JPS59163342A - ジカルボン酸ポリエ−テル誘導体をアルカリ土類金属イオン輸送担体とする陽イオン移送方法 - Google Patents
ジカルボン酸ポリエ−テル誘導体をアルカリ土類金属イオン輸送担体とする陽イオン移送方法Info
- Publication number
- JPS59163342A JPS59163342A JP58038636A JP3863683A JPS59163342A JP S59163342 A JPS59163342 A JP S59163342A JP 58038636 A JP58038636 A JP 58038636A JP 3863683 A JP3863683 A JP 3863683A JP S59163342 A JPS59163342 A JP S59163342A
- Authority
- JP
- Japan
- Prior art keywords
- solution
- compound
- cation
- formula
- ionophore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001768 cations Chemical class 0.000 title claims abstract description 51
- 238000012546 transfer Methods 0.000 title claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 title claims description 19
- 229920000570 polyether Polymers 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 10
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 title abstract description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 title description 2
- 239000002555 ionophore Substances 0.000 claims abstract description 17
- 230000000236 ionophoric effect Effects 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 150000002170 ethers Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 abstract description 16
- 150000002500 ions Chemical class 0.000 abstract description 10
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 125000006239 protecting group Chemical group 0.000 abstract description 2
- ULGYXJGQQGEELN-UHFFFAOYSA-N 2-[3-(4-tert-butylphenoxy)propoxy]benzoic acid Chemical compound C1=CC(C(C)(C)C)=CC=C1OCCCOC1=CC=CC=C1C(O)=O ULGYXJGQQGEELN-UHFFFAOYSA-N 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 63
- 230000032258 transport Effects 0.000 description 19
- 238000012360 testing method Methods 0.000 description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910001425 magnesium ion Inorganic materials 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011575 calcium Substances 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- -1 t-butoxy, sodium hydride Chemical compound 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000860832 Yoda Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 229910001422 barium ion Inorganic materials 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 230000037427 ion transport Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 108010087204 oncoimmunin-M Proteins 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups
Landscapes
- Treatment Of Liquids With Adsorbents In General (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58038636A JPS59163342A (ja) | 1983-03-08 | 1983-03-08 | ジカルボン酸ポリエ−テル誘導体をアルカリ土類金属イオン輸送担体とする陽イオン移送方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58038636A JPS59163342A (ja) | 1983-03-08 | 1983-03-08 | ジカルボン酸ポリエ−テル誘導体をアルカリ土類金属イオン輸送担体とする陽イオン移送方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59163342A true JPS59163342A (ja) | 1984-09-14 |
| JPH0114897B2 JPH0114897B2 (enrdf_load_stackoverflow) | 1989-03-14 |
Family
ID=12530725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58038636A Granted JPS59163342A (ja) | 1983-03-08 | 1983-03-08 | ジカルボン酸ポリエ−テル誘導体をアルカリ土類金属イオン輸送担体とする陽イオン移送方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59163342A (enrdf_load_stackoverflow) |
-
1983
- 1983-03-08 JP JP58038636A patent/JPS59163342A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0114897B2 (enrdf_load_stackoverflow) | 1989-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4388451A (en) | Polymers derived from allylphenol or substituted allylphenol and maleic anhydride | |
| Ichinari et al. | A novel approach to functionalization of aryl azides through the generation and reaction of organolithium species bearing masked azides in flow microreactors | |
| Verbelen et al. | Radical C H Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids | |
| TW201768B (enrdf_load_stackoverflow) | ||
| JP2005507004A (ja) | 芳香族イミド化合物および芳香族メチリジントリススルホニル化合物並びにその製造方法 | |
| Akae et al. | Effective synthesis and modification of α‐cyclodextrin‐based [3] rotaxanes enabling versatile molecular design | |
| JPS58146567A (ja) | イオノフオアとして有用なポリエ−テル誘導体 | |
| US4022712A (en) | Catalyzed hydrazine compound corrosion inhibiting composition containing complex of metal salt and amino derivative of carboxylic acid, and its use | |
| GB1450758A (en) | Process for the production of salts of poly-a-hydroxyacrylic acids | |
| JPS59163342A (ja) | ジカルボン酸ポリエ−テル誘導体をアルカリ土類金属イオン輸送担体とする陽イオン移送方法 | |
| KR880011223A (ko) | 폴리아릴렌설피드의 제조방법 | |
| US2769819A (en) | Alkylene-diazides | |
| Eaborn et al. | Effects of varying the media for base cleavage of some Benzyl-silicon and-tin compounds in alcohols | |
| US3796727A (en) | Synthesis of novel benzopyran compounds | |
| Rashidbaigi et al. | Synthesis and characterization of iodoazidobenzylpindolol | |
| US2520400A (en) | Production of sulfenamides | |
| Gao et al. | Manganese‐Mediated Electrooxidative Ring‐Opening Azidation of Cyclobutanol Derivatives with TMSN3 | |
| Takeuchi et al. | Thermolysis and photolysis of 1-anilino-2-methyl-4, 6-diphenylpyridinium tetrafluoroborate in arene–trifluoroacetic acid mixtures: a novel route to singlet and triplet phenylnitrenium ions | |
| US3856523A (en) | Process for preparing lithographic plates | |
| US2514328A (en) | Polyvinylisocyanate and derivatives thereof | |
| GB1454339A (en) | Dye bleach preparation for the photographic silver dye bleach process | |
| Keller et al. | Reactions of diborane with aromatic heterocycles. 3. Diborane-catalyzed polymerization of imidazole-borane | |
| US5319143A (en) | Bis(aminoethanethiols) | |
| JPS6272683A (ja) | １４−クラウン−４誘導体、金属イオン抽出比色試薬および液膜輸送剤 | |
| AU650149B2 (en) | Method for the preparation of 3,4-dihydroxy-5-nitrobenzaldehyde |