JPS54132694A - Preparation of high-performance water- and oil-repellent - Google Patents

Preparation of high-performance water- and oil-repellent

Info

Publication number
JPS54132694A
JPS54132694A JP4025678A JP4025678A JPS54132694A JP S54132694 A JPS54132694 A JP S54132694A JP 4025678 A JP4025678 A JP 4025678A JP 4025678 A JP4025678 A JP 4025678A JP S54132694 A JPS54132694 A JP S54132694A
Authority
JP
Japan
Prior art keywords
polyfluoroalkyl
oil
hydroxyl group
group
repellent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4025678A
Other languages
Japanese (ja)
Other versions
JPS6150082B2 (en
Inventor
Hitoshi Matsuo
Takashi Seki
Takao Hayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to JP4025678A priority Critical patent/JPS54132694A/en
Publication of JPS54132694A publication Critical patent/JPS54132694A/en
Publication of JPS6150082B2 publication Critical patent/JPS6150082B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

PURPOSE: To prepare a high-performance water- and oil-repellent useful for various fibers, textiles, etc., by the graft-polymerization of a polyfluoroalkyl group-containing vinyl monomer onto a hydroxyl group-containing backbone polymer.
CONSTITUTION: Graft polymerization of a mixture comprising (A) a backbone polymer having OH groups in the molecule (e.g. a copolymer of a terminal hydroxyl group-containing polyoxyethylene methacrylate with the other methacrylic acid esters, etc.), (B) a vinyl monomer having a 3W20C polyfluoroalkyl group (e.g. polyfluoroalkyl methacrylate, etc.), and (C) a graft polymerization catalyst, e.g. Ce(IV) ion-containing compound, etc., gives the desired polymer. Preferably the amount of the polyfluoroalkyl group in (B) is 10W900 parts by weight on the basis of 100 parts by weight of the backbone polymer, and the amount of the hydroxyl group in (A) is 0.01W40 wt%.
COPYRIGHT: (C)1979,JPO&Japio
JP4025678A 1978-04-07 1978-04-07 Preparation of high-performance water- and oil-repellent Granted JPS54132694A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4025678A JPS54132694A (en) 1978-04-07 1978-04-07 Preparation of high-performance water- and oil-repellent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4025678A JPS54132694A (en) 1978-04-07 1978-04-07 Preparation of high-performance water- and oil-repellent

Publications (2)

Publication Number Publication Date
JPS54132694A true JPS54132694A (en) 1979-10-15
JPS6150082B2 JPS6150082B2 (en) 1986-11-01

Family

ID=12575589

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4025678A Granted JPS54132694A (en) 1978-04-07 1978-04-07 Preparation of high-performance water- and oil-repellent

Country Status (1)

Country Link
JP (1) JPS54132694A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56163183A (en) * 1980-05-21 1981-12-15 Asahi Glass Co Ltd Highly durable water- and oil-repellant
JPS57180680A (en) * 1981-05-01 1982-11-06 Asahi Glass Co Ltd Water- and oil-repellant excellent in film formability at low temperature
JPS59219380A (en) * 1983-05-27 1984-12-10 Nippon Mektron Ltd Preparation of water-and oil-repellent emulsion
JPS62577A (en) * 1985-03-18 1987-01-06 Daikin Ind Ltd Water and oil repellent material
JPS6213422A (en) * 1985-07-11 1987-01-22 Toagosei Chem Ind Co Ltd Resin composition
JPS62179517A (en) * 1986-01-23 1987-08-06 イ−・アイ・デユポン・ドウ・ヌム−ル・アンド・カンパニ− Oil and water repellent copolymer
US6177531B1 (en) * 1997-07-23 2001-01-23 Asahi Glass Company Ltd. Water and oil repellent compositon
WO2007018276A1 (en) * 2005-08-05 2007-02-15 Daikin Industries, Ltd. Repellent composition containing graft copolymer, graft copolymer and method of preparing graft copolymer
JP2013523899A (en) * 2010-03-30 2013-06-17 ダイキン工業株式会社 Graft copolymer and repellent composition
US11566095B2 (en) 2019-10-31 2023-01-31 Daikin Industries. Ltd. Graft copolymer and soil resistant composition

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001158811A (en) * 1999-12-02 2001-06-12 Daikin Ind Ltd Graft copolymer, and solvent-based water- and oil- repellent agent composition using the same

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6321715B2 (en) * 1980-05-21 1988-05-09 Asahi Glass Co Ltd
JPS56163183A (en) * 1980-05-21 1981-12-15 Asahi Glass Co Ltd Highly durable water- and oil-repellant
JPS57180680A (en) * 1981-05-01 1982-11-06 Asahi Glass Co Ltd Water- and oil-repellant excellent in film formability at low temperature
JPS6367511B2 (en) * 1981-05-01 1988-12-26 Asahi Glass Co Ltd
JPS59219380A (en) * 1983-05-27 1984-12-10 Nippon Mektron Ltd Preparation of water-and oil-repellent emulsion
JPS62577A (en) * 1985-03-18 1987-01-06 Daikin Ind Ltd Water and oil repellent material
JPS6213422A (en) * 1985-07-11 1987-01-22 Toagosei Chem Ind Co Ltd Resin composition
JPS62179517A (en) * 1986-01-23 1987-08-06 イ−・アイ・デユポン・ドウ・ヌム−ル・アンド・カンパニ− Oil and water repellent copolymer
US6177531B1 (en) * 1997-07-23 2001-01-23 Asahi Glass Company Ltd. Water and oil repellent compositon
WO2007018276A1 (en) * 2005-08-05 2007-02-15 Daikin Industries, Ltd. Repellent composition containing graft copolymer, graft copolymer and method of preparing graft copolymer
JP2009503124A (en) * 2005-08-05 2009-01-29 ダイキン工業株式会社 Repellent composition containing graft copolymer, graft copolymer, and method for producing graft copolymer
KR101014115B1 (en) * 2005-08-05 2011-02-14 다이킨 고교 가부시키가이샤 Repellent composition containing graft copolymer, graft copolymer and method of preparing graft copolymer
US7968662B2 (en) 2005-08-05 2011-06-28 Daikin Industries, Ltd. Repellent composition containing graft copolymer, graft copolymer and method of preparing graft copolymer
JP2013523899A (en) * 2010-03-30 2013-06-17 ダイキン工業株式会社 Graft copolymer and repellent composition
US11566095B2 (en) 2019-10-31 2023-01-31 Daikin Industries. Ltd. Graft copolymer and soil resistant composition

Also Published As

Publication number Publication date
JPS6150082B2 (en) 1986-11-01

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