JPS54112861A - 1,2-substituted-4,5-dicyanoimidazole and its preparation - Google Patents
1,2-substituted-4,5-dicyanoimidazole and its preparationInfo
- Publication number
- JPS54112861A JPS54112861A JP1761278A JP1761278A JPS54112861A JP S54112861 A JPS54112861 A JP S54112861A JP 1761278 A JP1761278 A JP 1761278A JP 1761278 A JP1761278 A JP 1761278A JP S54112861 A JPS54112861 A JP S54112861A
- Authority
- JP
- Japan
- Prior art keywords
- dicyanoimidazole
- substituted
- herbicide
- dyestuff
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229940124346 antiarthritic agent Drugs 0.000 abstract 2
- 239000003435 antirheumatic agent Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 230000002363 herbicidal effect Effects 0.000 abstract 2
- 239000004009 herbicide Substances 0.000 abstract 2
- -1 1-[1-Methyl-1-(diphenoxyphosphinyl)ethyl]-2-tolyl-4,5-dicyanoimidazole Chemical compound 0.000 abstract 1
- MFLCAHVRBKHYKF-UHFFFAOYSA-N 2-(2-aminophenyl)-1h-imidazole-4,5-dicarbonitrile Chemical compound NC1=CC=CC=C1C1=NC(C#N)=C(C#N)N1 MFLCAHVRBKHYKF-UHFFFAOYSA-N 0.000 abstract 1
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract 1
- 125000005017 substituted alkenyl group Chemical group 0.000 abstract 1
Abstract
NEW MATERIAL:1,2-Substituted-4,5-dicyanoimidazole of formula I (R1 is aralkyl, diphenoxy-phosphinylalkyl; R2 is aryl, substituted phenyl, substituted alkenyl).
EXAMPLE: 1-[1-Methyl-1-(diphenoxyphosphinyl)ethyl]-2-tolyl-4,5-dicyanoimidazole.
USE: An intermediate for forming a nucleus of pharmaceuticals (e.g. anti-arthritic agent), pestcide (e.g. herbicide), dyestuff, etc.
PROCESS: The compound I is prepared by reacting a Shiff base II with a hypohalite (e.g. sodium hypochlorite, etc.). The compound can be converted into 2-aryl-4, 5- dicyanoimidazole useful as a herbicide and an anti-arthritic agent, and 2-aminophenyl-4,5-dicyanoimidazole useful as an intermediate of dyestuff.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1761278A JPS54112861A (en) | 1978-02-20 | 1978-02-20 | 1,2-substituted-4,5-dicyanoimidazole and its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1761278A JPS54112861A (en) | 1978-02-20 | 1978-02-20 | 1,2-substituted-4,5-dicyanoimidazole and its preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS54112861A true JPS54112861A (en) | 1979-09-04 |
Family
ID=11948699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1761278A Pending JPS54112861A (en) | 1978-02-20 | 1978-02-20 | 1,2-substituted-4,5-dicyanoimidazole and its preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS54112861A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7906724B2 (en) * | 2007-07-31 | 2011-03-15 | Agency For Science, Technology And Research | N-type conjugated materials based on 2-vinyl-4,5-dicyanoimidazoles and their use in organic photovoltaics |
WO2024074414A1 (en) * | 2022-10-06 | 2024-04-11 | Syngenta Crop Protection Ag | Herbicidal imidazole compounds |
-
1978
- 1978-02-20 JP JP1761278A patent/JPS54112861A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7906724B2 (en) * | 2007-07-31 | 2011-03-15 | Agency For Science, Technology And Research | N-type conjugated materials based on 2-vinyl-4,5-dicyanoimidazoles and their use in organic photovoltaics |
WO2024074414A1 (en) * | 2022-10-06 | 2024-04-11 | Syngenta Crop Protection Ag | Herbicidal imidazole compounds |
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