of warmth, whether or not the water cooled, and the skin. The moist feeling and effect on preventing rough skin were investigated.

以下亦8 第1表 その結果は第2表のとお9である。Below 8 Table 1 The result is 9 in Table 2.

第 2 表Table 2

Claims (1)

【特許請求の範囲】[Claims] 1 炭酸塩と酸を含有する弱酸性入浴剤において、ビタ
ミン類を配合し/こことを特徴とする弱酸性入浴剤。
1. A weakly acidic bath additive containing carbonate and acid, which is characterized by containing vitamins.
JP7150984A 1984-04-10 1984-04-10 Weak-acidity bath preparation Pending JPS60215613A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7150984A JPS60215613A (en) 1984-04-10 1984-04-10 Weak-acidity bath preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7150984A JPS60215613A (en) 1984-04-10 1984-04-10 Weak-acidity bath preparation

Publications (1)

Publication Number Publication Date
JPS60215613A true JPS60215613A (en) 1985-10-29

Family

ID=13462733

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7150984A Pending JPS60215613A (en) 1984-04-10 1984-04-10 Weak-acidity bath preparation

Country Status (1)

Country Link
JP (1) JPS60215613A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929378A (en) * 1986-07-03 1990-05-29 Takeda Chemical Industries, Ltd. Bath preparation
EP1759686A3 (en) * 2005-08-31 2007-05-02 Henkel Kommanditgesellschaft Auf Aktien Cosmetic compositions comprising quartz
JP2014005268A (en) * 2012-05-28 2014-01-16 Hot Album Tansansen Tablet Inc Solid bath agent, mineral impurity cleaning method and skin or hair cosmetic method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5970609A (en) * 1982-10-14 1984-04-21 Kao Corp Weakly acidic bathing agent

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5970609A (en) * 1982-10-14 1984-04-21 Kao Corp Weakly acidic bathing agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4929378A (en) * 1986-07-03 1990-05-29 Takeda Chemical Industries, Ltd. Bath preparation
EP1759686A3 (en) * 2005-08-31 2007-05-02 Henkel Kommanditgesellschaft Auf Aktien Cosmetic compositions comprising quartz
JP2014005268A (en) * 2012-05-28 2014-01-16 Hot Album Tansansen Tablet Inc Solid bath agent, mineral impurity cleaning method and skin or hair cosmetic method

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