JPS5716833A - Preparation of substituted acetic ester - Google Patents
Preparation of substituted acetic esterInfo
- Publication number
- JPS5716833A JPS5716833A JP9130680A JP9130680A JPS5716833A JP S5716833 A JPS5716833 A JP S5716833A JP 9130680 A JP9130680 A JP 9130680A JP 9130680 A JP9130680 A JP 9130680A JP S5716833 A JPS5716833 A JP S5716833A
- Authority
- JP
- Japan
- Prior art keywords
- raw material
- reaction
- formula
- water
- give
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled substance useful as a perfume substance in high yield under mild reaction conditions through simple operations, by reacting a substituted malonic diester as a raw material with water to give a reaction product, adding again the above-mentioned raw material to the reaction product without separating it and not using subsidiary raw materials, carrying out reaction under heating.
CONSTITUTION: A substituted malonic diester shown by the formula I(R1 is H or organic residue; R2 is organic residue; R3 is lower alkyl residue) is reacted with water under heating at 160W250°C, to give a substituted acetic acid shown by the formula II, which is reacted with the raw material compound shown by the formula I at the same temperature as that of the above-mentioned reaction, to give a compound shown by the formula III. The amount of water used in the reaction is much excess based on the raw material compound, however, when an acid catalyst, e.g., p-toluenesulfonic acid, etc. is used, the amount of water is sufficiently ≤ ten times molar amount of the raw material.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9130680A JPS5716833A (en) | 1980-07-04 | 1980-07-04 | Preparation of substituted acetic ester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9130680A JPS5716833A (en) | 1980-07-04 | 1980-07-04 | Preparation of substituted acetic ester |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5716833A true JPS5716833A (en) | 1982-01-28 |
Family
ID=14022773
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9130680A Pending JPS5716833A (en) | 1980-07-04 | 1980-07-04 | Preparation of substituted acetic ester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5716833A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5312842A (en) * | 1976-07-16 | 1978-02-04 | Roure Bertrand Dupont Sa | Process for preparing cycloalkyl compound |
-
1980
- 1980-07-04 JP JP9130680A patent/JPS5716833A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5312842A (en) * | 1976-07-16 | 1978-02-04 | Roure Bertrand Dupont Sa | Process for preparing cycloalkyl compound |
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