JPS5981376A - オルトケイ酸エステル含有熱伝達流体 - Google Patents
オルトケイ酸エステル含有熱伝達流体Info
- Publication number
- JPS5981376A JPS5981376A JP58181785A JP18178583A JPS5981376A JP S5981376 A JPS5981376 A JP S5981376A JP 58181785 A JP58181785 A JP 58181785A JP 18178583 A JP18178583 A JP 18178583A JP S5981376 A JPS5981376 A JP S5981376A
- Authority
- JP
- Japan
- Prior art keywords
- concentrate
- composition
- composition concentrate
- heat transfer
- orthosilicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 Ortho silicic acid ester Chemical class 0.000 title claims description 29
- 239000013529 heat transfer fluid Substances 0.000 title description 3
- 239000012141 concentrate Substances 0.000 claims description 47
- 239000000203 mixture Substances 0.000 claims description 36
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 238000005260 corrosion Methods 0.000 claims description 10
- 230000007797 corrosion Effects 0.000 claims description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
- 230000002401 inhibitory effect Effects 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 229910052909 inorganic silicate Inorganic materials 0.000 claims description 5
- 230000001476 alcoholic effect Effects 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Chemical class 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical group CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 5
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 10
- 239000000499 gel Substances 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000000872 buffer Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 150000004762 orthosilicates Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 108010053481 Antifreeze Proteins Proteins 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 241001474791 Proboscis Species 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052605 nesosilicate Inorganic materials 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000013100 final test Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US430374 | 1982-09-30 | ||
| US06/430,374 US4460478A (en) | 1982-09-30 | 1982-09-30 | Orthosilicate ester containing heat transfer fluids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5981376A true JPS5981376A (ja) | 1984-05-11 |
| JPS6352072B2 JPS6352072B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-10-17 |
Family
ID=23707286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58181785A Granted JPS5981376A (ja) | 1982-09-30 | 1983-09-29 | オルトケイ酸エステル含有熱伝達流体 |
Country Status (5)
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006510168A (ja) * | 2002-12-12 | 2006-03-23 | ビーエーエスエフ アクチェンゲゼルシャフト | 燃料電池−冷却系用のアゾール誘導体を含有している１，３−プロパンジオールをベースとする冷却剤 |
| WO2020158865A1 (ja) * | 2019-02-01 | 2020-08-06 | 株式会社デンソー | 熱マネジメントシステム |
| JP2023538745A (ja) * | 2020-08-26 | 2023-09-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 低い導電率を有する新規冷却剤 |
| US12148912B2 (en) | 2018-12-26 | 2024-11-19 | Denso Corporation | Vehicle thermal management system, heat transfer medium and method for cooling vehicle driving battery |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4676919A (en) * | 1984-07-23 | 1987-06-30 | First Brands Corporation | Low pH-buffered silicon/silicate antifreeze concentrates |
| US4707286A (en) * | 1985-12-16 | 1987-11-17 | Nalco Chemical Company | Coolant stabilizer |
| AU601050B2 (en) * | 1987-06-16 | 1990-08-30 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Antifreeze composition |
| US5262078A (en) * | 1991-04-12 | 1993-11-16 | Basf Corporation | Corrosion-inhibiting automotive coolant solutions containing effective amounts of sodium silicates and sodium nitrate, and methods of inhibiting corrosion of automotive cooling systems using such coolant solutions |
| US5266228A (en) * | 1991-08-29 | 1993-11-30 | Basf Corporation | Corrosion-inhibiting automotive coolant solutions containing effective amounts of sodium silicate having a low ratio of silica to sodium oxide |
| RU2165444C2 (ru) * | 1996-01-24 | 2001-04-20 | Самарский государственный технический университет | Теплоаккумулирующий состав |
| RU2145624C1 (ru) * | 1998-09-02 | 2000-02-20 | Прокудин Александр Васильевич | Охлаждающая жидкость |
| DE10063951A1 (de) * | 2000-12-20 | 2002-06-27 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben |
| DE10128530A1 (de) * | 2001-06-13 | 2002-12-19 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben enthaltend Azolderivate |
| US7387748B2 (en) * | 2002-12-02 | 2008-06-17 | Texaco Inc. | Antifreeze coolant composition for high temperature applications |
| JP2010530137A (ja) * | 2007-06-15 | 2010-09-02 | エスビーエー マテリアルズ，インコーポレイテッド． | 低ｋ誘電 |
| GB201307765D0 (en) * | 2013-04-30 | 2013-06-12 | Stephano Chm Gvc | Heat transfer liquid composition and energy saving heating method using it |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2349338A (en) * | 1940-06-08 | 1944-05-23 | Carbide & Carbon Chem Corp | Noncorrosive heat-transfer liquid |
| US2335012A (en) * | 1941-04-12 | 1943-11-23 | Little Inc A | High boiling compounds and method of preparing them |
| US2467177A (en) * | 1944-12-30 | 1949-04-12 | Standard Oil Dev Co | Heat exchange media |
| FR1042878A (fr) * | 1950-04-11 | 1953-11-04 | Union Chimique Belge Sa | Procédé d'échange de chaleur au moyen de silicates organiques comme a?nts de transmission thermique |
| DE960043C (de) * | 1954-03-19 | 1957-03-14 | Dow Corning | Antischaummittel fuer Alkohole und diese enthaltende Fluessigkeiten |
| US2815328A (en) * | 1955-02-25 | 1957-12-03 | Nat Aluminate Corp | Corrosion inhibitor composition for aqueous liquids |
| US3198820A (en) * | 1960-12-12 | 1965-08-03 | Union Carbide Corp | Silicone-silicate polymers |
| US3630917A (en) * | 1969-04-07 | 1971-12-28 | Douglas Mcdonnell Corp | Heat transfer composition |
| JPS5456040A (en) * | 1977-09-20 | 1979-05-04 | Otsuka Chem Co Ltd | Metal corrosion preventing composition |
-
1982
- 1982-09-30 US US06/430,374 patent/US4460478A/en not_active Expired - Lifetime
-
1983
- 1983-08-18 CA CA000434845A patent/CA1196490A/en not_active Expired
- 1983-09-29 EP EP83401911A patent/EP0105803B1/en not_active Expired
- 1983-09-29 DE DE8383401911T patent/DE3364204D1/de not_active Expired
- 1983-09-29 JP JP58181785A patent/JPS5981376A/ja active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006510168A (ja) * | 2002-12-12 | 2006-03-23 | ビーエーエスエフ アクチェンゲゼルシャフト | 燃料電池−冷却系用のアゾール誘導体を含有している１，３−プロパンジオールをベースとする冷却剤 |
| JP4944381B2 (ja) * | 2002-12-12 | 2012-05-30 | ビーエーエスエフ ソシエタス・ヨーロピア | 燃料電池−冷却系用のアゾール誘導体を含有している１，３−プロパンジオールをベースとする冷却剤 |
| US12148912B2 (en) | 2018-12-26 | 2024-11-19 | Denso Corporation | Vehicle thermal management system, heat transfer medium and method for cooling vehicle driving battery |
| WO2020158865A1 (ja) * | 2019-02-01 | 2020-08-06 | 株式会社デンソー | 熱マネジメントシステム |
| JP2020126726A (ja) * | 2019-02-01 | 2020-08-20 | 株式会社デンソー | 熱マネジメントシステム |
| JP2023538745A (ja) * | 2020-08-26 | 2023-09-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 低い導電率を有する新規冷却剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| US4460478A (en) | 1984-07-17 |
| DE3364204D1 (en) | 1986-07-24 |
| EP0105803B1 (en) | 1986-06-18 |
| EP0105803A1 (en) | 1984-04-18 |
| CA1196490A (en) | 1985-11-12 |
| JPS6352072B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-10-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4587028A (en) | Non-silicate antifreeze formulations | |
| US4588513A (en) | Non-borate, non-phosphate antifreeze formulations containing dibasic acid salts as corrosion inhibitors | |
| JPS5981376A (ja) | オルトケイ酸エステル含有熱伝達流体 | |
| US5000866A (en) | Antifreeze compositions containing alkane tetracarboxylic acid for use with hard water | |
| US4370255A (en) | Stabilization of aqueous silicates using alkali siliconates of silylalkyl phosphonates | |
| CA1310486C (en) | Corrosion-inhibited antifreeze formulation | |
| US4382008A (en) | Corrosion inhibitors and compositions containing them | |
| US4389371A (en) | Process for inhibiting the corrosion of aluminum | |
| US4382870A (en) | Antifreeze corrosion inhibitor composition for aluminum engines | |
| US4561990A (en) | High lead solder corrosion inhibitors | |
| US5997763A (en) | Corrosion inhibiting antifreeze compositions containing various carboxylic acids | |
| US6045719A (en) | Use of quaternized imidazoles as corrosion inhibitors for non-ferrous metals, and coolant compositions and antifreeze concentrates comprising them | |
| US5422026A (en) | Phosphate-free antifreeze formulation | |
| KR20070116052A (ko) | 부식 방지 특성을 갖는 글리세롤 함유 동결방지 농축물 | |
| JPH05306390A (ja) | 芳香族カルボン酸を含有し腐食抑制性を有する不凍液／冷却液組成物 | |
| KR100190977B1 (ko) | 알칼리 금속 규산염을 함유한 프로필렌 글리콜 부동액의 제조방법 | |
| US4354002A (en) | Novel aliphatic sulfosiloxane-silicate copolymers | |
| EP0248346B1 (en) | Antifreeze concentrates and coolants containing heteropolymolybdate compounds | |
| US5240631A (en) | Antifreeze formulation containing phosphorous acid | |
| US4241014A (en) | Hydroxybenzoic acid as pH buffer and corrosion inhibitor for alkali metal silicate-containing antifreeze compositions | |
| US4676919A (en) | Low pH-buffered silicon/silicate antifreeze concentrates | |
| US4701277A (en) | Silicate-containing antifreeze with carboxy-substituted organosilicon stabilizer | |
| CA1143925A (en) | Stabilization of aqueous silicates using alkali siliconates of silylalkyl phosphonates | |
| US4584119A (en) | Naphthalene dicarboxylic acid salts as corrosion inhibitors | |
| EP0739966A1 (en) | Antifreeze composition and aqueous fluid containing said composition |