JPS57207618A - Preparation of polyarylenevinylene - Google Patents

Preparation of polyarylenevinylene

Info

Publication number
JPS57207618A
JPS57207618A JP9215381A JP9215381A JPS57207618A JP S57207618 A JPS57207618 A JP S57207618A JP 9215381 A JP9215381 A JP 9215381A JP 9215381 A JP9215381 A JP 9215381A JP S57207618 A JPS57207618 A JP S57207618A
Authority
JP
Japan
Prior art keywords
compound
formula
divinylarylene
dihaloarylene
integer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9215381A
Other languages
Japanese (ja)
Other versions
JPS629607B2 (en
Inventor
Hiroshi Kawahara
Iwahiro Otsuka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP9215381A priority Critical patent/JPS57207618A/en
Publication of JPS57207618A publication Critical patent/JPS57207618A/en
Publication of JPS629607B2 publication Critical patent/JPS629607B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

PURPOSE: To obtain the titled polymer having improved heat resistance, electric conductivity and optical properties, by reacting a specific dihaloarylene compound with a divinylarylene compound in the presence of a catalyst and a hydrogen halide capturing agent.
CONSTITUTION: A dihaloarylene compound of formulaI(Ar is formula II, III, etc.;{Y is H, -R, -COOR, etc.;[R is H, (cyclo) alkyl, etc.]; Z1 is -N= or -C=; m is an integer 0W4, etc. when both of Z1s of formula II are -C=; m is an integer 0W6 when Z1 of formula III is -C=, etc.}; X is Br or I), e.g. p-dibromobenzene is reacted with a divinylarylene compound of formula IV (Ar' is the same as Ar; R1WR4 are H, CH3 or C2H5), e.g. p-divinylbenzene, in the presence of a palladium acetate and a triarylphosphine and a tertiary amine, tri-o-tolylphosphine as a catalyst, and a tertiary amine, e.g. n-butylamine as a hydrogen halide capturing agent, at 75W150°C for 1W50hr.
COPYRIGHT: (C)1982,JPO&Japio
JP9215381A 1981-06-17 1981-06-17 Preparation of polyarylenevinylene Granted JPS57207618A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9215381A JPS57207618A (en) 1981-06-17 1981-06-17 Preparation of polyarylenevinylene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9215381A JPS57207618A (en) 1981-06-17 1981-06-17 Preparation of polyarylenevinylene

Publications (2)

Publication Number Publication Date
JPS57207618A true JPS57207618A (en) 1982-12-20
JPS629607B2 JPS629607B2 (en) 1987-03-02

Family

ID=14046471

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9215381A Granted JPS57207618A (en) 1981-06-17 1981-06-17 Preparation of polyarylenevinylene

Country Status (1)

Country Link
JP (1) JPS57207618A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005049688A1 (en) * 2003-11-21 2005-06-02 Kansai Technology Licensing Organization Co., Ltd. Conductive resin capable of photopatterning
JP2007238725A (en) * 2006-03-07 2007-09-20 Kyoto Univ Conductive resin enabling photo-insolubilization

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005049688A1 (en) * 2003-11-21 2005-06-02 Kansai Technology Licensing Organization Co., Ltd. Conductive resin capable of photopatterning
JP5132057B2 (en) * 2003-11-21 2013-01-30 株式会社日本触媒 Conductive resin capable of optical patterning
JP2007238725A (en) * 2006-03-07 2007-09-20 Kyoto Univ Conductive resin enabling photo-insolubilization

Also Published As

Publication number Publication date
JPS629607B2 (en) 1987-03-02

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