JPS60177001A - 水に不溶性のカルボキシメチルセルロ−スエ−テルアルカリ塩の製造法 - Google Patents
水に不溶性のカルボキシメチルセルロ−スエ−テルアルカリ塩の製造法Info
- Publication number
- JPS60177001A JPS60177001A JP3121284A JP3121284A JPS60177001A JP S60177001 A JPS60177001 A JP S60177001A JP 3121284 A JP3121284 A JP 3121284A JP 3121284 A JP3121284 A JP 3121284A JP S60177001 A JPS60177001 A JP S60177001A
- Authority
- JP
- Japan
- Prior art keywords
- water
- cellulose
- alkali
- cmc
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001447 alkali salts Chemical class 0.000 title abstract description 3
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229920002678 cellulose Polymers 0.000 claims abstract description 29
- 239000001913 cellulose Substances 0.000 claims abstract description 29
- 239000003513 alkali Substances 0.000 claims abstract description 22
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 239000003960 organic solvent Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims description 13
- -1 carboxymethyl cellulose ether alkali salt Chemical class 0.000 claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 54
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract description 41
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 9
- 235000019441 ethanol Nutrition 0.000 abstract description 6
- 239000003431 cross linking reagent Substances 0.000 abstract description 3
- 239000013078 crystal Substances 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 238000006386 neutralization reaction Methods 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000003381 stabilizer Substances 0.000 abstract description 2
- 239000002562 thickening agent Substances 0.000 abstract description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 3
- 235000013305 food Nutrition 0.000 abstract 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 39
- 238000012710 chemistry, manufacturing and control Methods 0.000 description 39
- 238000000034 method Methods 0.000 description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- 238000003756 stirring Methods 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000002156 mixing Methods 0.000 description 11
- 238000006266 etherification reaction Methods 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000007810 chemical reaction solvent Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920001453 Arcel Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N butyl alcohol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N alpha-methyl toluene Natural products CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011153 ceramic matrix composite Substances 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940023144 sodium glycolate Drugs 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- JEJAMASKDTUEBZ-UHFFFAOYSA-N tris(1,1,3-tribromo-2,2-dimethylpropyl) phosphate Chemical compound BrCC(C)(C)C(Br)(Br)OP(=O)(OC(Br)(Br)C(C)(C)CBr)OC(Br)(Br)C(C)(C)CBr JEJAMASKDTUEBZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3121284A JPS60177001A (ja) | 1984-02-21 | 1984-02-21 | 水に不溶性のカルボキシメチルセルロ−スエ−テルアルカリ塩の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3121284A JPS60177001A (ja) | 1984-02-21 | 1984-02-21 | 水に不溶性のカルボキシメチルセルロ−スエ−テルアルカリ塩の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60177001A true JPS60177001A (ja) | 1985-09-11 |
| JPH0469161B2 JPH0469161B2 (hu) | 1992-11-05 |
Family
ID=12325122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3121284A Granted JPS60177001A (ja) | 1984-02-21 | 1984-02-21 | 水に不溶性のカルボキシメチルセルロ−スエ−テルアルカリ塩の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60177001A (hu) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995011925A1 (en) * | 1993-10-29 | 1995-05-04 | Kimberly-Clark Corporation | Modified polysaccharides having improved absorbent properties and process for the preparation thereof |
| JP2002536507A (ja) * | 1999-02-10 | 2002-10-29 | ハーキュリーズ・インコーポレイテッド | 誘導微小繊維ポリサッカライド |
| KR100462319B1 (ko) * | 2002-06-10 | 2004-12-17 | 박흥조 | 카르복시메틸셀룰로오스의 제조방법 |
| JP2008056889A (ja) * | 2006-08-01 | 2008-03-13 | Nippon Paper Chemicals Co Ltd | 非結晶セルロース誘導体 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54935A (en) * | 1977-06-06 | 1979-01-06 | Hitachi Ltd | Pattern detector |
| JPS5962602A (ja) * | 1982-10-04 | 1984-04-10 | Daicel Chem Ind Ltd | カルボキシメチルセルロ−スナトリウム塩 |
| JPS62141001A (ja) * | 1985-12-13 | 1987-06-24 | Dai Ichi Kogyo Seiyaku Co Ltd | 水不溶性のカルボキシアルキルセルロ−ス・アルカリ金属塩の製造方法 |
| JPH0235761A (ja) * | 1988-07-26 | 1990-02-06 | Matsushita Electric Ind Co Ltd | 熱電変換モジュール |
-
1984
- 1984-02-21 JP JP3121284A patent/JPS60177001A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54935A (en) * | 1977-06-06 | 1979-01-06 | Hitachi Ltd | Pattern detector |
| JPS5962602A (ja) * | 1982-10-04 | 1984-04-10 | Daicel Chem Ind Ltd | カルボキシメチルセルロ−スナトリウム塩 |
| JPS62141001A (ja) * | 1985-12-13 | 1987-06-24 | Dai Ichi Kogyo Seiyaku Co Ltd | 水不溶性のカルボキシアルキルセルロ−ス・アルカリ金属塩の製造方法 |
| JPH0235761A (ja) * | 1988-07-26 | 1990-02-06 | Matsushita Electric Ind Co Ltd | 熱電変換モジュール |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5550189A (en) * | 1992-04-17 | 1996-08-27 | Kimberly-Clark Corporation | Modified polysaccharides having improved absorbent properties and process for the preparation thereof |
| WO1995011925A1 (en) * | 1993-10-29 | 1995-05-04 | Kimberly-Clark Corporation | Modified polysaccharides having improved absorbent properties and process for the preparation thereof |
| JP2002536507A (ja) * | 1999-02-10 | 2002-10-29 | ハーキュリーズ・インコーポレイテッド | 誘導微小繊維ポリサッカライド |
| JP2013064134A (ja) * | 1999-02-10 | 2013-04-11 | Hercules Inc | 誘導化微小繊維ポリサッカライド |
| KR100462319B1 (ko) * | 2002-06-10 | 2004-12-17 | 박흥조 | 카르복시메틸셀룰로오스의 제조방법 |
| JP2008056889A (ja) * | 2006-08-01 | 2008-03-13 | Nippon Paper Chemicals Co Ltd | 非結晶セルロース誘導体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0469161B2 (hu) | 1992-11-05 |
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