JPS55136250A - Alkylation of terpene hydroxylamine - Google Patents

Alkylation of terpene hydroxylamine

Info

Publication number
JPS55136250A
JPS55136250A JP4461379A JP4461379A JPS55136250A JP S55136250 A JPS55136250 A JP S55136250A JP 4461379 A JP4461379 A JP 4461379A JP 4461379 A JP4461379 A JP 4461379A JP S55136250 A JPS55136250 A JP S55136250A
Authority
JP
Japan
Prior art keywords
formula
compound
hydroxylamine
alkylation
palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4461379A
Other languages
Japanese (ja)
Other versions
JPS626540B2 (en
Inventor
Tsuneo Ikawa
Yoshihiko Morooka
Kanji Suzuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to JP4461379A priority Critical patent/JPS55136250A/en
Publication of JPS55136250A publication Critical patent/JPS55136250A/en
Publication of JPS626540B2 publication Critical patent/JPS626540B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To synthesize various terpene compounds readily in high yield, by alkylating an O-linalyl-N,N-dialkyl-hydroxylamine with a specific compound capable of formint stable carbanions at a specific position under specified conditions.
CONSTITUTION: An O-linalyl-N,N-dialkylhydroxylamine of formula I: (R1 is alkyl group) is reacted with a compound of formula II: (R2 is H or 1W4C alkyl group; R3 is alkyl, alkenyl, or lower alkoxy group; R4 is lower alkoxy group) in the presence of a palladium catalyst to give a palladium complex of formula III, which is heated in a solvent in the presence of a trialkylchlorosilane to give the compound of formula IV free from palladium. The method permits alkylation of the compound of formula I in high yield at a specific position, and easy synthesis of terpenes. The compound of formula IV can be converted to an intermediate for perfumes and medicines.
COPYRIGHT: (C)1980,JPO&Japio
JP4461379A 1979-04-12 1979-04-12 Alkylation of terpene hydroxylamine Granted JPS55136250A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4461379A JPS55136250A (en) 1979-04-12 1979-04-12 Alkylation of terpene hydroxylamine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4461379A JPS55136250A (en) 1979-04-12 1979-04-12 Alkylation of terpene hydroxylamine

Publications (2)

Publication Number Publication Date
JPS55136250A true JPS55136250A (en) 1980-10-23
JPS626540B2 JPS626540B2 (en) 1987-02-12

Family

ID=12696285

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4461379A Granted JPS55136250A (en) 1979-04-12 1979-04-12 Alkylation of terpene hydroxylamine

Country Status (1)

Country Link
JP (1) JPS55136250A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013157955A1 (en) * 2012-04-19 2013-10-24 Nyken Holding B.V. Geranyl geranyl acetone analogs and uses thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013157955A1 (en) * 2012-04-19 2013-10-24 Nyken Holding B.V. Geranyl geranyl acetone analogs and uses thereof
WO2013157926A1 (en) * 2012-04-19 2013-10-24 Nyken Holding B.V. Geranyl geranyl acetone analogs and uses thereof
US9688651B2 (en) 2012-04-19 2017-06-27 Nyken Holding B.V. Geranyl geranyl acetone analogs and uses thereof

Also Published As

Publication number Publication date
JPS626540B2 (en) 1987-02-12

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