JPS58103127A - Manufacture of semiconductor device - Google Patents

Manufacture of semiconductor device

Info

Publication number
JPS58103127A
JPS58103127A JP56202858A JP20285881A JPS58103127A JP S58103127 A JPS58103127 A JP S58103127A JP 56202858 A JP56202858 A JP 56202858A JP 20285881 A JP20285881 A JP 20285881A JP S58103127 A JPS58103127 A JP S58103127A
Authority
JP
Japan
Prior art keywords
film
pattern
photoresist film
electrode
ion implantation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56202858A
Other languages
Japanese (ja)
Inventor
Michi Kozuka
古塚 岐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp, Nippon Electric Co Ltd filed Critical NEC Corp
Priority to JP56202858A priority Critical patent/JPS58103127A/en
Publication of JPS58103127A publication Critical patent/JPS58103127A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/039Macromolecular compounds which are photodegradable, e.g. positive electron resists
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/544Marks applied to semiconductor devices or parts, e.g. registration marks, alignment structures, wafer maps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2223/00Details relating to semiconductor or other solid state devices covered by the group H01L23/00
    • H01L2223/544Marks applied to semiconductor devices or parts
    • H01L2223/54453Marks applied to semiconductor devices or parts for use prior to dicing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/0002Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00

Abstract

PURPOSE:To reduce the number of photomasks and to obtain high positioning accuracy by a method wherein the positioning is performed to a pattern for forming the electrode of an MESFET by using a positioning mark formed together with a pattern for ion implantation. CONSTITUTION:In the drawing, numeral 21 represents a semiinsulating GaAs substrate, while the 22 is an SiO2 film coated on the substrate. The SiO2 film at the region including the parts becoming an operating layer and a pattern positioning mark is completely eliminated by using a positive-type photoresist film 23 as a mask with the aid of a mixed aqueous solution of NH4F and HF. Next, after implanting an Si ion (Drawing a) by using the laminated film of the SiO2 film 22 and the photoresist film 23 as a mask, the photoresist film 23 is removed. Then, activation is done by performing capless annealing under As atmosphere. After coating Al by a vacuum deposition method or the like with the aid of a pattern positioning mark 24, the Al film at an unnecessary part is lifted off by dissolving said photoresist film, and a Schottky barrier gate electrode 26 is formed (Drawing b). Next, a source electrode 27 and a drain electrode 28 consisting of metal films consecutively stacking an AuGe alloy and Ni are simultaneously formed by a lift-off method using the similar photoresist film, and a GaAsMESFET is completed (Drawing c).

Description

【発明の詳細な説明】 本発明は半導体装置の製造方法、特にイオン注入ニーを
含む半導体装置の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of manufacturing a semiconductor device, and particularly to a method of manufacturing a semiconductor device including an ion implantation knee.

半導体装置の動作層としては、従来、拡散層、エピタキ
シャル成長層等が用いられて来たが、動作層の中ヤリア
密度や厚さのより正確な制御を目的として、最近ではイ
オン注入層が用−られる様に&りて11え、を九、半導
体ウニへの表面に部分的に高中ヤリア密度のコンタクト
領域、あるいは絶縁領域とイオン注入法により形成する
技4%開発されている。その最も典型的な例がGaAs
を用−たシ■ットキ障壁ゲーF電界効果シランジスタ(
ME8FIT)である。イオン注入法を用いた(iaA
sMB8FMTの製造方法としては、例えば、従来よ)
lllli!IK示す方法空電いられて来た。即ち、初
めに半絶縁性GaAs基’[11を、例えば第1のホト
レジスジ膜12fマスクとしてエツチングし、パターン
位置会わせマーク13を形成し、(第1図(−)、鋏菖
lのホトレジス)膜を除去した後、該位置合わ豐!−夕
を用いてイオン注入のマスクとなるパターンを第2のホ
トレジス)1114によシ所定の位置に形成し、次−で
、該第2のホトレジスジ膜をマスクとして、Siイオン
を加速エネルギー5G key、 ドース量s x l
d”♂の条件で注入し(Jlt8!J(b))、続いて
ホトレジスト膜14を除来し、例えば厚さ0.2声mの
8i0.膜を被着して800℃の水素雰囲気中で20分
間加熱して活性化を行なった後fis:o、膜を除去し
、次にパターン位置合わせマーク13を用いて、例えば
AuGe合金、Niを順次積層したソース電極16およ
びドレイン電極17を所定の位置に形成しくI!1図(
c) ) 、更に例えばTi、 Pi、 Auを順次積
層したシ11ツ)キ障壁合わせマーク13は、イオン注
入により形成された動作層15に対してソース電極、ゲ
ート電極、ドレイン電極を位置合わせするために必要で
あり、イオン注入とは別の工程でパターン位置合わせマ
ークのみを形成する理由は、イオン注入ではGaA4面
に外観上はとんど痕跡が残らず、イオン注入の工程でG
aAs表面にパターン位置合わせマークを形成すること
が困蝋な丸めである。このような方法では、MR8F′
BT自体の構造には直接関係のなφ位置合わせマークを
形成するために1余分のホトマスクを必要とし、また位
置合わせマーク形成のための製造工程も必要である。し
かもME8FBTの各電極は、イオン注入のパターンに
対して直接位置合わせされるべきものにもfl−かわら
ず、製造ニーの最初に形成された位置合わせマークを介
して間接的[ME8Fli!Tの各電極とイオン注入の
パターンとが位置合わせされてしまい、位置合わせ精度
の低下を招く欠点があった。
Conventionally, diffusion layers, epitaxially grown layers, etc. have been used as the active layer of semiconductor devices, but recently, ion-implanted layers have been used for the purpose of more accurate control of the layer density and thickness in the active layer. 9. A technique has been developed to partially form a contact region or an insulating region with a high to medium density on the surface of a semiconductor by ion implantation. The most typical example is GaAs
A field-effect silane resistor (
ME8FIT). Using ion implantation method (iaA
For example, the manufacturing method of sMB8FMT is conventional)
lllli! I received a static call about how to show IK. That is, first, a semi-insulating GaAs base 11 is etched, for example, as a mask for the first photoresist film 12f, and pattern position alignment marks 13 are formed (FIG. 1 (-), photoresist with scissors I). After removing the membrane, align the position! A pattern that will serve as a mask for ion implantation is formed at a predetermined position using a second photoresist layer (1114) using a photoresist film. , dose amount s x l
d”♂ conditions (Jlt8!J(b)), then the photoresist film 14 is removed, and an 8i0. film with a thickness of 0.2 m, for example, is deposited and placed in a hydrogen atmosphere at 800°C. After activating by heating for 20 minutes with fis:o, the film is removed, and then, using pattern alignment marks 13, a source electrode 16 and a drain electrode 17, which are successively laminated with, for example, an AuGe alloy and Ni, are placed in predetermined positions. Form it in the position of Figure I!1 (
c)) Furthermore, for example, Ti, Pi, and Au are sequentially laminated.11) The barrier alignment mark 13 aligns the source electrode, gate electrode, and drain electrode with respect to the active layer 15 formed by ion implantation. The reason why only pattern alignment marks are formed in a process separate from ion implantation is that ion implantation leaves almost no visible traces on the four GaA surfaces;
It is difficult to form pattern alignment marks on the aAs surface due to rounding. In such a method, MR8F'
One extra photomask is required to form the φ alignment mark, which is not directly related to the structure of the BT itself, and a manufacturing process for forming the alignment mark is also required. Furthermore, each electrode of the ME8FBT should be directly aligned with the ion implantation pattern, but instead of being aligned directly with the ion implantation pattern, it is indirectly aligned via alignment marks formed at the beginning of the manufacturing process [ME8Fli! Each electrode of T and the ion implantation pattern are aligned, resulting in a disadvantage that alignment accuracy is lowered.

本発明の目的は、上記従来の欠点をなくした半導体装置
の製造方法を提供することにある。
An object of the present invention is to provide a method for manufacturing a semiconductor device that eliminates the above-mentioned conventional drawbacks.

本発明によれば、半導体基板の表面を第1の膜で櫃い、
ホトレジスト膜をマスクとしてイオン注入領域およびパ
ターン位置合わせマークとなる部分を含も領域上の該第
1の膜を除去し、該第1の膜あるいは該第1の膜と該ホ
トレジスト膜の積層膜をマスタとして選択的にイオン注
入領域を形成し、該第1の膜に形成されたパターン位置
合わせマークを用いて、半導体装置の少なくとも一種類
の電極を、所定の位置に形成する工程を含むことを特徴
とする半導体装置の製造方法を得ることができる。
According to the present invention, the surface of the semiconductor substrate is covered with the first film,
Using the photoresist film as a mask, the first film on the region including the ion implantation region and the pattern alignment mark is removed, and the first film or a laminated film of the first film and the photoresist film is removed. selectively forming an ion implantation region as a master, and using pattern alignment marks formed on the first film to form at least one type of electrode of the semiconductor device at a predetermined position. A characteristic method for manufacturing a semiconductor device can be obtained.

以下、図面によりGaAs MB8FETの製造方法を
例にとって本発明を説明する。
The present invention will be described below with reference to the drawings, taking as an example a method for manufacturing a GaAs MB8FET.

112図は本発明の一実施例を説明するための図面であ
る。図面において、21は半絶縁性GaAs基板、22
はこの上に1例えば熱分解法等によ抄被着し九厚さ0.
5jmのSin、膜で、動作層およびパターン位置合わ
せマークとなる部分を含む領域の8i0.膜をNH,P
とHFの混合水溶液を用い、厚さ2μmのポジティブ型
ホトレジスト膜23をマスクとして完全圧除去する。次
6c8i0.膜22とホトレジスト23の積層膜をマス
クとし、例えば8iイオンを加速エネルギー50 ke
y、  ドーズ量2.6 X IQ”m”の条件で注入
した後(第2図(m)、ホトレジスト膜23を除去する
。続いて、850℃のAs雰囲気中で15分間所■キャ
ップレスアニールを行なって活性化を行な−、パターン
位置合わせ!−ダ24を用いて、例えば、厚さlsmの
ホトレジスト膜によりゲート電極のパターンを所定の位
置に形成し、例えば厚さ0.4#mのA1を真空蒸着法
等によって被着した後、該ホトレジス)膜を溶解して不
要部分のAlmをり7トオフし、シ日ットキ障壁ゲート
電極26を形成する(第2図(b) )。若し、イオン
注入されていない領域のGaAs基板上にもM膜を設置
する必要がある場合は、該ホトレジスト膜によるゲート
電極のパターン形成ニーの後、該ホトレジスト膜によっ
て覆れない8i0.膜を、例えばNH4FとHFの混合
水溶液を用ψて除去し、A/膜を被着すればよい。次い
で、同様にホトレジスト膜を用いたリフトオフ法によね
、AuGe合金、Niを順次積層した金属膜よりなるソ
ース電極27およびドレイン電極28を同時に形成して
GaAsME8FETを完成した。(第2図(C))こ
のような本発明になる製造方法によれば、従来の実施例
で必要であった位置合わせ!−りのみを形成するための
工程が不要となり、製造工梅の短縮を図ることができ、
ホトマスタ数を節減することができた。また、ME8F
ETの電極形成のためのパターンは、イオン注入のため
のパターンと同時に形成された位置合わせマークを用い
て位置合わせされるために、従来の実施例に比べて高い
位置合わせ精度を得ることができた。
FIG. 112 is a drawing for explaining one embodiment of the present invention. In the drawing, 21 is a semi-insulating GaAs substrate, 22
1 is coated on top of this by, for example, a pyrolysis method to give a thickness of 0.
5jm of Sin, 8i0. The membrane is NH,P
Using a mixed aqueous solution of and HF, complete pressure removal is performed using the 2 μm thick positive type photoresist film 23 as a mask. Next 6c8i0. Using the laminated film of the film 22 and photoresist 23 as a mask, for example, 8i ions are accelerated at an energy of 50 ke.
After implantation at a dose of 2.6 x IQ "m" (Fig. 2 (m), the photoresist film 23 is removed. Subsequently, capless annealing is performed for 15 minutes in an As atmosphere at 850°C. Then, using the pattern alignment!-der 24, a gate electrode pattern is formed at a predetermined position using a photoresist film having a thickness of, for example, 1sm, and a pattern of a gate electrode is formed at a predetermined position by using a photoresist film having a thickness of, for example, 1sm. After depositing the photoresist film A1 by vacuum evaporation or the like, the photoresist film is melted and the unnecessary portions of Al are removed to form a barrier gate electrode 26 (FIG. 2(b)). If it is necessary to provide an M film on the GaAs substrate in areas where ions have not been implanted, after patterning the gate electrode with the photoresist film, the 8i0. The film may be removed using, for example, a mixed aqueous solution of NH4F and HF, and the A/film may be applied. Next, a source electrode 27 and a drain electrode 28 made of a metal film in which AuGe alloy and Ni were successively laminated were simultaneously formed by the same lift-off method using a photoresist film to complete a GaAsME8FET. (FIG. 2(C)) According to the manufacturing method of the present invention, alignment, which was necessary in the conventional embodiments, can be achieved! - The process for forming the ribs is no longer necessary, and the manufacturing time can be shortened.
The number of photo masters could be reduced. Also, ME8F
Since the pattern for forming the ET electrode is aligned using alignment marks formed at the same time as the pattern for ion implantation, higher alignment accuracy can be obtained compared to conventional embodiments. Ta.

なお、本実施例ではイオン注入領域が半導体装置の動作
層である場合について述べたが、イオン注入領域が高不
純物濃度のコンタクト領域の場合あるいはBや00イオ
ン注入による絶縁領域の場合などについても同様であり
、また、例えば本実施例に於て、工程の中に他の異なる
仕様の動作領域、あるいは高不純物濃度のフンタクト領
域等を形成するためのイオン注入工柵が更に追加される
場合についても同様である。また、GaAs Mg8F
ETの製造方法についてのみ示されたが、シ曹ットキ障
壁ダイオード等の半導体装置、ある(ρは(GaAs以
外の半導体についても同様に本発明が適用されることは
言うまでもない。
Although this embodiment describes the case where the ion implantation region is an active layer of a semiconductor device, the same applies to the case where the ion implantation region is a contact region with a high impurity concentration or an insulating region formed by B or 00 ion implantation. In addition, for example, in this embodiment, in the case where an ion implantation fence is further added to form an operating region with different specifications or a high impurity concentration contact region, etc. in the process. The same is true. Also, GaAs Mg8F
Although only a method for manufacturing an ET has been described, it goes without saying that the present invention is similarly applicable to semiconductor devices such as silicon barrier diodes and other semiconductors other than GaAs.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来のシッットキ接合ゲート電解効果トランジ
スタの製造方法ta明するだめの図面、第2図は本発明
の詳細な説明するための図面アある。図面において、1
1.21は半絶縁性GaAs基板、22は8i0.膜、
12.14.23はホFレジスト膜13.24はパター
ン位置合わせマーク、15.25はイオン注入領域、1
8.26はゲート電極、16.27はソース電極、17
.28はドレイン電極を示す。 慄 1 目 5
FIG. 1 is a diagram for explaining a conventional method of manufacturing a Schittky junction gate field effect transistor, and FIG. 2 is a diagram for explaining the present invention in detail. In the drawing, 1
1.21 is a semi-insulating GaAs substrate, 22 is an 8i0. film,
12.14.23 is a photo-F resist film 13.24 is a pattern alignment mark, 15.25 is an ion implantation area, 1
8.26 is the gate electrode, 16.27 is the source electrode, 17
.. 28 indicates a drain electrode. Horror 1 Eye 5

Claims (1)

【特許請求の範囲】[Claims] 半導体基板の表面を第1の膜で11−1ホトレジスト膜
をマスクとしてイオン注入領域およびパターン位置合わ
せマークとなる部分を含む領域上の該allの膜を除去
し、該#11の膜あるーは該@1の膜と該ホトレジスト
膜の積層膜をマスタとして選択的にイオン注入領域を形
成し、該第1の膜に形成されたパターン位置合わせ!−
夕を用いて半導体装置の少なくとも一穏IIO電極を所
会の位置に形成するニーを含むことを特徴とする半導体
装置の製造方法。
Using the first film and the #11-1 photoresist film as a mask, the surface of the semiconductor substrate is removed from all the films on the region including the ion implantation region and the part that will become the pattern alignment mark, and the #11 film is removed. Selectively form ion implantation regions using the laminated film of the @1 film and the photoresist film as a master, and align the pattern formed on the first film! −
1. A method of manufacturing a semiconductor device, comprising: forming at least one intermediate IIO electrode of the semiconductor device at a predetermined position using a metal plate.
JP56202858A 1981-12-16 1981-12-16 Manufacture of semiconductor device Pending JPS58103127A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56202858A JPS58103127A (en) 1981-12-16 1981-12-16 Manufacture of semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56202858A JPS58103127A (en) 1981-12-16 1981-12-16 Manufacture of semiconductor device

Publications (1)

Publication Number Publication Date
JPS58103127A true JPS58103127A (en) 1983-06-20

Family

ID=16464356

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56202858A Pending JPS58103127A (en) 1981-12-16 1981-12-16 Manufacture of semiconductor device

Country Status (1)

Country Link
JP (1) JPS58103127A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5001076A (en) * 1987-10-23 1991-03-19 Vitesse Semiconductor Corporation Process for fabricating III-V devices using a composite dielectric layer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5001076A (en) * 1987-10-23 1991-03-19 Vitesse Semiconductor Corporation Process for fabricating III-V devices using a composite dielectric layer

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