JPS5663928A - Method for carrying out organic ionic reaction - Google Patents
Method for carrying out organic ionic reactionInfo
- Publication number
- JPS5663928A JPS5663928A JP14034079A JP14034079A JPS5663928A JP S5663928 A JPS5663928 A JP S5663928A JP 14034079 A JP14034079 A JP 14034079A JP 14034079 A JP14034079 A JP 14034079A JP S5663928 A JPS5663928 A JP S5663928A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- compound
- layer
- reaction
- aqueous layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- 239000010410 layer Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000012044 organic layer Substances 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal salt Chemical class 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001983 dialkylethers Chemical class 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000006353 oxyethylene group Chemical group 0.000 abstract 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Landscapes
- Catalysts (AREA)
Abstract
PURPOSE: To recycle a polyethylene glycol dialkyl ether used as a catalyst of the titled reaction catalyzed with an alkali metal hydroxide, by extracting the catalyst from an organic layer to an aqueous layer, and separating from the aqueous layer taking advantage of the clouding point of the ether.
CONSTITUTION: The titled reaction catalyzed with an alkali metal hydroxide is carried out in the presence of a compound of formula (R1 and R2 are methyl, ethyl, propyl, butyl, or pentyl; (n) is the average number of oxyethylene units and is 6W 30), and the alkali metal salt is removed from the reaction mixture, which is then separated into an organic layer and a water layer. The organic layer is treated with water, etc. to extract the catalyst into the aqueous layer, and the reaction products, etc. are separated from the extraction residue. The aqueous layer is heated above the clouding point of the compound of formula to form the layer of the compound, which is then recycled to the titled reaction process.
EFFECT: The applicability of the titled reaction is improved and the process is simplified by the use of the compound of formula which is chemically stable and available at a low cost, as a catalyst.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14034079A JPS5663928A (en) | 1979-10-29 | 1979-10-29 | Method for carrying out organic ionic reaction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14034079A JPS5663928A (en) | 1979-10-29 | 1979-10-29 | Method for carrying out organic ionic reaction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5663928A true JPS5663928A (en) | 1981-05-30 |
Family
ID=15266547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14034079A Pending JPS5663928A (en) | 1979-10-29 | 1979-10-29 | Method for carrying out organic ionic reaction |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5663928A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62148441A (en) * | 1985-12-23 | 1987-07-02 | Mitsui Toatsu Chem Inc | Production of alkenylphenol |
| JP2015505546A (en) * | 2012-02-01 | 2015-02-23 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | Process for producing methylene-1,3-dioxolanes |
-
1979
- 1979-10-29 JP JP14034079A patent/JPS5663928A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62148441A (en) * | 1985-12-23 | 1987-07-02 | Mitsui Toatsu Chem Inc | Production of alkenylphenol |
| JPH0457657B2 (en) * | 1985-12-23 | 1992-09-14 | Mitsui Toatsu Chemicals | |
| JP2015505546A (en) * | 2012-02-01 | 2015-02-23 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | Process for producing methylene-1,3-dioxolanes |
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