JPS57109747A - Stabilization of cationic vinyl monomer - Google Patents
Stabilization of cationic vinyl monomerInfo
- Publication number
- JPS57109747A JPS57109747A JP18735080A JP18735080A JPS57109747A JP S57109747 A JPS57109747 A JP S57109747A JP 18735080 A JP18735080 A JP 18735080A JP 18735080 A JP18735080 A JP 18735080A JP S57109747 A JPS57109747 A JP S57109747A
- Authority
- JP
- Japan
- Prior art keywords
- acids
- phosphoric acid
- monomer
- vinyl monomer
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prevent the degradation of the titled monomer during storage, transportation or preparation, and to improve its stability remarkably without lowering the polymerization reactivity, by adding a chelating agent such as aminocarboxylic acid, phosphoric acid, etc. and a nitroso compound to the monomer.
CONSTITUTION: A cationic vinyl monomer of formula (R1 is H or OH; R2 and R3 are alkyl or hydroxyalkyl; R4 is H, benzyl or R2; A is O or NH; R is alkylene or hydroxyalkylene; X- is anionic counter ion) is incorporated with (A) a chelating agent selected from aminocarboxylic acids, oxycarboxylic acids, polycarboxylic acids, phosphoric acid, polyphosphoric acids, their salts, dialkylglyoximes, 1,3-diketones, semicarbazides, dipyridyl, and phenyl salicylate, and (B) a nitroso compound. The weight ratio of A:B is 100:(0.01W10). The preferable combination of the additives is ethylenediaminetetraacetic acid, phosphoric acid, etc. as the component (A) and p-nitrosophenol, etc. as the component (B).
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18735080A JPS57109747A (en) | 1980-12-26 | 1980-12-26 | Stabilization of cationic vinyl monomer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18735080A JPS57109747A (en) | 1980-12-26 | 1980-12-26 | Stabilization of cationic vinyl monomer |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57109747A true JPS57109747A (en) | 1982-07-08 |
Family
ID=16204448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18735080A Pending JPS57109747A (en) | 1980-12-26 | 1980-12-26 | Stabilization of cationic vinyl monomer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57109747A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2750697A1 (en) * | 1996-07-08 | 1998-01-09 | Atochem Elf Sa | PROCESS FOR PRODUCING AQUEOUS SOLUTIONS OF UNSATURATED QUATERNARY AMMONIUM SALTS |
JP2005343845A (en) * | 2004-06-04 | 2005-12-15 | Hakuto Co Ltd | Polymerization inhibitor of acrylonitrile and method for inhibiting polymerization |
-
1980
- 1980-12-26 JP JP18735080A patent/JPS57109747A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2750697A1 (en) * | 1996-07-08 | 1998-01-09 | Atochem Elf Sa | PROCESS FOR PRODUCING AQUEOUS SOLUTIONS OF UNSATURATED QUATERNARY AMMONIUM SALTS |
EP0818437A1 (en) * | 1996-07-08 | 1998-01-14 | Elf Atochem S.A. | Process for the preparation of aqueous solutions of insaturated quaternary ammonium salts |
CN1125036C (en) * | 1996-07-08 | 2003-10-22 | 埃勒夫阿托化学有限公司 | Process for manufacture of aqueous solutions of unsaturated quaternary ammonium salts |
JP2005343845A (en) * | 2004-06-04 | 2005-12-15 | Hakuto Co Ltd | Polymerization inhibitor of acrylonitrile and method for inhibiting polymerization |
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