JPS5731911A - Production of mono substituted acetylene polymer - Google Patents
Production of mono substituted acetylene polymerInfo
- Publication number
- JPS5731911A JPS5731911A JP10645680A JP10645680A JPS5731911A JP S5731911 A JPS5731911 A JP S5731911A JP 10645680 A JP10645680 A JP 10645680A JP 10645680 A JP10645680 A JP 10645680A JP S5731911 A JPS5731911 A JP S5731911A
- Authority
- JP
- Japan
- Prior art keywords
- transition metal
- metal carbonyl
- light
- polymer
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To obtain a high-MW polymer applicable to a semiconductor, gas adsorbent or polarizing material, by polymerizing a monosubstituted acetylene by use of a catalyst prepared by irradiating a transition metal carbonyl/organic halide mixture with light.
CONSTITUTION: A mixture of a transition metal carbonyl, e.g., tungsten hexacarbonyl, and an organic halide, e.g., CCl4, is irradiated with light. The irradiation is preferably such that the dosage corresponds to that obtained from a 100WW1kW light source placed about 30cm distant for at least 10min, pref., 30minW1hr. A monosubstituted acetylene of the formula, wherein R is a (substituted) alkyl or a (substituted) arly, e.g., phenylacetylene, is polymerized by use of the above-produced catalyst. The amount of the transition metal carbonyl used is suitably 0.1W 10mol%, based on the monomer of the formula. It is possible to obtain a high-MW polymer in high yields.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10645680A JPS5731911A (en) | 1980-08-04 | 1980-08-04 | Production of mono substituted acetylene polymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10645680A JPS5731911A (en) | 1980-08-04 | 1980-08-04 | Production of mono substituted acetylene polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5731911A true JPS5731911A (en) | 1982-02-20 |
| JPH0142964B2 JPH0142964B2 (en) | 1989-09-18 |
Family
ID=14434086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10645680A Granted JPS5731911A (en) | 1980-08-04 | 1980-08-04 | Production of mono substituted acetylene polymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5731911A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6031781A (en) * | 1983-08-01 | 1985-02-18 | 株式会社平和 | Pinball machine |
| JPS6092784A (en) * | 1983-10-26 | 1985-05-24 | 株式会社平和 | Pinball machine |
| JPS6096279A (en) * | 1983-10-31 | 1985-05-29 | 株式会社平和 | Pinball machine |
| JPS62267361A (en) * | 1986-05-10 | 1987-11-20 | バイエル・アクチエンゲゼルシヤフト | Polarizer based on polyacetylene and its production |
| CN109912740A (en) * | 2018-06-29 | 2019-06-21 | 郑州轻工业学院 | A kind of preparation method of polyphenylacetylene |
-
1980
- 1980-08-04 JP JP10645680A patent/JPS5731911A/en active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6031781A (en) * | 1983-08-01 | 1985-02-18 | 株式会社平和 | Pinball machine |
| JPH0547229B2 (en) * | 1983-08-01 | 1993-07-16 | Heiwa Corp | |
| JPS6092784A (en) * | 1983-10-26 | 1985-05-24 | 株式会社平和 | Pinball machine |
| JPS6096279A (en) * | 1983-10-31 | 1985-05-29 | 株式会社平和 | Pinball machine |
| JPH0417677B2 (en) * | 1983-10-31 | 1992-03-26 | Heiwa Corp | |
| JPS62267361A (en) * | 1986-05-10 | 1987-11-20 | バイエル・アクチエンゲゼルシヤフト | Polarizer based on polyacetylene and its production |
| CN109912740A (en) * | 2018-06-29 | 2019-06-21 | 郑州轻工业学院 | A kind of preparation method of polyphenylacetylene |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0142964B2 (en) | 1989-09-18 |
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