JPS60202937A - Dry etching device - Google Patents

Dry etching device

Info

Publication number
JPS60202937A
JPS60202937A JP5820884A JP5820884A JPS60202937A JP S60202937 A JPS60202937 A JP S60202937A JP 5820884 A JP5820884 A JP 5820884A JP 5820884 A JP5820884 A JP 5820884A JP S60202937 A JPS60202937 A JP S60202937A
Authority
JP
Japan
Prior art keywords
electrode
reaction gas
printed circuit
high frequency
circuit board
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5820884A
Other languages
Japanese (ja)
Inventor
Saburo Kanai
三郎 金井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP5820884A priority Critical patent/JPS60202937A/en
Publication of JPS60202937A publication Critical patent/JPS60202937A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

PURPOSE:To generate stable plasma, and to enable uniform dry etching by blowing off a reaction gas from the whole surface of one electrode surface of parallel plate electrodes, on the whole surfaces thereof field strength is equalized, and uniformly passing the reaction gas through the other electrode. CONSTITUTION:A high-frequency electrode 2 and a grounding electrode 3 are opposed in parallel and mounted in a vacuum vessel 1 with an exhaust port 13 connected to a vacuum pump 18. A high-frequency power supply 5 is connected to the electrode 2 while a reaction gas is introduced from the outside through an introducing hole 12, and the reaction gas is blown off from the whole surface of the lower surface of the electrode. The reaction gas is activated by high-frequency power applied to the electrode 2 and changed into a uniform stable plasma state, and collides with a printed substrate 7 and dry-etch the substrate, and is discharged equally to the lower baffle 17 side.

Description

【発明の詳細な説明】 〔発明の利用分野〕 本発明は、ドライエツチング装置に関するもので、特V
こ、銅張積層プリント基板のスルーホール内面のスミア
をプラズマエツチングVこより除去するのりこ好適なも
のである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Application of the Invention] The present invention relates to a dry etching device, and features
This glue is suitable for removing smear on the inner surface of a through hole in a copper-clad laminated printed circuit board using plasma etching.

〔発明の背景〕[Background of the invention]

従来の半導体製造プロセスで用いられているドライエツ
チング装置は、一般tこ、第1図tこ示す如く真空容器
1内に高周波電極2および接地電極3を対向して設置し
、試料4を上記高周波電a!2の上りこ置き、高周波電
極2に高周波電#5を接続した構成となっている。しか
して、真空容器1内へ活性ガスまたは不活性ガスを導入
し、所定の真空度を保った状態で高周波電源5より両電
極2,3に高周波電力を印加すると、両電極2.3間に
プラズマが生じ、プラズマ中のイオンにより試料4の表
面をスパッタエツチングするものである。
A dry etching apparatus used in a conventional semiconductor manufacturing process generally has a high frequency electrode 2 and a ground electrode 3 placed in a vacuum container 1 facing each other, as shown in FIG. Electric a! The configuration is such that high frequency electrode #5 is connected to high frequency electrode 2. Therefore, when an active gas or an inert gas is introduced into the vacuum container 1 and high frequency power is applied to both electrodes 2 and 3 from the high frequency power source 5 while maintaining a predetermined degree of vacuum, between the two electrodes 2 and 3. Plasma is generated, and the surface of the sample 4 is sputter-etched by ions in the plasma.

一方、第2図に示す如く、絶縁層9を介して銅板8を積
層した銅張積層プリント基板のスルーホール10a内面
のスミア10は、スルーホール10a内壁Vこ固着して
いるため、スパッタエツチングでは除去しりこくく、プ
ラズマにより活性化されたガス分子−こよる反応性エツ
チングが効果的である。このため、第1図において試料
4の代りrこ銅張積層プリント基板を置くのは好ましく
なく第3図に示す如き高周波電極2と接地型&3との中
間にプリント基板7を絶縁物すで保持した第3図tこ示
す構成が考えられる。
On the other hand, as shown in FIG. 2, the smear 10 on the inner surface of the through hole 10a of the copper-clad laminated printed circuit board in which the copper plate 8 is laminated via the insulating layer 9 is fixed to the inner wall V of the through hole 10a, so it cannot be etched by sputter etching. Reactive etching using gas molecules activated by plasma is effective for removal. For this reason, it is not preferable to place a copper-clad laminated printed circuit board instead of the sample 4 in FIG. 1, and the printed circuit board 7 is held between the high-frequency electrode 2 and the ground type &3 with an insulator as shown in FIG. The configuration shown in FIG. 3 can be considered.

しかしながら、第3図の構成1こおいて両電極2゜3の
間にプリント基板7のような導体を配置すると、プラズ
マの発生が接地電極3とプリント基板7との間をこ制限
され、高周波電極2とプリント基板7との間eこはプラ
ズマがほとんど発生しないことになる。したがって、こ
の状態でドライエツチングを行なうと、銅張積層プリン
ト基板の周辺部と中央部とでエツチングはの大中な相違
が生じてしまう問題点がある。
However, if a conductor such as a printed circuit board 7 is placed between the electrodes 2 and 3 in the configuration 1 shown in FIG. 3, plasma generation is restricted between the ground electrode 3 and the printed circuit board 7, and high frequency Almost no plasma is generated between the electrode 2 and the printed circuit board 7. Therefore, if dry etching is performed in this state, there is a problem in that the etching results will be significantly different between the periphery and the center of the copper-clad laminated printed circuit board.

米国rこおいては、第4,5図Vこ示す如き銅張積層プ
リント基板用のドライエツチング装置が開発されている
。この6式は、図eこ示す如くスリットが形成された高
周波電極2a〜2eおよび接地型8!3a〜3eを対に
してプリント基板7の両側1こ設置することにより、プ
リント基板7の周囲をプラズマ化するものであり、ガス
導入孔12a、12bおよび排気孔13a、13bが左
右eこ設けられ、反応ガスの流れを左行および右行Vこ
交互に変えてエツチングの均一化を図るものであるが、
ガスm1%の不均−eこよりプリント基板7全面Vこお
いてエツチングが不均一となるおそれがある。
In the United States, a dry etching apparatus for copper-clad laminated printed circuit boards as shown in FIGS. 4 and 5 has been developed. This type 6 is constructed by installing high frequency electrodes 2a to 2e with slits and grounding types 8!3a to 3e in pairs on both sides of the printed circuit board 7, as shown in Figure e. Gas inlet holes 12a, 12b and exhaust holes 13a, 13b are provided on the left and right sides, and the flow of the reactant gas is alternately changed between the left and right lines to achieve uniform etching. Yes, but
Due to the non-uniformity of the gas m1%, the etching may become non-uniform over the entire surface of the printed circuit board 7.

〔発明の目的〕[Purpose of the invention]

本発明は、上記問題点にかんがみ、反応ガスの流れを均
一にし安定したプラズマを得て均一なドライエツチング
が可能な装置を提供することを目的としたものである。
SUMMARY OF THE INVENTION In view of the above-mentioned problems, it is an object of the present invention to provide an apparatus that can uniformly flow a reactant gas, obtain stable plasma, and perform uniform dry etching.

〔発明の概要〕[Summary of the invention]

本発明は、電界強度が全面で均一な平行平板電極を用い
、高周波電極又は接地電極の電極下向全面から反応ガス
を吹き出し、一方、接地電極又は高周波?l!極は反応
ガスを均一1こ通過させ、かつ池の電極に対して電界強
度がほぼ均一となるようtこし、接地電極又は高周波電
極の下15iこプリント基板を設置し、さらにその下方
tこ反応ガスの流れを均−tこするバッフルを設けたも
ので、そneこより、高周波電極と接地電極間で均一な
プラズマを発生させ、プラズマtこより活性化されたガ
ス分子をプリント基板のスルーホール内へ均一に導いて
プリント基板全面のスルーホール内のスミアを均−rこ
除去するよう?こしたものである。
The present invention uses parallel plate electrodes with uniform electric field strength over the entire surface, and blows out a reactive gas from the entire downward surface of the high-frequency electrode or the ground electrode. l! Place the printed circuit board 15cm below the ground electrode or high-frequency electrode so that the reactant gas passes through the electrode uniformly, and the electric field strength is almost uniform with respect to the electrode. This device is equipped with a baffle that evens out the flow of gas, which generates a uniform plasma between the high-frequency electrode and the ground electrode, and the activated gas molecules from the plasma are transferred into the through holes of the printed circuit board. Is it possible to evenly remove smear in the through holes on the entire surface of the printed circuit board? It is strained.

〔発明の実施例〕[Embodiments of the invention]

以下、本発明を第6〜10図?こより詳細tこ説明する
The present invention will be explained in Figures 6 to 10 below. This will be explained in more detail.

fJS6,7図は、本発明の一実施例を示すものである
。図eこおいて、1は真空容器−であり、下部に排気孔
13が設けられ排気ポンプ]81こ接続されている。2
は高周波電極で、絶縁材14を介して真空容器1の上部
に取付けられ、その下方1こは格子状の接地電極3が高
周波電極2と対向して設けらrている。
Figures fJS6 and 7 show an embodiment of the present invention. In FIG. 2
A high frequency electrode is attached to the upper part of the vacuum vessel 1 via an insulating material 14, and a grid-shaped ground electrode 3 is provided below the high frequency electrode 2, facing the high frequency electrode 2.

例えば、銅張積層のプリント基板7は、接地電極3のす
ぐ下側1こ配置され、絶縁材のサポートI5で支持され
た基板受台16の上に設置されている。しかして、その
下j5tこはカス流nを均一にするためのバッフル17
が設けられる。
For example, a printed circuit board 7 made of a copper-clad laminate is disposed immediately below the ground electrode 3, and is placed on a board pedestal 16 supported by an insulating support I5. However, below it is a baffle 17 for making the waste flow n uniform.
is provided.

高周波電極2vこは高周波電源5が接続され、高周波電
力を供給できるとともtこ外部から反応ガス。
A high-frequency power source 5 is connected to the high-frequency electrode 2v, and high-frequency power can be supplied to the high-frequency electrode 2v, and a reactive gas can be supplied from the outside.

を導く導入孔12が設けてあり、電極面は第7図eこ示
す如く中空構造とされ、電極下向全面から反応カスを均
−Vこ吹出す構造である。第7図Vこおいて、19は多
孔板のバッフル、20は同じく多孔板の吹出し板で、一
旦バツフル19で反応ガスを電113!全面tこほぼ均
−tこした後、吹出し板20との間でさらに反応ガス圧
力を均−Vこして電極下面から吹出すものである。
The electrode surface has a hollow structure as shown in FIG. 7e, and the reaction residue is uniformly blown out from the entire downward surface of the electrode. In FIG. 7, 19 is a baffle made of a perforated plate, and 20 is a blowing plate also made of a perforated plate. After the entire surface is almost evenly strained, the pressure of the reaction gas is further equalized with the blowing plate 20 and then blown out from the lower surface of the electrode.

次1こ、この装置の作用tこりいて説明する。真空容器
】は排気ポンプ18により真空排気され、高周波電極2
から反応ガスが一定流級連続的を乙供給され、真空容器
1の内部は一定真空圧力(約0.1〜ITorr)rこ
保たれる。この状態で、高周波電極2へ高周波電源5よ
り高周波電力を印加すると、高周波電極2と接地電極3
との間は反応ガスが活性化されて均−Vこ安定したプラ
ズマ状態が得られる。
Next, the operation of this device will be explained in detail. The vacuum container] is evacuated by the exhaust pump 18, and the high frequency electrode 2
A reaction gas is continuously supplied at a constant flow rate from the reactor 1, and a constant vacuum pressure (approximately 0.1 to I Torr) is maintained inside the vacuum vessel 1. In this state, when high frequency power is applied from the high frequency power supply 5 to the high frequency electrode 2, the high frequency electrode 2 and the ground electrode 3
Between the two, the reactive gas is activated and a stable plasma state is obtained.

活性化された反応ガスは、排気ポンプ】8により格子状
の接地電極3を通過して下かのバッフル17側へ均一1
こ排気される。プリント基板7は接地電極3の下b1こ
設置されているため、活性化された反応ガスが均−rこ
当り、それをこよりプリント基板7のスルーホール内の
スミアはエツチング除去される。
The activated reaction gas is uniformly pumped through the grid-shaped ground electrode 3 by the exhaust pump 8 to the lower baffle 17 side.
This is exhausted. Since the printed circuit board 7 is placed below the ground electrode 3, the activated reaction gas is evenly distributed therethrough, and the smear in the through holes of the printed circuit board 7 is etched away.

第8図は、本発明の他の実施例を示し、第6図において
高周波電極2と接地電極3とを置き換えたものである。
FIG. 8 shows another embodiment of the present invention, in which the high frequency electrode 2 and the ground electrode 3 in FIG. 6 are replaced.

図Vこおいて、2は格子状の高周波電極であり、絶縁材
6tこより真空容器1から支えられ、高周波電源5が印
加されている。接地電極3vこは外部から反応ガスを導
く導入孔】2が設けてあり、電極面は第7図Vこ示亥如
き中空構造とされ、(ル極下面から反応ガスが均−tこ
吹出す構造である。また、プリント基板7およびバッフ
ル]7の取付けは、第6図と同様である。
In FIG. V, reference numeral 2 denotes a grid-shaped high frequency electrode, which is supported from the vacuum vessel 1 through an insulating material 6t, and a high frequency power source 5 is applied thereto. The ground electrode 3v is provided with an inlet hole 2 for introducing the reactive gas from the outside, and the electrode surface has a hollow structure as shown in Figure 7. Furthermore, the mounting of the printed circuit board 7 and the baffle 7 is the same as that shown in FIG.

かかる装置において、接地電極3より反応ガスを吹出し
高周波′IIi極2へ高周波電源5より高周波電力を印
加すると、篩周波電極2と接地゛電極3との間で均−V
こ安定したプラスマが得られ、活性化さn、 t、−g
応ガスは排気ポンプ】8#こより格子状の高周波電極2
を通過して下すのバッフル】7側へ均一1こ排気され、
途中eこ置かれたプリント基板7に均一1こ反応ガスが
当り、プリント基板7のスルーポール内のスミアがエツ
チング除去される。
In this device, when a reactive gas is blown out from the ground electrode 3 and high frequency power is applied from the high frequency power source 5 to the high frequency 'IIi electrode 2, an equal voltage of -V is generated between the sieve frequency electrode 2 and the ground electrode 3.
This stable plasma is obtained and activated n, t, -g
Exhaust pump for response gas] 8# lattice-shaped high frequency electrode 2
Pass through the baffle and lower it] Uniformly exhaust air to the 7 side,
A uniform reaction gas is applied to the printed circuit board 7 placed halfway, and the smear in the through poles of the printed circuit board 7 is etched away.

プラズマVこよるドライエツチング法では、高周波電極
および接地電極は熱が発生し、それtこより′電極自体
の変形が起これば装置の連続運転tこ支障を来たすこと
−こなる。そこで、電極を冷却する必要が生じ、第9,
10図はその一実施例を示す。
In the dry etching method using plasma V, heat is generated in the high frequency electrode and the ground electrode, and if the electrode itself is deformed due to this heat, continuous operation of the apparatus will be hindered. Therefore, it became necessary to cool the electrode, and the ninth
FIG. 10 shows an example thereof.

接地電極3は孔21が多数設けられた多孔板で、かつ吸
入孔23.排出孔24に通ずる冷却水*22が内部に設
けられている。接地11i#!3が昇温した場合、冷却
水溝22へ冷却水を通すと接地電極3は冷却されて昇温
は防止され、変形も生ずることなく装置の連続運転が可
能である。
The ground electrode 3 is a perforated plate provided with a large number of holes 21, and has suction holes 23. Cooling water *22 communicating with the discharge hole 24 is provided inside. Grounding 11i#! When the temperature of the ground electrode 3 rises, passing cooling water through the cooling water groove 22 cools the ground electrode 3 and prevents the temperature from rising, allowing continuous operation of the device without deformation.

〔発明の効果〕〔Effect of the invention〕

本発明1こよれば、反応カスの流れが均一で安定したプ
ラスマを発生できて均一なドライエツチングが可能とな
り、それ1こより、プリント基板全面のスルーホール門
スミアをエツチング除去できるという効果がある。
According to the present invention, the flow of reaction scum is uniform, stable plasma can be generated, and uniform dry etching can be performed, which has the effect of etching away through-hole gate smears on the entire surface of a printed circuit board.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の半導体製造プロセスVこ用いられている
ドライエツチング装置の基本構成を示す断面図、MS 
2図はスルーホール内のスミアの状態を示す断面図、!
@3図は従来のドライエツチング装[iこプリント基板
を設置した状態の断面図、第4図は従来のプリント基板
用ドライエツチング装置の基本構成を示す正面図、第5
図は第4図のA−A断面図、第6図は本発明1こよるプ
リント基板用ドライエツチング装置の一実施例の断面図
、第7図はその高周波電極の詳細断面図、第8図は本発
明の他の実施例の断面図、第9図は本発明1ご用いる接
地電極の一実施例の平面図、第10図は第9図のB−B
断面図である。 1・・・・・・真空容器、2・・曲高周波電極・3・・
聞接地電極、5・・・・・・高周波電源、7 、、、、
、、プリント基板、8 ”’ ”’銅板、9・・・・・
絶縁層、1o・・曲スミア、12・・・・・導入孔、1
3・・・・・・排気孔、14・・曲絶縁材、15・・・
・・・サポート、16・曲・基板受台、17・・・・・
バッフル、18・・・・・・排気ポンプ、19・・・・
・・バッフル、20・・・・・・吹出し板、21・・曲
孔、22・・・・・・冷却水溝、23・・・・・・吸入
孔、24・聞・排出孔 牙1日 才4図 tl 才5t2) オフ図 才8図 才′#u ′″rlO図
Figure 1 is a sectional view showing the basic configuration of a dry etching device used in a conventional semiconductor manufacturing process.
Figure 2 is a cross-sectional view showing the state of smear inside the through hole!
Figure 3 is a cross-sectional view of a conventional dry etching device with a printed circuit board installed, Figure 4 is a front view showing the basic configuration of a conventional dry etching device for printed circuit boards, and Figure 5
The figures are a cross-sectional view taken along the line A-A in FIG. 4, FIG. 6 is a cross-sectional view of an embodiment of the dry etching apparatus for printed circuit boards according to the present invention, FIG. 7 is a detailed cross-sectional view of the high-frequency electrode, and FIG. 9 is a sectional view of another embodiment of the present invention, FIG. 9 is a plan view of an embodiment of the ground electrode used in the first invention, and FIG. 10 is taken along the line BB in FIG.
FIG. 1...Vacuum container, 2...Curved high frequency electrode, 3...
Grounding electrode, 5...High frequency power supply, 7...
,,Printed circuit board, 8 ”'”'Copper plate, 9...
Insulating layer, 1o...Curved smear, 12...Introduction hole, 1
3... Exhaust hole, 14... Curved insulation material, 15...
・・・Support, 16・Song・PCB holder, 17・・・・・・
Baffle, 18...Exhaust pump, 19...
... Baffle, 20 ... Blowout plate, 21 ... Bent hole, 22 ... Cooling water groove, 23 ... Suction hole, 24 ... Discharge hole fang 1 day 4th figure tl 5t2) Off figure 8th figure s'#u ''rlO figure

Claims (1)

【特許請求の範囲】[Claims] 1、 均一なガス吹出し孔を有する高周波電極と接地電
極とを対向して設置し、上記ガス吹出し孔を通過したガ
スの流れの下流側に上記電極−こ対面してプリント基板
を設置するようにしたことを特徴とするドライエツチン
グ装置。
1. A high frequency electrode and a ground electrode having uniform gas blowing holes are installed facing each other, and a printed circuit board is installed facing the electrodes on the downstream side of the flow of gas that has passed through the gas blowing holes. A dry etching device characterized by:
JP5820884A 1984-03-28 1984-03-28 Dry etching device Pending JPS60202937A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5820884A JPS60202937A (en) 1984-03-28 1984-03-28 Dry etching device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5820884A JPS60202937A (en) 1984-03-28 1984-03-28 Dry etching device

Publications (1)

Publication Number Publication Date
JPS60202937A true JPS60202937A (en) 1985-10-14

Family

ID=13077623

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5820884A Pending JPS60202937A (en) 1984-03-28 1984-03-28 Dry etching device

Country Status (1)

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JP (1) JPS60202937A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4986216A (en) * 1989-05-10 1991-01-22 Mitsubishi Denki Kabushiki Kaisha Semiconductor manufacturing apparatus
US5129360A (en) * 1990-01-24 1992-07-14 The United States Of America As Represented By The Secretary Of The Air Force Actively cooled effusion cell for chemical vapor deposition
US5653806A (en) * 1995-03-10 1997-08-05 Advanced Technology Materials, Inc. Showerhead-type discharge assembly for delivery of source reagent vapor to a substrate, and CVD process utilizing same
US5741363A (en) * 1996-03-22 1998-04-21 Advanced Technology Materials, Inc. Interiorly partitioned vapor injector for delivery of source reagent vapor mixtures for chemical vapor deposition
US6167834B1 (en) 1986-12-19 2001-01-02 Applied Materials, Inc. Thermal CVD/PECVD reactor and use for thermal chemical vapor deposition of silicon dioxide and in-situ multi-step planarized process
US6194030B1 (en) * 1999-03-18 2001-02-27 International Business Machines Corporation Chemical vapor deposition velocity control apparatus
US6972071B1 (en) * 1999-07-13 2005-12-06 Nordson Corporation High-speed symmetrical plasma treatment system

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6167834B1 (en) 1986-12-19 2001-01-02 Applied Materials, Inc. Thermal CVD/PECVD reactor and use for thermal chemical vapor deposition of silicon dioxide and in-situ multi-step planarized process
US4986216A (en) * 1989-05-10 1991-01-22 Mitsubishi Denki Kabushiki Kaisha Semiconductor manufacturing apparatus
US5129360A (en) * 1990-01-24 1992-07-14 The United States Of America As Represented By The Secretary Of The Air Force Actively cooled effusion cell for chemical vapor deposition
US5653806A (en) * 1995-03-10 1997-08-05 Advanced Technology Materials, Inc. Showerhead-type discharge assembly for delivery of source reagent vapor to a substrate, and CVD process utilizing same
US5741363A (en) * 1996-03-22 1998-04-21 Advanced Technology Materials, Inc. Interiorly partitioned vapor injector for delivery of source reagent vapor mixtures for chemical vapor deposition
US6010748A (en) * 1996-03-22 2000-01-04 Advanced Technology Materials, Inc. Method of delivering source reagent vapor mixtures for chemical vapor deposition using interiorly partitioned injector
US6194030B1 (en) * 1999-03-18 2001-02-27 International Business Machines Corporation Chemical vapor deposition velocity control apparatus
US6972071B1 (en) * 1999-07-13 2005-12-06 Nordson Corporation High-speed symmetrical plasma treatment system

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