JPS5936879B2 - Thermal transfer recording medium - Google Patents
Thermal transfer recording mediumInfo
- Publication number
- JPS5936879B2 JPS5936879B2 JP52123349A JP12334977A JPS5936879B2 JP S5936879 B2 JPS5936879 B2 JP S5936879B2 JP 52123349 A JP52123349 A JP 52123349A JP 12334977 A JP12334977 A JP 12334977A JP S5936879 B2 JPS5936879 B2 JP S5936879B2
- Authority
- JP
- Japan
- Prior art keywords
- transfer recording
- thermal transfer
- recording medium
- thermal
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/41—Base layers supports or substrates
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
【発明の詳細な説明】
本発明は、熱転写記録方式において用いる転写媒体に関
する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a transfer medium used in a thermal transfer recording system.
更に詳しくは、熱転写記録用媒体構成の改良に関する。
多種多様の記録方式が広く実用に供されている現在、中
でもカールソンプロセスを利用した、所謂、プレーン・
ペーパー複写機が市場において急激な成長を遂げている
事実が示すように、消耗品たる記録用紙として、特殊紙
を使用せず、普通紙に転写記録をなす為の記録方式が望
まれるのは、用紙コスト、操作性、記録のフィーリング
、公害衛生等々の観点よりして、時代の趨勢であると言
える。斯かる記録方式にあつて、例えば、電子写真方式
、静電印刷方式を利用した装置は複雑な機構を必要とし
、大型化、又、高コスト化するのを避け得ないと云う欠
点があり、例えば卓上電算機に組み込む為の簡易なプリ
ンター等として応用するには限界がある。他方、装置的
には、比較的簡易なものとして、インクリボンの上から
活字プラテン、・〜ンマー、ワイヤードット等で衝激を
与えて、用紙に印字する、所謂、、インパクト方式の記
録装置が汎用されているのも事実であるが、これ等に共
通する欠点は、印字記録時の騒音が大きい事、メカ的な
稼動部が多い為、印字スピードが上げられない上、部品
の摩耗等による故障が多く、メンテナンスが頻わしい事
、等である。中では比較的欠点が少ないとされているワ
イヤードットインパクト方式の装置とても、大きな電磁
石を多数内蔵する為に、ヘッド部をコンパクト化する事
が困難な上、電磁石を、作動させる為の、大電力を消費
するという問題点を有する。何れにしろ、印字頻度が高
い場合にはインクリボンを頻繁に交換するわずられしさ
があり、又、反復使用のできる厚手のテープを使用する
と、印字品質が著しく劣悪化するという不利がある。又
、一方では斯かるインパクト方式の欠点を除く、所謂、
熱転写記録方式も幾つか提案されている。その一例が特
公昭４９−２６２４５号公報に開示されている。斯かる
技術思想を要約すると、略々、常温においては固相にあ
り、加熱によつて可逆的に液相になるか流動性を持つ如
き印刷用感熱インクを記録紙に印字する印刷機であり、
所定の文字又は図形を発生する如く構成された印刷要素
が前記感熱インクを前記所定の文字又は図形の形に局部
的に加熱して流動性を与え、前記記録紙に印字する機構
を有する事を特徴とする感熱インクを印字する印刷機で
あると理解され、確かに特殊紙を用いない簡易型の熱転
写式印刷機を提供した点、注目に値するものではあるが
、斯かる記録方式においてはインクキャリアを介して熱
像が付与される為、インク層への熱伝達を良くして鮮明
で濃い、即ち良品質の記録をなす為には、インクキャリ
アへのインクの塗布の厚みは極めて薄くする事、更にイ
ンクキャリアそれ自体が非常に薄い膜でなければならな
い事等、かなり厳しい条件の制約を受けるものであり、
その点不利である。又、インクキャリアが非常に薄い膜
である場合に床その機械的強度が低く、使用耐久性に乏
しいと云う不利もある。More specifically, the present invention relates to improvements in the structure of thermal transfer recording media.
Currently, a wide variety of recording methods are widely used in practice, and among them, so-called plain recording methods using the Carlson process
As evidenced by the rapid growth of paper copying machines in the market, it is desirable to have a recording method that allows transfer recording to be made on plain paper without using special paper as a consumable recording paper. From the viewpoints of paper cost, operability, recording feel, pollution and hygiene, etc., it can be said to be the trend of the times. Among such recording methods, for example, devices using electrophotographic methods or electrostatic printing methods have the disadvantage that they require complicated mechanisms and inevitably become larger and more expensive. For example, there are limits to its application as a simple printer that can be incorporated into a desktop calculator. On the other hand, as a relatively simple device, there is a so-called impact-type recording device that prints on paper by applying an impact with a type platen, a printer, a wire dot, etc. from above the ink ribbon. It is true that they are widely used, but the common drawbacks of these are that they make a lot of noise when recording, they have many mechanical moving parts, so printing speed cannot be increased, and parts wear out. There are many breakdowns, frequent maintenance, etc. The wire dot impact method, which is said to have relatively few drawbacks, has many large electromagnets built in, making it difficult to make the head compact, and it requires a large amount of power to operate the electromagnets. The problem is that it consumes a lot of energy. In any case, if the printing frequency is high, it is a hassle to frequently replace the ink ribbon, and if a thick tape that can be used repeatedly is used, there is a disadvantage that the printing quality deteriorates significantly. On the other hand, the so-called method that eliminates the drawbacks of such an impact method,
Several thermal transfer recording methods have also been proposed. An example of this is disclosed in Japanese Patent Publication No. 49-26245. To summarize this technical idea, it is a printing machine that prints on recording paper with thermal ink for printing, which is in a solid phase at room temperature and becomes reversibly liquid or fluid when heated. ,
The printing element configured to generate a predetermined character or figure has a mechanism for locally heating the thermal ink in the shape of the predetermined character or figure to give fluidity and printing on the recording paper. It is understood that it is a printing machine that prints with thermal ink, which is a characteristic feature, and it is certainly worth noting that it provided a simple thermal transfer printing machine that does not use special paper. Since a thermal image is applied via the carrier, the thickness of the ink applied to the ink carrier must be extremely thin in order to improve heat transfer to the ink layer and produce clear, dark, high-quality records. In addition, the ink carrier itself must be a very thin film, and is subject to quite severe restrictions.
In that respect, it is disadvantageous. Another disadvantage is that when the ink carrier is a very thin film, the mechanical strength of the ink carrier is low and the durability in use is poor.
本発明においては斯かる実情に鑑み、上述の如き熱転写
記録方式における転写媒体の改良をなさんとするもので
あり、第１に、転写効率良く、良質の記録をなすことの
できる熱転写記録用媒体を提供することを目的とする。In view of these circumstances, the present invention aims to improve the transfer medium used in the thermal transfer recording method as described above.Firstly, the present invention aims to improve the transfer medium used in the thermal transfer recording method as described above. The purpose is to provide
第２には、連続使用に適した耐久性のある熱転写記録用
媒体を提供することも目的である。上記の目的を達成す
る本発明とは、要するに、多数の貫通孔を有する担体と
前記貫通孔中に保持された熱塑性を示す固形インクとか
ら成ることを特徴とする熱転写記録用媒体である。以下
、本発明をより明瞭ならしめるため、図面を参照しつつ
詳細に説明する。第１図に、本発明熱転写記録用媒体の
一構成例を略示する。A second object is to provide a durable thermal transfer recording medium suitable for continuous use. The present invention, which achieves the above object, is, in short, a thermal transfer recording medium characterized by comprising a carrier having a large number of through holes and a solid ink exhibiting thermoplasticity held in the through holes. Hereinafter, in order to make the present invention more clear, the present invention will be described in detail with reference to the drawings. FIG. 1 schematically shows an example of the structure of the thermal transfer recording medium of the present invention.
第１図ａはその一部を示す平面図、第１図ｂは同側断面
図である。図において、１はステンレス、銅、アルミニ
ウム等の金属板、或いはナイロン、テトロン、テフロン
、アクリル樹脂、ポリカーボネート、ポリイミド、フェ
ノール樹脂等合成樹脂フィルムからなる基板であり、中
でも耐熱性及び可撓性のあるものが好適である。又その
厚さは約１０μから数Ｍｍのもの迄使用可能である。上
記基板１には、円筒状の貫通空孔２が多数穿設されてお
り、斯かる各空孔２中には、加熱により軟化或いは溶融
する常温においては固相にある感熱固形インクが充填さ
れている。第１図に例示した貫通孔の断面形状は円形状
であるが、本発明においては円形状に限らず、矩形状、
楕円状、モザイク状、又はこれ等の組み合わせによる形
状であつても良い。本発明に係る転写記録においては、
前記貫通孔の各々が形成されるべき画像の各画素に相当
する。中でも、使用上好適な貫通孔は、断面径約１００
μ以下の円筒状空孔である。第１図に示した熱転写記録
用媒体の固形インクのキャリアは基板に貫通孔を多数穿
設したものであるが、その他、メッシュ状基体を使用す
ることもできる。例えば、ステンレススチールの細線或
いは耐熱性のある合成繊維等を織ることによる可撓性の
網であり、そのメッシュ値は６０から４００メッシュ程
度である。このような網を使用する場合平織、あや織、
又はしゆす織による網の何れでも良く、更に、それ等の
網を加圧変形させて使用に供しても良い。以上、説明し
た固形インクのキャリア（担体）は第２図に示す如く、
スリーブ状に構成しても良く、又、第３図に示す如く無
端帯状に構成しても良い。FIG. 1a is a plan view showing a part thereof, and FIG. 1b is a sectional view of the same side. In the figure, 1 is a substrate made of a metal plate such as stainless steel, copper, or aluminum, or a synthetic resin film such as nylon, Tetron, Teflon, acrylic resin, polycarbonate, polyimide, or phenol resin. Preferably. Moreover, the thickness can range from about 10 μm to several mm. The substrate 1 is provided with a large number of cylindrical through-holes 2, each of which is filled with heat-sensitive solid ink that is in a solid state at room temperature and softens or melts when heated. ing. Although the cross-sectional shape of the through hole illustrated in FIG. 1 is circular, the present invention is not limited to the circular shape;
The shape may be an ellipse, a mosaic, or a combination thereof. In the transcription recording according to the present invention,
Each of the through holes corresponds to each pixel of the image to be formed. Among them, a through hole suitable for use has a cross-sectional diameter of about 100 mm.
It is a cylindrical hole with a size of less than μ. The solid ink carrier of the thermal transfer recording medium shown in FIG. 1 is a substrate with a large number of through holes, but it is also possible to use a mesh-like substrate. For example, it is a flexible net made by weaving fine stainless steel wire or heat-resistant synthetic fiber, and its mesh value is approximately 60 to 400 mesh. When using such nets, plain weave, twill weave,
Alternatively, it may be a net made of a silk weave, and furthermore, such a net may be used after being deformed under pressure. The solid ink carrier described above is as shown in Figure 2.
It may be constructed in the shape of a sleeve, or it may be constructed in the shape of an endless band as shown in FIG.
その時、前記キャリアの素材が可撓性を示すことは取扱
い上好都合である。本発明で使用する感熱固形インクは
染料、顔料等の色剤と、ろう様物質の単独或いは更に熱
可塑性樹脂とから組成されたものである。ろう様物質と
しては蜜ロウや鉱物油もしくは植物油等の油脂類が使用
できるが、例えば、マイクロクリスタリンワックス、カ
ルナウバワツクス、水素化ひまし油ワックス等のワック
ス類、ミリスチン酸、ステアリン酸、パルミチン酸、ベ
ヘン酸の如き、高級脂肪酸とその金属塩、その他、ステ
アリン酸モノグリセロール、パラフィン、ポリエチレン
グリコール、尿素、ベンズアミド、アセトアニリドベン
ズトリアゾール、フエナセチン、ジメドンビスフエノー
ルＡ等が更に具体的に挙げられる。熱可塑性樹脂として
は、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリビニル
ホルマール、ポリビニルブチラール、ポリビニルアルコ
ール、ポリビニルアセタール、ポリカーボネート、ポリ
スチレン、クマロン樹脂、塩化ビニルとアクリル酸エス
テルとの共重合体等が使用できる。色剤としては染料、
顔料の他、加熱された後着色する成分を使用することが
できる。At this time, it is convenient for handling that the carrier material exhibits flexibility. The heat-sensitive solid ink used in the present invention is composed of a colorant such as a dye or a pigment, and a wax-like substance alone or a thermoplastic resin. As the wax-like substance, beeswax, oils and fats such as mineral oil or vegetable oil can be used, and examples thereof include waxes such as microcrystalline wax, carnauba wax, hydrogenated castor oil wax, myristic acid, stearic acid, palmitic acid, More specific examples include higher fatty acids and metal salts thereof such as behenic acid, monoglycerol stearate, paraffin, polyethylene glycol, urea, benzamide, acetanilide benztriazole, phenacetin, dimedone bisphenol A, and the like. As the thermoplastic resin, polyvinyl chloride, polyvinylidene chloride, polyvinyl formal, polyvinyl butyral, polyvinyl alcohol, polyvinyl acetal, polycarbonate, polystyrene, coumaron resin, copolymer of vinyl chloride and acrylic ester, etc. can be used. Dye as a coloring agent,
In addition to pigments, components that color after being heated can be used.
例えば、長鎖脂肪酸鉄塩（たとえばステアリン酸第２鉄
、ミリスチン酸第２鉄）と、フェノール類（タンニン酸
、没食子酸、サルチル酸アンモニウム）又、有機貴金属
塩（ベヘン酸銀、ステアリン酸銀）と芳香族有機還元剤
（プロトカテキン酸、ハイドロキノン）、又、クリスタ
ルバイオレットラクトン等のラクトン類とフェノール類
（ビスフェノールＡ）フェノール樹脂）又、レゾルシン
とニトロノ化合物、又、テトラゾリウム塩と還元剤と塩
基などを例とする多成分系感熱発色剤、尿素誘導体など
のアミン発生剤とＰＨ指示薬又、アミン発生剤とジアゾ
化合物とカプラー、又、置換ベンゼンジアゾニウムクル
オボレートと多価フェノールとニトロソ化合物、アミン
発生剤とフッ化黒鉛など、ある温度になると熱分解が急
激におき、その熱分解物と発色反応をおこす物質の組み
合わせによる熱分解反応成分系、インドール誘導体ピロ
ロン誘導体、置換アミノジチオ蟻酸の重金属塩など単独
で熱により発色する単独発色系成分などがあげられる。For example, long-chain fatty acid iron salts (e.g. ferric stearate, ferric myristate), phenols (tannic acid, gallic acid, ammonium salicylate) and organic noble metal salts (silver behenate, silver stearate). and aromatic organic reducing agents (protocatechuic acid, hydroquinone), lactones such as crystal violet lactone, phenols (bisphenol A, phenolic resins), resorcinol and nitron compounds, tetrazolium salts, reducing agents and bases, etc. Examples include multi-component thermosensitive color formers, amine generators such as urea derivatives and PH indicators, amine generators, diazo compounds and couplers, substituted benzene diazonium clooborates, polyhydric phenols, nitroso compounds, and amine generators. When a certain temperature is reached, thermal decomposition occurs rapidly, such as fluorinated graphite, and the thermal decomposition reaction component system is a combination of the thermal decomposition product and a substance that causes a coloring reaction. Examples include single color-forming components that develop color when heated.
以上の成分が熱時混練され、それが軟化或いは溶融状態
にある間に、前述のキャリア中の空孔中に塗布、浸漬等
の手法により充填される。The above components are hot kneaded, and while the mixture is in a softened or molten state, it is filled into the pores in the carrier by coating, dipping, or other methods.
斯かる固形インクは、加熱源としてサーマル・ヘッドを
使用する際、ヘッドの加熱に充分応答できるよう約４０
℃乃至２００℃、特に好ましくは約４０℃乃至１６０℃
の温度範囲で熱塑性を示すよう予め、その組成比を規定
しておくことが望ましい。本発明に係る熱転写記録に際
しては、情報源としての熱が、固形インクに対して直接
印加される為情報伝達の効率が良く、固形インクの転写
を確実に行なうことができる。又それに要する熱量も従
来の方式に較べて少なくてすみ、経済的である。更に本
発明の熱転写記録用媒体においては、熱変質、変形の恐
れがなく、使用耐久性に富むものであり連続使用に適し
ている。ここで、本発明熱転写記録用媒体の適用例を図
面に添つて説明する。Such solid ink has a temperature of about 40 ml to sufficiently respond to the heating of the thermal head when the thermal head is used as a heating source.
°C to 200 °C, particularly preferably about 40 °C to 160 °C
It is desirable to specify the composition ratio in advance so that it exhibits thermoplasticity in the temperature range of . In thermal transfer recording according to the present invention, heat as an information source is directly applied to the solid ink, so information transmission is efficient and the solid ink can be transferred reliably. Also, the amount of heat required for this is less than that of conventional methods, making it economical. Further, the thermal transfer recording medium of the present invention has no fear of thermal deterioration or deformation, has excellent durability in use, and is suitable for continuous use. Here, an example of application of the thermal transfer recording medium of the present invention will be explained with reference to the drawings.
第４図は熱情報源として輻射線を利用して転写記録を行
なう方法を示しており、先に例示した如き熱転写記録用
媒体３と被転写媒体４としての紙、樹脂フィルム等とを
重ね合わせ、熱転写記録用媒体３側から熱情報５を印加
し、情報５に対応する箇所に感熱固形インク６の転写を
なす方法を略画断面図により示した。FIG. 4 shows a method of performing transfer recording using radiation as a thermal information source, in which a thermal transfer recording medium 3 as exemplified above and paper, resin film, etc. as a transfer medium 4 are superimposed. , a method of applying thermal information 5 from the thermal transfer recording medium 3 side and transferring heat-sensitive solid ink 6 to a location corresponding to the information 5 is shown by a schematic cross-sectional view.
なお、熱情報５を与える手段又は機器としては、キセノ
ン、ハロゲン等を例とするフラッシュ光源、タングステ
ンランプ等を例とする赤外線ランプ、炭酸ガス、半導体
、アルゴン等を例とするレーザー光源等を挙げることが
できるが、中でも望ましくは熱パターン以外の場所に゛
゜かぷり’’を生じさせぬうちに、所定のパターンにの
み高強度の輻射線を照射出来るものが良い。その点でフ
ラッシュ光源、レーザー光源等が望ましいものと言える
。又、熱転写記録用媒体３と被転写媒体４とは図示の如
く多少の間隔を置いて配されてもよく、密着した状態で
配されてもよい。Examples of means or devices for providing thermal information 5 include flash light sources such as xenon and halogen, infrared lamps such as tungsten lamps, laser light sources such as carbon dioxide, semiconductors, argon, etc. However, it is preferable to use a device that can irradiate high-intensity radiation only to a predetermined pattern without causing any "scabbing" in areas other than the heat pattern. In this respect, flash light sources, laser light sources, etc. are preferable. Further, the thermal transfer recording medium 3 and the transfer medium 4 may be arranged with some spacing as shown in the figure, or may be arranged in close contact with each other.
第５図により又別の方法を示す。Another method is shown in FIG.
斯かる方法においては、先ず電源部Ｔより発生した信号
が図示していない電気回路を経て熱ヘッド８に伝わり、
ここで熱ヘッド８に含まれる抵抗体が発熱し、その接触
箇所にある感熱固形インク６が第４図示例の場合と同様
に被転写媒体４上に転写される。本図示例において使用
する熱ヘッド８としては、蒸着法により抵抗体を構成す
るいわゆる薄膜ヘッド、スクリーン印刷等の方法により
抵抗体を構成する厚膜ヘッド、半導体作成手法により抵
抗体を構成する半導体ヘッド等がある。本発明において
は、感熱固形インクが転写によソー部欠如した熱転写記
録用媒体の空孔に再度、軟化或いは溶融状態にある感熱
インクを充填して固化したものを再度使用或いは連続使
用に供することもできる。In this method, first, a signal generated from the power source T is transmitted to the thermal head 8 via an electric circuit (not shown),
Here, the resistor included in the thermal head 8 generates heat, and the heat-sensitive solid ink 6 at the contact point is transferred onto the transfer medium 4 as in the case of the fourth illustrated example. The thermal head 8 used in this illustrated example includes a so-called thin film head that constructs a resistor by a vapor deposition method, a thick film head that constructs a resistor by a method such as screen printing, and a semiconductor head that constructs a resistor by a semiconductor manufacturing method. etc. In the present invention, the thermal ink in a softened or molten state is filled again into the holes of the thermal transfer recording medium where the heat-sensitive solid ink has been removed due to the transfer, and the solid ink is used again or for continuous use. You can also do it.
更に実施例を挙げて本発明を詳述する。Further, the present invention will be explained in detail by giving examples.
実施例１
直径５０μの円型空孔を１００μピッチでスクリーン状
にエッチングされたステンレスメッシュを用い、これに
下記組成の分散液を塗布し乾燥して転写記録用媒体を作
成した。Example 1 A transfer recording medium was prepared by using a stainless steel mesh in which circular holes with a diameter of 50 μm were etched at a pitch of 100 μm in the form of a screen, and a dispersion liquid having the following composition was applied thereto and dried.
この媒体と上質紙とを重ねて第４図のようにパターン状
にキセノンフラッシュ光を、理想科学社製のゼノフアツ
クスー１５０を用いて１／１０００秒間照射した所、光
の当つた所のメッシュ孔中のインクが紙の方へ転写され
、その部分のメッシュ孔は空となつた。This medium and high-quality paper were overlapped, and xenon flash light was irradiated in a pattern as shown in Figure 4 for 1/1000 seconds using Xenofax 150 manufactured by Riso Kagaku. The ink was transferred to the paper, and the mesh holes in that area became empty.
紙に転写されたインクはそのままで紙の面に固着されド
ットパターンを形成した。実施例２線径３０μ、１００
μピッチのステンレスブレス金網のメッシュ空孔に下記
組成の染料とバインダーの溶液をうめこみ、乾燥して転
写用媒体を作成した。The ink transferred to the paper remained fixed to the surface of the paper, forming a dot pattern. Example 2 Wire diameter 30μ, 100
A dye and binder solution having the following composition was filled into the mesh pores of a μ-pitch stainless steel wire mesh and dried to prepare a transfer medium.
この転写用媒体と上質紙を重ねて、第４図のように転写
用媒体側からスポット径５０μ、出力５００ｍＷのアル
ゴン−イオンレーザーを１／１０００秒間照射した所、
転写用媒体の空孔中にうめこまれていたカーボンとワッ
クスの混合物が紙の方に転写され固着された。This transfer medium and high-quality paper were stacked, and an argon-ion laser with a spot diameter of 50 μm and an output of 500 mW was irradiated from the transfer medium side for 1/1000 seconds as shown in Figure 4.
The mixture of carbon and wax embedded in the pores of the transfer medium was transferred and fixed to the paper.
実施例３
実施例１と同様にメッシュの空孔中に下記分散液をうめ
こみ乾燥して、転写用媒体を得た。Example 3 In the same manner as in Example 1, the following dispersion was filled into the pores of a mesh and dried to obtain a transfer medium.
この転写用媒体と紙を重ねて転写用媒体側からスポット
径５０μ、出力１００ｍＷのＹＡＧレーザーを１０ｍ／
Ｓｅｃのスピードで走査した所、レーザーの照射された
所の空孔中のカーボンブラックは、紙に転写され固着さ
れた・ 一方・該転写用媒体はレーザー光の当つた所は
空孔となつていた。この画像状に空孔を有する転写用媒
体と、新たに用意した紙とを重ねて転写用媒体側から孔
板印刷用インクを、ローラー等で全面に付与した所、画
像状に空孔となつた所から紙にインクがしみ込んで孔板
印刷がなされた。実施例４
実施例２と同様にして作成された転写用媒体をエンドレ
スベルト状に加工し、アルゴンイオンレーザー（出力５
００ｍＷ）スポット径５０μ）で走査し、紙へ染料を転
写した。This transfer medium and paper are overlapped, and a YAG laser with a spot diameter of 50μ and an output of 100mW is emitted from the transfer medium side for 10m/10m.
When scanning at a speed of Sec, the carbon black in the holes where the laser beam was irradiated was transferred and fixed to the paper. On the other hand, the transfer medium had holes where the laser beam hit. Ta. When this transfer medium with holes in the image form and a newly prepared paper are overlapped and ink for perforated plate printing is applied to the entire surface from the transfer medium side using a roller, holes appear in the image form. The ink soaked into the paper from where it was, creating hole-plate printing. Example 4 A transfer medium created in the same manner as in Example 2 was processed into an endless belt shape, and an argon ion laser (output 5
The dye was transferred to the paper by scanning with a spot diameter of 00 mW) and a spot diameter of 50 μ.
次いで、実施例２と同様の染料とバインダーからなる染
料溶液を転写用媒体に付与して、転写後の空孔となつた
部分に再度染料をうめこみ、乾燥して元の転写用媒体に
再生し、また転写記録を行なう工程をくり返して記録を
連続的に行なつた所、良好な結果を得た。Next, a dye solution consisting of the same dye and binder as in Example 2 is applied to the transfer medium, and the dye is filled into the voids after transfer, and the dye is dried to regenerate the original transfer medium. However, good results were obtained when the transfer recording process was repeated and recording was performed continuously.
【図面の簡単な説明】
第１図ａ及びｂ、第２図、第３図は夫々本発明熱転写記
録用媒体の構成例を説明する略式図であり、第４図及び
第５図は本発明熱転写記録用媒体の使用例を説明するた
めの略画断面図である。
図において、１ ・・・・・・基板、２・・・・・・貫
通空孔、３・・・・・・熱転写記録用媒体、４・・・・
・・被転写媒体、６・・・・・・感熱固形インク。[BRIEF DESCRIPTION OF THE DRAWINGS] FIGS. 1 a and b, 2, and 3 are schematic diagrams illustrating an example of the structure of the thermal transfer recording medium of the present invention, and FIGS. FIG. 2 is a schematic cross-sectional view for explaining an example of use of a thermal transfer recording medium. In the figure, 1...Substrate, 2...Through holes, 3...Thermal transfer recording medium, 4...
... Transfer medium, 6... Heat-sensitive solid ink.
Claims (1)
れた熱塑性を示す固形インクとから成ることを特徴とす
る熱転写記録用媒体。 ２ 貫通孔が円筒形状をなす特許請求の範囲第１項記載
の熱転写記録用媒体。 ３ 担体が回転体形状或いは無端帯状をなす特許請求の
範囲第１項記載の熱転写記録用媒体。 ４ 担体が耐熱性材料により構成されている特許請求の
範囲第１項記載の熱転写記録用媒体。 ５ 担体が可撓性を示す特許請求の範囲第１項記載の熱
転写記録用媒体。 ６ 固形インクが、ろう様物質と熱可塑性樹脂の何れか
一方、又は両方と色剤を含む組成物から成る特許請求の
範囲第１項記載の熱転写記録用媒体。 ７ 固形インクが、４０℃乃至２００℃の温度範囲で熱
塑性を示すものである特許請求の範囲第１項記載の熱転
写記録用媒体。[Scope of Claims] 1. A thermal transfer recording medium comprising a carrier having a large number of through holes and a thermoplastic solid ink held in the through holes. 2. The thermal transfer recording medium according to claim 1, wherein the through hole has a cylindrical shape. 3. The thermal transfer recording medium according to claim 1, wherein the carrier is in the shape of a rotating body or an endless belt. 4. The thermal transfer recording medium according to claim 1, wherein the carrier is made of a heat-resistant material. 5. The thermal transfer recording medium according to claim 1, wherein the carrier exhibits flexibility. 6. The thermal transfer recording medium according to claim 1, wherein the solid ink comprises a composition containing a wax-like substance, a thermoplastic resin, or both, and a coloring agent. 7. The thermal transfer recording medium according to claim 1, wherein the solid ink exhibits thermoplasticity in a temperature range of 40°C to 200°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP52123349A JPS5936879B2 (en) | 1977-10-14 | 1977-10-14 | Thermal transfer recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP52123349A JPS5936879B2 (en) | 1977-10-14 | 1977-10-14 | Thermal transfer recording medium |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58092881A Division JPS58212993A (en) | 1983-05-26 | 1983-05-26 | Thermal transfer recording method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5456847A JPS5456847A (en) | 1979-05-08 |
| JPS5936879B2 true JPS5936879B2 (en) | 1984-09-06 |
Family
ID=14858357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52123349A Expired JPS5936879B2 (en) | 1977-10-14 | 1977-10-14 | Thermal transfer recording medium |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5936879B2 (en) |
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-
1977
- 1977-10-14 JP JP52123349A patent/JPS5936879B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5456847A (en) | 1979-05-08 |
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