JPS5690811A - Polymerization of ethylene - Google Patents
Polymerization of ethyleneInfo
- Publication number
- JPS5690811A JPS5690811A JP16695679A JP16695679A JPS5690811A JP S5690811 A JPS5690811 A JP S5690811A JP 16695679 A JP16695679 A JP 16695679A JP 16695679 A JP16695679 A JP 16695679A JP S5690811 A JPS5690811 A JP S5690811A
- Authority
- JP
- Japan
- Prior art keywords
- solid component
- component
- compound
- ethylene
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To produce a polyethylene type polymer having a wide MW distribution, excellent rigidity and excellent resistance to environmental stress cracking, by employing a catalyst consisting of a specified solid component and an organometallic compound component.
CONSTITUTION: To the surface of an inorganic support such as magnesium chloride is attached a titanium compound represented by the formula, wherein R is a C3W C20 sec. or tert. hydrocarbon group, X is a halogen and n is 0W1.5, pref., 0.3W0.8. This product is heated to about 50W300°C to decompose the titanium compound and thereby to form a solid product substantially free from OR groups. Next, a solid component is obtained by reacting the above solid product with an organomagnesium compound such as AlMg6(C2H5)3(n-C4H9)12 at a temperature of about -80W 150°C in an inert reaction medium. Then, ethylene is polymerized by use of a catalyst prepared by combining the above solid component with an organometallic compound such as triethylaluminum.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16695679A JPS5690811A (en) | 1979-12-24 | 1979-12-24 | Polymerization of ethylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16695679A JPS5690811A (en) | 1979-12-24 | 1979-12-24 | Polymerization of ethylene |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5690811A true JPS5690811A (en) | 1981-07-23 |
Family
ID=15840729
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16695679A Pending JPS5690811A (en) | 1979-12-24 | 1979-12-24 | Polymerization of ethylene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5690811A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6287008A (en) * | 1985-10-14 | 1987-04-21 | 株式会社クボタ | Seedling growing box feeder |
-
1979
- 1979-12-24 JP JP16695679A patent/JPS5690811A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6287008A (en) * | 1985-10-14 | 1987-04-21 | 株式会社クボタ | Seedling growing box feeder |
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