JPS60215040A - 合成樹脂の安定化法 - Google Patents
合成樹脂の安定化法Info
- Publication number
- JPS60215040A JPS60215040A JP7053884A JP7053884A JPS60215040A JP S60215040 A JPS60215040 A JP S60215040A JP 7053884 A JP7053884 A JP 7053884A JP 7053884 A JP7053884 A JP 7053884A JP S60215040 A JPS60215040 A JP S60215040A
- Authority
- JP
- Japan
- Prior art keywords
- bis
- mercaptopropionate
- tris
- group
- abs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000006641 stabilisation Effects 0.000 title description 5
- 238000011105 stabilization Methods 0.000 title description 5
- 229920003002 synthetic resin Polymers 0.000 title description 5
- 239000000057 synthetic resin Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000002184 metal Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 10
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims abstract description 4
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 claims abstract description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 17
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 17
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 13
- 239000011976 maleic acid Substances 0.000 claims description 13
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 12
- 229920006026 co-polymeric resin Polymers 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 150000002688 maleic acid derivatives Chemical class 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 abstract description 41
- 150000001875 compounds Chemical class 0.000 abstract description 12
- 239000011593 sulfur Substances 0.000 abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- MKIJJIMOAABWGF-UHFFFAOYSA-N methyl 2-sulfanylacetate Chemical compound COC(=O)CS MKIJJIMOAABWGF-UHFFFAOYSA-N 0.000 abstract description 5
- PMUKAEUGVCXPDF-UAIGNFCESA-L dilithium;(z)-but-2-enedioate Chemical compound [Li+].[Li+].[O-]C(=O)\C=C/C([O-])=O PMUKAEUGVCXPDF-UAIGNFCESA-L 0.000 abstract 1
- -1 diene compound Chemical class 0.000 description 37
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 description 32
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 9
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical compound CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 description 8
- 239000012760 heat stabilizer Substances 0.000 description 6
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 5
- REFZTFPICLNNPM-UHFFFAOYSA-N 2-sulfanyldodecanoic acid Chemical compound CCCCCCCCCCC(S)C(O)=O REFZTFPICLNNPM-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- HTTYRACTMYJREK-UHFFFAOYSA-N hexyl 2-sulfanylacetate Chemical compound CCCCCCOC(=O)CS HTTYRACTMYJREK-UHFFFAOYSA-N 0.000 description 4
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- MADOXCFISYCULS-UHFFFAOYSA-N octyl 2-sulfanylacetate Chemical compound CCCCCCCCOC(=O)CS MADOXCFISYCULS-UHFFFAOYSA-N 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- DKIDEFUBRARXTE-UHFFFAOYSA-M 3-mercaptopropionate Chemical compound [O-]C(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-M 0.000 description 3
- BURDEKNVCUJHGU-UHFFFAOYSA-N 6-methoxy-2-sulfanylhexanoic acid Chemical compound COCCCCC(S)C(O)=O BURDEKNVCUJHGU-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- SKGVGRLWZVRZDC-UHFFFAOYSA-N butyl 2-sulfanylacetate Chemical compound CCCCOC(=O)CS SKGVGRLWZVRZDC-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229940071127 thioglycolate Drugs 0.000 description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Chemical class 0.000 description 2
- SXABRHRXLJEYQQ-UHFFFAOYSA-L SCC(C)C([O-])=O.SCC(C)C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC Chemical compound SCC(C)C([O-])=O.SCC(C)C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC SXABRHRXLJEYQQ-UHFFFAOYSA-L 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- SBQQTSREBYOKMO-UHFFFAOYSA-L [dibutyl-[6-methoxy-2-(sulfanylmethyl)hexanoyl]oxystannyl] 6-methoxy-2-(sulfanylmethyl)hexanoate Chemical compound COCCCCC(C(=O)[O-])CS.COCCCCC(C(=O)[O-])CS.C(CCC)[Sn+2]CCCC SBQQTSREBYOKMO-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- TVMDUMQNXXNGMG-UHFFFAOYSA-N dodecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCOC(=O)CS TVMDUMQNXXNGMG-UHFFFAOYSA-N 0.000 description 2
- HTOMOEJIHHORQT-UHFFFAOYSA-N dodecyl(sulfanylidene)tin Chemical compound CCCCCCCCCCCC[Sn]=S HTOMOEJIHHORQT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JQTFPHLEQLLQOT-UHFFFAOYSA-N octadecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CS JQTFPHLEQLLQOT-UHFFFAOYSA-N 0.000 description 2
- LWNSNYBMYBWJDN-UHFFFAOYSA-N octyl 3-sulfanylpropanoate Chemical compound CCCCCCCCOC(=O)CCS LWNSNYBMYBWJDN-UHFFFAOYSA-N 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- PCPYTNCQOSFKGG-ONEGZZNKSA-N (1e)-1-chlorobuta-1,3-diene Chemical compound Cl\C=C\C=C PCPYTNCQOSFKGG-ONEGZZNKSA-N 0.000 description 1
- BDFNPQHCQQRGFA-UHFFFAOYSA-N (3-methoxy-3-oxopropyl)tin Chemical compound COC(=O)CC[Sn] BDFNPQHCQQRGFA-UHFFFAOYSA-N 0.000 description 1
- VTWCVXKFWPSSNK-PLNGDYQASA-N (z)-4-(4-methoxybutoxy)-4-oxobut-2-enoic acid Chemical class COCCCCOC(=O)\C=C/C(O)=O VTWCVXKFWPSSNK-PLNGDYQASA-N 0.000 description 1
- FDNBQVCBHKEDOJ-FPLPWBNLSA-N (z)-4-(6-methylheptoxy)-4-oxobut-2-enoic acid Chemical class CC(C)CCCCCOC(=O)\C=C/C(O)=O FDNBQVCBHKEDOJ-FPLPWBNLSA-N 0.000 description 1
- IIPCXIGUIPAGQB-SEYXRHQNSA-N (z)-4-dodecoxy-4-oxobut-2-enoic acid Chemical class CCCCCCCCCCCCOC(=O)\C=C/C(O)=O IIPCXIGUIPAGQB-SEYXRHQNSA-N 0.000 description 1
- RNERBJNDXXEXTK-SREVYHEPSA-N (z)-4-hexoxy-4-oxobut-2-enoic acid Chemical class CCCCCCOC(=O)\C=C/C(O)=O RNERBJNDXXEXTK-SREVYHEPSA-N 0.000 description 1
- QKUGKZFASYQCGO-SREVYHEPSA-N (z)-4-oxo-4-phenylmethoxybut-2-enoic acid Chemical class OC(=O)\C=C/C(=O)OCC1=CC=CC=C1 QKUGKZFASYQCGO-SREVYHEPSA-N 0.000 description 1
- PSSJZBIVTOSSIU-UHFFFAOYSA-L 2,2,4-trimethylpentyl 3-[dibutyl-[3-oxo-3-(2,2,4-trimethylpentoxy)propyl]sulfanylstannyl]sulfanylpropanoate Chemical compound CC(C)CC(C)(C)COC(=O)CCS[Sn](CCCC)(CCCC)SCCC(=O)OCC(C)(C)CC(C)C PSSJZBIVTOSSIU-UHFFFAOYSA-L 0.000 description 1
- XIDZPWZINDODBR-UHFFFAOYSA-L 2,2-dimethyl-1,3,2-oxathiastannolan-5-one Chemical compound C[Sn]1(C)OC(=O)CS1 XIDZPWZINDODBR-UHFFFAOYSA-L 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- KRZTYSCUOUIFHR-BDAKNGLRSA-N 2-[(1r,3s)-2,2-dimethyl-3-(2-oxopropyl)cyclopropyl]acetonitrile Chemical compound CC(=O)C[C@H]1[C@@H](CC#N)C1(C)C KRZTYSCUOUIFHR-BDAKNGLRSA-N 0.000 description 1
- VBIHSPGWVQKYRG-UHFFFAOYSA-K 2-[bis(carboxymethylsulfanyl)-octylstannyl]sulfanylacetic acid Chemical compound [O-]C(=O)CS.[O-]C(=O)CS.[O-]C(=O)CS.CCCCCCCC[Sn+3] VBIHSPGWVQKYRG-UHFFFAOYSA-K 0.000 description 1
- DYIXPWUOHXEABU-UHFFFAOYSA-L 2-[carboxymethylsulfanyl(didodecyl)stannyl]sulfanylacetic acid Chemical compound [O-]C(=O)CS.[O-]C(=O)CS.CCCCCCCCCCCC[Sn+2]CCCCCCCCCCCC DYIXPWUOHXEABU-UHFFFAOYSA-L 0.000 description 1
- CMCOFAYLDYIEBR-UHFFFAOYSA-L 2-[carboxymethylsulfanyl(dioctyl)stannyl]sulfanylacetic acid Chemical compound [O-]C(=O)CS.[O-]C(=O)CS.CCCCCCCC[Sn+2]CCCCCCCC CMCOFAYLDYIEBR-UHFFFAOYSA-L 0.000 description 1
- CTXDOGDXQRUTKR-UHFFFAOYSA-L 2-butoxy-2-oxoethanethiolate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn](CCCCCCCC)(SCC(=O)OCCCC)SCC(=O)OCCCC CTXDOGDXQRUTKR-UHFFFAOYSA-L 0.000 description 1
- VHKGIWUCVBAITR-UHFFFAOYSA-K 2-ethylhexyl 2-[bis[[2-(2-ethylhexoxy)-2-oxoethyl]sulfanyl]-octylstannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCCCCCC)(SCC(=O)OCC(CC)CCCC)SCC(=O)OCC(CC)CCCC VHKGIWUCVBAITR-UHFFFAOYSA-K 0.000 description 1
- HHDNFMPQAVDNGA-UHFFFAOYSA-K 2-ethylhexyl 2-[butyl-bis[[2-(2-ethylhexoxy)-2-oxoethyl]sulfanyl]stannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCC)(SCC(=O)OCC(CC)CCCC)SCC(=O)OCC(CC)CCCC HHDNFMPQAVDNGA-UHFFFAOYSA-K 0.000 description 1
- PRIUALOJYOZZOJ-UHFFFAOYSA-L 2-ethylhexyl 2-[dibutyl-[2-(2-ethylhexoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCC(CC)CCCC PRIUALOJYOZZOJ-UHFFFAOYSA-L 0.000 description 1
- OSJAAYAWZBUHDN-UHFFFAOYSA-L 2-ethylhexyl 3-[[3-(2-ethylhexoxy)-3-oxopropyl]sulfanyl-dimethylstannyl]sulfanylpropanoate Chemical compound CCCCC(CC)COC(=O)CCS[Sn](C)(C)SCCC(=O)OCC(CC)CCCC OSJAAYAWZBUHDN-UHFFFAOYSA-L 0.000 description 1
- RFPITRAFRHNSRB-UHFFFAOYSA-L 2-ethylhexyl 3-[dibutyl-[3-(2-ethylhexoxy)-3-oxopropyl]sulfanylstannyl]sulfanylpropanoate Chemical compound CCCCC(CC)COC(=O)CCS[Sn](CCCC)(CCCC)SCCC(=O)OCC(CC)CCCC RFPITRAFRHNSRB-UHFFFAOYSA-L 0.000 description 1
- SUODCTNNAKSRHB-UHFFFAOYSA-N 2-ethylhexyl 3-sulfanylpropanoate Chemical compound CCCCC(CC)COC(=O)CCS SUODCTNNAKSRHB-UHFFFAOYSA-N 0.000 description 1
- PMNLUUOXGOOLSP-UHFFFAOYSA-M 2-sulfanylpropanoate Chemical compound CC(S)C([O-])=O PMNLUUOXGOOLSP-UHFFFAOYSA-M 0.000 description 1
- BEFRKDFWQCSRJO-UHFFFAOYSA-K 6-methylheptyl 2-[butyl-bis[[2-(6-methylheptoxy)-2-oxoethyl]sulfanyl]stannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCC)(SCC(=O)OCCCCCC(C)C)SCC(=O)OCCCCCC(C)C BEFRKDFWQCSRJO-UHFFFAOYSA-K 0.000 description 1
- IUNVCWLKOOCPIT-UHFFFAOYSA-N 6-methylheptylsulfanyl 2-hydroxyacetate Chemical compound CC(C)CCCCCSOC(=O)CO IUNVCWLKOOCPIT-UHFFFAOYSA-N 0.000 description 1
- OLTOAIPAMZECLG-UHFFFAOYSA-K C(CS)(=O)[O-].COC(=O)CC[Sn+3].C(CS)(=O)[O-].C(CS)(=O)[O-] Chemical compound C(CS)(=O)[O-].COC(=O)CC[Sn+3].C(CS)(=O)[O-].C(CS)(=O)[O-] OLTOAIPAMZECLG-UHFFFAOYSA-K 0.000 description 1
- HFYMWKJUUAMKIW-UHFFFAOYSA-L CCCCCCCCCCCCC(CS)C(=O)O[Sn](C)(C)OC(=O)C(CCCCCCCCCCCC)CS Chemical compound CCCCCCCCCCCCC(CS)C(=O)O[Sn](C)(C)OC(=O)C(CCCCCCCCCCCC)CS HFYMWKJUUAMKIW-UHFFFAOYSA-L 0.000 description 1
- RVORGJMKRLVXII-UHFFFAOYSA-K CCCCCCCCCCCCC(CS)C(=O)O[Sn](CCCCCCCC)(OC(=O)C(CCCCCCCCCCCC)CS)OC(=O)C(CCCCCCCCCCCC)CS Chemical compound CCCCCCCCCCCCC(CS)C(=O)O[Sn](CCCCCCCC)(OC(=O)C(CCCCCCCCCCCC)CS)OC(=O)C(CCCCCCCCCCCC)CS RVORGJMKRLVXII-UHFFFAOYSA-K 0.000 description 1
- SLHZQVJYKKHDIR-UHFFFAOYSA-L CCCCCCCC[Sn++]CCCCCCCC.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O Chemical compound CCCCCCCC[Sn++]CCCCCCCC.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O SLHZQVJYKKHDIR-UHFFFAOYSA-L 0.000 description 1
- VGOSZRPIKHQTAS-UHFFFAOYSA-K COCCCCC(C(=O)[O-])S.COCCCCC(C(=O)[O-])S.COCCCCC(C(=O)[O-])S.C(CCCCCCC)[Sn+3] Chemical compound COCCCCC(C(=O)[O-])S.COCCCCC(C(=O)[O-])S.COCCCCC(C(=O)[O-])S.C(CCCCCCC)[Sn+3] VGOSZRPIKHQTAS-UHFFFAOYSA-K 0.000 description 1
- 229920006385 Geon Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- MHQJUHSHQGQVTM-HNENSFHCSA-N Octadecyl fumarate Chemical class CCCCCCCCCCCCCCCCCCOC(=O)\C=C/C(O)=O MHQJUHSHQGQVTM-HNENSFHCSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- IKOBEOALWFLQST-UHFFFAOYSA-L [[6-methoxy-2-(sulfanylmethyl)hexanoyl]oxy-dimethylstannyl] 6-methoxy-2-(sulfanylmethyl)hexanoate Chemical compound COCCCCC(C(=O)[O-])CS.COCCCCC(C(=O)[O-])CS.C[Sn+2]C IKOBEOALWFLQST-UHFFFAOYSA-L 0.000 description 1
- CYGGDRWPUCJENS-UHFFFAOYSA-L [[8-methyl-2-(sulfanylmethyl)nonanoyl]oxy-dioctylstannyl] 8-methyl-2-(sulfanylmethyl)nonanoate Chemical compound CC(C)CCCCCC(CS)C([O-])=O.CC(C)CCCCCC(CS)C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC CYGGDRWPUCJENS-UHFFFAOYSA-L 0.000 description 1
- CCRHTZBIGPEKGC-UHFFFAOYSA-K [butyl-bis[[4-ethyl-2-(sulfanylmethyl)octanoyl]oxy]stannyl] 4-ethyl-2-(sulfanylmethyl)octanoate Chemical compound CCCC[Sn+3].CCCCC(CC)CC(CS)C([O-])=O.CCCCC(CC)CC(CS)C([O-])=O.CCCCC(CC)CC(CS)C([O-])=O CCRHTZBIGPEKGC-UHFFFAOYSA-K 0.000 description 1
- UNYQNFVJXRJWSQ-UHFFFAOYSA-L [didodecyl(3-sulfanylpropanoyloxy)stannyl] 3-sulfanylpropanoate Chemical compound CCCCCCCCCCCC[Sn](SCCC(O)=O)(SCCC(O)=O)CCCCCCCCCCCC UNYQNFVJXRJWSQ-UHFFFAOYSA-L 0.000 description 1
- KMBMHIUZIFCSHL-UHFFFAOYSA-L [didodecyl-[4-ethyl-2-(sulfanylmethyl)octanoyl]oxystannyl] 4-ethyl-2-(sulfanylmethyl)octanoate Chemical compound CCCCCCCCCCCC[Sn](CCCCCCCCCCCC)(OC(=O)C(CC(CC)CCCC)CS)OC(=O)C(CC(CC)CCCC)CS KMBMHIUZIFCSHL-UHFFFAOYSA-L 0.000 description 1
- QASXJOGGAHCHBO-UHFFFAOYSA-L [dimethyl(2-sulfanylpropanoyloxy)stannyl] 2-sulfanylpropanoate Chemical compound C[Sn+2]C.CC(S)C([O-])=O.CC(S)C([O-])=O QASXJOGGAHCHBO-UHFFFAOYSA-L 0.000 description 1
- JPLYYEIOHUCWPI-UHFFFAOYSA-L [dimethyl-(2-methyl-3-sulfanylpropanoyl)oxystannyl] 2-methyl-3-sulfanylpropanoate Chemical compound C[Sn+2]C.SCC(C)C([O-])=O.SCC(C)C([O-])=O JPLYYEIOHUCWPI-UHFFFAOYSA-L 0.000 description 1
- OXDSRJYUPSCKIX-UHFFFAOYSA-L [dimethyl-[2-(sulfanylmethyl)decanoyloxy]stannyl] 2-(sulfanylmethyl)decanoate Chemical compound C[Sn+2]C.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O OXDSRJYUPSCKIX-UHFFFAOYSA-L 0.000 description 1
- FDRAISLZUAHUSR-UHFFFAOYSA-L [dimethyl-[2-(sulfanylmethyl)hexanoyloxy]stannyl] 2-(sulfanylmethyl)hexanoate Chemical compound CCCCC(CS)C(=O)O[Sn](C)(C)OC(=O)C(CCCC)CS FDRAISLZUAHUSR-UHFFFAOYSA-L 0.000 description 1
- IGOGXRAECHXKAS-UHFFFAOYSA-L [dimethyl-[2-(sulfanylmethyl)icosanoyloxy]stannyl] 2-(sulfanylmethyl)icosanoate Chemical compound C(CCCCCCCCCCCCCCCCC)C(C(=O)[O-])CS.C(CCCCCCCCCCCCCCCCC)C(C(=O)[O-])CS.C[Sn+2]C IGOGXRAECHXKAS-UHFFFAOYSA-L 0.000 description 1
- HKHKUTINIUWQDU-UHFFFAOYSA-L [dioctyl(2-sulfanylpropanoyloxy)stannyl] 2-sulfanylpropanoate Chemical compound CCCCCCCC[Sn](OC(=O)C(C)S)(OC(=O)C(C)S)CCCCCCCC HKHKUTINIUWQDU-UHFFFAOYSA-L 0.000 description 1
- ADVRPFABJGOKFI-UHFFFAOYSA-L [dioctyl-[2-(sulfanylmethyl)decanoyloxy]stannyl] 2-(sulfanylmethyl)decanoate Chemical compound C(CCCCCCC)C(C(=O)[O-])CS.C(CCCCCCC)C(C(=O)[O-])CS.C(CCCCCCC)[Sn+2]CCCCCCCC ADVRPFABJGOKFI-UHFFFAOYSA-L 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- PTLASYHTXGUCJU-UHFFFAOYSA-N benzyl 2,3,3a,4,5,6,7,7a-octahydro-1h-indole-2-carboxylate;4-methylbenzenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1.C1C2CCCCC2NC1C(=O)OCC1=CC=CC=C1 PTLASYHTXGUCJU-UHFFFAOYSA-N 0.000 description 1
- JOTJTBFOURUJII-UHFFFAOYSA-N bis(3-butoxy-3-oxopropyl)tin Chemical compound CCCCOC(=O)CC[Sn]CCC(=O)OCCCC JOTJTBFOURUJII-UHFFFAOYSA-N 0.000 description 1
- MMGKOVRSCYWRDW-UHFFFAOYSA-N bis(3-ethoxy-3-oxopropyl)tin Chemical compound CCOC(=O)CC[Sn]CCC(=O)OCC MMGKOVRSCYWRDW-UHFFFAOYSA-N 0.000 description 1
- DLOCYALHUIOIKU-UHFFFAOYSA-L bis(3-methoxy-3-oxopropyl)tin(2+);2-sulfanylacetate Chemical compound [O-]C(=O)CS.[O-]C(=O)CS.COC(=O)CC[Sn+2]CCC(=O)OC DLOCYALHUIOIKU-UHFFFAOYSA-L 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- FAXZWVLVYZJMPC-UHFFFAOYSA-N butyl(sulfanylidene)tin Chemical compound CCCC[Sn]=S FAXZWVLVYZJMPC-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- XIZMMPKZMJWKFV-UHFFFAOYSA-N decyl 3-sulfanylpropanoate Chemical compound CCCCCCCCCCOC(=O)CCS XIZMMPKZMJWKFV-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- JJPZOIJCDNHCJP-UHFFFAOYSA-N dibutyl(sulfanylidene)tin Chemical compound CCCC[Sn](=S)CCCC JJPZOIJCDNHCJP-UHFFFAOYSA-N 0.000 description 1
- WCRDXYSYPCEIAK-UHFFFAOYSA-N dibutylstannane Chemical compound CCCC[SnH2]CCCC WCRDXYSYPCEIAK-UHFFFAOYSA-N 0.000 description 1
- LTWNGXCAVJUGCF-UHFFFAOYSA-L dibutyltin(2+);2-(sulfanylmethyl)decanoate Chemical compound CCCC[Sn+2]CCCC.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O LTWNGXCAVJUGCF-UHFFFAOYSA-L 0.000 description 1
- ZYIYJSWBGLPVEO-UHFFFAOYSA-L dibutyltin(2+);2-(sulfanylmethyl)hexanoate Chemical compound CCCC[Sn+2]CCCC.CCCCC(CS)C([O-])=O.CCCCC(CS)C([O-])=O ZYIYJSWBGLPVEO-UHFFFAOYSA-L 0.000 description 1
- QGQIZFGMTNYKSZ-UHFFFAOYSA-L dibutyltin(2+);2-(sulfanylmethyl)icosanoate Chemical compound CCCC[Sn+2]CCCC.CCCCCCCCCCCCCCCCCCC(CS)C([O-])=O.CCCCCCCCCCCCCCCCCCC(CS)C([O-])=O QGQIZFGMTNYKSZ-UHFFFAOYSA-L 0.000 description 1
- LGUARMJKHONSQN-UHFFFAOYSA-L dibutyltin(2+);2-sulfanyldecanoate Chemical compound CCCC[Sn+2]CCCC.CCCCCCCCC(S)C([O-])=O.CCCCCCCCC(S)C([O-])=O LGUARMJKHONSQN-UHFFFAOYSA-L 0.000 description 1
- ISHVYKAWSPILKE-UHFFFAOYSA-L dimethyltin(2+) 2-sulfanyldodecanoate Chemical compound C[Sn+2]C.CCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCC(S)C([O-])=O ISHVYKAWSPILKE-UHFFFAOYSA-L 0.000 description 1
- WDVGZZNLIOAJNO-UHFFFAOYSA-L dimethyltin(2+) 2-sulfanylhexanoate Chemical compound C[Sn+2]C.CCCCC(S)C([O-])=O.CCCCC(S)C([O-])=O WDVGZZNLIOAJNO-UHFFFAOYSA-L 0.000 description 1
- VSGRKLWYHXHXHB-UHFFFAOYSA-L dimethyltin(2+) 2-sulfanylicosanoate Chemical compound C[Sn+2]C.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O VSGRKLWYHXHXHB-UHFFFAOYSA-L 0.000 description 1
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 description 1
- IRFPIPNMASANJY-UHFFFAOYSA-L dimethyltin(2+);2-(6-methylheptoxy)-2-oxoethanethiolate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](C)(C)SCC(=O)OCCCCCC(C)C IRFPIPNMASANJY-UHFFFAOYSA-L 0.000 description 1
- HKPPFWSHODSGMF-UHFFFAOYSA-L dimethyltin(2+);2-sulfanyldecanoate Chemical compound C[Sn+2]C.CCCCCCCCC(S)C([O-])=O.CCCCCCCCC(S)C([O-])=O HKPPFWSHODSGMF-UHFFFAOYSA-L 0.000 description 1
- JCGSLDBLJGDNHD-UHFFFAOYSA-L dimethyltin(2+);3-sulfanylpropanoate Chemical compound C[Sn+2]C.[O-]C(=O)CCS.[O-]C(=O)CCS JCGSLDBLJGDNHD-UHFFFAOYSA-L 0.000 description 1
- RFAIKXASDCRKEP-UHFFFAOYSA-N dioctyl(sulfanylidene)tin Chemical compound CCCCCCCC[Sn](=S)CCCCCCCC RFAIKXASDCRKEP-UHFFFAOYSA-N 0.000 description 1
- PGMFOPJANVUDHV-UHFFFAOYSA-L dioctyltin(2+);2-octoxy-2-oxoethanethiolate Chemical compound CCCCCCCCOC(=O)CS[Sn](CCCCCCCC)(CCCCCCCC)SCC(=O)OCCCCCCCC PGMFOPJANVUDHV-UHFFFAOYSA-L 0.000 description 1
- JXQGQOSVTCVADL-UHFFFAOYSA-L dioctyltin(2+);2-sulfanyltetradecanoate Chemical compound CCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC JXQGQOSVTCVADL-UHFFFAOYSA-L 0.000 description 1
- HZHREVFVFOBHSK-UHFFFAOYSA-L dioctyltin(2+);4-ethyl-2-sulfanyloctanoate Chemical compound CCCCC(CC)CC(S)C([O-])=O.CCCCC(CC)CC(S)C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC HZHREVFVFOBHSK-UHFFFAOYSA-L 0.000 description 1
- VDEKURXOWJYWCG-UHFFFAOYSA-N dodecyltin Chemical compound CCCCCCCCCCCC[Sn] VDEKURXOWJYWCG-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- ISHZHUBSDUTOAN-UHFFFAOYSA-N methyl(sulfanylidene)tin Chemical compound C[Sn]=S ISHZHUBSDUTOAN-UHFFFAOYSA-N 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- NBKBMTQNRYKYBW-UHFFFAOYSA-K methyltin(3+);2-sulfanylacetate Chemical compound [Sn+3]C.[O-]C(=O)CS.[O-]C(=O)CS.[O-]C(=O)CS NBKBMTQNRYKYBW-UHFFFAOYSA-K 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- RFHIHPWSONFOHR-UHFFFAOYSA-N octyl(sulfanylidene)tin Chemical compound CCCCCCCC[Sn]=S RFHIHPWSONFOHR-UHFFFAOYSA-N 0.000 description 1
- KRRMWFGVZAYTID-UHFFFAOYSA-K octyltin(3+) 2-sulfanylicosanoate Chemical compound CCCCCCCC[Sn+3].CCCCCCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O KRRMWFGVZAYTID-UHFFFAOYSA-K 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7053884A JPS60215040A (ja) | 1984-04-09 | 1984-04-09 | 合成樹脂の安定化法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7053884A JPS60215040A (ja) | 1984-04-09 | 1984-04-09 | 合成樹脂の安定化法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60215040A true JPS60215040A (ja) | 1985-10-28 |
| JPH0456060B2 JPH0456060B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-09-07 |
Family
ID=13434406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7053884A Granted JPS60215040A (ja) | 1984-04-09 | 1984-04-09 | 合成樹脂の安定化法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60215040A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104910555A (zh) * | 2015-06-08 | 2015-09-16 | 湖北南星化工总厂 | 一种二元羧酸碱金属盐作为锌烧抑制剂的应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5278257A (en) * | 1975-12-25 | 1977-07-01 | Adeka Argus Chem Co Ltd | Halogen-containing resin compositions |
| JPS5398349A (en) * | 1977-02-09 | 1978-08-28 | Adeka Argus Chem Co Ltd | Synthetic resing composition |
| JPS58201851A (ja) * | 1982-05-18 | 1983-11-24 | Akishima Kagaku Kogyo Kk | 安定化された塩素含有樹脂組成物 |
-
1984
- 1984-04-09 JP JP7053884A patent/JPS60215040A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5278257A (en) * | 1975-12-25 | 1977-07-01 | Adeka Argus Chem Co Ltd | Halogen-containing resin compositions |
| JPS5398349A (en) * | 1977-02-09 | 1978-08-28 | Adeka Argus Chem Co Ltd | Synthetic resing composition |
| JPS58201851A (ja) * | 1982-05-18 | 1983-11-24 | Akishima Kagaku Kogyo Kk | 安定化された塩素含有樹脂組成物 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104910555A (zh) * | 2015-06-08 | 2015-09-16 | 湖北南星化工总厂 | 一种二元羧酸碱金属盐作为锌烧抑制剂的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0456060B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-09-07 |
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