JPS57139027A - Preparation of secondary or tertiary allyl alcohol - Google Patents

Preparation of secondary or tertiary allyl alcohol

Info

Publication number
JPS57139027A
JPS57139027A JP56024869A JP2486981A JPS57139027A JP S57139027 A JPS57139027 A JP S57139027A JP 56024869 A JP56024869 A JP 56024869A JP 2486981 A JP2486981 A JP 2486981A JP S57139027 A JPS57139027 A JP S57139027A
Authority
JP
Japan
Prior art keywords
compound
formula
hydrocarbon group
allyl alcohol
isomerizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP56024869A
Other languages
Japanese (ja)
Other versions
JPH0231699B2 (en
Inventor
Shoichi Kinoshita
Kenichi Oaku
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawamura Institute of Chemical Research
DIC Corp
Original Assignee
Kawamura Institute of Chemical Research
Dainippon Ink and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawamura Institute of Chemical Research, Dainippon Ink and Chemicals Co Ltd filed Critical Kawamura Institute of Chemical Research
Priority to JP56024869A priority Critical patent/JPS57139027A/en
Publication of JPS57139027A publication Critical patent/JPS57139027A/en
Publication of JPH0231699B2 publication Critical patent/JPH0231699B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prepare the titled compound in high conversion and selectivity, by isomerizing a primary allyl alcohol using tris-(trimethyl or triphenyl-germanoxy or silanoxy)vanadium oxide, etc. as a catalyst.
CONSTITUTION: The compound of formula V (R1 is H or lower hydrocarbon group; R2 is hydrocarbon group or may form a cyclic group together with R1) is prepared by isomerizing the compound of formula IV in the presence of a catalyst comprising a vanadium-containing polymer obtained by the condensation of the compound of formula III (R" and R''' are hydrocarbon group; X is halogen) with (A) the compound of formulaI[L is hydrocarbon group; R is L or Ge(L)3; m is 1, 2 or 3; n is 0, 1 or 2; m+n is 3], (B) the compound of formula II[R' is L or Si(L)3]or (C) the compound of formula M3VO4 or MVO3 (M is alkali metal or ammonium). Any of the above catalysts keeps its high activity during the reaction, is stable at high temperature, and can be used repeatedly.
COPYRIGHT: (C)1982,JPO&Japio
JP56024869A 1981-02-24 1981-02-24 Preparation of secondary or tertiary allyl alcohol Granted JPS57139027A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56024869A JPS57139027A (en) 1981-02-24 1981-02-24 Preparation of secondary or tertiary allyl alcohol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56024869A JPS57139027A (en) 1981-02-24 1981-02-24 Preparation of secondary or tertiary allyl alcohol

Publications (2)

Publication Number Publication Date
JPS57139027A true JPS57139027A (en) 1982-08-27
JPH0231699B2 JPH0231699B2 (en) 1990-07-16

Family

ID=12150207

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56024869A Granted JPS57139027A (en) 1981-02-24 1981-02-24 Preparation of secondary or tertiary allyl alcohol

Country Status (1)

Country Link
JP (1) JPS57139027A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5349097A (en) * 1992-08-29 1994-09-20 Basf Aktiengesellschaft Catalytic isomerization of α-alkenols
CN105218312A (en) * 2015-11-03 2016-01-06 山东新和成药业有限公司 A kind of allyl alcohol is through the method for isomerization process continuous production phantol

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5349097A (en) * 1992-08-29 1994-09-20 Basf Aktiengesellschaft Catalytic isomerization of α-alkenols
CN105218312A (en) * 2015-11-03 2016-01-06 山东新和成药业有限公司 A kind of allyl alcohol is through the method for isomerization process continuous production phantol

Also Published As

Publication number Publication date
JPH0231699B2 (en) 1990-07-16

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