JPS6015594B2 - Cutting blade for cutting tools - Google Patents

Cutting blade for cutting tools

Info

Publication number
JPS6015594B2
JPS6015594B2 JP54138573A JP13857379A JPS6015594B2 JP S6015594 B2 JPS6015594 B2 JP S6015594B2 JP 54138573 A JP54138573 A JP 54138573A JP 13857379 A JP13857379 A JP 13857379A JP S6015594 B2 JPS6015594 B2 JP S6015594B2
Authority
JP
Japan
Prior art keywords
cutting
diamond
volume
silicon nitride
cutting tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP54138573A
Other languages
Japanese (ja)
Other versions
JPS5663882A (en
Inventor
由雄 冨士原
泰次郎 杉澤
賢一 西垣
薫 川田
文洋 植田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP54138573A priority Critical patent/JPS6015594B2/en
Publication of JPS5663882A publication Critical patent/JPS5663882A/en
Publication of JPS6015594B2 publication Critical patent/JPS6015594B2/en
Expired legal-status Critical Current

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  • Ceramic Products (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Laminated Bodies (AREA)

Description

【発明の詳細な説明】 この発明は、すぐれた靭性と耐熱耐摩耗性を有し、特に
難削材を切削するに際して、切刃として使用するのに適
した切削工具用切刃に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a cutting blade for a cutting tool that has excellent toughness and heat and wear resistance, and is particularly suitable for use as a cutting blade when cutting difficult-to-cut materials. .

従釆、AIおよびAI合金、CuおよびCu合金などの
非鉄金属材料や、プラスチック、ゴム、黒鉛、およびセ
ラミックなどの非金属材料などの高速仕上切削には、ダ
イヤモンド基塚結材料の切刃層と、これに級性を付与す
る目的で炭化タングステン(以下WCで示す)基超硬合
金で構成された保持層との2層複合焼結体が切刃として
使用されている。
For high-speed finishing cutting of non-ferrous metal materials such as steel, AI and AI alloys, Cu and Cu alloys, and non-metallic materials such as plastics, rubber, graphite, and ceramics, the cutting edge layer of diamond-based material and A two-layer composite sintered body with a retaining layer made of tungsten carbide (hereinafter referred to as WC)-based cemented carbide is used as a cutting edge for the purpose of imparting grade to this.

上記従来切削工具用切刃は、通常、圧力:5〜6方気圧
、温度:1350〜1500午0の超高圧競結条件で製
造されており、したがって保持層を構成するWC基超硬
合金は液相焼結されることになる。
The above-mentioned cutting blades for conventional cutting tools are usually manufactured under ultra-high pressure conditions such as pressure: 5 to 6 atmospheres and temperature: 1350 to 1500 pm. It will be liquid phase sintered.

このような従来切削工具用切刃の保持層においては、そ
の製造時の高温高圧下において液相(通常はCoで構成
される)中に相当量のWCが溶解し、一方これに比例し
て凝固時におけるWCの析出もそれだけ活発化するため
、析出したWC粒は異常に細長く成長するようになり、
このWC粒の成長は炭素の濃度勾配が著しい上記切刃層
との界面において特に生じ易く、この結果として前記切
刃層と保持層との界面接合強度が劣るという問題がある
。このように切刃層と保持層との密着性が良好でない従
来切削工具用切刃においては、切削時に発生する微小振
動が増幅された状態となるために、切刃の摩耗進行が早
められ、さらにチッピングや欠損が発生しやすくなるも
のであった。本発明者等は、上述のような観点から、切
削工具用切刃について、切刃層を構成するダイヤモンチ
ド基暁結材料との界面接合強度が高く、さらに籾性およ
び耐熱耐摩耗性にすぐれた保持層形成材料を得べく研究
を行なった結果、‘aー 上記保持層形成材料を窒化け
し、素(以下Si3N4で示す)基暁給セラミックスで
構成すると、競結時に、前記保持層内部は勿論のこと、
前記切刃層との界面においても粒成長がきわせて4・さ
く、均質な微細組織が確保され、したがってダイヤモン
ド基競結材料で構成される切刃層との界面接合強度の高
い切削工具用切刃が得られること。
In the retaining layer of such a cutting edge for a conventional cutting tool, a considerable amount of WC is dissolved in the liquid phase (usually composed of Co) under high temperature and high pressure during manufacturing, while a proportionate amount of WC is dissolved in the liquid phase (usually composed of Co). As WC precipitation becomes more active during solidification, the precipitated WC grains grow abnormally long and thin.
The growth of these WC grains is particularly likely to occur at the interface with the cutting edge layer where there is a significant carbon concentration gradient, and as a result, there is a problem that the interfacial bonding strength between the cutting edge layer and the retaining layer is poor. In conventional cutting tool cutting edges where the adhesion between the cutting edge layer and the retaining layer is not good, the minute vibrations generated during cutting are amplified, which accelerates the progress of wear on the cutting edge. Furthermore, chipping and defects were more likely to occur. From the above-mentioned viewpoints, the present inventors have developed a cutting edge for a cutting tool that has high interfacial bonding strength with the diamond-based crystalline material constituting the cutting edge layer, and has excellent grain hardness and heat and wear resistance. As a result of research to obtain a retaining layer forming material, it was found that if the above retaining layer forming material was nitrided and composed of an elemental (hereinafter referred to as Si3N4) based ceramic, the inside of the retaining layer would be Of course,
Grain growth is also accelerated at the interface with the cutting edge layer, ensuring a homogeneous microstructure, and therefore a cutting tool for cutting tools with high interfacial bonding strength with the cutting edge layer made of diamond-based bonded material. Obtaining a blade.

【b} 切削工具用切刃の切刃層を構成するダイヤモン
ド基競鯖材料を、■ ダイヤモンド:92〜97容量%
、 Fe族金属のうちの1種または2種以上および不可避不
純物:残り、■ ダイヤモンド:舷〜97容量%、 Si合金および不可避不純物:残り、 ■ ダイヤモンド:60〜9柊容量%、 周期律表の傘および虫族の金属の炭化物、および室化物
、並びに室化アルミニウム(以下AINで示す)、炭化
けし・素(以下SICで示す)窒化けし、素(以下Si
3N4で示す)、さらにこれらの固溶体からなる群のう
ちの1種または2種以上および不可避不純物:残り、以
上■〜■のうちのいずれかの成分組成に椿定し、一方、
同保持層を構成するSi3N4基凝結セラミックスを、
■ Si3N4:90〜97容量%、 酸化マグネシウム(以下Mg○で示す)、酸化アルミニ
ウム(以下AI203で示す)、および酸化イットリウ
ム(以下Y2Qで示す)のうちの1種または2種以上お
よび不可避不純物:残り、■ Si3N4:斑〜97容
量%、鉄族金属およびSiのうちの1種または2種以上
および不可避不純物:残り、@ Si3N4:70〜9
7容量%、 NN、窒化チタン(以下TINで示す)、およびサィア
ロン(一般化学式:SiAI×Nzを有する)のうちの
1種または2種以上:残り、以上■〜■のいずれかの成
分組成に特定し、これらの袴定した成分組成を有する功
刃層と保持層とを適宜組合せて構成した切削工具用切刃
は、特に高に界面接合強度を有し、切削時にきわめてす
ぐれた切削性能を発揮すること。
[b} The diamond-based material that constitutes the cutting edge layer of the cutting edge for cutting tools is ■ Diamond: 92 to 97% by volume.
, One or more Fe group metals and unavoidable impurities: Remaining ■ Diamond: ~97% by volume, Si alloy and unavoidable impurities: Remaining ■ Diamond: 60~9% by volume, Periodic table Carbides and urides of umbrella and insect group metals, as well as aluminum nitride (hereinafter referred to as AIN), poppy carbide/silicon carbide (hereinafter referred to as SIC), poppy nitride, and nitride (hereinafter referred to as Si)
3N4), furthermore, one or more of the group consisting of these solid solutions and unavoidable impurities: the remaining component composition is determined to be any of the above (■ to ■), while,
The Si3N4-based condensed ceramic that makes up the retention layer is
■ Si3N4: 90 to 97% by volume, one or more of magnesium oxide (hereinafter referred to as Mg○), aluminum oxide (hereinafter referred to as AI203), and yttrium oxide (hereinafter referred to as Y2Q), and inevitable impurities: Remaining, ■ Si3N4: mottled to 97% by volume, one or more of iron group metals and Si, and unavoidable impurities: remaining, @ Si3N4: 70 to 9
7% by volume, one or more of NN, titanium nitride (hereinafter referred to as TIN), and Sialon (having the general chemical formula: SiAI×Nz): the remainder, the component composition of any of the above ■ to ■ The cutting tool blade, which is constructed by appropriately combining a special blade layer and a retaining layer that have a specified component composition, has particularly high interfacial bonding strength and exhibits extremely excellent cutting performance during cutting. To demonstrate.

以上{a’および‘b’に示される知見を得たのである
The findings shown in {a' and 'b' have been obtained above.

この発明は、上記知見にもとづいてなされたものであり
、しかもこの発明の切削工具用切刃は、通常の粉末捨金
法により、公知の超高圧高温発生装置を使用して製造す
ることができる。
This invention has been made based on the above findings, and furthermore, the cutting edge for a cutting tool of this invention can be manufactured using a known ultra-high pressure and high temperature generator by a normal powder waste method. .

すなわち、この発明の切削工具用切刃は、【aー それ
ぞれ所定の最終成分組成をもつように配タ合し、混合し
た切刃層および保持層形成のための混合粉末より、冷間
圧縮によって圧粉末をほぼ等しい収縮率をもつように別
々に形成し、‘b’必要に応じて、上記{a)工程で成
形された両圧粉体を1200oo以下の温度で仮暁し、
Z‘cー 上記両圧粉体または上記両仮嬢体
を容器内に複合した状態で装入し、加熱脱気した後封入
し、‘dー 上記封入圧粉末または封入仮嫌体を公知の
超高圧高温発生装置において焼結することによつZて切
刃層と保持層とが強固に密着一体化した2層複合競結体
を得ることからなる基本工程によって製造することがで
きる。
That is, the cutting edge for a cutting tool of the present invention is obtained by cold compression from a mixed powder for forming a cutting edge layer and a retaining layer, which are blended and mixed so that each has a predetermined final component composition. Form the green compacts separately so that they have approximately the same shrinkage rate, 'b' If necessary, both green compacts formed in the above {a) step are pre-frozen at a temperature of 1200 oo or less,
Z'c - The above-mentioned compacted powder or both temporary bodies are charged into a container in a combined state, heated and deaerated, and then sealed, It can be manufactured by a basic process consisting of obtaining a two-layer composite compact in which the cutting edge layer and the holding layer are tightly integrated into one by sintering in an ultra-high pressure and high temperature generator.

つぎに、この発明の切削工具用切刃を実施例により説明
する。
Next, the cutting blade for a cutting tool according to the present invention will be explained with reference to examples.

2実施例 1平均粒径1ぶ
れの合成ダイヤモンド粉末:9群容量%とSi−Co合
金(Si:15重量%含有)粉末:2容量%からなる切
刃層形成のための混合粉末よりlbn/幼の圧力で直径
6側0×厚さ1肋の寸法2をもった圧粉体を成形し、一
方均粒径0.8ぶれのQ−Si3N4粉末:9弦容量%
とSi一Co合金(Si:15重量%含有)粉末:5容
量%からなる保持層形成のための混合粉末より同一の条
件で圧粉体を成形し、このように成形した両圧粉末をN
j製円筒状3容器に重ねて装填し、真空炉中、温度:7
00℃、圧力:104tonの条件で加熱脱気した後、
Ni製上蓋を溶接することによって密閉し、ついで前記
封入圧粉末体をベルト型超高圧高温発生装置に装入し、
圧力:60Kb、温度140000、保持時間:30分
3の条件で焼結することによって切刃層と保持層とが一
体接合した2層複合焼鯖体からなるこの発明の切削工具
用切刃を製造した。
2 Examples 1 From a mixed powder for forming a cutting edge layer consisting of 9 group volume % of synthetic diamond powder with an average particle size of 1 deviation and 2 volume % of Si-Co alloy (Si: 15 weight % contained) powder. A powder compact with dimensions 2 of 6 diameter side 0 x thickness 1 rib was formed using small pressure, while Q-Si3N4 powder with average particle size 0.8 deviation: 9 string volume%
and Si-Co alloy (Si: containing 15% by weight) powder: A green compact was formed under the same conditions from a mixed powder for forming a retaining layer, and the thus formed compacted powder was heated with N.
Loaded into three cylindrical containers made by J and placed in a vacuum furnace at a temperature of 7.
After heating and degassing under the conditions of 00℃ and pressure: 104 tons,
It is sealed by welding a Ni upper cover, and then the encapsulated compressed powder body is charged into a belt-type ultra-high pressure and high temperature generator,
The cutting blade for a cutting tool of the present invention is manufactured by sintering under the conditions of pressure: 60 Kb, temperature 140,000, and holding time: 30 minutes, which is made of a two-layer composite sintered mackerel body in which the cutting blade layer and the retaining layer are integrally joined. did.

この結果得られた本発明切削工具用切刃を、ダイヤモン
ドホイールで研磨して組織観察を行なつ4たところ、切
刃層と保持層のいずれも理論密度比100%を有し、か
つ保持層内部は勿論のこと、特に切刃層との界面部にも
粒の異常成長は全く見られず、非常に微細な組織を有す
るものであった。
The resulting cutting edge for a cutting tool of the present invention was polished with a diamond wheel and the structure was observed.4 As a result, both the cutting edge layer and the holding layer had a theoretical density ratio of 100%, and the holding layer Abnormal growth of grains was not observed at all not only in the interior but especially at the interface with the cutting edge layer, and the specimen had a very fine structure.

また、上記保持層はビッカーズ硬さ:1700k9/嫌
を示した。一方、比較の目的で、保持層をWC−6重量
%Coの組成をもった超硬合金で構成する以外は、上記
本発明切削工具用切刃と同一の製造条件にて比較切削工
具用切刃を製造した。
Further, the above-mentioned retaining layer exhibited a Vickers hardness of 1700k9/poor. On the other hand, for the purpose of comparison, a cutting tool for a comparative cutting tool was manufactured under the same manufacturing conditions as the cutting edge for a cutting tool of the present invention, except that the retaining layer was made of a cemented carbide having a composition of WC-6% by weight Co. Manufactured the blade.

ついで、これな両切削工具用切刃を、それぞれWC基超
硬合金製切削チップ(スローアウェィチッブ)の切刃部
にろう付けにより取付け、さらにこれをバイトに取付け
、被削材:FC−25 (ブリネル硬さHB:220)、 切削速度:200m/肌、 送り:0.1豚/revへ 切込み:1.仇舷、 切削油:使用せず、 の条件で外蓬旋削試験を行ない、フランク摩耗中が0.
1柵に至るまでの切削時間を測定した。
Next, the cutting edges for both cutting tools were attached to the cutting edges of WC-based cemented carbide cutting tips (throw-away tips) by brazing, and then these were attached to the cutting tool, and the workpiece material: FC- 25 (Brinell hardness HB: 220), Cutting speed: 200m/skin, Feed: 0.1 pig/rev Depth of cut: 1. External turning test was conducted under the following conditions without using cutting oil and the flank wear was 0.
The cutting time until reaching one fence was measured.

この結果本発明切削工具用切刃を取付けた切削チップは
正常摩耗により35分で所定摩耗量に達したのに対して
、比較切削工具用切刃を取付けたものはチッピングを起
し、2分で所定摩耗量に至るものであった。実施例 2 切刃層および保持層形成のための混合粉末の配合割合を
第1表に示される条件とする以外は、上記実施例1にお
けると同一の条件にて、実質的に配合組成と同一の最終
成分組成をもった本発明a〜kをそれぞれ製造した。
As a result, the cutting tip to which the cutting edge for the cutting tool of the present invention was attached reached the specified wear amount in 35 minutes due to normal wear, whereas the tip to which the cutting edge for the comparative cutting tool was attached caused chipping and reached the specified wear amount in 2 minutes. The amount of wear reached the predetermined amount. Example 2 Substantially the same composition as in Example 1 above, except that the blending ratio of the mixed powder for forming the cutting edge layer and the retaining layer was as shown in Table 1. Each of the present invention a to k having a final component composition was manufactured.

この結果得られた本発明a〜k‘ま、いずれも微細組織
を有し、かつ切刃層と保持層の界面部は良好な密着性を
示すものであった。
All of the resulting inventive materials a to k' of the present invention had a fine structure, and the interface between the cutting edge layer and the holding layer showed good adhesion.

ついで、上記本発明a〜k、および実施例1において比
較の目的で用意したものと同じ比較を、切削チップの切
刃部にろう付けにより取付け、さらにこれをバイトに取
付け、被削材:FC−25 (ブリネル硬さHB:220)、 切削速度:200の/肋、 送り:0.1脚/revへ 切込み:1.仇肌、 の条件で切削試験を行ない、フランク摩耗中が船船 0.15肋に至るまでの切削時間を測定した。
Next, the same comparison as that prepared for the purpose of comparison in the above inventions a to k and Example 1 was attached to the cutting edge of the cutting tip by brazing, and this was further attached to the cutting tool, and the workpiece material: FC -25 (Brinell hardness HB: 220), Cutting speed: 200/rev, Feed: 0.1 leg/rev, Depth of cut: 1. A cutting test was conducted under the following conditions, and the cutting time until the flank wear reached 0.15 ribs was measured.

この測定結果を刃先状態と共に第1表に合せて示した。
第1表に示されるように、本発明切削工具用切刃a〜k
は、いずれもすくれた界面接合強度をもつので、正常摩
耗によりきわめて長い切削時間を確保した上で寿命に達
したのに対して、比較切削工具用切刃においては、切刃
層と保持層との界面接合強度が劣ったものになっている
ので、チッピングを起し、比較的短時間で寿命に至るも
のであつた。なお、上記実施例では切削工具用切刃を基
超硬合金製切削チップの切刃部に取付けて使用した場合
について述べたが、前記切削工具用切刃の形状を大型に
して、そのまま切削チップとして使用してもよいことは
勿論である。
The measurement results are shown in Table 1 along with the state of the cutting edge.
As shown in Table 1, the cutting blades a to k for the cutting tool of the present invention
All of these have low interfacial bonding strength, so they reached the end of their life after securing an extremely long cutting time due to normal wear, whereas the cutting edge of the comparative cutting tool has a cutting edge layer and a retaining layer. Since the strength of the interfacial bond with the material was poor, chipping occurred and the life span was reached in a relatively short period of time. In addition, in the above embodiment, a case was described in which the cutting edge for a cutting tool was attached to the cutting edge portion of a cutting tip made of a base cemented carbide. Of course, it may also be used as

Claims (1)

【特許請求の範囲】 1 60〜97容量%のダイヤモンドを含有するダイヤ
モンド基焼結材料の切刃層と、70〜97容量%の窒化
けい素を含有する窒化けい素基焼結セラミツクスの保持
層との2層複合焼結体からなることを特徴とする切削工
具用切刃。 2 上記ダイヤモンド基焼結材料が、 ダイヤモンド:92〜97容量%、 Fe族金属のうちの1種または2種以上および不可避
不純物:残り、 からなる組成をもつことを特徴とする
上記特許請求の範囲第1項記載の切削工具用切刃。 3 上記ダイヤモンド基焼結材料が、 ダイヤモンド:92〜97容量%、 Si合金および不可避不純物:残り、 からなる組成をもつことを特徴とする上記特許請求の
範囲第1項記載の切削工具用切刃。 4 上記ダイヤモンド基焼結材料が、 ダイヤモンド:60〜97容量%、 周期律表の4aおよび5a族の金属の炭化物、および
窒化物、並びに窒化アルミニウム、炭化けい素、窒化け
い素、さらにこれらの固溶体からなる群のうちの1種ま
たは2種以上および不可避不純物:残り、 からなる組
成をもつことを特徴とする上記特許請求の範囲第1項記
載の切削工具用切刃。 5 上記窒化けい素基焼結セラミツクスが、 窒化けい
素:90〜97容量%、 酸化マグネシウム、酸化アル
ミニウム、および酸化イツトリウムのうちの1種または
2種以上および不可避不純物:残り、 からなる組成を
もつことを特徴とする上記特許請求の範囲第1項、第2
項、第3項、または第4項記載の切削工具用切刃。 6 上記窒化けい素基焼結セラミツクスが、 窒化けい
素:88〜97容量%、 鉄族金属およびSiのうちの
1種または2種以上および不可避不純物:残り、 から
なる組成をもつことを特徴とする上記特許請求の範囲第
1項、第2項、第3項、または第4項記載の切削工具用
切刃。 7 上記窒化けい素基焼結セラミツクスが、 窒化けい
素:70〜97容量%、 窒化アルミニウム、窒化チタ
ン、およびサイアロンのうちの1種または2種以上およ
び不可避不純物:残り、 からなる組成をもつことを特
徴とする上記特許請求の範囲第1項、第2項、第3項、
または第4項記載の切削工具用切刃。
[Scope of Claims] 1. A cutting edge layer of a diamond-based sintered material containing 60 to 97% by volume of diamond, and a retaining layer of silicon nitride-based sintered ceramic containing 70 to 97% by volume of silicon nitride. A cutting blade for a cutting tool characterized by being made of a two-layer composite sintered body. 2. The above claim, wherein the diamond-based sintered material has a composition consisting of: 92 to 97% by volume of diamond, one or more Fe group metals, and the remainder of unavoidable impurities. The cutting blade for a cutting tool according to item 1. 3. The cutting blade for a cutting tool according to claim 1, wherein the diamond-based sintered material has a composition consisting of: 92 to 97% by volume of diamond, the remainder being Si alloy and unavoidable impurities. . 4 The diamond-based sintered material contains: Diamond: 60 to 97% by volume, carbides and nitrides of metals in groups 4a and 5a of the periodic table, aluminum nitride, silicon carbide, silicon nitride, and solid solutions thereof. The cutting edge for a cutting tool according to claim 1, characterized in that it has a composition consisting of one or more of the group consisting of: and the remainder unavoidable impurities. 5 The silicon nitride-based sintered ceramic has a composition consisting of: silicon nitride: 90 to 97% by volume, one or more of magnesium oxide, aluminum oxide, and yttrium oxide, and the remainder: unavoidable impurities. Claims 1 and 2 of the above claims are characterized in that:
The cutting blade for a cutting tool according to item 1, 3, or 4. 6. The silicon nitride-based sintered ceramic has a composition consisting of: silicon nitride: 88 to 97% by volume, one or more of iron group metals and Si, and the remainder: unavoidable impurities. A cutting blade for a cutting tool according to claim 1, 2, 3, or 4 above. 7. The silicon nitride-based sintered ceramic has a composition consisting of: silicon nitride: 70 to 97% by volume, one or more of aluminum nitride, titanium nitride, and sialon, and the remainder: unavoidable impurities. Claims 1, 2, and 3 of the above claims are characterized by:
Or the cutting blade for a cutting tool according to item 4.
JP54138573A 1979-10-26 1979-10-26 Cutting blade for cutting tools Expired JPS6015594B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54138573A JPS6015594B2 (en) 1979-10-26 1979-10-26 Cutting blade for cutting tools

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54138573A JPS6015594B2 (en) 1979-10-26 1979-10-26 Cutting blade for cutting tools

Publications (2)

Publication Number Publication Date
JPS5663882A JPS5663882A (en) 1981-05-30
JPS6015594B2 true JPS6015594B2 (en) 1985-04-20

Family

ID=15225282

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54138573A Expired JPS6015594B2 (en) 1979-10-26 1979-10-26 Cutting blade for cutting tools

Country Status (1)

Country Link
JP (1) JPS6015594B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03264201A (en) * 1990-03-09 1991-11-25 Mitsubishi Heavy Ind Ltd Sintered tool

Also Published As

Publication number Publication date
JPS5663882A (en) 1981-05-30

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