JPS59107861A - Manufacture of cutting grindstone - Google Patents

Manufacture of cutting grindstone

Info

Publication number
JPS59107861A
JPS59107861A JP21756282A JP21756282A JPS59107861A JP S59107861 A JPS59107861 A JP S59107861A JP 21756282 A JP21756282 A JP 21756282A JP 21756282 A JP21756282 A JP 21756282A JP S59107861 A JPS59107861 A JP S59107861A
Authority
JP
Japan
Prior art keywords
abrasive grains
parts
cutting
core
superhard abrasive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21756282A
Other languages
Japanese (ja)
Inventor
Kimitsugu Itou
伊藤 公「つぐ」
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Seito Co Ltd
Original Assignee
Fuji Seito Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Seito Co Ltd filed Critical Fuji Seito Co Ltd
Priority to JP21756282A priority Critical patent/JPS59107861A/en
Publication of JPS59107861A publication Critical patent/JPS59107861A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0018Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by electrolytic deposition

Abstract

PURPOSE:To manufacture easily an extremely thin cutting grindstone, in which superhard abrasive grains will never be dropped easily, by a method wherein an annular metallic thin plate is provided with an extremely thin grindstone supporting core at the circumferential rim thereof and the superhard abrasive grains of diamond or the like are bonded on the core electrically in order to form a cutting edge part. CONSTITUTION:Masking layers are formed remaining the rim parts of the front and rear surfaces of the annular metallic thin plate 1 as exposed parts, thereafter, the exposed parts are etched to form the extremely thin abrasive grains supporting parts 2. The extremely fine superhard abrasive grains 3 of diamond, cubic crystallizable boron nitride or the like are bonded electrically on the front and rear surfaces of said core parts 2 so as to be thicker than the thickness of the metallic thin plate 1, thereafter, the masking layers are removed to manufacture the cutting grindstone. In this case, the superhard abrasive grains 3 are bonded electrically by utilizing a metal, separated out of the core by the electric bonding, as a binding agent 5 to form the cutting edge parts. According to this method, the extremely thin cutting grindstone, in which the superhard abrasive grains 3 will never be dropped out easily, may be manufactured easily.

Description

【発明の詳細な説明】 本発明は硬質材の切断や溝切シに使用される極薄の切断
砥石の製造法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing an ultra-thin cutting wheel used for cutting or grooving hard materials.

硬質材の切断や溝切りに使用される極薄の切断砥石とし
ては環状の金属薄板の周縁刃部に多数の小切欠を鋸歯状
に設けてこの各小切欠にダイヤモンド、立方晶窒化硼素
などの極微細な超硬砥粒を合成樹脂結合剤により付着さ
せたものが知られているが、このような切断砥石は超硬
砥粒が鋸歯状の歯相互間に合成樹脂結合剤により付着さ
せているため、使用中研削熱や振動によって脱落する欠
点があシ、このような欠点がない切断砥石を安価に提供
できる切断砥石の製造法が業界において強く要望されて
いる。
As an ultra-thin cutting wheel used for cutting hard materials and grooving, a large number of small notches are provided in the peripheral edge of an annular thin metal plate in a serrated manner, and each small notch is injected with diamond, cubic boron nitride, etc. It is known that ultra-fine carbide abrasive grains are attached with a synthetic resin binder. Therefore, there is a drawback that the grinding wheel falls off due to grinding heat and vibration during use, and there is a strong demand in the industry for a method of manufacturing a cutting wheel that can provide a cutting wheel that does not have such a drawback at a low cost.

本発明は前記のような要望に応えた切断砥石の製造法を
目的として完成されたもので、環状の金属薄板の表裏面
の周縁刃部を露呈部として残してマスキング層を形成し
たうえ腐食液により該露呈部を腐食させて極薄な砥粒支
持芯材部とし、次いで該砥粒支持芯材部の表裏面に金属
薄板の厚さよりも厚くダイヤモンド、立方晶窒化硼素な
どの極微細な超硬砥粒をfi電着後マスキング層を除去
することを特徴とするものである。
The present invention has been completed with the aim of producing a cutting wheel that meets the above-mentioned demands.The present invention was completed with the aim of producing a cutting wheel that meets the above-mentioned demands. The exposed part is corroded to form an ultra-thin abrasive support core part, and then an extremely fine ultra-fine material such as diamond or cubic boron nitride is coated on the front and back surfaces of the abrasive support core part to be thicker than the thickness of the thin metal plate. This method is characterized in that the masking layer is removed after fi electrodeposition of hard abrasive grains.

本発明において使用される環状の金属薄板としては鉄板
、燐青銅板等を環状に打抜いた厚さ02〜/、0朋程度
の極薄のものが一般的であって、この環状の金属薄板は
先ず洗浄後ポリアミド樹脂をベースとしてこれに感光性
を付与した写真製版用の感光性樹脂を該金属薄板の表裏
両面に塗布、乾燥させる。次いで、周縁刃部に砥粒支持
芯材部に相当する部分が濃色に非透光部として現像され
ているネガフィルムを金属薄板の表面の感光性樹脂面に
密着焼き付けて砥粒支持芯材部に相当する部分を除き露
光させて現像すれば、感光性樹脂は露光部分が不溶解部
分として残されてマスキング層を形成するが、露光され
なかった砥粒支持芯材部に相当する部分は溶解して露呈
部としてあられれることとなる。次に、このマスキング
層が表裏両面に形成された金属薄板を塩化第二鉄水溶液
などの腐食液中に浸漬するか、該腐食液を表裏両面にス
プレーして金属薄板の表裏両面のうちマスキング層の形
成されていない露呈部のみを腐食させれば、該露呈部は
さらに極薄の砥粒支持芯材部となゐから、これを洗浄後
前記の感光性樹脂を該砥粒支持芯材部の表裏両面に塗布
、乾燥させ、ついで、必要に応じて砥粒保持用の形状に
相当する部分として砥粒保持用の孔部または砥粒充填用
の小凹部に相当する部分が濃色に非透光部として多数所
定間隔をおいて配設されているネガフィルムを砥けて砥
粒保持用の形状に相当する部分を除き露光させるととも
に裏面の感光性樹脂面にも砥粒保持用の孔部として貫通
孔を得ようとする部分は対称位置に重な9砥粒充填用の
小凹部を得ようとする部分はmJ記6色の非透光部の各
々が表面の露光されなかった部分の相互間に位置するよ
うに作成したネガフィルムを表面のパターンに整合させ
て密着焼き付けて現像し、マスキング層と露呈部とを形
成したうえ前記と同様な操作により腐食を行えば、極め
て肉薄の所要の砥粒支持芯材部を有する環状金属極薄板
が得られることとなるから、これを洗浄したのち砥粒支
持芯材部のマスキング材のみを除去し、その他のマスキ
ング材は除去することなくダイヤモンド、立方晶窒化硼
素などの平均粒径が約toμ以下の極微細な超硬砥粒を
底に敷き詰めたメッキ浴中の該超硬砥粒の層に埋め込ん
で該砥粒支持芯材部の両面および先端面に極微細な超硬
砥粒を電着すれば、マスキング層の塗着されていない砥
粒部分のみに結合剤としてのメッキ金属が析出して前記
超硬砥粒は砥粒支持芯材部に強固に固着されるから、そ
の後溶剤によシ該マスキング層を除去してラッピングな
どの仕上加工を施せば、ここに従来の製造法によっては
得ることのできない極薄のものでも極めて容易に量産で
きることとなる。なお、環状の金属薄板に設ける砥粒支
持芯材部を環状の金属薄板の外周に設けても内周に設け
ても製造法は同様である。
The annular thin metal plate used in the present invention is generally an extremely thin one with a thickness of about 02 to 0 mm, which is obtained by punching an iron plate, phosphor bronze plate, etc. into an annular shape. First, after washing, a photosensitive resin for photolithography, which is made of polyamide resin as a base and has been imparted with photosensitivity, is applied to both the front and back surfaces of the thin metal plate and dried. Next, a negative film in which the portion corresponding to the abrasive grain supporting core material is developed into a dark non-transparent region on the peripheral blade portion is baked in close contact with the photosensitive resin surface of the surface of the thin metal plate to form the abrasive grain supporting core material. If the photosensitive resin is exposed and developed, the exposed portion will remain as an insoluble portion and form a masking layer, but the portion corresponding to the abrasive support core material that was not exposed will be exposed and developed. It will dissolve and appear as an exposed part. Next, the thin metal plate with this masking layer formed on both the front and back sides is immersed in a corrosive liquid such as an aqueous ferric chloride solution, or the corrosive liquid is sprayed on both the front and back sides of the thin metal plate to form a masking layer on both the front and back sides. If only the exposed part where no . Apply the coating to both the front and back surfaces, dry it, and then, if necessary, remove the dark color from the part corresponding to the shape for holding the abrasive grains or the small concave part for filling the abrasive grains. A large number of negative films are arranged at predetermined intervals as transparent parts, and the parts corresponding to the shape for holding abrasive grains are removed and exposed, and holes for holding abrasive grains are also formed on the photosensitive resin surface on the back side. The part where a through hole is to be obtained overlaps in a symmetrical position.The part where a small concave part for filling abrasive grains is to be obtained is an unexposed part of the surface where each of the non-transparent parts of the six colors shown in mJ is. By aligning the negative film with the surface pattern, baking it in close contact with the surface pattern, and developing it to form a masking layer and an exposed area, and then corroding it in the same manner as above, an extremely thin layer can be created. Since an annular ultra-thin metal plate having the required abrasive grain supporting core material part is obtained, after cleaning this, only the masking material of the abrasive grain supporting core material part is removed, without removing other masking materials. Ultra-fine ultra-hard abrasive grains such as diamond or cubic boron nitride with an average grain size of about toμ or less are embedded in a layer of the ultra-hard abrasive grains in a plating bath at the bottom, and the abrasive support core material is If ultra-fine carbide abrasive grains are electrodeposited on both sides and the tip surface, the plating metal as a binder will precipitate only on the abrasive grain parts that are not coated with the masking layer, and the carbide abrasive grains will support the abrasive grains. Since it is firmly fixed to the core material, if the masking layer is then removed using a solvent and finishing processing such as wrapping is applied, even ultra-thin products that cannot be obtained using conventional manufacturing methods can be made. This means that it can be mass-produced easily. Note that the manufacturing method is the same whether the abrasive grain supporting core portion provided on the annular thin metal plate is provided on the outer periphery or the inner periphery of the annular thin metal plate.

このようにして製造された切断砥石は図示するように、
環状の金属薄板(1)の周縁刃部に極薄な砥粒支持芯材
部(2)を設け、ここにダイヤモンド、立方晶窒化硼素
等の平均粒径が≠Oμ以下の極微細な超硬砥粒(3)を
電着によシ析出する金属を結合剤(5)として[電着し
た切断用エツジ部に形成されているから、環状の金属薄
板(1)の取付孔(4)をもって砥石車軸に取付けて高
速回転させたうえ該金属薄板(1)の周縁刃部に被加工
物を接すると、該超硬砥粒(3)の発揮する切断作用に
よって良好な切味および加工精度を備えていて良好な硬
質材の切断や溝切り作業を行うことができ、しかも、環
状の金属薄板(1)の周縁刃部の砥粒支持芯材部に必要
に応じ砥粒保持用の孔部または小凹部を配設しておくこ
とによって砥粒支持芯材部(2)に充填された超硬砥粒
(3)は電着金属によって強固に極薄の砥粒支持芯材部
(2)に固着され、回転時に金属薄板(1)の周縁に加
えられる一方向への力によっても最後まで欠落すること
はなく、さらに、電着されている超硬砥粒(3)の厚み
が金属薄板(1)の厚みよりも厚いので、鋸歯のアサリ
と同様金属薄板の胴部と被加工物との接触摩擦も少なく
かつ切削屑の排出も容易であるから極薄の金属薄板に及
ばす応力は小さく、金属薄板の周縁に多数の小切欠を鋸
歯状に設けて各小切欠に超硬砥粒を付着さセた従来の切
断砥石と比較した場合耐久性は著しく増大するうえに従
来のこの種切断砥石では外周部のふれを修正すると切断
用エツジ部が殆んどなくなるのでふれ修正ができなかっ
たのに対し、本発明によるものは切断用エツジ部は内周
端まで有効1こ使えるのでふれ修正を行うことができ切
断加工精度を向上させることができる。   ′ 本発明は以上の説明によって明らかなように、ダイヤモ
ンドや立方晶窒化硼素などの超硬砥粒が容易に脱落する
ことのない極薄の切断砥石を容易に製造できる切断砥石
の製造法として業界にもたらす利益が極めて犬なもので
ある。
The cutting wheel manufactured in this way is shown in the figure.
An ultra-thin abrasive support core material (2) is provided on the peripheral cutting edge of the annular thin metal plate (1), and ultra-fine carbide particles such as diamond, cubic boron nitride, etc., with an average grain size of ≠Oμ or less are provided here. The abrasive grains (3) are deposited by electrodeposition, and the metal is used as a binder (5). When the grinding wheel is mounted on an axle and rotated at high speed, and a workpiece is brought into contact with the peripheral cutting edge of the thin metal plate (1), the cutting action of the carbide abrasive grains (3) provides good sharpness and machining accuracy. It is equipped with holes for holding abrasive grains in the abrasive grain supporting core part of the peripheral blade part of the annular thin metal plate (1) as required. Alternatively, by providing a small recess, the carbide abrasive grains (3) filled in the abrasive support core part (2) are firmly attached to the ultra-thin abrasive support core part (2) by electrodeposited metal. The thin metal plate (1) is firmly fixed to the metal plate (1) and will not be broken even by the unidirectional force applied to the periphery of the metal plate (1) during rotation. Since it is thicker than (1), there is little contact friction between the body of the thin metal plate and the workpiece, similar to the sawtooth clam, and it is easy to remove cutting chips, so the stress exerted on the ultra-thin metal sheet is Compared to a conventional cutting wheel, which is small and has many small notches arranged in a sawtooth pattern around the periphery of a thin metal plate and has carbide abrasive grains attached to each small notch, the durability is significantly increased, and the durability is significantly increased. With a cutting wheel, when correcting the runout on the outer periphery, there is almost no cutting edge, so it was not possible to correct the runout, whereas with the cutting wheel, the cutting edge can be effectively used up to the inner edge, so the runout can be corrected. Corrections can be made and cutting accuracy can be improved. ' As is clear from the above description, the present invention has been developed in the industry as a method for manufacturing cutting wheels that can easily produce ultra-thin cutting wheels from which ultra-hard abrasive grains such as diamond and cubic boron nitride do not easily fall off. The benefits it brings to the market are extremely limited.

実施例 ポリアミド樹脂を主材とする周知の感光性樹脂を厚さ0
.2 tnrt+の環状の鉄板に塗着した後該鉄板と同
大で周縁部に幅2朋の環状の濃色の非透光部を有するネ
ガフィルムを該鉄板の表裏両面に互に画像のズレがない
ように密着させて露光焼付は後両ネガフィルムを除去し
て該鉄板の表裏両面の感光性樹脂を塩化カルシウムの溶
解された低級アルコールで洗って感光性樹脂のうち露光
されていない部分を洗い流すことにより現状の鉄板の周
縁刃部の表裏両面に砥粒支持芯材部に相当する部分を露
呈部として残してマスキンク層を形成する。次いで、こ
の鉄板を流度’AO°C,1lOBeの塩化第二鉄水溶
液中に6分間浸漬して前記露呈部を腐蝕させたうえ水洗
、乾燥して厚さQ、 / sn+yの砥粒支持芯材部を
形成し、さらに、砥粒支持芯材部の表、裏画面に02朋
の厚さtrニー感光性樹脂を塗着し、砥粒光填用の小凹
部として幅aj;朋、長さ!開の大きさの濃色の非透光
部が多数所要の間隔をもって配設されている2枚のネガ
フィルムのうち7枚を砥粒支持芯材部の表面に密着させ
るとともに裏面に他の1枚を表面のネガフィルムにおり
る濃色の非透光部相互間に濃色の非透光部が位置するよ
うに密着させて露光焼付は後両ネガフィルムを除去して
上記の操作上同様にしてマスキング層を形成し、上記と
同様塩化第二鉄水溶液中に4分間浸漬して腐蝕きせたう
え、水洗、乾燥して幅Oj門長さ2朋深さ0.0 !;
 MWの小凹部を砥粒支持芯材部の表裏面に配設し、次
に、/lの水に硫酸ニッケ)v211−Og、塩化ニッ
ケ/I/! !; 9と硼酸309を溶解させるととも
に粒度がlOμ以下の極微細なダイヤモンド、立方晶窒
化硼素などの超硬砥粒を底tこ敷き詰めたpHjのメッ
キ浴中の該超硬砥粒の層に埋め込み、該メッキ浴の温度
jO°c、N流密度←旨セで前記鉄板をメッキしてマス
キング層が形成されていない砥粒支持芯材部のみに析出
されるニッケルをもって超硬砥粒を強固に電着し、最後
に、鉄板の表裏面に形成されているマスキング層を除去
したうえラッピングなどの仕上げ加工を行って製品とし
た。
Example A well-known photosensitive resin whose main material is polyamide resin is
.. 2 After coating a tnrt+ annular iron plate, a negative film of the same size as the iron plate and having an annular dark non-transparent area with a width of 2 mm at the periphery was applied to both the front and back sides of the iron plate to avoid image misalignment. After exposure and printing, remove both negative films and wash the photosensitive resin on both the front and back sides of the iron plate with lower alcohol containing dissolved calcium chloride to wash away the unexposed parts of the photosensitive resin. As a result, a masking layer is formed on both the front and back surfaces of the peripheral edge portion of the current iron plate, leaving a portion corresponding to the abrasive grain supporting core material portion as an exposed portion. Next, this iron plate was immersed in a ferric chloride aqueous solution with a flow rate of 'AO°C and 1 lOBe for 6 minutes to corrode the exposed portion, washed with water, and dried to form an abrasive support core with a thickness of Q, / sn + y. Further, a photosensitive resin with a thickness of 02 mm is applied to the front and back surfaces of the abrasive grain supporting core material part, and a width aj; difference! Seven of the two negative films, each of which has a large number of dark-colored non-transparent parts arranged at the required intervals, are brought into close contact with the surface of the abrasive grain supporting core material part, and the other one is placed on the back side. The sheets are placed in close contact with each other so that the dark non-transparent parts are located between the dark non-transparent parts of the negative film on the front side, and after exposure and printing, both negative films are removed and the procedure is the same as above. A masking layer was formed by immersing it in the ferric chloride aqueous solution for 4 minutes to etch it, then washing it with water and drying it to form a masking layer with a width of 0.0 m, length of 2 mm and depth of 0.0 mm. ;
A small concave portion of MW was arranged on the front and back surfaces of the abrasive grain supporting core material part, and then nickel sulfate) v211-Og, nickel chloride /I/! was added to /l of water. ! 9 and boric acid 309 are dissolved and embedded in a layer of ultra-fine diamond, cubic boron nitride, or other super-hard abrasive grains with a particle size of 10 μ or less in a pHj plating bath filled with the bottom. , the iron plate is plated at the temperature of the plating bath at jO°c and the N flow density ← to strengthen the cemented carbide abrasive grains with nickel precipitated only on the abrasive grain support core material where no masking layer is formed. After electrodeposition, the masking layers formed on the front and back surfaces of the iron plate were removed, and finishing processes such as wrapping were performed to create the product.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明により製造された切断砥石の一部切欠斜
視図、第2図は同じく要部の断面図、第3図は本発明に
より製造された切断砥石の他の実施例を示す要部の断面
図である0 (1):金(を薄板、(2):砥粒支持芯材部、(3)
:超硬砥粒、(4):取付孔、(5)!結合剤。 ノ 第2図
FIG. 1 is a partially cutaway perspective view of a cutting wheel manufactured according to the present invention, FIG. 2 is a sectional view of the main part, and FIG. 3 is a schematic diagram showing another embodiment of the cutting wheel manufactured according to the present invention. (1): Gold (thin plate), (2): Abrasive grain support core material, (3)
: Carbide abrasive grain, (4): Mounting hole, (5)! Binding agent. Figure 2

Claims (1)

【特許請求の範囲】[Claims] 環状の金属薄板の表裏面の周縁刃部を露呈部として残し
てマスキング層を形成したうえ腐食液により該露呈部を
腐食させて極薄な砥粒支持芯材部とし、次いで該砥粒支
持芯材部の表裏面に金属薄板の厚さよりも厚くダイヤモ
ンド、立方晶窒化硼素などの極微細な超硬°砥粒をIJ
I電着後マスキング層を除去することを特徴とする切断
砥石の製造法0
A masking layer is formed by leaving the peripheral edges of the front and back surfaces of the annular thin metal plate as exposed parts, and then the exposed parts are corroded with a corrosive solution to form an extremely thin abrasive support core. IJ is applied ultra-fine carbide abrasive grains such as diamond or cubic boron nitride to the front and back surfaces of the material to a thickness that is thicker than the thickness of the thin metal plate.
I Method for manufacturing a cutting wheel characterized by removing the masking layer after electrodeposition 0
JP21756282A 1982-12-11 1982-12-11 Manufacture of cutting grindstone Pending JPS59107861A (en)

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Application Number Priority Date Filing Date Title
JP21756282A JPS59107861A (en) 1982-12-11 1982-12-11 Manufacture of cutting grindstone

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Application Number Priority Date Filing Date Title
JP21756282A JPS59107861A (en) 1982-12-11 1982-12-11 Manufacture of cutting grindstone

Publications (1)

Publication Number Publication Date
JPS59107861A true JPS59107861A (en) 1984-06-22

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JP21756282A Pending JPS59107861A (en) 1982-12-11 1982-12-11 Manufacture of cutting grindstone

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62193775A (en) * 1986-02-18 1987-08-25 Sanwa Daiyamondo Kogyo Kk Hard work cutting circular saw
EP0284173A2 (en) * 1987-03-24 1988-09-28 Matsutani Seisakusho Co. Ltd., Dental diamond bar and manufacturing method thereof
US4909234A (en) * 1988-06-09 1990-03-20 Sanwa Diamond Industrial Co., Ltd. Cutter
JPH02237759A (en) * 1989-03-10 1990-09-20 Sanwa Daiyamondo Kogyo Kk Cutter and manufacture thereof
JP2015150683A (en) * 2014-02-18 2015-08-24 中国砂輪企業股▲ふん▼有限公司 Chemical mechanical polishing adjustor having high performance
CN106002659A (en) * 2016-07-21 2016-10-12 中国有色桂林矿产地质研究院有限公司 Superhard abrasive material cutting blade and manufacturing method thereof
CN110026610A (en) * 2019-04-19 2019-07-19 江苏锋菱超硬工具有限公司 Light-duty thinned abrasive compound brazing saw blade and its production method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62193775A (en) * 1986-02-18 1987-08-25 Sanwa Daiyamondo Kogyo Kk Hard work cutting circular saw
EP0284173A2 (en) * 1987-03-24 1988-09-28 Matsutani Seisakusho Co. Ltd., Dental diamond bar and manufacturing method thereof
US4909234A (en) * 1988-06-09 1990-03-20 Sanwa Diamond Industrial Co., Ltd. Cutter
JPH02237759A (en) * 1989-03-10 1990-09-20 Sanwa Daiyamondo Kogyo Kk Cutter and manufacture thereof
JP2015150683A (en) * 2014-02-18 2015-08-24 中国砂輪企業股▲ふん▼有限公司 Chemical mechanical polishing adjustor having high performance
CN106002659A (en) * 2016-07-21 2016-10-12 中国有色桂林矿产地质研究院有限公司 Superhard abrasive material cutting blade and manufacturing method thereof
CN110026610A (en) * 2019-04-19 2019-07-19 江苏锋菱超硬工具有限公司 Light-duty thinned abrasive compound brazing saw blade and its production method

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