JPS58200572A - Manufacture of semiconductor device - Google Patents

Manufacture of semiconductor device

Info

Publication number
JPS58200572A
JPS58200572A JP8384182A JP8384182A JPS58200572A JP S58200572 A JPS58200572 A JP S58200572A JP 8384182 A JP8384182 A JP 8384182A JP 8384182 A JP8384182 A JP 8384182A JP S58200572 A JPS58200572 A JP S58200572A
Authority
JP
Japan
Prior art keywords
layer
boron
film
single crystal
etching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8384182A
Other languages
Japanese (ja)
Inventor
Homare Matsumura
松村 誉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP8384182A priority Critical patent/JPS58200572A/en
Publication of JPS58200572A publication Critical patent/JPS58200572A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Thin Film Transistor (AREA)

Abstract

PURPOSE:To contrive to improve the gate withstand voltage by a method wherein, utilizing the difference of etching speeds by impurities, a semiconductor region wherein an impurity is not introduced is let to remain in the form of islands with smooth side surfaces, and then a gate insulation film is adhered to the thickness of approx. uniformity. CONSTITUTION:A single crystal Si layer 6 and an Si oxide film 7 are deposited on a sapphire substrate 5, and boron is ion-implanted by patterning, resulting in the formation of boron layers 9 of high density. When isotropic etching is performed by chemical dry etching, the single crystal Si layer 6 has a high etching speed on the upper side and low etching speed on the lower side wherein the boron layer 9 are formed, and accordingly the side surfaces of the single crystal Si layer 6 remaining in the form of islands becomes smooth slopes of 15-30l. The Si dioxide film 7 is removed and thermally oxidized into the gate insulation film 3. Thereafter, an SOS/MOS transistor is manufactured in accordance with the normal processes.

Description

【発明の詳細な説明】 〔発明の技術分針〕 本発明は、?pJh、縁蔓砂上に半導体領域を形成した
MOa型半導体装置の製造方法に関するものである。 
   ゛ 〔発明の技術B−j背景とその間軸点〕一般に絶縁基板
上に半導体領域を設けた半導体装置としては1例えばS
O8/MO8)ランジスタが代表的である。このSO8
/MO8)ランジスタの製造に当って咄縁番様上に設け
られた半導体膜の素子分離方法としては、素子間の半導
体膜をエツチング除去するコンベンショナル・プロセス
と、X手間に厚い絶縁膜を埋め込むコプレーナ・プロセ
ス(H経エレクトロニクス、1979.7,23%)’
122 ”)とがある。
[Detailed Description of the Invention] [Technology of the Invention Minute Hand] What is the present invention? pJh, relates to a method of manufacturing an MOa type semiconductor device in which a semiconductor region is formed on edge sand.
゛[Technology of the Invention B-j Background and Axis Points] In general, as a semiconductor device in which a semiconductor region is provided on an insulating substrate, 1, for example, S
A typical example is a transistor (O8/MO8). This SO8
/MO8) Device isolation methods for semiconductor films provided on the edge board during the manufacture of transistors include a conventional process in which the semiconductor film between the elements is removed by etching, and a coplanar process in which a thick insulating film is embedded in a time-consuming process.・Process (H Kei Electronics, 1979.7, 23%)'
122”).

このウチコンベンショナル・フロセスによル裕子分離方
法は、コプレーナ・フロセスに比べて寸法岐換差を小さ
くすることができるので高密健化に迩している。
Compared to the coplanar process, this method of separation using conventional floss can reduce the difference in size, leading to higher density.

コ(7)コンベンショナル・プロセスにより形成された
MOS)ランジスタの構造を81図に示すと、絶縁基数
1上に、台形状をなす島状に分離された素子領域2が設
けられ、更にこの上にケート絶縁膜3を介してゲート電
億4が形成されている。
Figure 81 shows the structure of a (7) MOS transistor formed by a conventional process. On an insulating base 1, an element region 2 separated into trapezoidal islands is provided, and on top of this is provided an element region 2 separated into trapezoidal islands. A gate electrode 4 is formed with a gate insulating film 3 interposed therebetween.

従来のコンベンショナル・プロセスで形成された台形状
をなす素子領域2の側面はかかり急峻な傾斜となる、例
えば素子唄wt2を単結晶シ11コンを用いて形成する
場合、単結晶シリコン1に:異方性エツチングして素子
性Mを行なうと、単結晶シリコン−A面が(1,0,0
>曲のとき、素子領域2の一山は<1 、1 、1>曲
となり、この@lと杷縁基81!1との成す角度は54
.7贋となる。この上にゲート杷$Sを被着すると、本
子頑域2の側面は急峻なため、ケート絶縁膜3は;!A
1図(BlにkWで囲って示すように、素子領域2のi
ll+mと絶縁基板1との昇l近傍で麹くなる。仁のよ
うVCCゲート縁膜3が局部的に薄くなると、ゲート耐
土が低下する原因となる(日経エレクトロニクス、19
79.7.23%PI 22参fF@)。
The sides of the trapezoidal device region 2 formed by the conventional conventional process have a steep slope. When element quality M is performed by directional etching, the single crystal silicon-A plane becomes (1,0,0
> song, one peak of the element region 2 becomes a <1, 1, 1> song, and the angle formed between this @l and the lobe edge base 81!1 is 54
.. 7 becomes a fake. When gate loquat $S is deposited on top of this, since the sides of the main area 2 are steep, the gate insulating film 3 becomes;! A
Figure 1 (as shown in Bl surrounded by kW, i of element region 2
It becomes koji in the vicinity of the height 1 between ll+m and the insulating substrate 1. If the VCC gate membrane 3 becomes locally thin, it will cause a decrease in gate earth resistance (Nikkei Electronics, 1999).
79.7.23% PI 22 reference fF@).

このタメ、コンベンショナル・プロセスにおける素子領
域2の側面角度とゲート耐圧との関係が従来研究されて
いる。文献TEEgTransactions  on
  Electron  Devices(Vol  
ED−28No、3 Murch 1981、P242
)によnti側l1ID角匿を35肢以Fにすることに
よりコンベンショナル・フーロセスにおいてもゲート耐
圧を大幅に同上させることができると馴9告されている
For this reason, the relationship between the side angle of the element region 2 and the gate breakdown voltage in the conventional process has been studied. LiteratureTEEgTransactions on
Electron Devices (Vol.
ED-28No, 3 Murch 1981, P242
), it has been reported that by setting the l1ID angle on the opposite side to 35 or more F, it is possible to significantly increase the gate withstand voltage even in conventional fluorocesses.

し発明の目的〕 本発明は、かかる知見に基づき、素子領域の一山1角変
金なたりかに形成する方法について研y+、り枯来、コ
ンベンショナル・フロセスニヨる素子分離におい□てゲ
ー)alli圧r同上させると共に、高密眩化Jt71
I]能にした半導体装置の製造方法を提供するものであ
る。
Based on this knowledge, the present invention has developed a method for forming an element region in a single ridge, one square shape, and a conventional process for element isolation. In addition to increasing the pressure r, high-density glare Jt71
I] Provides a method for manufacturing a semiconductor device that enables the above-mentioned functions.

〔発明の概要〕[Summary of the invention]

本発明は、絶縁基板上に被着した半導体膜の、前記絶縁
基板との界面近傍に選択的に不純物を場大した後、この
不純物を導入した領域の半導体I!1It−等方性エッ
チング技法により絶縁基板が麺出するまでエツチングし
、木純物によるエツチング速度の差を利用して、不純物
を導入していない半導体領域を、その側面がなだらかな
島状に残漬させ、ここにゲート絶縁−をほぼ均一の厚さ
に被着して、ゲート電圧の向上を図ることを特徴とする
ものである。
In the present invention, impurities are selectively increased in the vicinity of the interface with the insulating substrate of a semiconductor film deposited on an insulating substrate, and then the semiconductor I! 1It-isotropic etching technique is used to etch the insulating substrate until it comes out, and by taking advantage of the difference in etching speed due to the wood purity, the semiconductor region into which impurities have not been introduced is left in the shape of an island with gentle sides. This method is characterized in that the gate voltage is improved by dipping the gate insulator and depositing a gate insulator thereon with a substantially uniform thickness.

本発明において用いる絶縁基板としては1例えばサファ
イヤ基板の他、ガラス基板、スピネル(^l:IO,+
M)O)基板などが挙られる。
Examples of insulating substrates used in the present invention include 1, for example, sapphire substrates, glass substrates, spinel (^l: IO, +
M)O)substrate etc.

本発明において用いる半導体膜としては、例えば単結晶
シリコン、多結晶シリコン、アモルファスシリコンなど
がある。
Examples of the semiconductor film used in the present invention include single crystal silicon, polycrystalline silicon, and amorphous silicon.

本発明において半導体膜に導入する不純物としては1例
えばホロンが望ましく、ボロンのイオン注入において加
速電圧を高くすることにより半導体膜の絶縁基板との界
面近傍に選択的にボロンを導入することができる。
In the present invention, the impurity introduced into the semiconductor film is preferably 1, for example, holon, and by increasing the acceleration voltage during boron ion implantation, boron can be selectively introduced into the vicinity of the interface between the semiconductor film and the insulating substrate.

本発明では、半導体膜の不純物を祷大した領域を等方性
エツチング、例えばケミカルドライエツチング(ODE
)i用いることにより、不純物を導入した基板界面側の
エツチング速度が週くなり、島状lζζ残業る半導体領
域の@血管なだらかな傾斜にすることができる。この1
i11th]と絶縁基板とのなす角変は、15〜30!
fの軸回が望ましく、152未満では111djの(l
J!斜がなたらかになり過ぎて側面の幅が大きくなり、
素子開隔が広がるからであシ、また30度を越えると、
半導体領域の上に被着するゲート絶縁−が基板界面近傍
で周部的に博くなってゲート耐圧が低下するからである
In the present invention, a region of a semiconductor film heavily contaminated with impurities is etched by isotropic etching, such as chemical dry etching (ODE).
) By using i, the etching rate on the substrate interface side into which impurities have been introduced is increased, and the island-like semiconductor region can be made to have a gentle slope. This one
i11th] and the insulating substrate is 15 to 30!
It is preferable to have an axial rotation of f, and if it is less than 152, the (l
J! The slope becomes too flat and the width of the sides becomes large.
This is because the element gap widens, and if it exceeds 30 degrees,
This is because the gate insulating layer deposited on the semiconductor region becomes wider in the vicinity of the substrate interface, lowering the gate breakdown voltage.

〔発明の実施例〕[Embodiments of the invention]

以下本発明1i80s/MO8)ランジスタに進用した
場合の一実施例t−wJ2図を参照して詳細に説明する
Hereinafter, one embodiment of the present invention applied to a transistor (1i80s/MO8) will be described in detail with reference to figures twJ2.

先ず第2図囚Vこ示すようにサファイヤ基板5の上に5
000Ieの厚さの単結晶シリコン層6をエピタキシャ
ル技術により成長させた後、更にこの上にOVD技術に
より二酸化シリコン膜7t−堆槓させる。次に全面にレ
ジストを墜布した後、写真&!し刻により素子形成領域
となる部分にレジストパターンg をgt。
First, as shown in Figure 2, 5 is placed on the sapphire substrate 5.
After a single crystal silicon layer 6 with a thickness of 000 Ie is grown by epitaxial technology, a silicon dioxide film 7t is further deposited thereon by OVD technology. Next, after applying resist to the entire surface, take a photo &! A resist pattern g is formed in a portion that will become an element formation region by marking.

次にレジストパターン8を耐エツチングマスクとして二
酸化シ11コン膜1を選択的にエツチング除去して同図
(Blにボすように単結晶シリコン層6を鉢出させる。
Next, using the resist pattern 8 as an etching-resistant mask, the silicon dioxide 11 film 1 is selectively etched away, and the single crystal silicon layer 6 is exposed as shown in the figure (B1).

この後、同図(C)に示すようにパターニングされた二
数化シリコン膜7をマスクとしてボロンを加速電比20
0 Key、 5X10 〜IX10  /Ujb  
でイオンε人し、単結晶71137層6のす\ファイヤ
基板5との界面近傍に高#1のボロン層9を形成する。
After that, as shown in the same figure (C), using the patterned divalent silicon film 7 as a mask, boron is accelerated at an electric ratio of 20.
0 Key, 5X10 ~IX10 /Ujb
Then, ions ε are emitted to form a high #1 boron layer 9 near the interface between the single crystal 71137 layer 6 and the fire substrate 5.

次にレジストパターン8.、を除去した後、バターニン
グされた二酸化シリ□コン膜7をマスクとして、ケミカ
ルドライエツチングにより等方性エツチングを行なうと
、単結晶シリコン層6は上部側でエツチング速度が速く
、ポロンIII 9 t−彫工しぇド部体。エツーF7
グ速□8.o、同図(Dlに示すように、島状に残留し
た単結晶シリコン層Cの倒閣は15〜30度のなだらか
な!Ql料にすることができる。
Next, resist pattern 8. , and isotropically etched by chemical dry etching using the patterned silicon dioxide film 7 as a mask. -Sculptor's body. Etsu F7
G speed□8. o, the same figure (as shown in Dl, the slope of the single crystal silicon layer C remaining in the form of islands can be made into a gentle slope of 15 to 30 degrees!

この後、二酸化シリコン膜1を除去した後、熟成化して
同図1glに示すように趨くエト化シリコン[lI全形
成してゲート絶縁膜3とする。このときサファイヤ基数
5と接する単結晶シリコン+9’e 6の1llttn
の上にも十分な#−ざのゲート絶縁膜3ヶ形成させるこ
とができる。
Thereafter, after the silicon dioxide film 1 is removed, the silicon dioxide film 1 is aged, and as shown in FIG. At this time, single crystal silicon in contact with sapphire radix 5 + 9'e 6 1llttn
It is also possible to form three gate insulating films with sufficient number of gates.

次に同図tFlにボすように燐を含む多結晶シリコン膜
を全面に叡櫂させてゲート[値4を形成する。
Next, a polycrystalline silicon film containing phosphorus is applied over the entire surface as shown at tFl in the figure to form a gate [value 4].

尼I下、通宮のL程に従って、P#I闇杷−繞10を堆
積し、素子頭載となる島状の単結晶シリコンj−6に不
純物音導入してソース11とドレイン12を彰成し7た
後、外部′v!L憔13を設けて、同図(Glに示す5
t)S/MO8トランジスタを製造するものである。
P#I Loquat 10 is deposited according to the L direction of Tsugu, and the source 11 and drain 12 are formed by introducing impurity sound into the island-shaped monocrystalline silicon J-6 that will be the top of the element. After completing 7, external 'v! 5 shown in the same figure (Gl).
t) Manufacturing an S/MO8 transistor.

〔発明の効果〕〔Effect of the invention〕

旬上べ明した如く、本発明に係わる半導体装置の製造方
法によれば、従来のコンベンショナル・プロセスとほぼ
同様の工程で素子分離できるため高密f:集積化を図る
ことができ、しかもゲート絶縁膜をほぼ均一の厚さに形
成できるのでゲー)11F(圧は、従来のコンベンショ
ナル・プロセスに対し、本発明方法では約1.5倍に向
上させることができ、電界!!fにすると、5..5〜
6.5MV/+31にもな9鮒圧性に優れた半導体装置
を得ることができる。
As explained earlier, according to the method for manufacturing a semiconductor device according to the present invention, elements can be separated in almost the same steps as conventional conventional processes, and high-density integration can be achieved. The method of the present invention can improve the pressure by about 1.5 times compared to the conventional conventional process, and when the electric field is increased to 5. .5~
It is possible to obtain a semiconductor device with excellent pressure resistance of 6.5 MV/+31.

【図面の簡単な説明】[Brief explanation of drawings]

!l!lid囚は従来のコンベンショナル・プロセスに
よシ表造した5081MO8トランジスタの料視図、同
図(Blは同四国のB−B@断面図、第2四国乃至同図
(qは本発明の一実施例に上る808/MO8)ランジ
スタを製造する工程を順次ボす1ITIlkI図である
。 1・・・絶縁基板、2・・・素子領域、3・・・ゲート
−絶縁膜、4・・・ケート電憔、5・・・サファイヤ基
数、6・・・単結晶シリコンj−17・・・二酸化シリ
コン膜、8・・・レジストパターン、9・・・ポロン層
、10・・・層曲杷縁膜、IJ・・・ソース、12・・
・ドレイン、13・・・外邪電惟。
! l! The lid is a perspective view of a 5081 MO8 transistor fabricated using the conventional conventional process. It is a 1ITIlkI diagram sequentially showing the steps of manufacturing an example 808/MO8) transistor. 1... Insulating substrate, 2... Element region, 3... Gate-insulating film, 4... Kate electrode. 5...Sapphire base number, 6...Single crystal silicon j-17...Silicon dioxide film, 8...Resist pattern, 9...Poron layer, 10...Layered loquat edge film, IJ... sauce, 12...
・Drain, 13... Gaijakudenkyou.

Claims (2)

【特許請求の範囲】[Claims] (1)  絶縁基板上に半導体膜を被着する工程と、と
の半導体膜の絶縁基板との界面近傍に選択的に不純物番
4人する工程と、この不純物を導入した領域を等方性エ
ツチング技法にょプ絶縁基板が蕗出するまでエツチング
して、不純物を祷大していない領域を断面台形をなす島
状に残wさせる工程と、この島状に残響した半導体w4
域の表面にゲート、絶縁膜を形成する工程と、前配半尋
体領域に素子を形成する工程とから成ることを特徴とす
る半導体装置の線通方法。
(1) A step of depositing a semiconductor film on an insulating substrate, a step of selectively adding an impurity near the interface between the semiconductor film and the insulating substrate, and isotropic etching of the region where the impurity is introduced. Technique: A step in which the insulating substrate is etched until it bulges out, leaving areas with no impurities in an island shape with a trapezoidal cross section, and the semiconductor that reverberates in this island shape.
1. A method for wiring a semiconductor device, comprising the steps of forming a gate and an insulating film on the surface of the semiconductor region, and forming an element on the front half-layer region.
(2)不純物としてボロンを用い、ボロンt−(オン注
入して半導体験の絶縁基板の界面近傍に第択的に導入す
ることを特徴とする特1FF−請求の範囲第1項記載の
半導体装置の製造方法。 (31島状に残留する半一体領域の@面と、絶縁基板と
のなす角度を15〜30奴に形成することをaEFtと
する特許請求の範囲第1項配軟の半導体装置の製造方法
(2) The semiconductor device according to claim 1, characterized in that boron is used as an impurity and boron t-(on-implanted) is selectively introduced into the vicinity of the interface of the insulating substrate of the semiconductor device. (Claim 1) A flexible semiconductor device in which aEFt is defined as forming an angle between the @ plane of the semi-integrated region remaining in the form of an island and the insulating substrate to be 15 to 30 degrees. manufacturing method.
JP8384182A 1982-05-18 1982-05-18 Manufacture of semiconductor device Pending JPS58200572A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8384182A JPS58200572A (en) 1982-05-18 1982-05-18 Manufacture of semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8384182A JPS58200572A (en) 1982-05-18 1982-05-18 Manufacture of semiconductor device

Publications (1)

Publication Number Publication Date
JPS58200572A true JPS58200572A (en) 1983-11-22

Family

ID=13813928

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8384182A Pending JPS58200572A (en) 1982-05-18 1982-05-18 Manufacture of semiconductor device

Country Status (1)

Country Link
JP (1) JPS58200572A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5381029A (en) * 1991-03-01 1995-01-10 Mitsubishi Denki Kabushiki Kaisha Semiconductor device including semiconductor layer having impurity region and method of manufacturing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5381029A (en) * 1991-03-01 1995-01-10 Mitsubishi Denki Kabushiki Kaisha Semiconductor device including semiconductor layer having impurity region and method of manufacturing the same
US5446301A (en) * 1991-03-01 1995-08-29 Mitsubishi Denki Kabushiki Kaisha Semiconductor device including semiconductor layer having impurity region and method of manufacturing the same

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