JPS5855403A - Soil disease controller for agricultural and horticultural purpose - Google Patents

Soil disease controller for agricultural and horticultural purpose

Info

Publication number
JPS5855403A
JPS5855403A JP15262081A JP15262081A JPS5855403A JP S5855403 A JPS5855403 A JP S5855403A JP 15262081 A JP15262081 A JP 15262081A JP 15262081 A JP15262081 A JP 15262081A JP S5855403 A JPS5855403 A JP S5855403A
Authority
JP
Japan
Prior art keywords
compound
methylthiol
carbamate
trifluoromethyl
methylsulfonyloxyphenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP15262081A
Other languages
Japanese (ja)
Other versions
JPH0121121B2 (en
Inventor
Katsuhiro Fujishima
藤島 捷洋
Fujio Araki
荒木 不二夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Nihon Nohyaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Nihon Nohyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd, Nihon Nohyaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Priority to JP15262081A priority Critical patent/JPS5855403A/en
Publication of JPS5855403A publication Critical patent/JPS5855403A/en
Publication of JPH0121121B2 publication Critical patent/JPH0121121B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE:The titled controller that contains a combination of o-trifluoromethyl- m'-isopropoxybenzoic acid anilide and 4-methylsulfonyloxyphenyl-N-methylthiol carbamate, thus showing increased effect controlling soil diseases. CONSTITUTION:The titled controller contains, as active ingredients (A) o-trifluoromethyl-m'-isopropoxybenzoic acid anilide and (B) 4-methylsulfonyloxyphenyl-N-methylthiol carbamate or (C) N-(1-n-butoxy-2,2,2-trichloroethyl)-2-hydroxybenzamide. The resultant composition develops higher controlling effects against soil diseases such as dampfing-off of rice plant than in case of their single use, especially, the combination of A and B shows synergic effect against snow mold caused by Fusarium and that of A and C against radish disease caused by Aphanomyces.

Description

【発明の詳細な説明】 本発明は、o−トリフルオロメチル−M−イ−ソブロボ
キシ安息香−アニリド(以下、化合物Aといつ)と4−
メチルスルホニルオキシ7エ二ルーN−メチルチオール
カーバメート(以下、化合物Bという)もしくけN−(
1−n−ブトキシ−2,2,2−1リクロロエチル)−
2−ヒドロキシベンズアミド(以下、化合物0という)
とを有効成分として含有することを特徴とする農園芸用
土壌病害防除剤に関するものである0ここで化合vyJ
Aは特開昭53〜9739号公報明細書記載の公知化合
物であり、主として稲紋枯病に対して有効である。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to o-trifluoromethyl-M-isobroboxybenzoanilide (hereinafter referred to as compound A) and 4-
Methylsulfonyloxy7enyl-N-methylthiol carbamate (hereinafter referred to as compound B) also contains N-(
1-n-butoxy-2,2,2-1lichloroethyl)-
2-hydroxybenzamide (hereinafter referred to as compound 0)
The invention relates to a soil disease control agent for agriculture and horticulture, which is characterized by containing as an active ingredient the compound vyJ
A is a known compound described in JP-A-53-9739, and is mainly effective against rice sheath blight.

また、化合物B及び化合vJCは各々特開昭53−47
527号、特開昭54−39040号公報記載の公知化
合物であり、土壌病害防除剤としての活性を有する。
Compound B and compound vJC are each JP-A-53-47
It is a known compound described in No. 527 and JP-A-54-39040, and has activity as a soil disease control agent.

本発明者等は今般、土壌病害防除剤の研究を進めてきた
結果、種菌立枯病、野菜菌立枯病、キュウリ立枯性疫病
、ナス半身萎凋病、イチゴ芽枯病、イチゴ根腐れ病、ダ
イコン亀裂褐変症、麦雪腐れ病、芝雪腐れ病、ブラウン
パッチ、春はげ症等の土壌病害に対し、化合舎人と化き
物Bもしくは化合物Cとを有効成分として含有する当該
防除剤は、各単剤で用いるよりも極めて高い防除効果を
示すことを見い出した。
As a result of research on soil disease control agents, the present inventors have recently discovered the following: seed fungus damping-off, vegetable fungus damping-off, cucumber damping-off, eggplant half-wilt, strawberry bud blight, and strawberry root rot. , radish crack browning, wheat snow rot, turf snow rot, brown patch, spring baldness, and other soil diseases. It was discovered that the control effect was significantly higher than that of each agent alone.

これら上張病害のうち、化合物Aと化合物Bとを有効成
分として含有する当該防除剤は、麦および芝の雪腐れ病
、特に7ザリウム(Fusarium)菌に起因する紅
色雪腐れ病に対して、各単剤の効果と比して相乗的な効
果を有する。
Among these epitonic diseases, the control agent containing Compound A and Compound B as active ingredients is effective against snow rot of wheat and grass, especially red snow rot caused by Fusarium fungi. It has a synergistic effect compared to the effect of each single agent.

まな、化合物Aと化合物Cとを有効成分として含有する
当該防除剤は、ダイコン亀裂褐変症、とりわけア7アノ
マイセス菌(Aphenomyces )に起因する同
病害に対して、各単剤の効果に比して相乗的な効果を仔
する。
Furthermore, the control agent containing Compound A and Compound C as active ingredients is more effective than each single agent against radish crack browning disease, especially the disease caused by Aphenomyces. Produces a synergistic effect.

化合物Aと化合物Bもしくけ化合物0とを有効1ル分と
して含有する土壌病害防除剤を製造するには、両成分を
農薬製剤上の常法に従って担体(希釈剤)と混合し、必
要により所望の補助剤、例えば界面活性剤、分数剤、固
着剤等を添加し、使用に都合のよい剤型、例えば粉剤、
乳剤、フロアブル、錠剤、水和剤、微粒剤、粒剤等に調
輌すれけよい。
To produce a soil disease control agent containing an effective amount of Compound A, Compound B, or Compound 0, both components are mixed with a carrier (diluent) according to a conventional method for agricultural chemical formulations, and if necessary, the desired amount is added. Auxiliary agents such as surfactants, fractionating agents, fixing agents, etc. are added to form a dosage form convenient for use, such as powders, etc.
It can be prepared into emulsions, flowables, tablets, wettable powders, microgranules, granules, etc.

本発明は、化合4IJ人と化合?lJ Bもしくは化合
10とを併用することにより土壌病害防除に卓効を有す
ることに基づくものであるので、化合−Aと化合物Bも
しくけ化合物0とをそれぞれ独立した製剤とじなものを
、使用の際に両者混用する態様も本発明の範囲に属する
Is the present invention a combination of compound 4IJ and people? This is based on the fact that the combined use of IJ B or Compound 10 has an excellent effect on controlling soil diseases. Embodiments in which both are used in combination also belong to the scope of the present invention.

化合物Aと化合物Bもしくは化合物0との配合割合は、
必々に応じて加減し得るが、6:l ないし1:10の
範囲から適宜選択するのが都合がよい。
The blending ratio of compound A and compound B or compound 0 is
Although the ratio can be adjusted according to necessity, it is convenient to select the ratio as appropriate from the range of 6:l to 1:10.

製剤中に於ける有効成分化合物の割合は、粉剤或いは粒
剤の場合、通常0.5〜加X(−一)、また乳剤或いは
水和剤の場合、10〜50%(改it)が適当である。
The proportion of the active ingredient compound in the preparation is usually 0.5 to +X (-1) in the case of powders or granules, and 10 to 50% (modified IT) in the case of emulsions or wettable powders. It is.

本発明け、保護すべき作物の地り部にじかにあるいは土
壌を介して、予防的または治療的に適用する態様を包含
する。
The present invention includes embodiments in which it is applied prophylactically or therapeutically to the ground of crops to be protected, either directly or through the soil.

本発明防除剤の使用量は、種々の因子、例えば被害の程
度、発生傾向、天候、環境条件、剤型等によって変動す
る。例えば乳剤や水和剤のように最終的には液状で使用
する場合、一般には有効成分の最終製産が0.01%(
重置)以、トになる如く#製すればよい。
The amount of the pest control agent of the present invention to be used varies depending on various factors such as the degree of damage, tendency of occurrence, weather, environmental conditions, dosage form, etc. For example, when the final product is used in a liquid form, such as an emulsion or a wettable powder, the final product of the active ingredient is generally 0.01% (
(Overlapping) From now on, you can make # as shown in (G).

また粉剤や粒剤のようにそのまま使用する場合には、有
効成分としてlOアール当り、50g以ト散布すればよ
い。
When used directly as a powder or granule, 50 g or more of the active ingredient may be sprayed per 10 are.

また、本発明防除剤を他の除草剤、殺虫剤、土壌病害防
除剤、殺菌剤または肥料等と配合して・本発明防除剤の
適用範囲の拡大を図ることもaf能である。
It is also possible to expand the scope of application of the pesticidal agent of the present invention by blending it with other herbicides, insecticides, soil disease control agents, fungicides, fertilizers, etc.

次に、実施例の若干を挙けるが、本発明がこれらのみに
限定されるものではない0なお、[部]け東一部を示す
Next, some examples will be listed, but the present invention is not limited to these examples.

実権例1 化合物A              1部化合物B(
もしくけ化合物0)   0.5部ホワイトカーボン 
        1部PAPLイソプロピルアシッドホ
ス7エート:日本化学■製〕0.3部 クレー              97.2部を均一
に混合粉砕して粉剤とする0 実施例2 化合物A             241%Ii化合
物B(もしくは化身物0)    6部キシレン   
         55部ポリオキシエチレンアルキル
アリルエーテル  15部を均一に混合溶解して乳剤と
する。
Practical example 1 Compound A 1 part Compound B (
Compound 0) 0.5 part white carbon
1 part PAPL isopropyl acid phos7ate: manufactured by Nippon Kagaku ■ 0.3 parts Clay 97.2 parts are uniformly mixed and ground to make a powder Example 2 Compound A 241% Ii Compound B (or incarnation 0) 6 parts xylene
55 parts polyoxyethylene alkyl allyl ether 15 parts were uniformly mixed and dissolved to prepare an emulsion.

実−例3 化合*A             22部化合物B 
(4L<ハ化合vJO)    8部ホワイトカーボン
         20部ドデシルベンゼンスルホン酸
ソーダ       5部クレー          
     45$を均一に混合粉砕して水和剤とする。
Practical example 3 Compound *A 22 parts Compound B
(4L<Ha compound vJO) 8 parts white carbon 20 parts sodium dodecylbenzenesulfonate 5 parts clay
45$ was uniformly mixed and ground to make a wettable powder.

実施例4 化合舎人             8部化合物B(も
しくは化合物0)   7部ポリビニルアルコール  
     2部ホワイトカーボン         5
部ドデシルベンゼンスルホン酸ソーダ      0.
2部クレー              77.8部を
混合粉砕し水18部を加えて混練し、押出造粒機により
造粒乾燥して粒剤とする。
Example 4 Compound Toneri 8 parts Compound B (or Compound 0) 7 parts Polyvinyl alcohol
Part 2 White Carbon 5
Part Sodium Dodecylbenzenesulfonate 0.
2 parts 77.8 parts of clay are mixed and pulverized, 18 parts of water is added and kneaded, and the mixture is granulated and dried using an extrusion granulator to form granules.

次に、本発明の試験例を示す。Next, test examples of the present invention will be shown.

試験例1 ムギ雪腐れ病防除試験 紅色雪腐れ病〔病原菌フザリウムニアくしくFusar
ium n+vale) )が多発する小麦(品種:ホ
ロシリコムギ)圃場に、実−例3と同様にして製剤化し
た本発明水和剤全、所定量根雪直前に加田式噴錆機にて
散布した。
Test Example 1 Wheat snow rot control test Red snow rot [Pathogen Fusarium
A predetermined amount of the entire wettable powder of the present invention, which was formulated in the same manner as in Example 3, was sprayed using a Kada-type rust sprayer on a field of wheat (variety: hollywheat) where a large number of wheat (variety: wheat) were found to have a high incidence of .

なお、1区当りの而#Iは15m2 とした。In addition, #I per ward was set to 15 m2.

融雪後、発病指数別に調査し、次式によって発病度を算
出し、防除価を求めた0 発病指数4:完全枯死 3:全集及び茎の半数枯死 2:全集及び茎の一部枯死 l二乗の半数枯死 0:健全 需勤哩り兄貢匿 第1表に試験結果を示す。
After the snow melted, the disease index was investigated, and the disease severity was calculated using the following formula to determine the control value. Half of the plants withered and died 0: Healthy demand and growth The test results are shown in Table 1.

第1表 試験例2 ダイコン亀裂褐変症防除試験リゾクトニア 
ソラニ(Rh1zoctonia 5olani)r’
j 染土壌に77アノマイセス ラファ二(Apha−
nomyses raphani )の胞子懸fRJ液
を潅注して病上を作成し、実施例1と同様にして製剤化
しな本発明粉剤を所定量よく混和したのち、ダイコン(
品種=lLみの早生1号)の種子を播種した。
Table 1 Test Example 2 Radish crack browning disease control test Rhizoctonia
solani (Rh1zoctonia 5olani) r'
j 77 Anomyces raphani (Apha-
A spore-suspending fRJ solution of Japanese radish (Japanese radish) was irrigated to prepare a diseased surface, and a predetermined amount of the powder of the present invention, which had not been formulated in the same manner as in Example 1, was thoroughly mixed therein.
Seeds of cultivar = 1L Mino Waseda No. 1) were sown.

なお1区の116檀は18m2としな。The 116 dan in the 1st ward is 18m2.

播4後あ日月にダイコンを抜きとり、程度側に発病調査
を行い、次式によって発病度を鄭出し防除価を求めた0 N n :発病面積率1%以下の株数 唱 n2 :   ”    1〜3%の株数ns :  
 、/3%以上Q株数 N :調査株数 第2表に試験結果を示す。
Four days after sowing, the radish plants were pulled out, and the disease severity was investigated.The disease severity was determined using the following formula, and the control value was determined. ~3% shares ns:
, /3% or more Q Number of strains N: Number of investigated strains The test results are shown in Table 2.

第2表Table 2

Claims (1)

【特許請求の範囲】[Claims] 0−トリフルオロメチル−m′−イソプロポキシ安息香
酸アニリドと4−メチルスルホニルオキシフェニル−N
−メチルチオールカーバメートもしくはN−(1−n−
ブトキシ−2,2,2−トリクロロエチル)−2−ヒド
ロキシベンズアミドとを有効成分として含有することを
特徴とする農園芸用土壌病害防除剤。
0-Trifluoromethyl-m'-isopropoxybenzoic acid anilide and 4-methylsulfonyloxyphenyl-N
-methylthiol carbamate or N-(1-n-
1. A soil disease control agent for agriculture and horticulture, characterized in that it contains 2,2,2-trichloroethyl)-2-hydroxybenzamide as an active ingredient.
JP15262081A 1981-09-26 1981-09-26 Soil disease controller for agricultural and horticultural purpose Granted JPS5855403A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15262081A JPS5855403A (en) 1981-09-26 1981-09-26 Soil disease controller for agricultural and horticultural purpose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15262081A JPS5855403A (en) 1981-09-26 1981-09-26 Soil disease controller for agricultural and horticultural purpose

Publications (2)

Publication Number Publication Date
JPS5855403A true JPS5855403A (en) 1983-04-01
JPH0121121B2 JPH0121121B2 (en) 1989-04-19

Family

ID=15544354

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15262081A Granted JPS5855403A (en) 1981-09-26 1981-09-26 Soil disease controller for agricultural and horticultural purpose

Country Status (1)

Country Link
JP (1) JPS5855403A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6169614U (en) * 1984-10-09 1986-05-13
JP2009286786A (en) * 2008-04-28 2009-12-10 Ishihara Sangyo Kaisha Ltd Agricultural and horticultural bactericide composition and plant disease control agent

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5347527A (en) * 1976-10-08 1978-04-28 Nippon Kayaku Co Ltd Soil fungicides for agriculture and horticulture
JPS5439040A (en) * 1977-09-01 1979-03-24 Nippon Kayaku Co Ltd Novel 2-hydroxybenzamide derivatives and bactericides for the soil
JPS5531048A (en) * 1978-08-28 1980-03-05 Kumiai Chem Ind Co Ltd Agricultural and horticultural fungicide composition
JPS5553204A (en) * 1978-10-17 1980-04-18 Nippon Nohyaku Co Ltd Agricultural and horticultural fungicidal composition
JPS5559103A (en) * 1978-10-26 1980-05-02 Kumiai Chem Ind Co Ltd Germicidal composition
JPS5566504A (en) * 1978-11-13 1980-05-20 Kumiai Chem Ind Co Ltd Agricultural and horticultural fungicide composition
JPS55129213A (en) * 1979-03-22 1980-10-06 Nippon Nohyaku Co Ltd Agricultural and horticultural microbicide
JPS55164604A (en) * 1979-06-12 1980-12-22 Nippon Nohyaku Co Ltd Germicidal composition for agricultural and horticultural use

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5347527A (en) * 1976-10-08 1978-04-28 Nippon Kayaku Co Ltd Soil fungicides for agriculture and horticulture
JPS5439040A (en) * 1977-09-01 1979-03-24 Nippon Kayaku Co Ltd Novel 2-hydroxybenzamide derivatives and bactericides for the soil
JPS5531048A (en) * 1978-08-28 1980-03-05 Kumiai Chem Ind Co Ltd Agricultural and horticultural fungicide composition
JPS5553204A (en) * 1978-10-17 1980-04-18 Nippon Nohyaku Co Ltd Agricultural and horticultural fungicidal composition
JPS5559103A (en) * 1978-10-26 1980-05-02 Kumiai Chem Ind Co Ltd Germicidal composition
JPS5566504A (en) * 1978-11-13 1980-05-20 Kumiai Chem Ind Co Ltd Agricultural and horticultural fungicide composition
JPS55129213A (en) * 1979-03-22 1980-10-06 Nippon Nohyaku Co Ltd Agricultural and horticultural microbicide
JPS55164604A (en) * 1979-06-12 1980-12-22 Nippon Nohyaku Co Ltd Germicidal composition for agricultural and horticultural use

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6169614U (en) * 1984-10-09 1986-05-13
JPH033767Y2 (en) * 1984-10-09 1991-01-31
JP2009286786A (en) * 2008-04-28 2009-12-10 Ishihara Sangyo Kaisha Ltd Agricultural and horticultural bactericide composition and plant disease control agent

Also Published As

Publication number Publication date
JPH0121121B2 (en) 1989-04-19

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