JPS5616471A - Novel basic substance and its preparation - Google Patents
Novel basic substance and its preparationInfo
- Publication number
- JPS5616471A JPS5616471A JP9090179A JP9090179A JPS5616471A JP S5616471 A JPS5616471 A JP S5616471A JP 9090179 A JP9090179 A JP 9090179A JP 9090179 A JP9090179 A JP 9090179A JP S5616471 A JPS5616471 A JP S5616471A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- preparation
- reaction
- basic substance
- produce
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/64—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms, e.g. histidine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/91—Nitro radicals
- C07D233/92—Nitro radicals attached in position 4 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
NEW MATERIAL:Basic substances of formula I (R is H, 1W17C alkyl, aryl, benzyl, pyridyl, nitro).
EXAMPLE: 1-(m-Styryl)methylimidazole.
USE: Monomers for homo- or copolymer: they can produce functional high polymers such as adsorbent or ion-exchange resin.
PREPARATION: The reaction of a halogenomethylstyrene of formula II (X is halogen) such as m-chloromethylstyrene with a substituted imidazole of formula III is conducted in an inert solvent at -50W60°C, preferably in the presence of a polymerization inhibitor, to produce the compound of formula I. The use of at least one selected from inorganic alkaline compounds, organic basic compounds, metals and metal halides on the reaction oftentimes shortens the reaction time and increases the yield.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9090179A JPS6047257B2 (en) | 1979-07-19 | 1979-07-19 | Novel basic substances and their production methods |
GB8020971A GB2054567B (en) | 1979-07-19 | 1980-06-26 | Basic styrene compounds and process for the preparation thereof |
AU60258/80A AU530504B2 (en) | 1979-07-19 | 1980-07-09 | 1-styrylmethylimidazole compounds |
FR8015523A FR2461704A1 (en) | 1979-07-19 | 1980-07-11 | BASIC STYRENE COMPOUND AND PROCESS FOR PREPARING THE SAME |
DE19803026410 DE3026410A1 (en) | 1979-07-19 | 1980-07-11 | BASIC CONNECTIONS AND PRODUCTION METHOD |
BE0/201437A BE884355A (en) | 1979-07-19 | 1980-07-17 | BASIC STYRENE COMPOUND AND PROCESS FOR ITS PREPARATION |
NL8004166A NL8004166A (en) | 1979-07-19 | 1980-07-18 | NEW BASIC STYRENE COMPOUNDS AND METHOD FOR THE PREPARATION THEREOF. |
CA000356454A CA1154025A (en) | 1979-07-19 | 1980-07-18 | Basic styrene compounds and process for preparation thereof |
US06/335,943 US4430445A (en) | 1979-07-19 | 1981-12-30 | Novel basic imidazolylmethylstyrene compound, its polymer, a process for the preparation thereof and a use as ion exchange resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9090179A JPS6047257B2 (en) | 1979-07-19 | 1979-07-19 | Novel basic substances and their production methods |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6221680A Division JPS5632462A (en) | 1980-05-13 | 1980-05-13 | Novel basic substance and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5616471A true JPS5616471A (en) | 1981-02-17 |
JPS6047257B2 JPS6047257B2 (en) | 1985-10-21 |
Family
ID=14011293
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9090179A Expired JPS6047257B2 (en) | 1979-07-19 | 1979-07-19 | Novel basic substances and their production methods |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS6047257B2 (en) |
AU (1) | AU530504B2 (en) |
BE (1) | BE884355A (en) |
CA (1) | CA1154025A (en) |
DE (1) | DE3026410A1 (en) |
FR (1) | FR2461704A1 (en) |
GB (1) | GB2054567B (en) |
NL (1) | NL8004166A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2125416B (en) * | 1982-07-14 | 1985-11-27 | Asahi Chemical Ind | Imidazolylmethyl styrene polymers use thereof as ion exchange resins |
DE3811574A1 (en) * | 1988-03-31 | 1989-10-19 | Schering Ag | N-SUBSTITUTED IMIDAZOLES, METHODS FOR THEIR PRODUCTION AND THEIR USE IN MEDICINAL PRODUCTS |
EP1501825A2 (en) | 2002-05-08 | 2005-02-02 | Neurogen Corporation | Substituted imidazolylmethyl pyridine and pyrazine derivatives: gaba a receptor ligands |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US443563A (en) * | 1890-12-30 | Sigmund bergmann | ||
US3226372A (en) * | 1961-06-02 | 1965-12-28 | Dow Chemical Co | Novel heterocyclic compounds and polymers |
AT370095B (en) * | 1977-10-19 | 1983-02-25 | Wellcome Found | METHOD FOR PRODUCING NEW 1-ARYL-ALKYL-IMIDAZOLE DERIVATIVES AND THEIR SALTS |
-
1979
- 1979-07-19 JP JP9090179A patent/JPS6047257B2/en not_active Expired
-
1980
- 1980-06-26 GB GB8020971A patent/GB2054567B/en not_active Expired
- 1980-07-09 AU AU60258/80A patent/AU530504B2/en not_active Ceased
- 1980-07-11 FR FR8015523A patent/FR2461704A1/en active Granted
- 1980-07-11 DE DE19803026410 patent/DE3026410A1/en active Granted
- 1980-07-17 BE BE0/201437A patent/BE884355A/en not_active IP Right Cessation
- 1980-07-18 CA CA000356454A patent/CA1154025A/en not_active Expired
- 1980-07-18 NL NL8004166A patent/NL8004166A/en active Search and Examination
Also Published As
Publication number | Publication date |
---|---|
FR2461704A1 (en) | 1981-02-06 |
DE3026410A1 (en) | 1981-02-05 |
JPS6047257B2 (en) | 1985-10-21 |
FR2461704B1 (en) | 1985-01-04 |
AU6025880A (en) | 1981-01-22 |
GB2054567B (en) | 1983-09-21 |
NL8004166A (en) | 1981-01-21 |
CA1154025A (en) | 1983-09-20 |
DE3026410C2 (en) | 1987-01-02 |
AU530504B2 (en) | 1983-07-21 |
GB2054567A (en) | 1981-02-18 |
BE884355A (en) | 1981-01-19 |
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