JPS56118087A - Preparation of organic magnesium-aluminum complex - Google Patents
Preparation of organic magnesium-aluminum complexInfo
- Publication number
- JPS56118087A JPS56118087A JP2161280A JP2161280A JPS56118087A JP S56118087 A JPS56118087 A JP S56118087A JP 2161280 A JP2161280 A JP 2161280A JP 2161280 A JP2161280 A JP 2161280A JP S56118087 A JPS56118087 A JP S56118087A
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- component
- benzene
- react
- metallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
PURPOSE: To prepare the titled compound useful in the organic synthesis reaction, etc., by reacting a reaction product of a halogenated hydrocarbon and metallic Mg, with an aluminum compound in an inert hydrocarbon medium at a specific temperature for a specific time interval under specific conditions.
CONSTITUTION: A halogenated hydrocarbon (e.g. ethyl bromide) is made to react with metallic Mg in a reaction medium such as benzene. The reaction product (A) is made to react with an aluminum compound (B) of formula Al(OR1)3 (R1 is 1W20C hydrocarbon group) in a reaction medium such as benzene at 120W200°C for 0.5W10hr. A halogen-free organic Mg-Al complex wherein the equivalent ratio of OR1 to Mg-C bond is ≤0.005 can be prepared by carrying out the above reaction keeping the equivalent ratio of Al in the (B) component to Mg-C bond in the (A) component between 0.005 and 0.1, and separating the liquid component from the solid component.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2161280A JPS56118087A (en) | 1980-02-25 | 1980-02-25 | Preparation of organic magnesium-aluminum complex |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2161280A JPS56118087A (en) | 1980-02-25 | 1980-02-25 | Preparation of organic magnesium-aluminum complex |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56118087A true JPS56118087A (en) | 1981-09-16 |
JPS6323997B2 JPS6323997B2 (en) | 1988-05-18 |
Family
ID=12059859
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2161280A Granted JPS56118087A (en) | 1980-02-25 | 1980-02-25 | Preparation of organic magnesium-aluminum complex |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56118087A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6327382U (en) * | 1986-08-05 | 1988-02-23 |
-
1980
- 1980-02-25 JP JP2161280A patent/JPS56118087A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6327382U (en) * | 1986-08-05 | 1988-02-23 | ||
JPH0517276Y2 (en) * | 1986-08-05 | 1993-05-10 |
Also Published As
Publication number | Publication date |
---|---|
JPS6323997B2 (en) | 1988-05-18 |
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