JPS5536442A - Sesquiterpene derivative and its preparation - Google Patents

Sesquiterpene derivative and its preparation

Info

Publication number
JPS5536442A
JPS5536442A JP11036078A JP11036078A JPS5536442A JP S5536442 A JPS5536442 A JP S5536442A JP 11036078 A JP11036078 A JP 11036078A JP 11036078 A JP11036078 A JP 11036078A JP S5536442 A JPS5536442 A JP S5536442A
Authority
JP
Japan
Prior art keywords
formula
derivative
preparation
sesquiterpene
sesquiterpene derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11036078A
Other languages
Japanese (ja)
Other versions
JPS5920673B2 (en
Inventor
Hiroyuki Akita
Takeshi Oishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN Institute of Physical and Chemical Research
Original Assignee
RIKEN Institute of Physical and Chemical Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN Institute of Physical and Chemical Research filed Critical RIKEN Institute of Physical and Chemical Research
Priority to JP11036078A priority Critical patent/JPS5920673B2/en
Publication of JPS5536442A publication Critical patent/JPS5536442A/en
Publication of JPS5920673B2 publication Critical patent/JPS5920673B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)

Abstract

NEW MATERIAL:Sesquiterpene derivative of formula 13.
USE: Synthetic intermediate of naturally occurring drimane-type sesquiterpene, such as warburganal [A] and polygodial [B] having antifeedant activity against African army worm.
PREPARATION: 11,14-Diacetoxy-furan derivative of formula 12 is stood together with an oxidant as OsO4 in a solvent of ether-pyridine to form the objective dihydroxy derivative of formula 13. The reaction is effected at 0W30°C, preferably room temperature, for 1W60 days. The compound 12 is derived from β-ionone through many steps.
COPYRIGHT: (C)1980,JPO&Japio
JP11036078A 1978-09-08 1978-09-08 Sesquiterpene derivatives and their production method Expired JPS5920673B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11036078A JPS5920673B2 (en) 1978-09-08 1978-09-08 Sesquiterpene derivatives and their production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11036078A JPS5920673B2 (en) 1978-09-08 1978-09-08 Sesquiterpene derivatives and their production method

Publications (2)

Publication Number Publication Date
JPS5536442A true JPS5536442A (en) 1980-03-14
JPS5920673B2 JPS5920673B2 (en) 1984-05-15

Family

ID=14533797

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11036078A Expired JPS5920673B2 (en) 1978-09-08 1978-09-08 Sesquiterpene derivatives and their production method

Country Status (1)

Country Link
JP (1) JPS5920673B2 (en)

Also Published As

Publication number Publication date
JPS5920673B2 (en) 1984-05-15

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