JPS5661344A - 4-substituted benzoic acid 3',5'-dicyanophenyl esters - Google Patents
4-substituted benzoic acid 3',5'-dicyanophenyl estersInfo
- Publication number
- JPS5661344A JPS5661344A JP13716979A JP13716979A JPS5661344A JP S5661344 A JPS5661344 A JP S5661344A JP 13716979 A JP13716979 A JP 13716979A JP 13716979 A JP13716979 A JP 13716979A JP S5661344 A JPS5661344 A JP S5661344A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound shown
- give
- liquid crystal
- dicyanophenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Crystal Substances (AREA)
Abstract
NEW MATERIAL:The titled compound shown by the formula I [X is R(alkyl); RO(alkoxy), alkylphenyl, etc., R is 3W8C straight-chain alkyl].
EXAMPLE: 4-n-Hexyloxybenzoic acid 3',5'-dicyanophenyl ester.
USE: An additve for a liquid crystal composition having high dielectric anisotropy. When it is added to a nematic liquid crystal composition, negative or positive dielectric anisotropy is made higher positive value, and a voltage of threshold is reduced, the addition is effective in the drive of low voltage. The compound has improved compatibility with other liquid crystal and can be mixed with it uniformly.
PROCESS: A compound shown by the formula II is debrominated in the presence of AlCl3 as a catalyst in a solvent of benzene under heating to give a compound shown by the formula III. This compound is cyanized to give a compound shown by the formula IV, which is reacted with a compound shown by the formula VI obtained from a compound shown by the formula V and SOCl2, to give the titled compound shown by the formula I.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13716979A JPS5661344A (en) | 1979-10-24 | 1979-10-24 | 4-substituted benzoic acid 3',5'-dicyanophenyl esters |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13716979A JPS5661344A (en) | 1979-10-24 | 1979-10-24 | 4-substituted benzoic acid 3',5'-dicyanophenyl esters |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5661344A true JPS5661344A (en) | 1981-05-26 |
JPS6312058B2 JPS6312058B2 (en) | 1988-03-17 |
Family
ID=15192425
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13716979A Granted JPS5661344A (en) | 1979-10-24 | 1979-10-24 | 4-substituted benzoic acid 3',5'-dicyanophenyl esters |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5661344A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61245930A (en) * | 1985-04-22 | 1986-11-01 | Toyota Motor Corp | Rolling method |
GB2350361A (en) * | 1999-05-22 | 2000-11-29 | Merck Patent Gmbh | Liquid crystalline 3,4,5-tricyanophenyl derivatives |
-
1979
- 1979-10-24 JP JP13716979A patent/JPS5661344A/en active Granted
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61245930A (en) * | 1985-04-22 | 1986-11-01 | Toyota Motor Corp | Rolling method |
JPH0448539B2 (en) * | 1985-04-22 | 1992-08-07 | Toyota Jidosha Kk | |
GB2350361A (en) * | 1999-05-22 | 2000-11-29 | Merck Patent Gmbh | Liquid crystalline 3,4,5-tricyanophenyl derivatives |
GB2350361B (en) * | 1999-05-22 | 2003-12-03 | Merck Patent Gmbh | 3,4,5-tricyanophenyl derivatives |
Also Published As
Publication number | Publication date |
---|---|
JPS6312058B2 (en) | 1988-03-17 |
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