JPS55162727A - Reductive addition reaction of aromatic hydrocarbon - Google Patents
Reductive addition reaction of aromatic hydrocarbonInfo
- Publication number
- JPS55162727A JPS55162727A JP4876080A JP4876080A JPS55162727A JP S55162727 A JPS55162727 A JP S55162727A JP 4876080 A JP4876080 A JP 4876080A JP 4876080 A JP4876080 A JP 4876080A JP S55162727 A JPS55162727 A JP S55162727A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- aromatic hydrocarbon
- strong acid
- organic acid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare a cyclohexanol derivative useful as a solvent and a raw material of polymer, in one step, by the reductive addition reaction of an aromatic hydrocarbon with hydrogen in the presence of a mixture containing a strong acid, water, and if necessary, an organic acid, using a noble metal of VIII group of the periodic table as a catalyst.
CONSTITUTION: The preparation of cyclohexanol derivative of formula (Ac is H, organic acid residue or strong acid residue; R is alkyl; n is 0, 1 or 2) by the hydrogenation of an aromatic hydrocarbon (e.g. benzene) using a noble metal of the VIII group of the periodic table (pref. Ru or Rh) as a catalyst, is carried out in the presence of a strong acid, and water and/or an organic acid. The presence of the strong acid is essential, and its amount is ≥2% of the sum of the strong acid and water and/or an organic acid. The strong acid is, e.g. sulfuric acid, phosphoric acid, etc., and the organic acid is, preferably acetic acid.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55048760A JPS5929172B2 (en) | 1980-04-15 | 1980-04-15 | Reductive addition reaction method for aromatic hydrocarbons |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55048760A JPS5929172B2 (en) | 1980-04-15 | 1980-04-15 | Reductive addition reaction method for aromatic hydrocarbons |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55162727A true JPS55162727A (en) | 1980-12-18 |
JPS5929172B2 JPS5929172B2 (en) | 1984-07-18 |
Family
ID=12812231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55048760A Expired JPS5929172B2 (en) | 1980-04-15 | 1980-04-15 | Reductive addition reaction method for aromatic hydrocarbons |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5929172B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60252437A (en) * | 1984-05-28 | 1985-12-13 | Asahi Chem Ind Co Ltd | Production of alcohol by hydration of olefin |
-
1980
- 1980-04-15 JP JP55048760A patent/JPS5929172B2/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60252437A (en) * | 1984-05-28 | 1985-12-13 | Asahi Chem Ind Co Ltd | Production of alcohol by hydration of olefin |
JPH0513134B2 (en) * | 1984-05-28 | 1993-02-19 | Asahi Chemical Ind |
Also Published As
Publication number | Publication date |
---|---|
JPS5929172B2 (en) | 1984-07-18 |
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