JPS5773139A - Treatment of copper electrolytic slime - Google Patents
Treatment of copper electrolytic slimeInfo
- Publication number
- JPS5773139A JPS5773139A JP14850680A JP14850680A JPS5773139A JP S5773139 A JPS5773139 A JP S5773139A JP 14850680 A JP14850680 A JP 14850680A JP 14850680 A JP14850680 A JP 14850680A JP S5773139 A JPS5773139 A JP S5773139A
- Authority
- JP
- Japan
- Prior art keywords
- copper
- slime
- selenium
- sulfuric acid
- freed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
PURPOSE: To efficiently extract and separate most of copper and selenium in copper electrolytic slime by reducing the free sulfuric acid concn. of the slime, oxidizing the slime with oxygen at a high temp. under pressure, and carrying out extraction with sulfuric acid.
CONSTITUTION: Copper electrolytic slime is freed of liquor and washed in water or neutralized to reduce the free sulfuric acid concn. to ≤25g/l. This slime is charged into a pressure reactor in the form of an aqueous slurry and oxidized at a high temp. such as about 150W300°C under a high partial pressure of oxygen such as ≥about 4kg/cm2. By this reaction most of copper and selenium in the slime are converted into acid-soluble compounds. Sulfuric acid is then added and agitated to extract copper and selenium. This liq. extract is freed of silver and treated with a reducing agent such as gaseous SO2 to recover selenium as a simple substance. The remaining liq. contg. copper is freed of tellurium and fed to a blue vitriol process to recover copper. The extraction residue contains little copper and selenium, so it is dried and supplied to an ordinary dissolving and presipitating process.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14850680A JPS5773139A (en) | 1980-10-23 | 1980-10-23 | Treatment of copper electrolytic slime |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14850680A JPS5773139A (en) | 1980-10-23 | 1980-10-23 | Treatment of copper electrolytic slime |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5773139A true JPS5773139A (en) | 1982-05-07 |
Family
ID=15454278
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14850680A Pending JPS5773139A (en) | 1980-10-23 | 1980-10-23 | Treatment of copper electrolytic slime |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5773139A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5271909A (en) * | 1991-08-15 | 1993-12-21 | Noranda, Inc. | Method of tellurium separation from copper electrorefining slime |
-
1980
- 1980-10-23 JP JP14850680A patent/JPS5773139A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5271909A (en) * | 1991-08-15 | 1993-12-21 | Noranda, Inc. | Method of tellurium separation from copper electrorefining slime |
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