JPS56117167A - Method for analysis of n-acyl-l-prolyl halogenide - Google Patents

Method for analysis of n-acyl-l-prolyl halogenide

Info

Publication number
JPS56117167A
JPS56117167A JP2092580A JP2092580A JPS56117167A JP S56117167 A JPS56117167 A JP S56117167A JP 2092580 A JP2092580 A JP 2092580A JP 2092580 A JP2092580 A JP 2092580A JP S56117167 A JPS56117167 A JP S56117167A
Authority
JP
Japan
Prior art keywords
acyl
halogenide
expressed
formula
prolyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2092580A
Other languages
Japanese (ja)
Inventor
Takafumi Oi
Masao Horiba
Hajime Kitahara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP2092580A priority Critical patent/JPS56117167A/en
Publication of JPS56117167A publication Critical patent/JPS56117167A/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/29—Chiral phases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Investigating Or Analysing Biological Materials (AREA)

Abstract

PURPOSE:To analyze N-acyl-L-plolyl halogenide easily and accurately by reacting this to a specific amide deriv., then separating antipode by a gas chromatography having a specific optically active stationary phase. CONSTITUTION:The N-acyl-L-prolyl halogenide expressed by the formula I (A1 is lower fatty acid acyl or halogen-substituted acyl, X is halogen) is reacted with the amine expressed by the formula II (A2 is alkyl of >=C3, cycloakyl) to an amide deriv. The soln. of said amide derivative is supplied to a gas chromatography having the optically active S-triazine having at least two asymmetric carbon atoms such as the one expressed by the formula III as its stationary phase, and the antipode is separated and determined, whereby the assay of optical purity which has been difficult in conventional methods is made possible.
JP2092580A 1980-02-20 1980-02-20 Method for analysis of n-acyl-l-prolyl halogenide Pending JPS56117167A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2092580A JPS56117167A (en) 1980-02-20 1980-02-20 Method for analysis of n-acyl-l-prolyl halogenide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2092580A JPS56117167A (en) 1980-02-20 1980-02-20 Method for analysis of n-acyl-l-prolyl halogenide

Publications (1)

Publication Number Publication Date
JPS56117167A true JPS56117167A (en) 1981-09-14

Family

ID=12040789

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2092580A Pending JPS56117167A (en) 1980-02-20 1980-02-20 Method for analysis of n-acyl-l-prolyl halogenide

Country Status (1)

Country Link
JP (1) JPS56117167A (en)

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