JPS60204308A - Manufacture of laminate - Google Patents

Manufacture of laminate

Info

Publication number
JPS60204308A
JPS60204308A JP59061923A JP6192384A JPS60204308A JP S60204308 A JPS60204308 A JP S60204308A JP 59061923 A JP59061923 A JP 59061923A JP 6192384 A JP6192384 A JP 6192384A JP S60204308 A JPS60204308 A JP S60204308A
Authority
JP
Japan
Prior art keywords
forming pressure
pressure
laminate
fiber
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59061923A
Other languages
Japanese (ja)
Other versions
JPH0114851B2 (en
Inventor
Tadao Arai
荒井 忠雄
Saburo Amano
天野 三郎
Kokichi Sato
孝吉 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP59061923A priority Critical patent/JPS60204308A/en
Publication of JPS60204308A publication Critical patent/JPS60204308A/en
Publication of JPH0114851B2 publication Critical patent/JPH0114851B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/26Component parts, details or accessories; Auxiliary operations
    • B29C51/42Heating or cooling
    • B29C51/426Producing specific thermal regimes during thermoforming to obtain particular properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/12Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor of articles having inserts or reinforcements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2061/00Use of condensation polymers of aldehydes or ketones or derivatives thereof, as moulding material
    • B29K2061/04Phenoplasts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2711/00Use of natural products or their composites, not provided for in groups B29K2601/00 - B29K2709/00, for preformed parts, e.g. for inserts
    • B29K2711/12Paper, e.g. cardboard
    • B29K2711/126Impregnated

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To obtain the laminate excellent in mold releasing property for a panel plate even if outer mold release agent is not used by applying the forming pressure under heating repeatedly at the pressure equal to or lower than the maximum forming pressure, after phenol resin has been impregnated into the base material of cellulose family fiber paper cloth and it has been dried. CONSTITUTION:A prepreg is obtained, impregnating phenol resin into the base material of cellulose family fiber paper cloth and drying it. The objective laminate may be formed, while lowering the forming pressure of said prepreg to the pressure P2 in the range of 70-0% of forming pressure P1 from the time t1 of resin fusion starting temperature T1, and then raising and lowering said forming pressure at the internal of t0 in the period until the time t2 of resin fusion finishing temperature T2. EFFECT:The laminate with smooth surface may be formed without the occurrence of fiber exposure, and the fiber adhering to a flat panel surface may be prevented, thereby elongating the life of the panel plate.

Description

【発明の詳細な説明】 (産業上の利用分封) 本@明に、セルロース糸槍維租イF基材に2ヱ/ −A
、樹脂28Rh 乾燥しπプリプレグτ刀ロ熟〃ロ比丁
ゐ槓膚淑の衷盾法に関す心。
[Detailed Description of the Invention] (Industrial Application Separation) In this @Ming, cellulose thread fiber F base material is 2ヱ/-A
, Resin 28Rh Dry π Prepreg τ Katana Rokiro Hi Ding 槓 Skin Suk's Covering Method.

(発明の背景) セルロース糸繊維租布丞材に2工ノール側脂τ廿反、乾
燥したプリプレグτ刀1勢刈1圧丁Φ礪台、b)t、型
部1at、圧力に第1図にボ丁ように、戟型虐敵が樹脂
の浴融開始態度′l゛1から樹脂の帛融終了由tf T
sの曲は趙望の成型圧力P、τ1禾す寺している0第1
図に於て1け成型時間と成型圧力との関係忙示すグラフ
、2LIff成型時曲と成型時間との関係τ不丁グ′″
)2であ心〇 セルロース糸fa維租布基祠21ノール倒脂の言置紙布
τ用いて、 7JIl力ロ圧τ行lうことによって成型
する槓虐伍−説値との型啼nτ良く丁ゐ7ζめに内部離
m創及び外部瀦型創τ併用丁ゐ〇しかしながらカーボン
印刷抵lIL坏用槓膚叡。
(Background of the invention) Cellulose yarn fiber cloth material, 2 knoll side fat τ, dried prepreg τ knife 1 cutting 1 pressing Φ table, b) t, mold part 1 at, pressure in Fig. 1 As shown in the figure, the sword-type brutal enemy starts melting the resin from the attitude 'l゛1 to the end of melting the resin.
s song is Zhao Wang's molding pressure P, τ1
In the figure, 1 is a graph showing the relationship between molding time and molding pressure, and 2Liff is a graph showing the relationship between molding time and molding time.
) 2 core 〇 cellulose yarn fa textile fabric foundation 21 using paper cloth τ of reversible fat, 7JIl force and pressure τ to mold the mold with the estimated value nτ However, carbon printing is not suitable for use with internal avulsions and external avulsions at about 7ζ.

接盾剤塗布用04J−叡寺rコ外部蘭!ちり創の炊直物
が仮盾俸の″M有力を弱め心ので外部喘ルシ沖Jの使用
σ小鳩である0迎に外部離型創γ1史用しないと型蘭7
L71−いちじるしく損う0型爵ILτ偵った槓ノ曽慎
の次面りt#、維の漏出睨隊か廟り〃為つ、跳板表面に
も繊維の枯盾現象力u9さている。
For applying shielding agent 04J-Eiji rko external orchid! The cooking of the dust weakens the ``M power of the temporary shield salary, so the use of the external pane Rushi Oki J is σ Kobato.
L71 - Kai no Soshin's next face, which was caught by the 0-type ILτ, which was seriously damaged, and Tsui's leaking glare team, was also visible, and the fiber's shield phenomenon power u9 was also visible on the surface of the spring board.

(発明の目的) 本発明aこのエラな点にルみてなさrLkもので、槓層
叡表開の密庸力τ弱めること7ffi<、説板とのM型
性の回よした積層載の製遁江T提供すゐものである。
(Objective of the Invention) The present invention has not been taken into account in view of this point, and is intended to weaken the secret force τ of the 7ffi<7ffi<, and to manufacture a laminated mount with improved M-type characteristics with the board. This is something provided by Toronoe T.

(発明の栴成) 不発明け、セルロース糸繊維紙亜基材にフェノール俯脂
τ貧反、乾燥したグリプレグτ、M望のg銅比ツバ 崗
凝で〃0勢ガ0圧Tゐ槓ノ曽似の製造法に於て、但J胎
の浴融中の成型圧力τ、ツカ蜜の成型圧力の70%〜0
%の軛I/f4に1戊下ざぜることτ〈!ll返し何い
、悄屈の浴融終f恢にM埴の成型圧力にもどし刀口熱加
出すゐことt狩叡と丁ゐものである。
(Serialization of the invention) Uninvented, cellulose thread fiber paper base material, phenol fat τ thin film, dried Gripreg τ, M desired g copper ratio tsubame. In a similar manufacturing method, however, the molding pressure τ during bath melting of the honey is 70% to 0 of the molding pressure of the honey.
% of the yoke I/f4 to be lowered by 1 τ〈! In return, at the end of the agonizing bath melting, I returned to the molding pressure of the M-hani and heated it up using the knife.

すなわち本発明の成型法でr:J第2図に示すyll(
衛脂#j融開始11゛1時の時間【1から榴鹿m−終了
温度1゛g時の時間t3の間に成型圧力τM望の成型圧
力P1からPltlc低゛トさせて、セルロース極細の
樹脂倉の少11/′1部分と説叡聞の間へ宮反厭布巾の
樹脂かにし与出丁ことτ各局にさせた状態で8舵取型圧
力てP、に1列、させて成型T々0成型圧力P、からP
sに低Fさせて告鍵klに上昇さゼゐことてくり返し行
9ことにより向一層の9JJ米が発揮T心。PyrzP
、の70%〜Ω%のり二刀である。
That is, by the molding method of the present invention, r:Jyll(
During the time t3 when the melting start temperature is 11゛1 and the end temperature is 1゛g, the molding pressure τM is lowered from the desired molding pressure P1 to Pltlc, and the cellulose ultrafine Between the small 11/'1 part of the resin store and the lecture room, place the resin cloth of the Miyazaki cloth in each station, press 8 steering molds, press P, and mold in one row. T0 molding pressure P, to P
By lowering F to s and raising the key to kl, repeating row 9, Mukai's 9JJ rice was demonstrated. PyrzP
It is 70% to Ω% of .

以上睨明したように5本兄明a型爵nτ1泪看丁0セル
ロース繊維の衛(財産の少ないif) jすと続叡面と
の間へ言vM〜布中の衝IJi vにじ4出ざぜて#l
!維と説破の枯麿τ防止することにょリタを部瀦型卸J
τ使用ゼずに卑喘γLτ艮〈丁ゐta山型法ろる〇 夾施例 リンター紙基材2ヱノール側脂言反厭(側屈重49貞′
に1.%)τ使用して板厚&b關の偵膚叡を外ttll
jlff型痢釦使用ぜずに従米払及び不発明法でそγL
ぞn成型τ竹なったときの状況り別表の如くである〇 成型栄汗 P、: 160kg/an’P、: 30k
g/(2)t 【。: 6分間 (0返し回数:11旧) (発明の幼果) 以上睨明し1こように本発明の方法に於てσ。
As we have seen above, the five brothers, A-type, nτ, 1, and 0, the cellulose fiber guard (if they have little wealth), say the words between J and the next screen, vM ~ the conflict in the cloth, IJi, and v Niji 4. Come out #l
! In order to prevent the conflict between the two
τ does not use ze and it is difficult to use it.
1. %) Use τ to remove the plate thickness &b connection.
Jlff type button was not used and was paid in accordance with the non-invention law.
The situation when it becomes molded τ bamboo is as shown in the attached table. Molded Sakae sweat P: 160kg/an'P: 30k
g/(2)t [. : 6 minutes (Number of zero returns: 11 old) (Young fruit of the invention) In light of the above, in the method of the present invention, σ.

外部All#型剤τ使用ぜずIc型陥nが良くて、繊維
露出が発生ぜず、表向状態が平滑なる積層板で取型出米
、父、虜似六面へ繊維の枯眉が肋止出米ることによt)
緯伍の〜館が処ひるオリ点がある0
Without using external All # molding agent τ, the Ic type depression is good, no fibers are exposed, and the surface condition is smooth. t)
The starting point is 0

【図面の簡単な説明】[Brief explanation of the drawing]

1141図a便米法の成型時間と成型圧力・態度の関係
を示すグラフ%第2凶σ不帖明り成型時間と成型圧力・
泥裏の関係τ丁子グラフであるOR方の説明 1、成型時間とtJ!t′m圧力の関係tボ丁グラ22
、hX、型時間と成型繊度の関係τボ丁グラフ代塊人ニ
アP埋士 七 朴 部 珍 5− 第1図 第2図 成型時間
1141 Figure a Graph showing the relationship between molding time and molding pressure/attitude of the rice method
Explanation of the OR method which is a τ clove graph of the relationship between the mud back 1, molding time and tJ! Relationship between t′m pressure tbochogura 22
, h

Claims (1)

【特許請求の範囲】[Claims] 1、セルロース丞極維戯布基材に2エノール樹脂で含攪
、乾珠したグリプレグで、趙望の成型圧力、 崗鵬で刀
口潜力り圧子ゐ慎ノ曽似の暴り道■云に於て、側屈り玲
噛中の成型圧力τM望の成型圧力の70%〜0%の範囲
に1肱下させゐCとてくり返し付い、樹脂の沼−梃了恢
に均望の成型出力にもどし苅1 #l )A1圧丁ゐこ
とτ轡倣と丁ゐ積層機のIJA造法O
1. Cellulose fiber cloth base material is impregnated with 2-enol resin and dried with Gripreg, and Zhao Wang's molding pressure, Gangpeng's knife mouth latent force and indenter Shinno So-like's violent path. Then, lower the molding pressure τM by one elbow in the range of 70% to 0% of the desired molding pressure while bending over to the side. Restoration 1 #l) A1 stamping IJA manufacturing method of τ copying and stacking machine O
JP59061923A 1984-03-29 1984-03-29 Manufacture of laminate Granted JPS60204308A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59061923A JPS60204308A (en) 1984-03-29 1984-03-29 Manufacture of laminate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59061923A JPS60204308A (en) 1984-03-29 1984-03-29 Manufacture of laminate

Publications (2)

Publication Number Publication Date
JPS60204308A true JPS60204308A (en) 1985-10-15
JPH0114851B2 JPH0114851B2 (en) 1989-03-14

Family

ID=13185162

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59061923A Granted JPS60204308A (en) 1984-03-29 1984-03-29 Manufacture of laminate

Country Status (1)

Country Link
JP (1) JPS60204308A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2617755A1 (en) * 1987-07-06 1989-01-13 Aerospatiale PROCESS FOR MANUFACTURING FIBER / RESIN COMPOSITE MATERIAL AND MATERIAL OBTAINED
JPH0459249A (en) * 1990-06-28 1992-02-26 Hitachi Chem Co Ltd Production of melamine resin/metal decorative panel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2617755A1 (en) * 1987-07-06 1989-01-13 Aerospatiale PROCESS FOR MANUFACTURING FIBER / RESIN COMPOSITE MATERIAL AND MATERIAL OBTAINED
JPH0459249A (en) * 1990-06-28 1992-02-26 Hitachi Chem Co Ltd Production of melamine resin/metal decorative panel

Also Published As

Publication number Publication date
JPH0114851B2 (en) 1989-03-14

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