JPS5665833A - Isomerization of beta-gamma unsaturated alcohol and its derivative - Google Patents

Isomerization of beta-gamma unsaturated alcohol and its derivative

Info

Publication number
JPS5665833A
JPS5665833A JP14242079A JP14242079A JPS5665833A JP S5665833 A JPS5665833 A JP S5665833A JP 14242079 A JP14242079 A JP 14242079A JP 14242079 A JP14242079 A JP 14242079A JP S5665833 A JPS5665833 A JP S5665833A
Authority
JP
Japan
Prior art keywords
selenium
isomerization
catalyst
solvent
cis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14242079A
Other languages
Japanese (ja)
Inventor
Seiji Tsuchiya
Hideo Suzuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to JP14242079A priority Critical patent/JPS5665833A/en
Publication of JPS5665833A publication Critical patent/JPS5665833A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To carry out highly selectively the isomerization between a cis and a trans form derivatives of the titled alcohol, by using selenium and/or a selenium compound which is readily obtainable as a catalyst and separated easily for reuse, or in the presence of a solvent besides it.
CONSTITUTION: The isomerization between a cis and a trans form compounds shown by the formula [R1 is H or lower alkyl; R2 is saturated or unsaturated hydrocarbon group which may have a hetero atom, e.g., O, S, N, etc.; R3 is H, -COX (X is H, alkyl, or aromatic hydrocarbon group)] is carried out using selenium and/ or a selenium compound as a catalyst, or in the presence of a solvent besides it. The selenium catalyst is preferable in the form of metal selenium powder or a selenium oxide and its amount is preferably 0.5W20wt% based on raw material. n-Butanaol, tetrahydrofurfuryl alcohol, DMF, etc. may be used as the solvent. The reaction temperature is 120W250°C.
COPYRIGHT: (C)1981,JPO&Japio
JP14242079A 1979-11-02 1979-11-02 Isomerization of beta-gamma unsaturated alcohol and its derivative Pending JPS5665833A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14242079A JPS5665833A (en) 1979-11-02 1979-11-02 Isomerization of beta-gamma unsaturated alcohol and its derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14242079A JPS5665833A (en) 1979-11-02 1979-11-02 Isomerization of beta-gamma unsaturated alcohol and its derivative

Publications (1)

Publication Number Publication Date
JPS5665833A true JPS5665833A (en) 1981-06-03

Family

ID=15314908

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14242079A Pending JPS5665833A (en) 1979-11-02 1979-11-02 Isomerization of beta-gamma unsaturated alcohol and its derivative

Country Status (1)

Country Link
JP (1) JPS5665833A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5724326A (en) * 1980-07-21 1982-02-08 Shin Etsu Chem Co Ltd Isomerization of unsaturated aliphatic ester

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5724326A (en) * 1980-07-21 1982-02-08 Shin Etsu Chem Co Ltd Isomerization of unsaturated aliphatic ester
JPS629578B2 (en) * 1980-07-21 1987-02-28 Shinetsu Chem Ind Co

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