JPS55139325A - Manufacture of olefin from carbon monoxide and hydrogen - Google Patents

Manufacture of olefin from carbon monoxide and hydrogen

Info

Publication number
JPS55139325A
JPS55139325A JP4207579A JP4207579A JPS55139325A JP S55139325 A JPS55139325 A JP S55139325A JP 4207579 A JP4207579 A JP 4207579A JP 4207579 A JP4207579 A JP 4207579A JP S55139325 A JPS55139325 A JP S55139325A
Authority
JP
Japan
Prior art keywords
olefin
hydrogen
manufacture
carbon monoxide
monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4207579A
Other languages
English (en)
Inventor
Burian Maachison Kureigu
Ei Maadeitsuku Dauei
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US05/944,228 priority Critical patent/US4199522A/en
Priority claimed from US05/944,228 external-priority patent/US4199522A/en
Priority to CA323,780A priority patent/CA1107304A/en
Priority to ZA791448A priority patent/ZA791448B/xx
Priority to EP79100985A priority patent/EP0016851B1/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to DD79212097A priority patent/DD143900A5/de
Priority to JP4207579A priority patent/JPS55139325A/ja
Publication of JPS55139325A publication Critical patent/JPS55139325A/ja
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/043—Sulfides with iron group metals or platinum group metals
    • C07C2527/045—Platinum group metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP4207579A 1977-07-11 1979-04-09 Manufacture of olefin from carbon monoxide and hydrogen Pending JPS55139325A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US05/944,228 US4199522A (en) 1977-07-11 1978-09-20 Process for producing olefins from carbon monoxide and hydrogen
CA323,780A CA1107304A (en) 1978-09-20 1979-03-20 Process for producing olefins from carbon monoxide and hydrogen
ZA791448A ZA791448B (en) 1978-09-20 1979-03-27 Process for producing olefins from carbon monoxide and hydrogen
EP79100985A EP0016851B1 (en) 1978-09-20 1979-04-02 Process for producing olefins from carbon monoxide and hydrogen
DD79212097A DD143900A5 (de) 1978-09-20 1979-04-09 Verfahren zur herstellung von kohlenwasserstoffen durch behandlung von kohlenmonoxid und wasserstoff bei reaktiven bedingungen
JP4207579A JPS55139325A (en) 1978-09-20 1979-04-09 Manufacture of olefin from carbon monoxide and hydrogen

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US05/944,228 US4199522A (en) 1977-07-11 1978-09-20 Process for producing olefins from carbon monoxide and hydrogen
CA323,780A CA1107304A (en) 1978-09-20 1979-03-20 Process for producing olefins from carbon monoxide and hydrogen
ZA791448A ZA791448B (en) 1978-09-20 1979-03-27 Process for producing olefins from carbon monoxide and hydrogen
EP79100985A EP0016851B1 (en) 1978-09-20 1979-04-02 Process for producing olefins from carbon monoxide and hydrogen
DD79212097A DD143900A5 (de) 1978-09-20 1979-04-09 Verfahren zur herstellung von kohlenwasserstoffen durch behandlung von kohlenmonoxid und wasserstoff bei reaktiven bedingungen
JP4207579A JPS55139325A (en) 1978-09-20 1979-04-09 Manufacture of olefin from carbon monoxide and hydrogen

Publications (1)

Publication Number Publication Date
JPS55139325A true JPS55139325A (en) 1980-10-31

Family

ID=27543304

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4207579A Pending JPS55139325A (en) 1977-07-11 1979-04-09 Manufacture of olefin from carbon monoxide and hydrogen

Country Status (5)

Country Link
EP (1) EP0016851B1 (ja)
JP (1) JPS55139325A (ja)
CA (1) CA1107304A (ja)
DD (1) DD143900A5 (ja)
ZA (1) ZA791448B (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5692826A (en) * 1979-12-18 1981-07-27 Haldor Topsoe As Method and catalyst for manufacturing gas mixture containing high quantity of methane
JPS6166790A (ja) * 1983-04-28 1986-04-05 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− ルテニウム担持触媒を使用する液状炭化水素の合成
JPS621783A (ja) * 1985-06-28 1987-01-07 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素の製造方法
US6534553B1 (en) 2001-07-17 2003-03-18 President Of Tohoku University Hydrogenation of carbon monoxide using sulfide catalysts
US6605647B2 (en) 2000-07-04 2003-08-12 President Of Tohoku University Hydrogenation of carbon monoxide using sulfide catalysts

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2510551A1 (fr) * 1981-07-28 1983-02-04 Inst Francais Du Petrole Procede de synthese du methane par reduction catalytique d'oxyde de carbone en phase aqueuse
FR2513625A1 (fr) * 1981-09-28 1983-04-01 Shell Int Research Procede pour la production d'hydrocarbures a partir de gaz de synthese
EP0231401B1 (en) * 1984-06-29 1992-09-09 Exxon Research And Engineering Company Ruthenium-rhenium-titania catalysts, and use thereof for fischer-tropsch synthesis
GB8421646D0 (en) * 1984-08-25 1984-09-26 British Petroleum Co Plc Fischer-tropsch catalysts
CN103191788B (zh) * 2013-02-20 2015-07-22 神华集团有限责任公司 改进沉淀铁费托催化剂前体料浆特性的方法、料浆及制法、由料浆制备的催化剂及制法
CN115364870A (zh) * 2022-09-29 2022-11-22 中国科学院上海高等研究院 一种用于合成气一步法直接合成高碳烯烃产物的催化剂、制备方法及其应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL56879C (ja) * 1900-01-01
DE597515C (de) * 1931-01-29 1934-05-26 Gewerk Victor Chem Werke Verfahren zur Darstellung von Kohlenwasserstoffen aus kohlenoxyd- und wasserstoffhaltigen Gasen
US2490488A (en) * 1947-03-28 1949-12-06 Phillips Petroleum Co Hydrocarbon synthesis catalyst
FR1019738A (fr) * 1949-06-01 1953-01-26 Standard Oil Dev Co Procédé de production d'hydrocarbures oléfiniques
GB833976A (en) * 1957-09-27 1960-05-04 Kurt Peters Improvements in or relating to the production of ethylene
GB1219281A (en) * 1967-01-13 1971-01-13 Gas Council Improvements relating to catalysts
US3941819A (en) * 1973-12-14 1976-03-02 Exxon Research And Engineering Company Catalytic formation of hydrocarbons from CO hydrogen mixtures
US4045461A (en) * 1975-02-03 1977-08-30 Shell Oil Company High temperature methanation with molten salt-based catalyst systems
US4042614A (en) * 1976-04-05 1977-08-16 Exxon Research And Engineering Co. Hydrocarbon synthesis from CO and H2 using Ru supported on a titanium oxide
US4042615A (en) * 1976-04-05 1977-08-16 Exxon Research And Engineering Co. Hydrocarbon synthesis from CO and H2 using Ni supported on a titanium oxide
US4050908A (en) * 1976-07-20 1977-09-27 The Ralph M. Parsons Company Process for the production of fuel values from coal

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5692826A (en) * 1979-12-18 1981-07-27 Haldor Topsoe As Method and catalyst for manufacturing gas mixture containing high quantity of methane
JPS6166790A (ja) * 1983-04-28 1986-04-05 エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− ルテニウム担持触媒を使用する液状炭化水素の合成
JPH0581635B2 (ja) * 1983-04-28 1993-11-15 Exxon Research Engineering Co
JPS621783A (ja) * 1985-06-28 1987-01-07 Res Assoc Petroleum Alternat Dev<Rapad> 炭化水素の製造方法
JPH0528278B2 (ja) * 1985-06-28 1993-04-23 Shinnenryoyu Kaihatsu Gijutsu Kenkyu Kumiai
US6605647B2 (en) 2000-07-04 2003-08-12 President Of Tohoku University Hydrogenation of carbon monoxide using sulfide catalysts
US6534553B1 (en) 2001-07-17 2003-03-18 President Of Tohoku University Hydrogenation of carbon monoxide using sulfide catalysts

Also Published As

Publication number Publication date
DD143900A5 (de) 1980-09-17
EP0016851A1 (en) 1980-10-15
EP0016851B1 (en) 1983-01-26
ZA791448B (en) 1980-04-30
CA1107304A (en) 1981-08-18

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