JPS59105067A - Binder for acetate fiber - Google Patents
Binder for acetate fiberInfo
- Publication number
- JPS59105067A JPS59105067A JP57213763A JP21376382A JPS59105067A JP S59105067 A JPS59105067 A JP S59105067A JP 57213763 A JP57213763 A JP 57213763A JP 21376382 A JP21376382 A JP 21376382A JP S59105067 A JPS59105067 A JP S59105067A
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- binder
- bonding agent
- propanediol
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011230 binding agent Substances 0.000 title abstract description 9
- 229920006221 acetate fiber Polymers 0.000 title abstract 2
- 239000007767 bonding agent Substances 0.000 claims description 22
- 239000000835 fiber Substances 0.000 abstract description 14
- -1 fatty acid ester Chemical class 0.000 abstract description 8
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 abstract description 7
- 235000019504 cigarettes Nutrition 0.000 abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 6
- 229930195729 fatty acid Natural products 0.000 abstract description 6
- 239000000194 fatty acid Substances 0.000 abstract description 6
- 239000000796 flavoring agent Substances 0.000 abstract description 5
- 235000019634 flavors Nutrition 0.000 abstract description 5
- 235000019640 taste Nutrition 0.000 abstract description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000012043 crude product Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 235000019260 propionic acid Nutrition 0.000 description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007123 defense Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- GNBPEYCZELNJMS-UHFFFAOYSA-N 2-methylbutane-1,3-diol Chemical compound CC(O)C(C)CO GNBPEYCZELNJMS-UHFFFAOYSA-N 0.000 description 1
- 241000257465 Echinoidea Species 0.000 description 1
- 208000002260 Keloid Diseases 0.000 description 1
- 206010023330 Keloid scar Diseases 0.000 description 1
- NPPQSCRMBWNHMW-UHFFFAOYSA-N Meprobamate Chemical compound NC(=O)OCC(C)(CCC)COC(N)=O NPPQSCRMBWNHMW-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 240000001417 Vigna umbellata Species 0.000 description 1
- 235000011453 Vigna umbellata Nutrition 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940021019 disal Drugs 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 210000001117 keloid Anatomy 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
本発明はアｔ？ｊ−１・１１ｆ用接合剤に関り−るもの
であり、史に訂しくは７ ｔテ〜トｌＪｉ’ ａｆｔの
結束成形の際、接合剤とし−（２−メチル−１，ｓ３−
ブＩＩパンジＡ−ルの低級脂ＢｈＭジエスデルを利用す
ることに関りるものである。[Detailed Description of the Invention] The present invention provides at? This is related to the bonding agent for J-1 and 11F, and historically, it was used as a bonding agent during the bundling of 7 tons of t-shirts.
The present invention relates to the use of BhM diesel, a lower fat of BhM BhM BhM BhM Diesdel of Panjal.
本弁明に使用−４る２−メチル−１，３−ブ［１パンジ
オールの低級脂肪酸エステルは繊組の接合剤としての用
途は知られていない。The lower fatty acid ester of 2-methyl-1,3-butanediol used in the present invention is not known to be used as a bonding agent for fiber braiding.
本発明は、かかる化合物が特にアレテート繊維の接合剤
とし−Ｃ有用なことを見出しなされたものである。The present invention is based on the discovery that such a compound is particularly useful as a binder for aretate fibers.
さて、アｂ ｊ−ｔ−綴紐は接合剤を４・す用しＣ１各
種結束成形体を製造Ｊることができる。−その代表的な
ものに、たばこ煙濾過体や４ツインペンのインキ吸蔵用
中芯等に利用される綴紐ロットか挙げられる。このロツ
１−の製造について述べると、接合剤とは繊組の１〜つ
（Ｔ ＯＷ ）から１］ツドを特造りる場合に使用され
るものであり、イのＩ幾ｉ！’Ｉは、それが添加される
と繊組にランタムに接触し、接触しＩｃ部分ハ！ＪＩｉ
／ｉ’ｌｔをンＲＷ（Ｌ／、ソ（７） ンＨＷ（Ｌ タ
＋ｉ、ｉ Ｔ： ４．ｌＪ 庁ｆｌを相亙に結合さけて
三次元網状構造を形成りることによりロッド形状を保１
＼′ｉけしめ、ＩＩ ’−） ｉＭ ｔαの硬度を付！
ｊ′？ｌることにある。接合剤の添加ｌｊ法はｊルデ−
１〜機Ｈ＋−ウヘ接合剤が均一にｌＪ盾しｊ（）れに工
いづれの方法でも良いが一般にはスプレーガンあるいは
ウィックによるトウの上下両面にイ」着させる１５法な
どが取られている。Now, the abj-t-string can be used to produce various binding molded bodies by using a bonding agent. - Typical examples include string lots used for cigarette smoke filters, ink storage cores of 4-twin pens, etc. Regarding the manufacture of this lot 1-, the bonding agent is used when making a special 1] do from one to one (TOW) of the fiber braid, 'I touch the lantum to the fibers when it is added and touch the Ic part ha! JIi
/i'lt to RW(L/, so(7)) to HW(L ta+i, i T: 4.lJ The rod shape is created by forming a three-dimensional network structure by combining the agency fl with each other. Ho 1
\'i Keshime, II '-) iM tα hardness attached!
j'? It's about being able to do something. The lj method of adding bonding agent is
Any method may be used to apply the bonding agent uniformly to both the top and bottom of the tow using a spray gun or wick. .
さて、アセデー１へ繊１１１０ンドの接合剤として要求
される特１１は次のごとくである。Now, the characteristics 11 required as a bonding agent for fibers 1110 to Acede 1 are as follows.
（１）室温で硬化ＩＪ能イｒこと。(1) IJ function that hardens at room temperature.
（２）硬化１１、）間（縄肩１が固定化りるための時間
）がスＯいこと。(2) The curing time (time for the rope shoulder 1 to become fixed) is short.
（３）繊条の摺合が１分Ｃあること。(3) The sliding of the filaments is 1 minute C.
（４）硬い織眉１［−１ツドを製）青Ｃ゛きること。(4) Hard woven eyebrows 1 [-1 Tsudo made] Blue C゛ cut.
（５）繊組［−１ラド切１１Ｊｉ端面に−［羽立ら、陥
没がないこと。(5) Fiber braid [-1 Lad cut 11Ji end face -] There shall be no feathers or depressions.
（６）非貼着１１−Ｃあること。(6) Non-stick 11-C.
（７）製品の香喫味が４ぐれく−いること。（特にタハ
〕二１フィルター用）
（８）人体に無害であること。(7) The product must have a 4-degree flavor. (Especially for Taha 21 filters) (8) Must be harmless to the human body.
このＪ、うに接合剤としＣ要求される特性は多数である
。There are many properties required for this J to be used as a sea urchin bonding agent.
従来の接合剤どしく一公知のものには、ポリオール１ス
プル系化合物、アルコキシアルキルフタレーｉ〜系化合
物′；９がある。具体的には、例えばポリオールニスア
ル系化合物とし′ＣはグリＬ Ｄ−／し１〜リアセテ−
１〜、１，３−ブチレングリ］ −／ｌ／ジアレテー１
へ、１−リエチレングリコールシアレテー１〜同ジブロ
ビオネ−１〜等がある。又、ｊフル」キシアル千ルフタ
レー１〜系化合物としてはシメ！−キシ：■−チルフタ
レート、ジエ１へキシエチルフタシー１〜等その他クエ
ン酸１〜リエチル等々がある。こ１″Ｌらの化合物は先
に列挙した接合剤に要求される特性力＼ら兄た場合−長
−７，ｕ ”Ｃある。現在］−業的（こ使用されている
グリセロールトリアセテ−１へは硬化時間か長いという
欠点かある。１へり］−チレンクリコールの低級脂肪酸
土ステルは硬化速度は甲（＼ｂ（香喫味が不十分であり
、クエンｉｌｌ！ｉ ｌ−リエチル」−スプルは硬化の
際掌湿以」二の高温か必要である。Some of the well-known conventional binders include polyol 1 sprue type compounds and alkoxyalkyl phthalate type compounds ';9. Specifically, for example, when a polyolnisal compound is used,
1-, 1,3-butylene glycol] -/l/diarethe 1
and 1-lyethylene glycol sialete-1 to dibrobione-1 and the like. Also, as a compound of the ``JFlu'' xial 1,000 ruphthalene 1~ series, it is not good! -oxy: ■-Tylphthalate, die 1 hexyethyl phthalate, etc., and citric acid 1 - ethyl, etc. These compounds have the properties required for the bonding agents listed above. Currently, the glycerol triacetate 1 used in this industry has the disadvantage of a long curing time. The quenching process is insufficient, and the quench-lethyl sprue requires temperatures higher than the humidity of the palm of your hand for curing.
かくして、本発明によれは、一般式：
％式％
（ＲおよびＢはメチル基また゛はエチル１．ｔ）で示さ
れる２−メチル−１，３−ブト１パンジｔ −ルの低級
脂肪酸エステルからなるアセテ−１へ繊維用接合剤が提
供される。Thus, according to the present invention, from lower fatty acid esters of 2-methyl-1,3-buto-1-panditol having the general formula: % (R and B are methyl or ethyl) A fiber bonding agent is provided to Acete-1.
本弁明による接合剤は硬化が室温でかつ短い時間で可能
であること、並びにタバコ用フィルターに使用される場
合は、タバコの香喫味を損なうことなく十分に満足づる
ものであることなどの特徴を右づる。The bonding agent according to the present defense has the characteristics that it can be cured at room temperature and in a short time, and that when used in cigarette filters, it is fully satisfactory without impairing the aroma and taste of cigarettes. Right side.
本発明に使用４る化合物は、たとえば次の反応式に従っ
て製造づることができる。The four compounds used in the present invention can be produced, for example, according to the following reaction formula.
反応は公知のエステル化反応の手段を用い−Ｃ行うこと
ができる。即ち、このニスデル化反応はたとえば２−メ
チル−１，３−ブ１」パンジオール１モルに対しそれぞ
れ耐酸又は／及びプロピオン酸を２乃至４モル、水との
共沸溶剤及びエステル化触媒を同時に仕込み、通常のニ
スデル化反応を行なう。水との共ｄ１１溶剤としてはヘ
キサジ、ペンげン、１〜ルエン、ギシレン等を用い、エ
ステル化触媒どしては塩酸、硫酸、パラ１−ル土ンスル
ホン酸等が好適である。反応完結後、アルカリ中和にて
触媒及び未反応の酸を除去し、減圧下での溶剤回収工程
を紅て、真空黒布による精製で２−メチル−１，３−プ
ロパンジオールのエステルを１ｑることができる。回収
した酢酸又はプロピオン酸は精製した後、連続的に繰り
返し使用づることができる。The reaction can be carried out using known esterification reaction means. That is, in this Nisderization reaction, for example, 2 to 4 moles of acid-resistant and/or propionic acid, an azeotropic solvent with water, and an esterification catalyst are simultaneously added to 1 mole of 2-methyl-1,3-but-1"panediol. Prepare and perform the usual Nisder reaction. As the co-d11 solvent with water, hexadiene, pentene, 1-toluene, gysilene, etc. are used, and as the esterification catalyst, hydrochloric acid, sulfuric acid, para-1-althosulfonic acid, etc. are suitable. After the reaction was completed, the catalyst and unreacted acid were removed by alkali neutralization, the solvent recovery process was carried out under reduced pressure, and 1 q of ester of 2-methyl-1,3-propanediol was purified using a vacuum black cloth. can be done. After the recovered acetic acid or propionic acid is purified, it can be continuously and repeatedly used.
このような２−メチル−１，３−プロパンジオールのジ
エステルを単独で使用することは勿論、伯の公知の接合
剤と混合して、アレチー１−れ（組接合剤として使用す
ることも考えられるか、その場合の公知の接合剤として
は、たとえは前記以外のポリオールエステル系化合物、
アルコキシアルキシフタレ−１〜系化合物などがある。Of course, such a diester of 2-methyl-1,3-propanediol can be used alone, but it can also be mixed with a known binder to form a binder. In that case, known bonding agents include polyol ester compounds other than those listed above,
Examples include alkoxyalkoxyphthalate-1-based compounds.
ポリオール１スプル系化合物としては例えばグリレロー
ルトリアレデー１−１１，３−プチレングリニ１−ルシ
アレテートなど、アルコキシアルキシフタレ−１〜系化
合物としてはたとえばシメｉ〜キシエチルフタレー１〜
、ジ］二１〜キシエチルフタレー゛ｌ−など、が挙けら
れるが特にこれらに限定されるものではない。Examples of polyol 1 sprue-based compounds include glycerol trialede 1-11,3-butylene glinyl 1-rusiaretate, and examples of alkoxyalkoxyphthalate-1-based compounds include, for example, xyethyl phthalate 1-
, di]2-xyethyl phthalate, etc., but are not particularly limited to these.
本発明の接合剤の対象とするアセテ−１〜繊紐は、通常
１〜１６デニールの連続繊維を３，０００〜１００，０
００木集め、２５ ｒｔｎｎａ）長すニツイテ１０へ一
３０岡の均一な捲縮を付した帯状の１−ウ（ＴＯＷ）ど
けばれるものであるが、本発明は特にこれらの条イ９に
限定されるものではない。なａ５、このアレーｒ ｌ
−４，を目１ｒは、アレデル化１９３７．３〜７１２．
３％ｂｂ＜は結合酢酸帛５２〜５９％の酢化度を右りる
ものが好ましい。The acetate-1 to strands that are the target of the bonding agent of the present invention usually consist of 3,000 to 100,000 continuous fibers of 1 to 16 deniers.
00 trees collected, 25 rtnnna) A strip-shaped 1-U (TOW) with uniform crimps of 130 strands is removed from the long strip 10, but the present invention is particularly limited to these strips 9. It's not something you can do. Naa5, this array r l
-4, 1r is alledelized 1937.3-712.
It is preferable that 3% bb< is determined by the degree of acetylation of the bound acetic acid film from 52 to 59%.
また本発明に使用される接合剤の綴紐重（イ）に対する
添加量は一１〜２０重（１）％が好ましく、添加ωを増
加するど繊肩ｆが溶解して俗にケロイドと称する箇所が
増加したり、５１．た〕ス１〜高どなる等の欠点があり
、ζ３−＝ １０弔１１％がより好ましい。Further, the amount of the binder used in the present invention added to the weight of the binding string (a) is preferably 11 to 20 weight (1)%, and as the addition ω increases, the fiber shoulder f dissolves, which is commonly called a keloid. 51. However, there are drawbacks such as a high pitch of 1 to 1%, so ζ3-=10% to 11% is more preferable.
更に前記の公知接合剤をｉｆＮ合してしよく、その場合
、本発明の接合剤全体に対する割合は４０〜９９市ｔＴ
Ｉ％が好ましい。Furthermore, the above-mentioned known bonding agent may be combined with ifN, in which case the proportion of the bonding agent of the present invention to the total amount is 40 to 99 tT.
I% is preferred.
次に参内まＣ゛に本発明に使用される化合物の２−メヂ
ルー′１，３−ブ］］パンジＡ−ルジアレテ−１・と２
−メチル−１，３−プロパンジオールジブ【」ピオネ−
１〜の製造法の例を挙げる。Next, we will introduce the compounds used in the present invention, 2-medyru'1,3-b]] panzi A-rujiarete-1 and 2.
-Methyl-1,3-propanediol dib[''Pioney-
Examples of manufacturing methods 1 to 1 are given below.
参考例 １． ２−メチル−１，３−ブロノ＼ン）晶度
計、撹拌棒、滴下ローｈ、コンテンサーと分離器とを−
Ｆ下に接続した装置を備えた２９の４つロフラスコに、
２−メチル−１，３−プロパンジオール２７００ （
３Ｅル）、酢酸４２０ｇ （７モル） 、ヘン１ン３０
０（＋ 及び硫Ｍ０．６（Ｉを同１時に仕込／υ〕乙反
応（品度８０〜１００’Ｃで加熱撹拌しながらニスデル
化反応で生成した生成水を系外に分ＰＩｉ Ｌ、反応を
完結さけた。反応ｉ昆合液はヘンげン、酢酸を溜人後、
再度へンげンを追加して炭酸ソータ水で中和した。中和
後五合液はベンゼンを溜去し、粗製品４８１ｑを得た。Reference example 1. 2-methyl-1,3-brono\n) crystallinity meter, stirring bar, dropping funnel h, condenser and separator.
29 four-loaf flasks with equipment connected below F.
2-Methyl-1,3-propanediol 2700 (
3Ele), acetic acid 420g (7mol), Hen 1ton 30
0 (+ and sulfur M0.6 (I are charged at the same time / υ)) Reaction (80 to 100'C, while heating and stirring, the water produced by the Nisdell reaction is separated from the system PIi L, reaction The reaction mixture was mixed, and after adding acetic acid,
Red bean was added again and neutralized with carbonated sorta water. After neutralization, benzene was distilled off from the mixed solution to obtain crude product 481q.
Ｖｒられだ粗製品は真空度１５ｍｍ１−Ｈで蒸溜精製し
、沸点１００〜１０５℃の面分て／Ｉ３８りの精製ジｊ
）Ｌ？ｊ−−１〜が１ｑられた。The crude product was purified by distillation at a vacuum level of 15 mm 1-H, and purified by distillation with a boiling point of 100 to 105°C.
) L? j--1～ was 1q.
参考例１と同様の装置を用い２−メチル−１，３−プロ
パンジオール２２５（１（２，５モル）、プロピオン酸
３８９ｑ （５，２５モル）、ベンゼン３００ＩＪ２ｉ
ｔｌＦＩＩｉ！Ｉｆｌｌｆｆ １ 、１！Ｊ 全仕込み
、反応温度８０〜１０５“Ｃで生成水を連続的に系外に
分Ｉｌ！１１させながら、５１１Ｊ間加熱ｊ朕拌し、反
応を完結さＩだ。Using the same apparatus as in Reference Example 1, 2-methyl-1,3-propanediol 225 (1 (2.5 mol), propionic acid 389q (5,25 mol), benzene 300IJ2i
tlFIIi! Ifllff 1, 1! After all the charges were made, the reaction temperature was 80 to 105"C, and the reaction was completed by heating for 511J and stirring while continuously discharging the produced water out of the system.
反応混合液を冷ｌｉｌ後、２０％力セイソータ水溶液に
て触媒の１！ｉＩＩ酸及び未反応の酸を中和し、水層を
分離した１資、ｉ品度１００ ′Ｃ真空度２０ｍｍＨｃ
＋の条（’ｌに（反応ンＨ剤のヘンゾールを溜六し、５
０６ｇの粗製品をｉ’ｊ ｌ：ｃ。粗製品を真空度１ｍ
ｍＨｇ−Ｃ蒸溜精製し、沸ｒ：ａ ９８〜１００℃の溜
分で４６ＨＩの精製ジブピΔネートが得られた。After the reaction mixture was cooled, it was diluted with a 20% aqueous solution of the catalyst. III acid and unreacted acid were neutralized and the aqueous layer was separated.I grade 100'C vacuum degree 20mmHc
Add the reaction H agent Henzol to the + line ('l), and
06 g of crude product i'j l:c. Vacuum degree of 1m for crude products
The product was purified by mHg-C distillation, and purified dibupinate Δ of 46HI was obtained as a fraction having a boiling point r:a of 98 to 100°C.
更に２−メｊルー゛１，３−プロパンジΔ−ルの酢酸と
ブ［］ピピレンとのｆｆｆｉ合エスチェステル製造方法
にＪ、っＣ製ｊ貴可能である。Further, it is possible to use a method for producing a ester formed by combining 2-methyl 1,3-propanedil with acetic acid and propylene.
以上、２−メチル−１，３−フ゛ロパンジオールジアセ
テ−１〜と２−メヂルー’１．３−ブ■パンジオールジ
ブ１」ピオネ−１〜の２つの化合物を使用した実施例に
ついく述べるが本発明はこれらにＪζっで限定されるも
のではない。The above describes examples using two compounds, 2-methyl-1,3-propanediol diacetate-1 and 2-methyl-1,3-panediol diacetate-1. However, the present invention is not limited to these.
実施例−′１〜と５
フィシメン１〜デニール４．１〜−タルデニール４３
、０００Ｊｆｆ１６故２６ （２５ｍｍ長あたり）の）
７しデー１へ繊維１ヘウを開繊し、２−メチル−１，３
−プロパンジオールの低級脂肪酸ジエステルおよび該ジ
エステル化合物と他の化合物の等重量混合物を繊肩１小
ｍに対し、４乃至６車ｍ％添加し、巻上は装置によつ−
Ｃ巻上げて、紙まきロツ１〜とし、９Ｑｍｍ長に切［ｆ
ｌｉ シたのち、重用、通気抵抗、円周及び巻上げ１時
間後と２０℃で２４時間故買後の硬度どを測定し、１゛
ｌられた諸性性を第１表に示した。Examples-'1 to 5 Ficimen 1 to Denier 4.1 to Tardenier 43
, 000Jff16 26 (per 25mm length))
7. On Day 1, 1 fiber was opened and 2-methyl-1,3
- Lower fatty acid diester of propanediol and a mixture of equal weights of the diester compound and other compounds are added in an amount of 4 to 6 m% per 1 m of fiber shoulder, and the winding is carried out using a device.
Roll up the paper and cut it into 9Qmm length [f
After heating, heavy use, airflow resistance, circumference, and hardness after 1 hour of winding up and after 24 hours of aging at 20°C were measured, and the calculated properties are shown in Table 1.
比較例−１〜４
実施例−１〜５と同様のアレチー１〜織組トつを開繊し
、接合剤を全く使用しないものと、公知の接合剤を用い
て同一の条ｆ′１Ｆて紙誉さプラグに巻上げたのら、１
１ｊ１−測定方法によって５１１特性を測定し、第１表
にイノ１記した。Comparative Examples 1 to 4 Arechee 1 to woven fabrics similar to Examples 1 to 5 were opened, and the same threads f'1F were prepared using no bonding agent at all, and those using a known bonding agent. If you roll up the paper honor plug, 1
511 characteristics were measured by the 1j1-measurement method and are listed in Table 1.
次に第１表の測定項目について説明りる。Next, the measurement items in Table 1 will be explained.
（１）ロッド市川（単位二ｇ／本）
繊維ロッド１本の重量
（２）通気抵抗（単位： ｍｍＨ２０）９０ｍｍ長の１
１１１１０ツドに空気を１７．５１ｎρ／秒通気したと
きの抵抗を水柱（ｍｍ）で表示したものである。(1) Rod Ichikawa (unit: 2g/piece) Weight of one fiber rod (2) Airflow resistance (unit: mmH20) 90mm long 1
The resistance is expressed in water columns (mm) when air is aerated at a rate of 17.51 nρ/sec through a 11110 mm tube.
［３］ Ｄットの硬度
水平に置いたデス１〜ピース上に直径１２ ｍｍｃｌン
の円板を介し−Ｕ３００（Ｉの荷重を１０秒間か（〕た
場合に生り“るデス１〜ピースの変形ｍを０．１＋ｎｍ
単位て′読みとった数値をもって見掛けの硬度としてい
る。[3] Hardness of Dt: The hardness that occurs when a load of -U300 (I) is applied for 10 seconds on a piece placed horizontally through a disk with a diameter of 12 mm. Deformation m of 0.1+nm
The value read in units is the apparent hardness.
該硬度値は人なる程柔らかく、小さくなる稈堅いことを
示している。時系列の変化を知るために１時間後と２４
時間後との硬度を示した。早く硬度値が小さくなる程硬
化時間は短く、１′１−業性は良い。The hardness value indicates that the culm becomes softer and harder as the culm decreases. After 1 hour and 24 hours to know the changes in the time series
The hardness after time is shown. The faster the hardness value decreases, the shorter the curing time and the better the 1'1-performance.
（４）香喫味
響喫味の判定は市販のハイライ１〜のフィルタ一部を取
除いて、本発明のロンドで同等の通気抵抗を有するたば
こを作り１０名の試喫者が両者を比較した。本弁明１１
ツドをＩＩＪ したたばこがうまく感じた名が、渦Ｔ数
を占める場合には○じるしを附し ｌこ 。(4) To judge the flavor of the smoker, a part of the filter of commercially available Hi-Rai 1~ was removed, and cigarettes with the same airflow resistance were made with the Rondo of the present invention, and 10 tasters compared the two. Main defense 11
If the name of the tobacco that tastes good with the Tsudo IIJ occupies the number of whirlpools, mark it with an ○.
たば゛こノイルター川アレデートｆｌｕ Ｉｆｆロット
の良否の判定は十に（３）の［−１ラド硬度と（４）の
香喫味との２点より行なうことがＣさる。The quality of a Tobacco Ilter River Aledate Flu If lot is determined based on two points: (3) [-1 rad hardness] and (4) flavor.
以トのようイ１測定項目の試験を行ない、次のような結
果を１１Ｆだ。I conducted the test for measurement items A1 as described above, and the following results were 11F.
実施例−１へ・５の１」ツ１〜の硬度は１時間接に実用
的に充分秀れた値である硬度′１０ｊメ下に達している
が、比較１）ｌ−１・〜・３−Ｃはその１直に徨づるの
に２４時間を関している。Go to Example-1.The hardness of 5-1'' 1 ~ reaches below the hardness '10j, which is a sufficiently excellent value for practical use after 1 hour contact, but comparison 1) l-1... 3-C relates to the 24 hours it takes to wander during the first shift.
香喫味に関しＣは実施例−１−・５はりくれているが、
比較例−４は劣っＣいる。Regarding the aroma and taste, C is better than Example-1-5, but
Comparative Example-4 was inferior.
Ｊメ」−の結果より、本発明に使用される２−メチル−
１，３３−プロパンジＡ−ルの低級脂肪酸ジ１スアルは
従来品に比へ−Ｕ ’Ｊぐれた接合剤であることが判る
。From the results of JMe, 2-methyl- used in the present invention
It can be seen that the lower fatty acid disal of 1,33-propanedial is a bonding agent that is superior to conventional products.
なＪ３本発明にＪ、る接合剤はここに例示りるアレデー
１〜繊雇Ｉ」ラドの製造以外にアレチー１へれＩｉ ＃
Ｉｔのシー１へ、不織イ［、クロス、パイプ、フィルタ
ーなどの結束成形用に単独ｊ：たは公知の接合剤とＯｆ
用して綴紐用量にり＝ｌ Ｌ−Ｃ１〜２０重ｔｎ％の添
加呈Ｃ゛広く用いることができる。J3 The bonding agent used in the present invention may be used in addition to the production of the exemplified here.
It can be used alone or with a known bonding agent for binding and forming non-woven fabrics, cloth, pipes, filters, etc.
It can be widely used if the amount of binding cord is 1 to 20 weight tn%.
Claims (1)
（１） ｆＬ’： ｌ＆ Ｄｈ Ｄｊｊ ｎｕ Ｊｌｌ
ステルｈｌ ’） ｌｊ ルア ｔ ｉ −１” ｍ
Ｎ用接合剤。[Claims] 1. General formula: 2-Mejiru'1,3-p1'pandiol (1) fL': l&Dh Djj nu Jll
stell hl') lj lua t i -1” m
Bonding agent for N.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57213763A JPS59105067A (en) | 1982-12-06 | 1982-12-06 | Binder for acetate fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57213763A JPS59105067A (en) | 1982-12-06 | 1982-12-06 | Binder for acetate fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59105067A true JPS59105067A (en) | 1984-06-18 |
| JPH0326231B2 JPH0326231B2 (en) | 1991-04-10 |
Family
ID=16644617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57213763A Granted JPS59105067A (en) | 1982-12-06 | 1982-12-06 | Binder for acetate fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59105067A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102721596A (en) * | 2012-05-29 | 2012-10-10 | 广东中烟工业有限责任公司 | Pretreatment method for cigarette flavor |
-
1982
- 1982-12-06 JP JP57213763A patent/JPS59105067A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102721596A (en) * | 2012-05-29 | 2012-10-10 | 广东中烟工业有限责任公司 | Pretreatment method for cigarette flavor |
| CN102721596B (en) * | 2012-05-29 | 2015-08-05 | 广东中烟工业有限责任公司 | A kind of pre-treating method of cigarette perfume material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0326231B2 (en) | 1991-04-10 |
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