JPS5531059A - Preparation of alkali metal p-styrenesulfonate - Google Patents

Preparation of alkali metal p-styrenesulfonate

Info

Publication number
JPS5531059A
JPS5531059A JP12731078A JP12731078A JPS5531059A JP S5531059 A JPS5531059 A JP S5531059A JP 12731078 A JP12731078 A JP 12731078A JP 12731078 A JP12731078 A JP 12731078A JP S5531059 A JPS5531059 A JP S5531059A
Authority
JP
Japan
Prior art keywords
alkali metal
haloethylbenzene
styrenesulfonate
preparation
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12731078A
Other languages
Japanese (ja)
Other versions
JPS5715115B2 (en
Inventor
Hajime Fujii
Tatsuo Hattori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Toyo Soda Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Soda Manufacturing Co Ltd filed Critical Toyo Soda Manufacturing Co Ltd
Priority to JP12731078A priority Critical patent/JPS5531059A/en
Publication of JPS5531059A publication Critical patent/JPS5531059A/en
Publication of JPS5715115B2 publication Critical patent/JPS5715115B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE: To obtain the title compound in high yield, without discoloration, by sulfonating a haloethylbenzene in the presence of a specific amount of an organic carboxylic acid, and by reacting the n sulfonic acid with an alkali metal hydroxide in the presence of a specific amount of water.
CONSTITUTION: A 2-haloethylbenzene (B) and 0.5W20wt%, preferably 0.5W 5wt%, based on (B) of an organic carboxylic acid, e.g. acetic acid, are dissolved in an organic solvent, e.g. methylene chloride, inent to sulfur trioxide (S). A small excess of S is added to sulfonate B to give a p-2-haloethylbenzene-sulfonic acid (H), which is reacted with an alkali metal hydroxide in the presence of water in an amount of 0.7W1.4 times that of H at 100°C or above to form the objective alkali metal p-styrenesulfonate of formula (M is alkali metal).
COPYRIGHT: (C)1980,JPO&Japio
JP12731078A 1978-10-18 1978-10-18 Preparation of alkali metal p-styrenesulfonate Granted JPS5531059A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12731078A JPS5531059A (en) 1978-10-18 1978-10-18 Preparation of alkali metal p-styrenesulfonate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12731078A JPS5531059A (en) 1978-10-18 1978-10-18 Preparation of alkali metal p-styrenesulfonate

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP993373A Division JPS5521030B2 (en) 1973-01-25 1973-01-25

Publications (2)

Publication Number Publication Date
JPS5531059A true JPS5531059A (en) 1980-03-05
JPS5715115B2 JPS5715115B2 (en) 1982-03-29

Family

ID=14956773

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12731078A Granted JPS5531059A (en) 1978-10-18 1978-10-18 Preparation of alkali metal p-styrenesulfonate

Country Status (1)

Country Link
JP (1) JPS5531059A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS554376A (en) * 1978-06-12 1980-01-12 Chemithon Corp Sulfonation of alkylated aromatic hydrocarbon
JPS59173626U (en) * 1983-05-10 1984-11-20 鶴見曹達株式会社 Cylinder moving device
JPH0194315U (en) * 1987-12-11 1989-06-21
JPH0524636A (en) * 1991-07-24 1993-02-02 Honda Motor Co Ltd Conveyor device
JP2014080380A (en) * 2012-10-15 2014-05-08 Tosoh Organic Chemical Co Ltd Sodium p-styrene sulfonate with excellent flowability and solubility, and method of producing the same
US9505713B2 (en) 2012-10-15 2016-11-29 Tosoh Organic Chemical Co., Ltd High-purity sodium p-styrenesulfonate with excellent hue, method for producing the same, poly(sodium p-styrenesulfonate) with excellent hue using the same, and dispersant and synthetic starch for clothing finishing using the poly(sodium p-styrenesulfonate)
CN109836359A (en) * 2017-11-27 2019-06-04 荆楚理工学院 A kind of preparation method of sodium p styrene sulfonate

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106946745A (en) * 2017-04-27 2017-07-14 山东星之联生物科技股份有限公司 The preparation method of sodium p styrene sulfonate

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS554376A (en) * 1978-06-12 1980-01-12 Chemithon Corp Sulfonation of alkylated aromatic hydrocarbon
JPS59502B2 (en) * 1978-06-12 1984-01-07 ザ・ケミゾン・コ−ポレ−シヨン Sulfonation method for alkylated aromatic hydrocarbons
JPS59173626U (en) * 1983-05-10 1984-11-20 鶴見曹達株式会社 Cylinder moving device
JPH0144496Y2 (en) * 1983-05-10 1989-12-22
JPH0194315U (en) * 1987-12-11 1989-06-21
JPH0524636A (en) * 1991-07-24 1993-02-02 Honda Motor Co Ltd Conveyor device
JP2014080380A (en) * 2012-10-15 2014-05-08 Tosoh Organic Chemical Co Ltd Sodium p-styrene sulfonate with excellent flowability and solubility, and method of producing the same
US9505713B2 (en) 2012-10-15 2016-11-29 Tosoh Organic Chemical Co., Ltd High-purity sodium p-styrenesulfonate with excellent hue, method for producing the same, poly(sodium p-styrenesulfonate) with excellent hue using the same, and dispersant and synthetic starch for clothing finishing using the poly(sodium p-styrenesulfonate)
CN109836359A (en) * 2017-11-27 2019-06-04 荆楚理工学院 A kind of preparation method of sodium p styrene sulfonate
CN109836359B (en) * 2017-11-27 2021-12-31 荆楚理工学院 Preparation method of sodium p-styrene sulfonate

Also Published As

Publication number Publication date
JPS5715115B2 (en) 1982-03-29

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