JPS57109747A - Stabilization of cationic vinyl monomer - Google Patents

Stabilization of cationic vinyl monomer

Info

Publication number
JPS57109747A
JPS57109747A JP18735080A JP18735080A JPS57109747A JP S57109747 A JPS57109747 A JP S57109747A JP 18735080 A JP18735080 A JP 18735080A JP 18735080 A JP18735080 A JP 18735080A JP S57109747 A JPS57109747 A JP S57109747A
Authority
JP
Japan
Prior art keywords
acids
phosphoric acid
monomer
vinyl monomer
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18735080A
Other languages
Japanese (ja)
Inventor
Akira Okada
Kimihiko Noda
Yoshitsugu Takai
Yoichi Hasegawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Chemical Industries Ltd
Original Assignee
Sanyo Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Chemical Industries Ltd filed Critical Sanyo Chemical Industries Ltd
Priority to JP18735080A priority Critical patent/JPS57109747A/en
Publication of JPS57109747A publication Critical patent/JPS57109747A/en
Pending legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To prevent the degradation of the titled monomer during storage, transportation or preparation, and to improve its stability remarkably without lowering the polymerization reactivity, by adding a chelating agent such as aminocarboxylic acid, phosphoric acid, etc. and a nitroso compound to the monomer.
CONSTITUTION: A cationic vinyl monomer of formula (R1 is H or OH; R2 and R3 are alkyl or hydroxyalkyl; R4 is H, benzyl or R2; A is O or NH; R is alkylene or hydroxyalkylene; X- is anionic counter ion) is incorporated with (A) a chelating agent selected from aminocarboxylic acids, oxycarboxylic acids, polycarboxylic acids, phosphoric acid, polyphosphoric acids, their salts, dialkylglyoximes, 1,3-diketones, semicarbazides, dipyridyl, and phenyl salicylate, and (B) a nitroso compound. The weight ratio of A:B is 100:(0.01W10). The preferable combination of the additives is ethylenediaminetetraacetic acid, phosphoric acid, etc. as the component (A) and p-nitrosophenol, etc. as the component (B).
COPYRIGHT: (C)1982,JPO&Japio
JP18735080A 1980-12-26 1980-12-26 Stabilization of cationic vinyl monomer Pending JPS57109747A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18735080A JPS57109747A (en) 1980-12-26 1980-12-26 Stabilization of cationic vinyl monomer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18735080A JPS57109747A (en) 1980-12-26 1980-12-26 Stabilization of cationic vinyl monomer

Publications (1)

Publication Number Publication Date
JPS57109747A true JPS57109747A (en) 1982-07-08

Family

ID=16204448

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18735080A Pending JPS57109747A (en) 1980-12-26 1980-12-26 Stabilization of cationic vinyl monomer

Country Status (1)

Country Link
JP (1) JPS57109747A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2750697A1 (en) * 1996-07-08 1998-01-09 Atochem Elf Sa PROCESS FOR PRODUCING AQUEOUS SOLUTIONS OF UNSATURATED QUATERNARY AMMONIUM SALTS
JP2005343845A (en) * 2004-06-04 2005-12-15 Hakuto Co Ltd Polymerization inhibitor of acrylonitrile and method for inhibiting polymerization

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2750697A1 (en) * 1996-07-08 1998-01-09 Atochem Elf Sa PROCESS FOR PRODUCING AQUEOUS SOLUTIONS OF UNSATURATED QUATERNARY AMMONIUM SALTS
EP0818437A1 (en) * 1996-07-08 1998-01-14 Elf Atochem S.A. Process for the preparation of aqueous solutions of insaturated quaternary ammonium salts
CN1125036C (en) * 1996-07-08 2003-10-22 埃勒夫阿托化学有限公司 Process for manufacture of aqueous solutions of unsaturated quaternary ammonium salts
JP2005343845A (en) * 2004-06-04 2005-12-15 Hakuto Co Ltd Polymerization inhibitor of acrylonitrile and method for inhibiting polymerization

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