JPS5736106A - Preparation of polymer of 2-chloro-1-phenylacetylene - Google Patents

Preparation of polymer of 2-chloro-1-phenylacetylene

Info

Publication number
JPS5736106A
JPS5736106A JP11210880A JP11210880A JPS5736106A JP S5736106 A JPS5736106 A JP S5736106A JP 11210880 A JP11210880 A JP 11210880A JP 11210880 A JP11210880 A JP 11210880A JP S5736106 A JPS5736106 A JP S5736106A
Authority
JP
Japan
Prior art keywords
polymer
chloro
phenylacetylene
preparation
pref
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11210880A
Other languages
Japanese (ja)
Other versions
JPH0142965B2 (en
Inventor
Toshinobu Higashimura
Toshio Masuda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP11210880A priority Critical patent/JPS5736106A/en
Publication of JPS5736106A publication Critical patent/JPS5736106A/en
Publication of JPH0142965B2 publication Critical patent/JPH0142965B2/ja
Granted legal-status Critical Current

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  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PURPOSE: To prepare the titled polymer having high molecular weight, in high polymer conversion, by the use of a polymerization catalyst obtained by the photo-irradiation of a mixture of a VI-group transition metal carbonyl and an organic halide.
CONSTITUTION: A VI-group transition metal carbonyl, pref. molybdenum hexacarbonyl is mixed with an organic halide (e.g. carbon tetrachloride), and the mixture is irradiated with, e.g. a 100WW1kW high-pressure mercury lamp. The objective polymer is obtained by polymerizing 2-chloro-1-phenylacetylene (e.g. the compound of formula (A is alkyl, aryl, alkoxy, etc.; n is 0W5) in the presence of pref. 0.1W 10mol%, based on the monomer, of the catalyst obtained above. As an alternative method, the preparation of the catalyst and the polymerization are carried out simultaneously by using 2-chloro-1-acetylene as the halide.
COPYRIGHT: (C)1982,JPO&Japio
JP11210880A 1980-08-13 1980-08-13 Preparation of polymer of 2-chloro-1-phenylacetylene Granted JPS5736106A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11210880A JPS5736106A (en) 1980-08-13 1980-08-13 Preparation of polymer of 2-chloro-1-phenylacetylene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11210880A JPS5736106A (en) 1980-08-13 1980-08-13 Preparation of polymer of 2-chloro-1-phenylacetylene

Publications (2)

Publication Number Publication Date
JPS5736106A true JPS5736106A (en) 1982-02-26
JPH0142965B2 JPH0142965B2 (en) 1989-09-18

Family

ID=14578346

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11210880A Granted JPS5736106A (en) 1980-08-13 1980-08-13 Preparation of polymer of 2-chloro-1-phenylacetylene

Country Status (1)

Country Link
JP (1) JPS5736106A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5993705A (en) * 1982-11-19 1984-05-30 Toshinobu Higashimura Preparation of polymer of 1-bromo-2-phenylacetylene compound
CN109912740A (en) * 2018-06-29 2019-06-21 郑州轻工业学院 A kind of preparation method of polyphenylacetylene

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5993705A (en) * 1982-11-19 1984-05-30 Toshinobu Higashimura Preparation of polymer of 1-bromo-2-phenylacetylene compound
CN109912740A (en) * 2018-06-29 2019-06-21 郑州轻工业学院 A kind of preparation method of polyphenylacetylene

Also Published As

Publication number Publication date
JPH0142965B2 (en) 1989-09-18

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