JPS5855401A - Soil disease controlled for agricultural and horticultural purpose - Google Patents

Soil disease controlled for agricultural and horticultural purpose

Info

Publication number
JPS5855401A
JPS5855401A JP15262181A JP15262181A JPS5855401A JP S5855401 A JPS5855401 A JP S5855401A JP 15262181 A JP15262181 A JP 15262181A JP 15262181 A JP15262181 A JP 15262181A JP S5855401 A JPS5855401 A JP S5855401A
Authority
JP
Japan
Prior art keywords
compound
crops
soil
active ingredients
dithiolan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP15262181A
Other languages
Japanese (ja)
Other versions
JPS6147804B2 (en
Inventor
Katsuhiro Fujishima
藤島 捷洋
Fujio Araki
荒木 不二夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Nihon Nohyaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Nihon Nohyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd, Nihon Nohyaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Priority to JP15262181A priority Critical patent/JPS5855401A/en
Publication of JPS5855401A publication Critical patent/JPS5855401A/en
Publication of JPS6147804B2 publication Critical patent/JPS6147804B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:The titled composition that contains diisopropyl 1,3-dithiolan-2-ylidene- malonate and another compound as active ingredients, thus developing higher controlling effect against soil diseases such as cabbage clubrot than the single use. CONSTITUTION:The objective controlled contains diisopropyl 1,3-dithiolan-2-ylidenemalonate, effective mainly against rice blast and N-(1-n-butoxy-2,2,2-trichloroethyl)-2-hydroxybenzamide, effective against soil diseases at a ratio of 3/1-1/3. The resultant controller can also completely cure the withering at the above- ground part of the crops as in case of their single applications. The controller is applied to the above-ground part of the crops to be protected or through soil treatment for both preventive and curing purposes. The does is more than 500g/10a as the active ingredients, when it is used directly in the form of dust or granules.

Description

【発明の詳細な説明】 本発明は、ジイソプロピルl、 3−ジチオラン−2−
イリデンマロネート(以下、化合舎人という)とN−(
1−n−ブトキシ−2,2,2−トリクロロエチル)−
2−とドルキシベンズアミド(以下、化合物Bという)
とを有効成分として含有することを特徴とする農園芸用
土壌病害防除剤に関する0 ここで化合力Aは特公昭47−34126号公報記載の
公知化合物であり、主としてイネ、イモチ病に対し有効
である。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides diisopropyl, 3-dithiolane-2-
Ylidene malonate (hereinafter referred to as compound Toneri) and N-(
1-n-butoxy-2,2,2-trichloroethyl)-
2- and droxibenzamide (hereinafter referred to as compound B)
Regarding a soil disease control agent for agriculture and horticulture, which is characterized by containing as an active ingredient, Compound A is a known compound described in Japanese Patent Publication No. 47-34126, and is mainly effective against rice and rice blast diseases. be.

また化合物Bは特開昭54−39040号公報記載の公
知化合物であり、土壌病害防除剤としての活性を有する
Compound B is a known compound described in JP-A-54-39040 and has activity as a soil disease control agent.

本発明者等は、今般、土壌病害防除剤の研究を進めてき
た結果、キャベツ根こぶ病、白菜板こぶ病、ダイコン亀
裂褐変症、ジャガイモ粉状そうか病等の、土壌病害に対
し、化合物Aと化合物Bとを有効成分として含有する当
該防除剤が各単剤で用いるより高い防除効果を示すこと
を見−出した。特にキャベツ根こぶ病、白菜板こぶ病に
対しては、各単剤の効果と比較して相乗的な効果を示す
ことを見い出しな0 本発明QCお−て、化合物A自体の根こぶ病防除効果は
きわめて、小であるのに、化合舎人に化合物Bを併用す
ることにより顕著な相乗効果が得られるということhi
t<べきことである。
As a result of research into soil disease control agents, the present inventors have discovered that compounds can be used to prevent soil diseases such as cabbage clubroot, Chinese cabbage clubroot, radish crack browning, and potato powdery scab. It has been found that the pesticidal agent containing A and Compound B as active ingredients exhibits a higher pesticidal effect than when each agent is used alone. In particular, we have found that Compound A has a synergistic effect on cabbage clubroot disease and Chinese cabbage clubroot disease compared to the effects of each agent alone. Although the effect is extremely small, a remarkable synergistic effect can be obtained by using Compound B together with Compound Toneri.hi
t<should.

しかも、化合舎人と化合物Bとを併用することにより、
各々単独で用いた場合の作物地り部のしおれが、完全に
治癒するとの知見も得た。
Moreover, by using Compound B together with Compound Toneri,
It has also been found that wilting in the soil area of crops can be completely cured when each of them is used alone.

この作物地上部のしおれは土壌病害に由来するものであ
り、したがって作物地上部のしおれ治癒も本発明に属す
る0 化合物Aと化合gt/JBとを有効成分として含有する
土壌病害防除剤を製造するには、両成分を農薬製剤上の
常法に従い担体(希釈剤)と混合し、必要により所望の
補助剤例えば、lv面活性剤、分散剤、固着剤等?添加
し、使用に都合のよい剤型例えば粉剤、乳剤、フロアブ
ル、錠剤、水相剤、微粒剤、粒剤等に調製すればよい。
This wilting of the above-ground parts of crops is caused by soil diseases, and therefore, curing of the wilting of above-ground parts of crops also belongs to the present invention.Producing a soil disease control agent containing compound A and compound gt/JB as active ingredients To do this, both components are mixed with a carrier (diluent) according to the conventional method for agricultural chemical formulations, and if necessary, desired adjuvants such as lv surfactants, dispersants, fixing agents, etc. are added. They may be added to form a dosage form convenient for use, such as powders, emulsions, flowables, tablets, aqueous preparations, fine granules, granules, etc.

本発明は、化合物Aと化合物Bとを併用することにより
土壌病害防除に阜効を有することに基づくものであるの
で、化合物Aと化合物Bとをそれぞれ独立した製剤とし
たものを、使用の瞭に両者混用する態様も本発明の範囲
に属する。
The present invention is based on the fact that the combined use of Compound A and Compound B is effective in controlling soil diseases. Embodiments in which both are used in combination also belong to the scope of the present invention.

化合物Aと化合物Bとの配合割合は、必要に応じて加減
し得るが、3:1から1=3までのII@聞から適宜選
択するのがよい。
The blending ratio of Compound A and Compound B can be adjusted as necessary, but it is preferably selected as appropriate from 3:1 to 1=3.

製剤中に於ける有効成分化合物の割合は、粉剤或いは粉
剤の場合には通常0.5〜20X (檎旙)、ま危乳剤
或いは水和剤とする場合にはlO〜51.1%(ル殖)
が適当である。
The proportion of the active ingredient compound in the preparation is usually 0.5 to 20X in the case of a powder or powder, and 10 to 51.1% in the case of an emulsion or wettable powder. breeding)
is appropriate.

本発明は、保護すべき作物の地−上部あるいは土壌を介
して予防的にま念は后療的に適用する態様を包含する。
The present invention includes embodiments in which it is applied prophylactically, therapeutically or therapeutically to the top of the crop to be protected or through the soil.

本発明防除剤の使用鷺は、櫨々の因子例えば被害の程j
に、発生傾向、天候、環境電性、剤型等によって変動す
るが、例えば乳剤や水相剤の様に最終的には液状で使用
すS場合には、一般には有効成分の最終濃度が0.01
%(−Ml)以上になるように#製すればよい。また粉
剤や粒剤の如くそのまま使用する場合には、有効成分と
して10アール当り500g以上散布すればよい。
The pest control agent of the present invention is applied to the heron, depending on factors such as the degree of damage
Although it varies depending on the occurrence tendency, weather, environmental conductivity, dosage form, etc., for example, when the final concentration of the active ingredient is used as a liquid, such as an emulsion or an aqueous phase agent, the final concentration of the active ingredient is generally 0. .01
%(-Ml) or more. When used directly as a powder or granule, 500 g or more of the active ingredient may be dispersed per 10 ares.

さらに本発明防除剤を他の#に解削、殺虫剤、土壌病害
防除剤、殺菌剤もしくは肥料などと配合して、本則の適
用範囲の拡大を図ることh oJ能であゐ。
Furthermore, it is possible to expand the scope of application of this rule by blending the pesticidal agent of the present invention with other chemicals, insecticides, soil disease control agents, fungicides, or fertilizers.

次に、実施例を挙げてさらに本発明を説明するが、本発
明はこれらのみに限定されるものではない。なお、例中
「部」は重M部を示す〇実施例1 化合物A             0.5部化合物B
              l  部ホワイトカーボ
ン         1 部PAP[(ソプロピルアシ
ッドホス7エート日本化学■製]0.3g クレー               97.2gを均
一に混合粉砕して粉剤とする。
Next, the present invention will be further explained with reference to Examples, but the present invention is not limited to these. In addition, "part" in the example indicates heavy M part 〇Example 1 Compound A 0.5 part Compound B
1 part white carbon 1 part PAP [(sopropyl acid phos7ate manufactured by Nippon Kagaku ■) 0.3 g Clay 97.2 g were uniformly mixed and pulverized to obtain a powder.

実施例2 化合物A             10  g化合物
B             20  gキシレン  
          55  gポリオキシエチレンア
ルキルアリルエーテル 15 sを均一に混合溶解して
乳剤とする。
Example 2 Compound A 10 g Compound B 20 g Xylene
55 g of polyoxyethylene alkyl allyl ether (15 s) were uniformly mixed and dissolved to form an emulsion.

実袖例3 化合物A             10  部化合物
8            20  部ホワイトカーボ
ン        20 部ドデシルペンセンスルホン
酸ソーダ      5 部クレー         
      45  gを均一に混合粉砕して水和剤と
する〇 実施例4 化合舎人             5 都化合物B 
            10  gポリビニルアルコ
ール       2 部ホワイトカーボン     
    5 部ドデシルベンゼンスルホン酸ソーダ  
     0.2部クレー             
  77.8部を混合粉砕し、水18部を加えて混練し
、押出造粒機により造粒乾燥して粒剤とする。
Actual sleeve example 3 Compound A 10 parts Compound 8 20 parts White carbon 20 parts Dodecylpensene sodium sulfonate 5 parts Clay
Mix and grind 45 g uniformly to make a wettable powder Example 4 Compound Toneri 5 Miyako Compound B
10 g polyvinyl alcohol 2 parts white carbon
5 parts Sodium dodecylbenzenesulfonate
0.2 parts clay
77.8 parts were mixed and ground, 18 parts of water was added and kneaded, and the mixture was granulated and dried using an extrusion granulator to form granules.

以下に本発明の試−例を示す。Examples of the present invention are shown below.

試験例 キャベツ根こぶ病防除試験 キャベツ根こぶ病菌(Pl!asmodiophOra
  bra−bs 1cae)汚染−場に実施例1と同
様にして製剤化しな本発明粉剤を所定量加えて畦に混和
処理したのち、キャベツ(品m:錦秋)の5〜6葉期の
苗を定植した。1区当りの面梳け5.7m (20株)
としな。
Test example Cabbage clubroot control test Cabbage clubroot fungus (Pl!asmodiophOra
bra-bs 1cae) Contamination - A predetermined amount of the powder of the present invention, which was not formulated in the same manner as in Example 1, was added to the field and mixed into the ridges, and then cabbage (product M: Nishikishu) seedlings at the 5-6 leaf stage were was planted. 5.7 m of combing per section (20 combs)
Toshina.

Claims (1)

【特許請求の範囲】[Claims] (1)  ジイソプロピル1.3−ジチオラン−2−イ
リデンマロネートとN−(1−n−ブトキシ−2,2,
2−トリクロロエチル)−2−ヒドロキシベンズアミド
とを有効成分として含有することを特徴とする農−装用
土壌病害防除剤0
(1) Diisopropyl 1,3-dithiolane-2-ylidene malonate and N-(1-n-butoxy-2,2,
Agricultural soil disease control agent 0 characterized by containing 2-trichloroethyl)-2-hydroxybenzamide as an active ingredient.
JP15262181A 1981-09-26 1981-09-26 Soil disease controlled for agricultural and horticultural purpose Granted JPS5855401A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15262181A JPS5855401A (en) 1981-09-26 1981-09-26 Soil disease controlled for agricultural and horticultural purpose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15262181A JPS5855401A (en) 1981-09-26 1981-09-26 Soil disease controlled for agricultural and horticultural purpose

Publications (2)

Publication Number Publication Date
JPS5855401A true JPS5855401A (en) 1983-04-01
JPS6147804B2 JPS6147804B2 (en) 1986-10-21

Family

ID=15544375

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15262181A Granted JPS5855401A (en) 1981-09-26 1981-09-26 Soil disease controlled for agricultural and horticultural purpose

Country Status (1)

Country Link
JP (1) JPS5855401A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH067205A (en) * 1992-06-26 1994-01-18 Ngk Insulators Ltd Metallic inner cushion for shoes

Also Published As

Publication number Publication date
JPS6147804B2 (en) 1986-10-21

Similar Documents

Publication Publication Date Title
JPS5855401A (en) Soil disease controlled for agricultural and horticultural purpose
JPH05112405A (en) Insecticidal composition
JPS6242902A (en) Stable pasty agricultural chemical coating agent
JPS5855403A (en) Soil disease controller for agricultural and horticultural purpose
JPS5855404A (en) Soil disease controller for agricultural and horticultural purpose
JP3232552B2 (en) Herbicide composition
JPS5945648B2 (en) Sterilizing composition for agriculture and horticulture
JPH07157404A (en) Microbicidal composition for agricultural and horticultural use
JPS5829762B2 (en) Fungicidal composition for agriculture and horticulture
JPH01175910A (en) Germicidal composition
JPS6141490B2 (en)
JPS6152802B2 (en)
JPH05117118A (en) Herbicidal composition
JPS5877802A (en) Herbicide
JPH10101504A (en) Herbicidal composition
JPH045203A (en) Insecticidal or insecticidal and bactericidal composition
JPS6125685B2 (en)
JPS6348841B2 (en)
JPH03284602A (en) Bactericide for agriculture and horticulture
JPS6135962B2 (en)
JP2000256111A (en) Insecticide for agriculture and horticulture containing sesquiterpene pyridine alkaloid compound
JPS5899404A (en) Agricultural and gardening herbicide for soil blight
JPS61194003A (en) Herbicidal composition
JPS60172911A (en) Herbicidal composition for paddy field
JPS63190803A (en) Herbicidal composition