JPS58208655A - Ph measuring apparatus - Google Patents

Ph measuring apparatus

Info

Publication number
JPS58208655A
JPS58208655A JP9128382A JP9128382A JPS58208655A JP S58208655 A JPS58208655 A JP S58208655A JP 9128382 A JP9128382 A JP 9128382A JP 9128382 A JP9128382 A JP 9128382A JP S58208655 A JPS58208655 A JP S58208655A
Authority
JP
Japan
Prior art keywords
float
wall
sensor
cylindrical
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9128382A
Other languages
Japanese (ja)
Inventor
Seiji Matsuura
松浦 清治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON DANFUOSU SEIZO KK
Original Assignee
NIPPON DANFUOSU SEIZO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON DANFUOSU SEIZO KK filed Critical NIPPON DANFUOSU SEIZO KK
Priority to JP9128382A priority Critical patent/JPS58208655A/en
Publication of JPS58208655A publication Critical patent/JPS58208655A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/38Cleaning of electrodes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Biological Materials (AREA)

Abstract

PURPOSE:To impart self-cleaning function, by a method wherein a cylindrical pH sensor part having a measuring window is contained in an inner wall and a float part containing the measuring window as the part of an outer wall and having an outer shape molded into a spherical form is provided. CONSTITUTION:A pH sensor part 7 is cylindrical and the lower periphery of the inner liquid storage part 13 thereof is a liquid communication part 11 while the measuring window provided to the under surface thereof is a glass electrode 12. A float part 20 consists of a spherical outer wall 21, a cylindrical inner wall 22 and an attachment part 23 to an arm. The attachment part 23 is similarily cylindrical and the lower part of the inner wall thereof is provided with a thread part 29 and engaged with the peripheral flange 31 of a holder 30 above the pH sensor part 1 by the thread part. Because the pH sensor part is embedded in the float part and the under surface thereof immersed in a liquid for the sake of measurement is formed as the part of the float part, the pH sensor part is subjected to self-cleaning by a water stream and extremely convenient.

Description

【発明の詳細な説明】 この発明は、PH濱、定装置に関するものである。[Detailed description of the invention] The present invention relates to a PH concentration device.

排水処理や下水処@等においてに、水のPHをKat値
にコントロールすることが求められる。
In wastewater treatment, sewage treatment, etc., it is required to control the pH of water to the Kat value.

通常、IJ&理済の水はPH7にもどされることが求め
られ、このような処理過程で、数多くのP H@r定装
rが使用される。
Normally, IJ&Risa water is required to be returned to a pH of 7, and a large number of P H@r systems are used in this treatment process.

ところで、PHセンサーF:fラスを歇七用いたものが
知られているが、このPHセンサーのガラス電極d排水
醇に没せられて使用されるため、シラス電極等に所謂1
′水あか7′が蓄積し、正確なPH測測定行なえなくな
ったり、極艷なt合PHそのものの測定が困難となった
By the way, a PH sensor F is known that uses f glass electrodes, but since the glass electrode d of this PH sensor is used by being immersed in waste water, the so-called glass electrode etc.
``Water scale 7'' accumulated, making it impossible to carry out accurate PH measurements, and making it difficult to measure the extreme pH itself.

そこで、PHセンサーのガラス電析部分に、水あるいは
空気を吹き付けて、水中にて水あかを洗浄する手法が考
えられる。しかし、この手法では水あるいは空気を吹き
付けるための特別な装置を必要とする。しかも、PHセ
ンf−に洗浄機構の一部を取り付けねばならぬから、P
H測定装置自体が大型化し、複雑化する。更に、全装置
のコストがアップしてしまう欠点がおった。
Therefore, a method can be considered in which water or air is sprayed onto the glass electrodeposited portion of the PH sensor to clean the water scale underwater. However, this method requires special equipment for spraying water or air. Moreover, since a part of the cleaning mechanism must be attached to the PH sensor f-,
The H measuring device itself becomes larger and more complex. Furthermore, there was a drawback that the cost of the entire device increased.

本発明は、このような欠点に鑑みなされたもので、その
目的は、大型化及び複雑化することがなく、かつ、大幅
なコストアップとならなし、自己挽浄機能を有するPH
測定装【を徒供することである。
The present invention has been made in view of these drawbacks, and its purpose is to provide a PH having a self-cleaning function without increasing the size and complexity, and without causing a significant increase in cost.
It is to provide measurement equipment.

第1図は本発明に用いられるPHセンサ一部の側面図で
ある。同図において、11はPHセンサー部1の液絡部
を示し、12は測定用策たるガラスを杯を示す。PHセ
ンサ一部1は円筒状で心って、同部液貯蔵部13の下方
¥TU日が液絡部11であり、下面のジ1]定用愈がガ
ラスを極12である。
FIG. 1 is a side view of a portion of the PH sensor used in the present invention. In the figure, numeral 11 indicates a liquid junction of the PH sensor section 1, and numeral 12 indicates a glass used for measurement. The pH sensor part 1 has a cylindrical shape, and the lower part of the liquid storage part 13 is the liquid junction part 11, and the lower part 1 has a glass pole 12.

内■シ液貯蔵都13の上方はプラグ部J4であって、0
リン!15が設けられ、その上部1グネジ16となり更
に、その上方にコネクタ17となっていて、コネクタ1
7を介してPH[関する信号−二出力される。
Above the inner liquid storage cap 13 is the plug part J4, which is 0
Rin! 15 is provided, and the upper part thereof is a 1-inch screw 16, and further above that is a connector 17, which connects the connector 1.
7, a signal related to PH[-2 is output.

第29a浮子部を示す。浮子部20Fi、球状の外販2
1と、円筒状の内壁22と、アームへの取付部23とか
らなる。
The 29th a float part is shown. Float part 20Fi, spherical external sales 2
1, a cylindrical inner wall 22, and an attachment part 23 to the arm.

外壁21と内壁22とは、一体に形成され、それらが作
り出す箆24には、下方に鉄片25が重りとして。
The outer wall 21 and the inner wall 22 are integrally formed, and a piece of iron 25 serves as a weight at the bottom of the bar 24 created by them.

発電スチロール26がバーストとして入れられる。Power-generating styrene 26 is put in as a burst.

これによって、浮子部20汀液体表曲27にやや没して
浮くことができる。また、内壁22には、その上)y5
人ロー・らネジ28Aが切られ、取付部23のネジ28
Bとによって、Ptlセンヤ一部lを駁納する構造とな
っている。取付部23も同筒状で、その内壁の下方には
ネジ29が切られ、PHセンサ一部1の上方のホルダ3
0の周線31とネジでかみ合わ畑イユ、石、。
Thereby, the float part 20 can be slightly submerged in the liquid surface curve 27 and float. In addition, on the inner wall 22,
The human row screw 28A is cut, and the screw 28 of the mounting part 23 is cut.
B, the structure is such that a portion of the Ptl senya l is delivered. The mounting part 23 also has the same cylindrical shape, and a screw 29 is cut in the lower part of the inner wall thereof, and the holder 3 above the PH sensor part 1
Field Iyu, stone, interlocked with the circumferential line 31 of 0 with screws.

ホルダ30の上方には、モール一部32が設けられ6、
PHセセンー剖1のコネクタ17からリード綜33が延
びるようになっている。
A molding part 32 is provided above the holder 30 6,
A lead heel 33 extends from the connector 17 of the PH sensor 1.

このように構成された浮子部20は、第3図のように、
アーム50と取付部23とが連結さカフることにより、
一定の範囲を運動するようになる。
The float part 20 configured in this way is as shown in FIG.
By connecting the arm 50 and the attachment part 23,
You will be able to move within a certain range.

アーム50#′i固定具51に貫通して設けられる。こ
の固定具51は調整ネ−)52と、本体53と、固定具
51を回動自在とした切欠部54とからなる。
The arm 50#'i is provided to penetrate the fixture 51. This fixture 51 consists of an adjustment needle 52, a main body 53, and a notch 54 that allows the fixture 51 to rotate freely.

固定具51は、調整ネジ52によって、アーム50の長
さを調整可能であり、液体面27の上下による浮子部2
0の上下運動に追従して回動する。
The fixture 51 can adjust the length of the arm 50 with an adjustment screw 52, and the length of the arm 50 can be adjusted by adjusting the length of the float part 2 depending on the upper and lower sides of the liquid level 27.
It rotates following the vertical movement of 0.

55ハ台であって、液から立設され、この台55からは
支持1156A、56Bが2本立てられる。この支持棒
56A156Bには、図の手前方向に突出したw#57
が6本設けられる。このI!57の高さによっても浮子
部20の運動範囲が制限される。また、破線で示すよう
に液体面27の変動に浮子部20が最従しかつ一点鎖線
のようにされて、保守・点検がなされる。
55 is a stand erected from the liquid, and two supports 1156A and 56B are erected from this stand 55. This support rod 56A156B has w#57 protruding toward the front in the figure.
There are six. This I! The range of movement of the float section 20 is also limited by the height of the float section 57. Further, as shown by the broken line, the float part 20 is made to follow the fluctuations of the liquid level 27 as shown by the dashed line, and maintenance and inspection are performed.

以上のように、PH測定装置が構成されているので、例
えば、液体面では、第3図のように支持棒56Aの最上
段に設けられた棒57に固定具51を紺り付i1アーム
50を所定の長さとして、調整ネ−)52を締め付ける
。すると、浮子部20は液体面27の変動によって、あ
るいは、液体の流れによって、一定範囲を浮遊する。こ
のとき、浮子g[!20の下面1−1PHセンサ一部1
のガラス電極12や液絡部11となっている。したがっ
て、これらガラス電極12や液絡部11に、第4図に示
されるような水流によって断えず洗浄される。即ち、浮
子部20が上昇するときには、浮子部20の下面に対し
て第4図Aの矢印Xuで示されるような水流が生じ、ガ
ラス電極12や液絡11を自己洗浄する。また、浮子部
20が下降するときには、浮子部20の下面に対して第
4図Bの矢印XLlで示されるような水流か生じ、ガラ
ス電極12や液絡部11を自己洗浄する。
As the PH measuring device is configured as described above, for example, at the liquid level, the fixture 51 is attached to the rod 57 provided at the top of the support rod 56A as shown in FIG. Adjust the length to the specified length and tighten the adjustment screw 52. Then, the float part 20 floats within a certain range due to fluctuations in the liquid level 27 or due to the flow of the liquid. At this time, the float g[! Bottom surface of 20 1-1 PH sensor part 1
The glass electrode 12 and the liquid junction 11 are formed by the glass electrode 12 and the liquid junction part 11. Therefore, the glass electrode 12 and the liquid junction 11 are constantly cleaned by the water flow as shown in FIG. That is, when the float part 20 rises, a water flow as shown by the arrow Xu in FIG. 4A is generated against the lower surface of the float part 20, and the glass electrode 12 and the liquid junction 11 are self-cleaned. Further, when the float part 20 descends, a water flow as shown by the arrow XLl in FIG. 4B is generated on the lower surface of the float part 20, and the glass electrode 12 and the liquid junction part 11 are self-cleaned.

この他、横方向の水流によっても浮子部20F:を液体
面を運動するから自己洗浄がなされて、。
In addition, the float part 20F: is also self-cleaned by moving on the liquid surface due to the horizontal water flow.

このる、PHセン廿−剖1の下面(でと、るガラス電極
や液絡部にに一部め〃ニア゛が付着しにくく、実用上、
長らく保守・点検の作業は不要となる。
In this case, the glass electrode and liquid junction on the bottom surface of the PH sensor unit 1 are difficult to adhere to, so in practice,
Maintenance and inspection work will be unnecessary for a long time.

また、保守点検のFKに、第3図の一点鎖線で示したよ
うに、支持棒56A、56Bに水平にして点検すること
ができる。
In addition, during maintenance and inspection, the FK can be inspected by placing it horizontally on the support rods 56A and 56B, as shown by the dashed line in FIG.

このように、本発明によれば、PH−t7サ一部を浮子
部に埋め込み、かつ、測定の為に液体中に没しられてい
る下面を浮子部の一部としているので、水流により、自
己洗浄され、極めて便利でおる。
As described above, according to the present invention, a part of the PH-t7 is embedded in the float part, and the lower surface that is submerged in the liquid for measurement is part of the float part, so that the water flow can It is self-cleaning and extremely convenient.

このような本発明の装置によれば、装置を大型化、複雑
化することなく、かつ、大幅なコストアップを防止でき
る。
According to such a device of the present invention, it is possible to prevent the device from becoming larger or more complicated, and to prevent a significant increase in cost.

尚、本発明においての、PHの最終的測定は、PHセン
サ一部から得られた電流をり−、ドfg33から図示せ
ぬ計fl!I装艷に導き、これを増幅し、電圧に変換し
、この電圧に比例させてメータを振らせる等する。
Incidentally, in the present invention, the final measurement of PH is carried out by using the current obtained from a part of the PH sensor and from fg33 to a total fl! (not shown). It is led to the I equipment, amplified, converted to voltage, and made to swing a meter in proportion to this voltage.

【図面の簡単な説明】[Brief explanation of drawings]

第1図に本発明に用いられるPHセセン一部の側面図、
第2図は浮子部の断面図、第3図は本発明装はの実施例
の斜視図、第4図は自己洗浄される様子を示す図である
FIG. 1 is a side view of a part of the PH sensor used in the present invention.
FIG. 2 is a sectional view of the float, FIG. 3 is a perspective view of an embodiment of the device of the present invention, and FIG. 4 is a diagram showing how it is self-cleaned.

Claims (1)

【特許請求の範囲】 測定用意を下面に有する円S状PH七ンサ一部と、*P
H十ンサー音2を内先に駅組し、前記浮゛]定用惣を外
壁の一部としてt与、その外形を球状とした浮子部と、
浮子部を吊すアームと、該浮子部とアームとを連結する
取付部と、棒に取シ付けられ。 アームのぎさを調整し、浮子部の運動に応じて回動する
固定具とを有することを製徴とするPH沌]定装【。
[Claims] A part of a circular S-shaped PH7 sensor having a measurement preparation on the lower surface, *P
A float part with the H tensa sound 2 placed at the inner end, the said floating part being attached as a part of the outer wall, and the outer shape of the float part being spherical;
An arm for suspending a float part, a mounting part for connecting the float part and the arm, and a mounting part attached to a rod. The PH Chaos set is characterized by having a fixture that adjusts the tension of the arm and rotates according to the movement of the float.
JP9128382A 1982-05-31 1982-05-31 Ph measuring apparatus Pending JPS58208655A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9128382A JPS58208655A (en) 1982-05-31 1982-05-31 Ph measuring apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9128382A JPS58208655A (en) 1982-05-31 1982-05-31 Ph measuring apparatus

Publications (1)

Publication Number Publication Date
JPS58208655A true JPS58208655A (en) 1983-12-05

Family

ID=14022128

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9128382A Pending JPS58208655A (en) 1982-05-31 1982-05-31 Ph measuring apparatus

Country Status (1)

Country Link
JP (1) JPS58208655A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05322840A (en) * 1992-05-18 1993-12-07 Mitsui Eng & Shipbuild Co Ltd Water content measuring instruemtn and method
US11874137B1 (en) 2022-11-08 2024-01-16 Synca Group, Ltd. Measurement apparatus

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5766350A (en) * 1980-10-09 1982-04-22 Nippon Danfuosu Seizo Kk Measuring method for concentration of dissolved oxygen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5766350A (en) * 1980-10-09 1982-04-22 Nippon Danfuosu Seizo Kk Measuring method for concentration of dissolved oxygen

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05322840A (en) * 1992-05-18 1993-12-07 Mitsui Eng & Shipbuild Co Ltd Water content measuring instruemtn and method
US11874137B1 (en) 2022-11-08 2024-01-16 Synca Group, Ltd. Measurement apparatus
JP2024068280A (en) * 2022-11-08 2024-05-20 株式会社シンカグループ Measurement equipment

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