JPS569226A - Novel complex compound and its manufacture - Google Patents
Novel complex compound and its manufactureInfo
- Publication number
- JPS569226A JPS569226A JP8249179A JP8249179A JPS569226A JP S569226 A JPS569226 A JP S569226A JP 8249179 A JP8249179 A JP 8249179A JP 8249179 A JP8249179 A JP 8249179A JP S569226 A JPS569226 A JP S569226A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- integer
- formula
- novel complex
- complex compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title abstract 10
- 238000004519 manufacturing process Methods 0.000 title 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 229910021604 Rhodium(III) chloride Inorganic materials 0.000 abstract 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract 1
- -1 amine compound Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 abstract 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Abstract
PURPOSE: To obtain a novel complex compound having a specific ligand structure and applicable to a hydrogenation catalyst, etc. by reacting an Rh compound and an Sn compound in a hydrochloric acid soln. so that the atomic number ratio of Rh to Sn becomes a specified value and reacting the liq. reaction product with a specified amine compound.
CONSTITUTION: An Rh compound such as RhCl3.nH2O and an Sn compound such as SnCl2.nH2O are reacted in a hydrochloric acid soln. in 1:7W1:10 ratio of number of atoms of Rh to Sn, and the liq. reaction product is reacted with a compound such as [Rh(NH3)6]3 represented by formula I (where M is Rh or Ir, R is ammine or ethylene diamine (H2N-CH2-CH2-NH2) diamine, k is an integer of 3W6 and X is halogen) under appropriate conditions to obtain a novel complex compound represented by general formula II [where M is Rh or Ir, R is ammine (NH3) or ethylenediamine, K is an integer of 3W6 and n is an integer of 0W4 which expresses the number of the water of crystallizations]. This compound may be of formula III, IV or V correspondingly to the compound of formula I, and it is applicable to a hydrogenation catalyst or a catalyst for dehydrogenation reaction in which light energy takes part.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54082491A JPS583976B2 (en) | 1979-06-29 | 1979-06-29 | Novel complex compound and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54082491A JPS583976B2 (en) | 1979-06-29 | 1979-06-29 | Novel complex compound and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS569226A true JPS569226A (en) | 1981-01-30 |
| JPS583976B2 JPS583976B2 (en) | 1983-01-24 |
Family
ID=13775958
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54082491A Expired JPS583976B2 (en) | 1979-06-29 | 1979-06-29 | Novel complex compound and its production method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS583976B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60165080U (en) * | 1984-04-11 | 1985-11-01 | 田中 惠 | vibration sorter |
| JPH0192280U (en) * | 1987-12-08 | 1989-06-16 | ||
| JP6622268B2 (en) | 2017-09-15 | 2019-12-18 | アイシン精機株式会社 | Grill shutter device |
-
1979
- 1979-06-29 JP JP54082491A patent/JPS583976B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS583976B2 (en) | 1983-01-24 |
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