JPH11228667A - 向上した耐水性および耐溶剤性を有する水性ポリウレタン分散物 - Google Patents
向上した耐水性および耐溶剤性を有する水性ポリウレタン分散物Info
- Publication number
- JPH11228667A JPH11228667A JP10221127A JP22112798A JPH11228667A JP H11228667 A JPH11228667 A JP H11228667A JP 10221127 A JP10221127 A JP 10221127A JP 22112798 A JP22112798 A JP 22112798A JP H11228667 A JPH11228667 A JP H11228667A
- Authority
- JP
- Japan
- Prior art keywords
- group
- water
- dispersed material
- parts
- diisocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000004814 polyurethane Substances 0.000 title abstract description 41
- 229920002635 polyurethane Polymers 0.000 title abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 27
- 239000000463 material Substances 0.000 title abstract description 6
- 239000002904 solvent Substances 0.000 title description 5
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 21
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 13
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims abstract description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000002723 alicyclic group Chemical group 0.000 claims abstract description 3
- 230000001588 bifunctional effect Effects 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 9
- 229920003009 polyurethane dispersion Polymers 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 15
- 229920005862 polyol Polymers 0.000 abstract description 11
- 150000003077 polyols Chemical class 0.000 abstract description 10
- 238000000576 coating method Methods 0.000 abstract description 9
- 239000000243 solution Substances 0.000 abstract description 9
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 abstract description 9
- 239000011248 coating agent Substances 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 4
- 239000004970 Chain extender Substances 0.000 abstract description 3
- 150000002430 hydrocarbons Chemical group 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 37
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 18
- 239000002023 wood Substances 0.000 description 9
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 7
- 125000003010 ionic group Chemical group 0.000 description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- -1 preferably 4 Chemical compound 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- GFNDFCFPJQPVQL-UHFFFAOYSA-N 1,12-diisocyanatododecane Chemical compound O=C=NCCCCCCCCCCCCN=C=O GFNDFCFPJQPVQL-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- UNVGBIALRHLALK-UHFFFAOYSA-N 1,5-Hexanediol Chemical compound CC(O)CCCCO UNVGBIALRHLALK-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- MGYGFNQQGAQEON-UHFFFAOYSA-N 4-tolyl isocyanate Chemical compound CC1=CC=C(N=C=O)C=C1 MGYGFNQQGAQEON-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 239000005700 Putrescine Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- LNWBFIVSTXCJJG-UHFFFAOYSA-N [diisocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)(N=C=O)C1=CC=CC=C1 LNWBFIVSTXCJJG-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/16—Two dimensionally sectional layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/16—Two dimensionally sectional layer
- Y10T428/163—Next to unitary web or sheet of equal or greater extent
- Y10T428/164—Continuous two dimensionally sectional layer
- Y10T428/167—Cellulosic sections [e.g., parquet floor, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31591—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31989—Of wood
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19731864A DE19731864A1 (de) | 1997-07-24 | 1997-07-24 | Wäßrige PUR-Dispersionen mit verbesserten Eigenschaften |
| DE19731864.9 | 1997-07-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11228667A true JPH11228667A (ja) | 1999-08-24 |
| JPH11228667A5 JPH11228667A5 (enExample) | 2005-10-27 |
Family
ID=7836771
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10221127A Ceased JPH11228667A (ja) | 1997-07-24 | 1998-07-22 | 向上した耐水性および耐溶剤性を有する水性ポリウレタン分散物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6248415B1 (enExample) |
| EP (1) | EP0893460B1 (enExample) |
| JP (1) | JPH11228667A (enExample) |
| AT (1) | ATE201889T1 (enExample) |
| CA (1) | CA2243720A1 (enExample) |
| DE (2) | DE19731864A1 (enExample) |
| ES (1) | ES2159163T3 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040005448A (ko) * | 2002-07-10 | 2004-01-16 | 한국신발피혁연구소 | 에틸알코올형 폴리우레탄 접착제의 제조방법 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040254292A1 (en) * | 2001-12-21 | 2004-12-16 | Imperial Chemical Industries Plc | Aqueous coating compositions containing polyurethane-acrylic hybrid polymer dispersions |
| WO2004041891A1 (en) * | 2002-11-04 | 2004-05-21 | Invista Technologies S.À.R.L. | Aqueous poly (urea/urethanes) dispersions using polyester glycol |
| GB2397578B (en) | 2002-12-17 | 2004-12-08 | Ici Plc | Aqueous dispersions of polyurethane-addition polymer hybrid particles especially for use in coating compositions |
| JP2006022132A (ja) * | 2004-07-06 | 2006-01-26 | Nippon Polyurethane Ind Co Ltd | 水性ポリウレタンエマルジョン、その製造方法及びそれを用いた水性印刷インキ |
| US20070287824A1 (en) * | 2006-06-08 | 2007-12-13 | Johnson Mitchell T | Waterbased polyurethane floor coating composition |
| JP5484319B2 (ja) * | 2007-05-17 | 2014-05-07 | ディバーシー・インコーポレーテッド | 表面コーティングシステムおよび方法 |
| WO2012162640A2 (en) | 2011-05-25 | 2012-11-29 | Diversey, Inc. | Surface coating system and method of using surface coating system |
| TW202104720A (zh) | 2019-05-09 | 2021-02-01 | 英商萊卡英國有限公司 | 具有固體低熔融粉末之可轉印彈性分散物 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53135931A (en) * | 1977-04-28 | 1978-11-28 | Toray Ind Inc | Lysine ester triisocyanate |
| US5380792A (en) * | 1993-04-19 | 1995-01-10 | Miles Inc. | Two-component aqueous polyurethane dispersions having improved pot life and coatings prepared therefrom |
| JPH07149857A (ja) * | 1993-09-02 | 1995-06-13 | Miles Inc | 液体ジフェニルメタンジイソシアネート並びにその製造および使用方法 |
| JPH07179815A (ja) * | 1993-10-20 | 1995-07-18 | Bayer Ag | ラッカーポリイソシアネートおよびそれらの使用 |
| DE4403233A1 (de) * | 1994-02-03 | 1995-08-10 | Bayer Ag | Oberhalb 5 DEG C flüssige Polyisocyanatmischungen |
| JPH07304724A (ja) * | 1994-05-09 | 1995-11-21 | Bayer Ag | アロファネート基を含有する光安定性ポリイソシアネートの製造方法 |
| JPH07305025A (ja) * | 1994-05-05 | 1995-11-21 | Bayer Ag | 被膜の調製方法 |
| JPH08104728A (ja) * | 1994-09-14 | 1996-04-23 | Bayer Corp | 低表面エネルギーポリイソシアネート、及び一又は二成分塗料におけるそれらの使用 |
| JPH08193112A (ja) * | 1994-08-29 | 1996-07-30 | Bayer Ag | ポリイソシアネート/ポリアミン混合物及びポリウレア被膜の製造におけるその用途 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3523856A1 (de) * | 1985-07-04 | 1987-01-08 | Bayer Ag | Waessrige loesungen oder dispersionen von polyisocyanat-additionsprodukten, ein verfahren zu ihrer herstellung, sowie ihre verwendung als beschichtungsmittel oder als leimungsmittel fuer papier |
| JP3137201B2 (ja) * | 1991-01-24 | 2001-02-19 | 旭化成工業株式会社 | 低粘度ポリイソシアネート |
| EP0566037A2 (en) * | 1992-04-14 | 1993-10-20 | Takeda Chemical Industries, Ltd. | Polyisocyanates, their production and use |
| US5319053A (en) | 1993-09-02 | 1994-06-07 | Miles Inc. | Liquid diphenylmethane diisocyanate |
| ES2197959T3 (es) * | 1996-03-01 | 2004-01-16 | Bayer Ag | Poliuretanoureas solubles o dispersables en agua, procedimiento para su fabricacion y su uso como recubrimiento de cualquier sustrato. |
| DE19619636A1 (de) * | 1996-05-15 | 1997-11-20 | Basf Ag | Latent vernetzende wässerige Polyurethandispersionen |
-
1997
- 1997-07-24 DE DE19731864A patent/DE19731864A1/de not_active Withdrawn
-
1998
- 1998-07-13 ES ES98112966T patent/ES2159163T3/es not_active Expired - Lifetime
- 1998-07-13 EP EP98112966A patent/EP0893460B1/de not_active Expired - Lifetime
- 1998-07-13 DE DE59800815T patent/DE59800815D1/de not_active Expired - Lifetime
- 1998-07-13 AT AT98112966T patent/ATE201889T1/de active
- 1998-07-17 US US09/118,657 patent/US6248415B1/en not_active Expired - Lifetime
- 1998-07-20 CA CA002243720A patent/CA2243720A1/en not_active Abandoned
- 1998-07-22 JP JP10221127A patent/JPH11228667A/ja not_active Ceased
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53135931A (en) * | 1977-04-28 | 1978-11-28 | Toray Ind Inc | Lysine ester triisocyanate |
| US5380792A (en) * | 1993-04-19 | 1995-01-10 | Miles Inc. | Two-component aqueous polyurethane dispersions having improved pot life and coatings prepared therefrom |
| JPH07149857A (ja) * | 1993-09-02 | 1995-06-13 | Miles Inc | 液体ジフェニルメタンジイソシアネート並びにその製造および使用方法 |
| JPH07179815A (ja) * | 1993-10-20 | 1995-07-18 | Bayer Ag | ラッカーポリイソシアネートおよびそれらの使用 |
| DE4403233A1 (de) * | 1994-02-03 | 1995-08-10 | Bayer Ag | Oberhalb 5 DEG C flüssige Polyisocyanatmischungen |
| JPH07224140A (ja) * | 1994-02-03 | 1995-08-22 | Bayer Ag | 5℃より高温で液体であるポリイソシアネート混合物 |
| JPH07305025A (ja) * | 1994-05-05 | 1995-11-21 | Bayer Ag | 被膜の調製方法 |
| JPH07304724A (ja) * | 1994-05-09 | 1995-11-21 | Bayer Ag | アロファネート基を含有する光安定性ポリイソシアネートの製造方法 |
| JPH08193112A (ja) * | 1994-08-29 | 1996-07-30 | Bayer Ag | ポリイソシアネート/ポリアミン混合物及びポリウレア被膜の製造におけるその用途 |
| JPH08104728A (ja) * | 1994-09-14 | 1996-04-23 | Bayer Corp | 低表面エネルギーポリイソシアネート、及び一又は二成分塗料におけるそれらの使用 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040005448A (ko) * | 2002-07-10 | 2004-01-16 | 한국신발피혁연구소 | 에틸알코올형 폴리우레탄 접착제의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59800815D1 (de) | 2001-07-12 |
| ATE201889T1 (de) | 2001-06-15 |
| DE19731864A1 (de) | 1999-01-28 |
| CA2243720A1 (en) | 1999-01-24 |
| EP0893460B1 (de) | 2001-06-06 |
| EP0893460A1 (de) | 1999-01-27 |
| ES2159163T3 (es) | 2001-09-16 |
| US6248415B1 (en) | 2001-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI293962B (en) | Polyurethane-polyurea dispersions | |
| JP2630394B2 (ja) | ポリウレタンポリ尿素の水性分散液の製造方法 | |
| JP2909939B2 (ja) | 水性結合剤組成物およびその製造方法 | |
| JP3189985B2 (ja) | ポリイソシアネート混合物、その製造方法、および被覆組成物における架橋剤としてのその使用 | |
| JP3493796B2 (ja) | 水性ポリウレタン樹脂塗料 | |
| KR101161888B1 (ko) | 코팅제 조성물 | |
| CA2193031C (en) | Dispersion of post-curable coating compounds | |
| JPS6312890B2 (enExample) | ||
| US4598121A (en) | Cold-crosslinking polyurethane dispersions, manufacture and use of the same | |
| KR20060066656A (ko) | 고-고형분 폴리우레탄-폴리우레아 분산액 | |
| CZ301652B6 (cs) | Polyurethanové roztoky s alkoxysilanovými strukturními jednotkami, zpusob jejich výroby, jejich použití, povlaky z nich vyrobené a výrobky tyto povlaky obsahující | |
| JPS6320248B2 (enExample) | ||
| JP7440500B2 (ja) | アスパラギン酸エステル官能性ポリシロキサン、それらの調製およびそれらの使用 | |
| US5569706A (en) | Aqueous polyurea dispersions with improved hardness and solvent resistance | |
| CN106432663A (zh) | 不含脲的聚氨酯分散体 | |
| JP2008531772A (ja) | ポリウレタンウレア溶液 | |
| JPH11228667A (ja) | 向上した耐水性および耐溶剤性を有する水性ポリウレタン分散物 | |
| JPH11228667A5 (enExample) | ||
| EP0982331B1 (en) | An improved process for the preparation of stable aqueous urethane dispersions | |
| JPH0370734B2 (enExample) | ||
| JPH0340730B2 (enExample) | ||
| JP2007146162A (ja) | ウレタン基含有ヒドロキシ官能性ポリエステル水性分散体 | |
| US6239213B1 (en) | Process for the preparation of stable aqueous urethane dispersions | |
| EP0373671A2 (en) | Waterborne polyurethane dispersions | |
| EP1426391A1 (en) | Aqueous polyurethane dispersions and their use for preparation of coatings that are permeable to water vapor |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050720 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050720 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20071113 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080318 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090630 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20090930 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20091005 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20091102 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20091106 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20091130 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20091203 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100928 |
|
| A045 | Written measure of dismissal of application [lapsed due to lack of payment] |
Free format text: JAPANESE INTERMEDIATE CODE: A045 Effective date: 20110125 |