JPS5745121A - Preparation of primary or secondary allyl alcohol - Google Patents

Preparation of primary or secondary allyl alcohol

Info

Publication number
JPS5745121A
JPS5745121A JP55119869A JP11986980A JPS5745121A JP S5745121 A JPS5745121 A JP S5745121A JP 55119869 A JP55119869 A JP 55119869A JP 11986980 A JP11986980 A JP 11986980A JP S5745121 A JPS5745121 A JP S5745121A
Authority
JP
Japan
Prior art keywords
allyl alcohol
hydrocarbon group
catalyst
tertiary allyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP55119869A
Other languages
Japanese (ja)
Inventor
Shoichi Kinoshita
Kenichi Oaku
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawamura Institute of Chemical Research
DIC Corp
Original Assignee
Kawamura Institute of Chemical Research
Dainippon Ink and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawamura Institute of Chemical Research, Dainippon Ink and Chemicals Co Ltd filed Critical Kawamura Institute of Chemical Research
Priority to JP55119869A priority Critical patent/JPS5745121A/en
Publication of JPS5745121A publication Critical patent/JPS5745121A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prepare the titled substance in high yield without producing by-products, by isomerizing a tertiary allyl alcohol using a catalyst obtained from vanadium pentoxide, a trialkylsilanol, etc., stable even under high-temperature conditions, lasting well the activity of the catalyst.
CONSTITUTION: In the presence of a compound shown by the formula I [L is hydrocarbon group; R is L or Si-(L)3; m is 1W3; n is 0W2, with the proviso that the sum of m and n is 3], e.g., tris-(trimethyl-silanoxy)-vanadium oxide as a catalyst, a tertiary allyl alcohol shown by the formula II (R1 is lower hydrocarbon group; R2 is hydrocarbon group or R1 and R2 form cyclic group; R3 is H or hydrocarbon group) is isomerized, to give a compound shown by the formula III. The reaction temperature is properly at from normal temperature to 300°C. In the conversion from the tertiary allyl alcohol, several hours heating after adding 0.005W20mol%, preferably 0.02W5mol% catalyst to the tertiary allyl alcohol provides effect better.
COPYRIGHT: (C)1982,JPO&Japio
JP55119869A 1980-09-01 1980-09-01 Preparation of primary or secondary allyl alcohol Pending JPS5745121A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55119869A JPS5745121A (en) 1980-09-01 1980-09-01 Preparation of primary or secondary allyl alcohol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55119869A JPS5745121A (en) 1980-09-01 1980-09-01 Preparation of primary or secondary allyl alcohol

Publications (1)

Publication Number Publication Date
JPS5745121A true JPS5745121A (en) 1982-03-13

Family

ID=14772269

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55119869A Pending JPS5745121A (en) 1980-09-01 1980-09-01 Preparation of primary or secondary allyl alcohol

Country Status (1)

Country Link
JP (1) JPS5745121A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0679048U (en) * 1993-04-13 1994-11-04 オムロン株式会社 Joystick
US10974225B1 (en) 2020-01-17 2021-04-13 Zhejiang Nhu Company Ltd. Metal oxide coated ceramic corrugated plate catalyst, preparation and application in preparation of key intermediates of citral

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0679048U (en) * 1993-04-13 1994-11-04 オムロン株式会社 Joystick
US10974225B1 (en) 2020-01-17 2021-04-13 Zhejiang Nhu Company Ltd. Metal oxide coated ceramic corrugated plate catalyst, preparation and application in preparation of key intermediates of citral

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