JPS60191021A - ウラン回収方法 - Google Patents
ウラン回収方法Info
- Publication number
- JPS60191021A JPS60191021A JP59068402A JP6840284A JPS60191021A JP S60191021 A JPS60191021 A JP S60191021A JP 59068402 A JP59068402 A JP 59068402A JP 6840284 A JP6840284 A JP 6840284A JP S60191021 A JPS60191021 A JP S60191021A
- Authority
- JP
- Japan
- Prior art keywords
- uranium
- wpa
- resin
- crude
- cation exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052770 Uranium Inorganic materials 0.000 title claims description 58
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title claims description 58
- 238000000034 method Methods 0.000 claims description 46
- 239000011347 resin Substances 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 22
- 239000003729 cation exchange resin Substances 0.000 claims description 19
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 150000001768 cations Chemical class 0.000 claims description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 238000005341 cation exchange Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000005352 clarification Methods 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 34
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 239000001099 ammonium carbonate Substances 0.000 description 14
- 238000005342 ion exchange Methods 0.000 description 14
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 13
- 238000010828 elution Methods 0.000 description 12
- 235000012501 ammonium carbonate Nutrition 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000002367 phosphate rock Substances 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 229940023913 cation exchange resins Drugs 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 4
- 239000003456 ion exchange resin Substances 0.000 description 4
- 229920003303 ion-exchange polymer Polymers 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KPUBIZJWWGSWGQ-UHFFFAOYSA-N azane;carbonic acid Chemical compound N.N.N.OC(O)=O.OC(O)=O KPUBIZJWWGSWGQ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- ZAASRHQPRFFWCS-UHFFFAOYSA-P diazanium;oxygen(2-);uranium Chemical compound [NH4+].[NH4+].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[U].[U] ZAASRHQPRFFWCS-UHFFFAOYSA-P 0.000 description 2
- 238000011067 equilibration Methods 0.000 description 2
- -1 impropyl Chemical group 0.000 description 2
- 238000000622 liquid--liquid extraction Methods 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- TXKPGZOYBXKOHB-UHFFFAOYSA-N [Au].[U] Chemical compound [Au].[U] TXKPGZOYBXKOHB-UHFFFAOYSA-N 0.000 description 1
- UMHKOAYRTRADAT-UHFFFAOYSA-N [hydroxy(octoxy)phosphoryl] octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OP(O)(=O)OCCCCCCCC UMHKOAYRTRADAT-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N ammonium carbonate Chemical class N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical group O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012468 concentrated sample Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001570 methylene group Chemical class [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- SWMBQMGPRYJSCI-UHFFFAOYSA-N octylphosphane Chemical compound CCCCCCCCP SWMBQMGPRYJSCI-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/0265—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
Landscapes
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL69384 | 1983-08-01 | ||
IL69384A IL69384A0 (en) | 1983-08-01 | 1983-08-01 | Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60191021A true JPS60191021A (ja) | 1985-09-28 |
JPS6230130B2 JPS6230130B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-06-30 |
Family
ID=11054444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59068402A Granted JPS60191021A (ja) | 1983-08-01 | 1984-04-07 | ウラン回収方法 |
Country Status (6)
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6165367A (en) * | 1991-09-19 | 2000-12-26 | Siemens Power Corporation | Method for removing a heavy metal from a waste stream |
US5385713A (en) * | 1992-05-29 | 1995-01-31 | Ecotek, Inc. | Metal and fluorine values recovery from mineral ore treatment |
US5273725A (en) * | 1992-05-29 | 1993-12-28 | Eco Tek, Inc. | Metal and fluorine values recovery from mineral ore treatment |
US5302273A (en) * | 1993-02-08 | 1994-04-12 | Kemmerer Terry L | Induced ionic reaction device with radial flow |
US8883096B2 (en) | 2008-07-31 | 2014-11-11 | Urtek, Llc | Extraction of uranium from wet-process phosphoric acid |
RU2011102292A (ru) * | 2008-07-31 | 2012-09-10 | Уртек, Ллс (Us) | Выделение урановых соединений из фосфорной кислоты, полученной мокрым способом |
EP2458024A1 (en) | 2010-11-24 | 2012-05-30 | Rohm and Haas Europe Services ApS Succursale France | Method for the recovery of uranium from pregnant liquor solutions |
CA2783047C (en) * | 2011-07-29 | 2015-11-24 | Rohm And Haas Company | Method for the recovery of uranium from pregnant liquor solutions |
CA2854145A1 (en) * | 2011-10-31 | 2013-05-10 | Urtek, Llc | Extraction of uranium from wet-process phosphoric acid |
WO2014018422A1 (en) * | 2012-07-21 | 2014-01-30 | K-Technologies, Inc. | Processes for the recovery of uranium from wet-process phosphoric acid using a single dual or dual single cycle ion exchange approaches |
US8557201B1 (en) | 2012-08-08 | 2013-10-15 | Rohm And Haas Company | Method for the recovery of uranium from pregnant liquor solutions |
FR3002463B1 (fr) | 2013-02-25 | 2016-08-19 | Commissariat Energie Atomique | Materiau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux contenant de l'acide phosphorique, ses procedes de preparation et ses utilisations |
RU2571764C1 (ru) * | 2014-08-26 | 2015-12-20 | Открытое акционерное общество "Ведущий научно-исследовательский институт химической технологии" | Способ сорбционного извлечения урана из фторсодержащих сред |
FR3044006B1 (fr) | 2015-11-19 | 2020-03-06 | Orano Mining | Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique |
FR3044018B1 (fr) | 2015-11-19 | 2017-12-22 | Areva Mines | Procedes d'extraction et de recuperation de l'uranium present dans une solution aqueuse comprenant de l'acide phosphorique |
US11384411B2 (en) | 2017-06-02 | 2022-07-12 | Dow Global Technologies Llc | Recovery of uranium |
CN110668546B (zh) * | 2019-10-25 | 2021-11-19 | 南华大学 | 一种催化还原含铀废水中铀酰离子的方法 |
MX2023003486A (es) * | 2020-09-25 | 2023-04-14 | Ocp S A | Procesos para la recuperacion de uranio. |
CN113387412A (zh) * | 2021-05-19 | 2021-09-14 | 中核四0四有限公司 | 一种用于硝酸和碳酸混合体系下含铀废水处理的离子交换装置 |
CN116351384A (zh) * | 2021-12-28 | 2023-06-30 | 比亚迪股份有限公司 | 锂吸附剂及盐湖提锂方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2770520A (en) * | 1950-04-11 | 1956-11-13 | Ray S Long | Recovery of uranium from phosphoric acid and phosphate solutions by ion exchange |
US2795480A (en) * | 1951-08-03 | 1957-06-11 | Elmer F Stephan | Recovery of uranium from aqueous phosphate containing solutions |
US3737513A (en) * | 1970-07-02 | 1973-06-05 | Freeport Minerals Co | Recovery of uranium from an organic extractant by back extraction with h3po4 or hf |
US3835214A (en) * | 1972-08-15 | 1974-09-10 | Atomic Energy Commission | Oxidative stripping process for the recovery of uranium from wet-process phosphoric acid |
FR2279453A1 (fr) * | 1974-07-24 | 1976-02-20 | Dia Prosim | Echangeurs d'ions selectifs pour separer et fixer les metaux |
JPS5244396A (en) * | 1975-10-07 | 1977-04-07 | Asahi Chem Ind Co Ltd | New continuous development method |
FR2380228A1 (fr) * | 1977-02-09 | 1978-09-08 | Cogema | Procede de traitement de liqueurs alcalines contenant des ions sulfate |
FR2380346A1 (fr) * | 1977-02-09 | 1978-09-08 | Cogema | Procede de separation de l'uranium contenu dans une liqueur alcaline, notamment d'extraction a partir d'un minerai uranifere |
FR2489711A1 (fr) * | 1980-04-21 | 1982-03-12 | Minemet Rech Sa | Compositions echangeuses de cations metalliques |
US4402917A (en) * | 1980-09-05 | 1983-09-06 | Allied Chemical Corporation | Extraction of uranium from phosphoric acid using supported extractants |
CA1181953A (en) * | 1980-09-26 | 1985-02-05 | Terrance Laterra | Method and apparatus for recovery of uranium from carbonate leach liquors |
US4432944A (en) * | 1980-12-22 | 1984-02-21 | General Electric Company | Ion exchange recovery of uranium |
-
1983
- 1983-08-01 IL IL69384A patent/IL69384A0/xx unknown
-
1984
- 1984-02-13 US US06/579,544 patent/US4599221A/en not_active Expired - Fee Related
- 1984-02-14 DE DE8484300934T patent/DE3473889D1/de not_active Expired
- 1984-02-14 EP EP84300934A patent/EP0132902B1/en not_active Expired
- 1984-04-07 JP JP59068402A patent/JPS60191021A/ja active Granted
- 1984-07-16 ES ES534362A patent/ES8505619A1/es not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE3473889D1 (en) | 1988-10-13 |
EP0132902A2 (en) | 1985-02-13 |
ES534362A0 (es) | 1985-06-16 |
EP0132902B1 (en) | 1988-09-07 |
US4599221A (en) | 1986-07-08 |
JPS6230130B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-06-30 |
IL69384A0 (en) | 1983-11-30 |
ES8505619A1 (es) | 1985-06-16 |
EP0132902A3 (en) | 1986-03-19 |
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