JPH11335258A - Cosmetic - Google Patents

Cosmetic

Info

Publication number
JPH11335258A
JPH11335258A JP10153732A JP15373298A JPH11335258A JP H11335258 A JPH11335258 A JP H11335258A JP 10153732 A JP10153732 A JP 10153732A JP 15373298 A JP15373298 A JP 15373298A JP H11335258 A JPH11335258 A JP H11335258A
Authority
JP
Japan
Prior art keywords
cosmetic
cosmetics
pentanediol
butylene glycol
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10153732A
Other languages
Japanese (ja)
Inventor
Kazuaki Tanaka
一昭 田中
Akira Kotaka
晶 小鷹
Hiroko Hitsuda
廣子 櫃田
Naomi Sato
直美 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fancl Corp
Original Assignee
Fancl Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fancl Corp filed Critical Fancl Corp
Priority to JP10153732A priority Critical patent/JPH11335258A/en
Publication of JPH11335258A publication Critical patent/JPH11335258A/en
Pending legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a cosmetic having excellent utility, safety and antiseptic, useful for lotions, milky lotions, creams, etc., of skin cosmetic, foundations of makeup cosmetic, etc., by including pentanediol and butylene glycol. SOLUTION: This cosmetic contains (A) 1,2-pentanediol and (B) 1,3-butylene glycol in the ratio of preferably 0.5-20 wt.% of the component A and 0.5-20 wt.% of the component B, more preferably 1-10 wt.% of the component A and 0.5-15 wt.% of the component B. This cosmetic is useful for packs, jellies, liquid cosmetics, shampoos of hair cosmetic, rinses, hair growing cosmetics, etc.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は使用性と安全性と
防腐性に優れた化粧料に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic having excellent usability, safety and preservability.

【0002】[0002]

【従来の技術】通常、化粧料中には、防腐防黴性を確保
して保存性を向上させることを目的として防腐剤や多価
アルコール類が配合される。そして、代表的な化粧料に
おける防腐剤としては、パラオキシ安息香酸エステル
(通称、パラベン類)、及び2−フェノキシエタノール
を、多価アルコール類としては1,3−ブチレングリコ
ール、ジプロピレングリコール等を挙げることができ
る。このパラベン類、及び2−フェノキシエタノールは
化粧料中において使用時に刺激感を伴う場合がみられ
る。また、防腐防黴性を確保するために多価アルコール
類を化粧料中に高配合することにより使用時に刺激感を
伴う場合や、使用性を損なう傾向がみられる。
2. Description of the Related Art In general, preservatives and polyhydric alcohols are incorporated into cosmetics for the purpose of ensuring preservative and antifungal properties and improving preservability. Examples of preservatives in typical cosmetics include paraoxybenzoic acid esters (commonly called parabens) and 2-phenoxyethanol, and examples of polyhydric alcohols include 1,3-butylene glycol and dipropylene glycol. Can be. The parabens and 2-phenoxyethanol may be accompanied by a feeling of irritation during use in cosmetics. In addition, when a polyhydric alcohol is added to a cosmetic in a high content in order to ensure antiseptic and antifungal properties, there is a tendency that a irritating feeling is caused at the time of use, or the usability tends to be impaired.

【0003】[0003]

【発明が解決しようとする課題】1,2−ペンタンジオ
ールは、化粧料の基剤成分として、保湿効果を発揮する
ために配合される。また、1,2−ペンタンジオールと
2−フェノキシエタノ−ルを含有する外用組成物が、防
腐性確保の上で有効であると提案されている(特開平1
0−53510号公報)。しかし、1,2−ペンタンジ
オール単独で、または他の成分とともに配合しても、化
粧料として効果を発揮するまでには至らなかった。
SUMMARY OF THE INVENTION 1,2-Pentanediol is blended as a base component of cosmetics to exhibit a moisturizing effect. Further, it has been proposed that a composition for external use containing 1,2-pentanediol and 2-phenoxyethanol is effective in ensuring the preservative property (Japanese Patent Application Laid-Open No. HEI 1-1990).
0-53510). However, even if 1,2-pentanediol was used alone or in combination with other components, it did not reach an effect as a cosmetic.

【0004】そこでこの発明は、こうした課題に鑑み鋭
意研究を重ねた結果、1,3−ブチレングリコール単独
で配合した場合に比べ画期的に防腐性が高まり、且つ安
全性と使用性に優れた化粧料を提供し、上記課題を解決
しようとするものである。
Accordingly, the present invention has made intensive studies in view of the above problems, and as a result, it has been found that, as compared with the case where 1,3-butylene glycol is blended alone, the antiseptic property is remarkably improved, and the safety and usability are excellent. An object of the present invention is to provide cosmetics and solve the above-mentioned problems.

【0005】[0005]

【課題を解決するための手段】すなわちこの発明は、使
用性と安全性と防腐性に優れた化粧料であり、1,2−
ペンタンジオールと1,3−ブチレングリコールを配合
してなる化粧料とした。
That is, the present invention provides a cosmetic composition having excellent usability, safety and preservative properties.
A cosmetic was prepared by blending pentanediol and 1,3-butylene glycol.

【0006】[0006]

【実施の形態例】以下、この発明の実施の形態例を詳細
に説明する。この発明に用いる1,2ペンタンジオール
は二価の脂肪族アルコールの一種で公知の物質であり、
以下の性質を有する。 分子量:104 分子式:C↓5H↓12O↓2 外観:無色透明の液体 本物質は、保湿成分として化粧料中に使用されており、
容易に入手しこの発明の化粧料中への配合が可能である
が、公知の方法により合成したものをこの化粧料中に配
合することも出来る。
Embodiments of the present invention will be described below in detail. 1,2-pentanediol used in the present invention is a known substance as a kind of dihydric aliphatic alcohol,
It has the following properties. Molecular weight: 104 Molecular formula: C ↓ 5H ↓ 12O ↓ 2 Appearance: Colorless and transparent liquid This substance is used in cosmetics as a moisturizing ingredient,
Although it is easily available and can be incorporated into the cosmetic of the present invention, it is also possible to incorporate a compound synthesized by a known method into the cosmetic.

【0007】上記1,2−ペンタンジオールと共にこの
発明化粧料中に配合される1,3−ブチレングリコール
は、以下の性質を有する。 分子量:90.12 分子式:C4H10O2 外観:無色透明な粘性の液 沸点:207.5°C 比重:1.004〜1.007 本物質は、通常保湿剤として化粧料中に配合されている
成分である。
[0007] The 1,3-butylene glycol compounded in the cosmetic of the present invention together with the 1,2-pentanediol has the following properties. Molecular weight: 90.12 Molecular formula: C4H10O2 Appearance: Colorless transparent viscous liquid Boiling point: 207.5 ° C. Specific gravity: 1.004 to 1.007 This substance is a component that is usually blended in cosmetics as a humectant. is there.

【0008】前記1,2−ペンタンジオールの配合量
は、目的とする抗菌効果を発揮させるためには、0.5
〜20重量%が一般的には好ましく、1〜10重量%の
配合が特に好ましい。また、1,3−ブチレングリコー
ルの配合量は、一般的に0.5〜20重量%が配合され
る。15重量%以上配合すると使用感がべたつき、好ま
しくない。
[0008] The amount of the 1,2-pentanediol is 0.5% in order to exert the desired antibacterial effect.
-20% by weight is generally preferred, with 1-10% by weight being particularly preferred. The amount of 1,3-butylene glycol is generally 0.5 to 20% by weight. If the content is more than 15% by weight, the feeling of use becomes sticky, which is not preferable.

【0009】両成分の配合量が上記の範囲にあると、こ
の発明の目的とする効果が得られる。以上のように、
1,2−ペンタンジオール及び1,3−ブチレングリコ
ールを組み合わせて配合することにより防腐性を保ちな
がら、使用感と安全性に優れたこの発明の化粧料が提供
可能となった。
When the amounts of the two components are within the above ranges, the desired effects of the present invention can be obtained. As mentioned above,
By combining 1,2-pentanediol and 1,3-butylene glycol in combination, the cosmetics of the present invention having excellent usability and safety can be provided while preserving antiseptic properties.

【0010】この発明は、化粧料、医薬部外品など広く
応用することができる。例えば、皮膚化粧料のローショ
ン類、乳液類、クリーム類、パック類、ジェル類、美容
液類等に適用することができる。更に、メーキャップ化
粧料のファンデーション類や頭髪化粧料のシャンプー
類、リンス類、養毛化粧料類など、多様な剤型に広く適
用出来る。医薬部外品も同様で、水系、乳化系、可溶化
系等の広い剤型に応用が可能である。なお、この発明の
化粧料には上記の他に色素、香料、防腐剤、界面活性
剤、顔料、抗酸化剤等をこの発明の目的を達成する範囲
内で適宜配合することができる。
[0010] The present invention can be widely applied to cosmetics, quasi-drugs and the like. For example, it can be applied to lotions, emulsions, creams, packs, gels, serums, and the like of skin cosmetics. Furthermore, it can be widely applied to various dosage forms such as foundations for makeup cosmetics, shampoos, rinses, and hair restoration cosmetics for hair cosmetics. Similarly, quasi-drugs can be applied to a wide range of dosage forms such as aqueous, emulsified, and solubilized systems. In addition, the cosmetics of the present invention may optionally contain, in addition to the above, dyes, fragrances, preservatives, surfactants, pigments, antioxidants, and the like, as long as the object of the present invention is achieved.

【0011】[0011]

【実施例】次に実施例及び比較例に基づいてこの発明を
詳述する。また、この発明に使用した使用テスト、防腐
力テストは以下の通りである。
Next, the present invention will be described in detail based on examples and comparative examples. The use test and antiseptic test used in the present invention are as follows.

【0012】〔使用テスト〕化粧品や化学物質や外部環
境の変化に対して肌トラブルを起こしやすい敏感肌の女
子被験者(35〜55歳)20人にこの発明の化粧料及
び比較例の化粧料を1日2回(朝・夕)連続1週間使用
させて、皮膚刺激性と使用感を評価した。試験結果の皮
膚刺激性は皮膚刺激を訴えた人数で示し、使用感は皮膚
の湿潤性、平滑性、弾力性の各項目に対して、皮膚に潤
いが生じた、皮膚が滑らかになった、皮膚に張りが生じ
たと回答した人数で示した。
[Use test] The cosmetics of the present invention and the cosmetics of the comparative examples were applied to 20 female subjects (35 to 55 years old) with sensitive skin who are liable to cause skin troubles due to changes in cosmetics, chemical substances and external environment. The skin was used twice a day (morning / evening) for one continuous week to evaluate skin irritation and feeling of use. The skin irritation of the test results is indicated by the number of people who complained of skin irritation, and the feeling of use was moisturized, smooth, and smooth, for each item of skin wettability, smoothness, and elasticity. The number of respondents who indicated that skin tension occurred was indicated.

【0013】〔防腐力テスト〕試料20gに菌液を接種
後、混釈法により菌数の変化を調べた。なお、接種菌は
細菌、真菌を用いて、4週間経過時までに菌数変化によ
り防腐力を評価し、得られた結果を以下の3段階の基準
に分類した。なお、以下の分類のうち◎ないし○のもの
を合格と判定した。
[Preservative test] After inoculating a bacterial solution to 20 g of a sample, a change in the number of bacteria was examined by a pour method. The inoculated bacteria were evaluated for their antiseptic activity by a change in the number of bacteria using bacteria and fungi by 4 weeks, and the obtained results were classified into the following three criteria. In addition, among the following classifications, those of ◎ or ○ were judged to be acceptable.

【0014】 ◎:顕著な菌数の減少が認められる。 ○:菌数の減少が認められる。 ×:ほとんど菌数が減少しないか、全く菌数が減少しな
い。
A: A remarkable decrease in the number of bacteria is observed. :: A decrease in the number of bacteria is observed. ×: The number of bacteria hardly decreases or the number of bacteria hardly decreases.

【0015】[比較例1〜8及び実施例1〜10]表1
記載の組成の化粧液、比較例1〜8及び表2記載の化粧
液、実施例1〜10をそれぞれ常法に従って調製し、前
記諸試験を実施し、結果を表3、及び表4に記載する。
Comparative Examples 1 to 8 and Examples 1 to 10
Cosmetic liquids having the compositions described, Comparative Examples 1 to 8 and cosmetic liquids described in Table 2 and Examples 1 to 10 were each prepared according to a conventional method, and the above tests were carried out. The results are shown in Tables 3 and 4. I do.

【0016】[0016]

【表1】 [Table 1]

【0017】[0017]

【表2】 [Table 2]

【0018】[0018]

【表3】 [Table 3]

【0019】[0019]

【表4】 [Table 4]

【0020】これらの結果から、基本となる比較例1の
化粧液に1,2−ペンタンジオール、1,3−ブチレン
グリコールをそれぞれ単独に配合した化粧液、即ち、比
較例2〜8に比べ、1,2−ペンタンジオールと1,3
−ブチレングリコールを組み合わせて配合した化粧液、
即ち、実施例1〜10が皮膚刺激テストにおいて刺激性
が低く、また使用感テストにおいては評価が高く、防腐
力テストにおいては防腐効果が高いことが示された。
From these results, it can be seen that the cosmetic liquid of Comparative Example 1, which is a basic cosmetic liquid, contains only 1,2-pentanediol and 1,3-butylene glycol alone, ie, Comparative Examples 2 to 8. 1,2-pentanediol and 1,3
-A cosmetic liquid combined with butylene glycol,
That is, Examples 1 to 10 showed low irritation in the skin irritation test, high evaluation in the usability test, and high antiseptic effect in the antiseptic test.

【0021】[比較例9〜16及び実施例11〜20]
表5記載の組成の乳液、比較例9〜16及び表6記載の
乳液、実施例11〜20をそれぞれ常法に従って調製
し、前記諸試験を実施し、結果を表7及び表8に記載す
る。
[Comparative Examples 9 to 16 and Examples 11 to 20]
Emulsions having the compositions shown in Table 5 and Comparative Examples 9 to 16 and Emulsions shown in Table 6 and Examples 11 to 20 were respectively prepared according to a conventional method, and the above tests were carried out. The results are shown in Tables 7 and 8. .

【0022】[0022]

【表5】 [Table 5]

【0023】[0023]

【表6】 [Table 6]

【0023】[0023]

【表7】 [Table 7]

【0024】[0024]

【表8】 [Table 8]

【0025】これらの結果から、基本となる比較例9の
乳液に1,2−ペンタンジオールと1,3−ブチレング
リコールをそれぞれ単独に配合した乳液、即ち、比較例
10〜16に比べ、1,2−ペンタンジオールと1,3
−ブチレングリコールを組み合わせて配合した乳液、即
ち、実施例11〜20が皮膚刺激テストにおいて刺激性
が低く、また使用感テストにおいては評価が高く、防腐
力テストにおいては防腐効果が高いことが示された。
From these results, it can be seen that the emulsion of the basic comparative example 9 was prepared by independently mixing 1,2-pentanediol and 1,3-butylene glycol. 2-pentanediol and 1,3
-An emulsion containing a combination of butylene glycol, that is, Examples 11 to 20 showed low irritation in skin irritation test, high evaluation in usability test, and high antiseptic effect in antiseptic test. Was.

【0026】[0026]

【発明の効果】以上記載のごとく、この発明は、使用性
と安全性と防腐性に優れた化粧料を提供することができ
る。
As described above, the present invention can provide a cosmetic having excellent usability, safety and preservability.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 佐藤 直美 神奈川県小田原市曽比1611番地1号 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Naomi Sato 1611-1, So, Odawara-shi, Kanagawa

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 1,2−ペンタンジオールと1,3−ブ
チレングリコールを含有することを特徴とする、化粧
料。
1. A cosmetic comprising 1,2-pentanediol and 1,3-butylene glycol.
JP10153732A 1998-05-19 1998-05-19 Cosmetic Pending JPH11335258A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10153732A JPH11335258A (en) 1998-05-19 1998-05-19 Cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10153732A JPH11335258A (en) 1998-05-19 1998-05-19 Cosmetic

Publications (1)

Publication Number Publication Date
JPH11335258A true JPH11335258A (en) 1999-12-07

Family

ID=15568895

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10153732A Pending JPH11335258A (en) 1998-05-19 1998-05-19 Cosmetic

Country Status (1)

Country Link
JP (1) JPH11335258A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000204017A (en) * 1999-01-13 2000-07-25 Pola Chem Ind Inc Bleaching preparation
JP2002308720A (en) * 2001-04-16 2002-10-23 Pola Chem Ind Inc Skin-protecting cosmetic
JP2003292433A (en) * 2002-02-01 2003-10-15 Masayoshi Kachi Cosmetic
JP2008056609A (en) * 2006-08-31 2008-03-13 Mandom Corp Cleansing cosmetic material
US7582681B2 (en) 2002-02-19 2009-09-01 Symrise Gmbh & Co. Kg Synergistic mixtures of 1,2-alkane diols
JP2009234970A (en) * 2008-03-26 2009-10-15 Kose Corp Makeup remover
JP2015063485A (en) * 2013-09-25 2015-04-09 ロート製薬株式会社 External composition

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07330505A (en) * 1994-06-08 1995-12-19 Masato Suzuki Antimicrobial composition
WO1997030692A1 (en) * 1996-02-21 1997-08-28 Stoa S.A. Cosmetic, dermopharmaceutical or veterinary compositions for disinfecting human or animal skin
JPH1045558A (en) * 1996-08-02 1998-02-17 Noevir Co Ltd Antimicrobial and low-irritant cosmetic
JPH1053510A (en) * 1996-05-27 1998-02-24 Shiseido Co Ltd Composition for external use
JPH11193208A (en) * 1997-09-25 1999-07-21 Shiseido Co Ltd Solubilized perfume-containing composition and composition for external use formulated therewith
JPH11302151A (en) * 1998-04-22 1999-11-02 Nikko Seiyaku Kk Cosmetic

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07330505A (en) * 1994-06-08 1995-12-19 Masato Suzuki Antimicrobial composition
WO1997030692A1 (en) * 1996-02-21 1997-08-28 Stoa S.A. Cosmetic, dermopharmaceutical or veterinary compositions for disinfecting human or animal skin
JPH1053510A (en) * 1996-05-27 1998-02-24 Shiseido Co Ltd Composition for external use
JPH1045558A (en) * 1996-08-02 1998-02-17 Noevir Co Ltd Antimicrobial and low-irritant cosmetic
JPH11193208A (en) * 1997-09-25 1999-07-21 Shiseido Co Ltd Solubilized perfume-containing composition and composition for external use formulated therewith
JPH11302151A (en) * 1998-04-22 1999-11-02 Nikko Seiyaku Kk Cosmetic

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000204017A (en) * 1999-01-13 2000-07-25 Pola Chem Ind Inc Bleaching preparation
JP2002308720A (en) * 2001-04-16 2002-10-23 Pola Chem Ind Inc Skin-protecting cosmetic
JP2003292433A (en) * 2002-02-01 2003-10-15 Masayoshi Kachi Cosmetic
US7582681B2 (en) 2002-02-19 2009-09-01 Symrise Gmbh & Co. Kg Synergistic mixtures of 1,2-alkane diols
JP2008056609A (en) * 2006-08-31 2008-03-13 Mandom Corp Cleansing cosmetic material
JP2009234970A (en) * 2008-03-26 2009-10-15 Kose Corp Makeup remover
JP2015063485A (en) * 2013-09-25 2015-04-09 ロート製薬株式会社 External composition

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