JPS5687536A - Monoterpenoid compound - Google Patents
Monoterpenoid compoundInfo
- Publication number
- JPS5687536A JPS5687536A JP16455879A JP16455879A JPS5687536A JP S5687536 A JPS5687536 A JP S5687536A JP 16455879 A JP16455879 A JP 16455879A JP 16455879 A JP16455879 A JP 16455879A JP S5687536 A JPS5687536 A JP S5687536A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- tetramethylbicyclo
- heptan
- propionate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
NEW MATERIAL:4,4,6,6-Tetramethylbicyclo[3,1,1]heptan-2-yl propionate of formula I, and 4-ethyl-6,6-dimethylbicyclo[3,1,1]hept-3-en-2-yl propionate of formula II.
USE: Cockroach attractant.
PROCESS: Verbenyl acetate prepared by reacting α-pinene with Pb(OAc)4 and acetic acid is hydrolyzed with an alkali and then oxidized with a chromium oxide to give verbenone, which is treated with (CH3)2CuLi to afford 4,4,6,6-tetramethylbicyclo [3,1,1]heptan-2-one. The compound obtained is made to react with aluminum triisopropoxide and then with propionic anhydride to give the compound of formula I. The compound of formula II is prepared from α-pinene according to the reaction scheme.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16455879A JPS5687536A (en) | 1979-12-18 | 1979-12-18 | Monoterpenoid compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16455879A JPS5687536A (en) | 1979-12-18 | 1979-12-18 | Monoterpenoid compound |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5687536A true JPS5687536A (en) | 1981-07-16 |
Family
ID=15795438
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16455879A Pending JPS5687536A (en) | 1979-12-18 | 1979-12-18 | Monoterpenoid compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5687536A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4911907A (en) * | 1986-10-14 | 1990-03-27 | Taisho Pharmaceutical Co., Ltd. | Cockroach attractants |
-
1979
- 1979-12-18 JP JP16455879A patent/JPS5687536A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4911907A (en) * | 1986-10-14 | 1990-03-27 | Taisho Pharmaceutical Co., Ltd. | Cockroach attractants |
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