JPH11193454A - Wear resistant part and its production - Google Patents

Wear resistant part and its production

Info

Publication number
JPH11193454A
JPH11193454A JP36685797A JP36685797A JPH11193454A JP H11193454 A JPH11193454 A JP H11193454A JP 36685797 A JP36685797 A JP 36685797A JP 36685797 A JP36685797 A JP 36685797A JP H11193454 A JPH11193454 A JP H11193454A
Authority
JP
Japan
Prior art keywords
hardness
quenching
casting
wear
stainless steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP36685797A
Other languages
Japanese (ja)
Other versions
JP3844867B2 (en
Inventor
Masatoshi Akiyama
正稔 秋山
Isamu Sasa
勇 笹
Toshiji Arishima
利治 有島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NETSUREN KOFU KK
Neturen Co Ltd
THK Co Ltd
Original Assignee
NETSUREN KOFU KK
Neturen Co Ltd
THK Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NETSUREN KOFU KK, Neturen Co Ltd, THK Co Ltd filed Critical NETSUREN KOFU KK
Priority to JP36685797A priority Critical patent/JP3844867B2/en
Publication of JPH11193454A publication Critical patent/JPH11193454A/en
Application granted granted Critical
Publication of JP3844867B2 publication Critical patent/JP3844867B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide inexpensive, lightweight and wear resistant parts usable at high temp., and their production. SOLUTION: A member, composed of a martensitic chromium stainless steel containing, by weight, 0.4-0.6% C, 9.5-13.0% Cr, and 0.3-1.0% Mo at least, is hardened to <=HRC55 hardness by means of plasma carburizing and quenching and then tempered at 430 to 570 deg.C to undergo secondary hardening. Further, this member is subjected to cast-in insert by means of aluminum alloy casting, by which the wear resistant parts are formed.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、ボールねじナット
やスライドレールのスライダなどのように耐摩耗面を焼
入硬化させた複雑な形状の耐摩耗部品の製造方法に関す
るものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a wear-resistant part having a complicated shape, such as a ball screw nut or a slider of a slide rail, having a wear-resistant surface hardened and hardened.

【0002】[0002]

【従来の技術】機械部品としては、ベアリングの軌道面
やスライドテーブルの摺動面などを焼入硬化して耐摩耗
性を向上した部品が多く使用されている。その製造方法
としては、鋼材から機械加工により削りだしたり、熱
間、温間あるいは冷間加工した部材から機械加工する方
法が多く採られている。このような耐摩耗部品の焼入面
の硬さは高いほど望ましく、少なくもHRC55以上の
硬さが要求される。かかる用途には従来から軸受鋼が多
く使用されている。
2. Description of the Related Art As mechanical parts, many parts whose wear resistance is improved by quenching and hardening a raceway surface of a bearing or a sliding surface of a slide table are used. As a manufacturing method, a method of shaving a steel material by machining or a method of machining a hot, warm or cold-worked member is often used. The higher the hardness of the quenched surface of such wear-resistant parts, the more desirable it is, and at least a hardness of 55 or more is required. Conventionally, bearing steels are often used for such applications.

【発明が解決しようとする課題】[Problems to be solved by the invention]

【0003】しかしながら、これらの部品が単純な形状
の場合には、容易に一体の材料から切削加工などにより
成形して製造されるが、複雑な形状、例えばボールねじ
ナットのような部品は、内径の軌道面は耐摩耗性を要す
るために高い硬さを必要とする一方、外周部には鋼球の
循環路を設けるため複雑な形状になる。これを製造する
ために丸棒の棒鋼から切削加工により成形し熱処理する
ことは大変な工数がかかりコストが高くなる。また全体
を鋼材で作ると重量も大きくなり、動体部品などの場合
は慣性が大きくなって動きのレスポンスに欠けるという
問題点もある。そこで本発明では、所定硬さに焼入れし
た部材の外周をアルミニュームダイカストで肉付けして
複雑な形状を形成させることにより、機械加工を減じて
軽量で安価な耐摩耗部品の製造を図った。
[0003] However, when these parts have a simple shape, they are easily formed by cutting or the like from an integral material, but a complicated shape, for example, a part such as a ball screw nut, has an inner diameter. The track surface requires high hardness due to the need for wear resistance, while the outer peripheral portion has a complicated shape because a steel ball circulation path is provided. Forming and heat-treating a round bar from a steel bar in order to manufacture it requires a great deal of man-hours and increases costs. In addition, there is also a problem that when the whole is made of steel, the weight increases, and in the case of moving body parts, the inertia increases and the response of movement is lacking. Therefore, in the present invention, the outer periphery of the member quenched to a predetermined hardness is formed by aluminum die casting to form a complicated shape, thereby reducing machining and manufacturing a lightweight and inexpensive wear-resistant part.

【0004】一方、前記従来から広く使用されている軸
受鋼は、通常200℃以下の温度で焼戻しして使用さ
れ、焼戻し温度が200℃を超えると急激に硬さが下が
る。従って、このような温度で焼入・焼戻した軸受鋼を
アルミニュームダイカストで肉付けすると、もとの焼戻
温度より高いダイカスト鋳造時の温度で焼戻しされて硬
さが低下し所要硬さを得ることができなかった。これに
対し、高合金鋼、例えばJIS.SKD11などの高炭
素高クロム工具鋼などを使用すればダイカスト鋳造時の
温度による硬さの低下は防止できるが、かかる鋼材は高
価であるためコストが増し、また入手が容易でないとい
う問題点がある。
On the other hand, the bearing steels which have been widely used in the past are usually used after tempering at a temperature of 200 ° C. or less, and when the tempering temperature exceeds 200 ° C., the hardness rapidly decreases. Therefore, if the bearing steel quenched and tempered at such a temperature is fleshed with aluminum die casting, it will be tempered at the temperature during die casting higher than the original tempering temperature, and the hardness will decrease to obtain the required hardness. Could not. On the other hand, high alloy steel such as JIS. The use of high-carbon high-chromium tool steel such as SKD11 can prevent a decrease in hardness due to the temperature at the time of die casting, but such a steel material is expensive, so that the cost increases and it is not easy to obtain. .

【0005】そこで本発明は、安価なマルテンサイト系
クロムステンレス鋼をプラズマ浸炭焼入れすると浸炭層
に通常のガス浸炭などで得られない高い炭素量が得られ
て、プラズマ浸炭焼入れした後430℃〜570℃で焼
戻しすると2次硬化することに着目し、安価な耐摩耗部
品及びその製造法を提供することを目的としたものであ
る。また、前記処理したステンレス鋼はアルミニューム
ダイカスト時の鋳造温度でも軟化しないことに着目し、
これをアルミニュームダイカストで肉付けして複雑な形
状を形成させ、焼入れ面にHRC58以上の硬さを有す
る軽量で安価な耐摩耗部品及びその製造法を提供するこ
とを目的とする。
Accordingly, the present invention provides a method of plasma carburizing and quenching inexpensive martensitic chromium stainless steel to obtain a high carbon content in a carburized layer which cannot be obtained by ordinary gas carburizing and the like. The purpose of the present invention is to provide an inexpensive wear-resistant part and a method for producing the same, by paying attention to secondary hardening when tempered at ° C. Also, focusing on the fact that the treated stainless steel does not soften even at the casting temperature during aluminum die casting,
It is an object of the present invention to provide a lightweight and inexpensive wear-resistant part having a hardened surface having a hardness of HRC 58 or more and a method of manufacturing the same, by forming a complicated shape by filling this with aluminum die casting.

【0006】[0006]

【課題を解決するための手段】上記目的を達成するため
に、本発明の耐摩耗部品及びその製造方法は、少なくも
C:0.4〜0.6wt%,Cr:9.5〜13.0w
t%,Mo:0.3〜1.0wt%を含むマルテンサイ
ト系クロムステンレス鋼からなる部材をプラズマ浸炭焼
入れによりHRC55以上の硬さに焼入れした後430
℃〜570℃で焼戻しして2次硬化させてなることを特
徴とするものである。
In order to achieve the above-mentioned object, a wear-resistant part of the present invention and a method for producing the wear-resistant part include at least C: 0.4 to 0.6 wt%, Cr: 9.5 to 13. 0w
After quenching a member made of martensitic chromium stainless steel containing t%, Mo: 0.3 to 1.0 wt% to HRC 55 or more by plasma carburizing and quenching 430
It is characterized in that it is tempered at a temperature of from 570C to 570C and is secondarily cured.

【0007】従来、耐摩耗部品に広く使用されている焼
入・焼戻しされた軸受鋼(JIS.SUJ)では200
℃以上に加熱されると硬さが低下するために高温での使
用ができないという問題点がある。これに対して、上記
マルテンサイト系クロムステンレス鋼をプラズマ浸炭焼
入れした浸炭焼入層は430〜570℃の焼戻しにより
2次硬化して硬さが上昇する。従って本発明の処理を行
った耐摩耗部品は高温で使用される耐摩耗部材にも硬さ
の低下がなく使用できる。この焼入層の焼戻硬化は焼入
時に残留する残留オーステナイトの相変化と固溶合金の
析出によるものである。また、プラズマ浸炭焼入れよれ
ば、浸炭層にガス浸炭で得られない2%以上の高い炭素
量が得られ、短時間で浸炭が終了するので熱処理変形が
少なく研削などの取代が減じて加工工数を低減できると
いう利点がある。
Conventionally, quenched and tempered bearing steel (JIS. SUJ) widely used for wear-resistant parts is 200.
There is a problem that when heated to a temperature of not less than ℃, the hardness is lowered, so that it cannot be used at a high temperature. On the other hand, the carburized and quenched layer obtained by plasma carburizing and quenching the above martensitic chromium stainless steel is secondarily hardened by tempering at 430 to 570 ° C., and the hardness increases. Therefore, the wear-resistant parts subjected to the treatment of the present invention can be used for wear-resistant members used at high temperatures without a decrease in hardness. This tempering hardening of the quenched layer is due to a phase change of retained austenite remaining during quenching and precipitation of a solid solution alloy. In addition, according to the plasma carburizing and quenching, a high carbon content of 2% or more, which cannot be obtained by gas carburizing, can be obtained in the carburized layer, and the carburizing is completed in a short time. There is an advantage that it can be reduced.

【0008】従来、本発明のようにステンレス鋼をプラ
ズマ浸炭して使用する例はない。ここで、前記マルテン
サイト系クロムステンレス鋼の成分をC:0.4〜0.
6wt%とするのは、Cがこれより低すぎるとプラズマ
浸炭の時間がかかり過ぎることと、かつ母材の強度が低
くなり浸炭層の亀裂や剥離が生じやすいからである。ま
た、Cがこれより高すぎると浸炭層のみでなく内部まで
硬さが増して全体の対衝撃性が低下することと、材料が
高価になりコストがアップするからである。
Conventionally, there is no example in which stainless steel is plasma carburized and used as in the present invention. Here, the component of the martensitic chromium stainless steel is C: 0.4 to 0.1.
The reason why the content of C is set to 6 wt% is that if C is too low, it takes too much time for plasma carburization, and the strength of the base material is lowered, so that cracks and peeling of the carburized layer are likely to occur. On the other hand, if C is too high, the hardness of not only the carburized layer but also the inside thereof increases to lower the overall impact resistance, and the material becomes expensive and the cost increases.

【0009】前記成分をCr:9.5〜13.0wt
%,Mo:0.3〜1.0wt%とするのは、焼戻しに
よる2次硬化のために必要な合金量として広く知られて
いるところであり、2次硬化の焼戻し硬さを得易くする
ためである。上記の本発明のマルテンサイト系クロムス
テンレス鋼は、AISI440Cなどのさらに高炭素・
高合金のステンレス鋼に比し機械加工が容易で安価に入
手できる。
The above component is composed of Cr: 9.5 to 13.0 wt.
%, Mo: 0.3 to 1.0 wt% is widely known as an amount of alloy necessary for secondary hardening by tempering, and is intended to make it easier to obtain the tempering hardness of secondary hardening. It is. The above-described martensitic chromium stainless steel of the present invention has a higher carbon content such as AISI440C.
Easy to machine and cheaper than high alloy stainless steel.

【0010】プラズマ浸炭層の炭素濃度は2%前後の高
い炭素量が得られるので、焼入れの際には残留オーステ
ナイトにより硬さがあまり高くならない場合がある。こ
こで最初の焼入硬さをHRC55以上とするのは、この
化学成分でプラズマ浸炭したものは最初の焼入硬さがH
RC55以上あれば、430〜570℃の焼戻しにより
残留オーステナイトが相変化してマルテンサイト化し、
析出硬化とともに焼戻し後にHRC58以上の所用硬さ
が確実に得られるからである。
[0010] Since a high carbon content of about 2% is obtained in the plasma carburized layer, the hardness may not be too high due to residual austenite during quenching. Here, the first quench hardness is set to HRC55 or more because the first quench hardness of the steel carburized with this chemical component is H
If it is RC55 or more, the retained austenite undergoes a phase change by tempering at 430 to 570 ° C. to become martensite,
This is because the required hardness of HRC 58 or more can be reliably obtained after tempering together with precipitation hardening.

【0011】また、本発明の耐摩耗部品及びその製造方
法は、少なくもC:0.4〜0.6wt%,Cr:9.
5〜13.0wt%,Mo:0.3〜1.0wt%を含
むマルテンサイト系クロムステンレス鋼からなる部材の
所定面をプラズマ浸炭焼入れによりHRC55以上の硬
さに焼入れした後430℃〜570℃で焼戻しして2次
硬化させ、該部材をアルミニューム合金鋳造により肉付
けして形成したことを特徴とするものである。
Further, the wear-resistant part and the method of manufacturing the same according to the present invention are characterized in that at least C: 0.4 to 0.6 wt%, Cr: 9.
A predetermined surface of a member made of martensitic chromium stainless steel containing 5 to 13.0 wt% and Mo: 0.3 to 1.0 wt% is quenched to a hardness of HRC 55 or more by plasma carburizing and then 430 ° C to 570 ° C. Characterized by being tempered and secondarily hardened, and the member is formed by thickening by aluminum alloy casting.

【0012】即ち、本発明によれば耐摩耗を要する部分
は焼入硬化させた単純な形状の鋼材を使用して形成さ
せ、複雑な形状で耐摩耗性を要しない部分はアルミニュ
ーム合金鋳造により肉付けして形成することで、軽量で
安価な耐摩耗部材を提供しようとするものである。
That is, according to the present invention, a portion requiring wear resistance is formed by using a quenched and hardened steel material having a simple shape, and a portion having a complicated shape and not requiring wear resistance is formed by casting an aluminum alloy. The purpose of the present invention is to provide a lightweight and inexpensive wear-resistant member by forming it with a flesh.

【0013】この様に耐摩耗性を要しない部分をアルミ
ニューム合金鋳造により肉付けして形成すれば、一体む
くの鋼材から削り出して成型するのに比し容易に複雑な
形状が得られて加工工数を大幅に低減できる。また、少
量生産の場合にも近似の型を使用してアルミニューム合
金によりニヤネットシェイプに成形してアルミニューム
合金の部分を機械加工すれば鋼材の加工より容易で加工
工数が少なくて済む。なお、アルミニューム合金鋳造と
してはダイカスト鋳造やグラビティ鋳造など種々の鋳造
方法が利用できる。
[0013] If a portion that does not require abrasion resistance is formed by thickening by aluminum alloy casting, a complicated shape can be easily obtained as compared with shaving from a solid steel material and molding. Man-hours can be significantly reduced. Also, in the case of small-scale production, if an aluminum alloy is formed into a near net shape using an approximate die and the aluminum alloy portion is machined, it is easier than a steel material and requires less man-hours. Various casting methods such as die casting and gravity casting can be used as the aluminum alloy casting.

【0014】しかし、従来の焼入・焼戻しした軸受鋼で
は、アルミニューム合金鋳造により肉付けする際に鋳造
時の温度で軸受鋼が軟化するために所定のHRC58以
上の硬さが得られなかった。そこで、本発明は前記ステ
ンレス鋼のプラズマ浸炭した浸炭層が430〜570℃
の加熱により2次硬化して硬さが上昇することに着目し
た。即ち、このような温度で焼戻ししておけば、鋳造時
の温度では軟化することなく所定のHRC58以上の硬
さが得られるので、上記アルミニューム合金の肉付けに
よる軽量化とコスト低減が容易にできる。なお、アルミ
ニューム合金の鋳造温度は通常570℃の焼戻温度より
も高いが、溶湯の凝固時間は短時間であるので430〜
570℃で焼戻しした前記ステンレスが鋳造時に軟化す
ることはない。また、この用途に焼戻し軟化の少ないダ
イス鋼の使用も可能であるが、高価で管材などの入手が
困難である。これに対し、本ステンレス鋼は安価に入手
できる利点がある。
However, in the case of the conventional hardened and tempered bearing steel, when the aluminum alloy is cast, the bearing steel is softened at the temperature at the time of casting, so that a hardness higher than the predetermined HRC 58 cannot be obtained. Therefore, the present invention provides a method of forming a plasma-carburized carburized layer of the stainless steel at 430 to 570 ° C.
It was noted that the secondary curing caused by the heating caused the hardness to increase. That is, if tempering is performed at such a temperature, a hardness equal to or higher than the predetermined HRC 58 can be obtained without softening at the temperature at the time of casting, so that weight reduction and cost reduction can be easily achieved by thickening the aluminum alloy. . Although the casting temperature of the aluminum alloy is usually higher than the tempering temperature of 570 ° C., the solidification time of the molten metal is short, so that it is 430 to 430 ° C.
The stainless steel tempered at 570 ° C. does not soften during casting. Die steel with low tempering softening can be used for this purpose, but it is expensive and it is difficult to obtain a pipe material. On the other hand, the present stainless steel has an advantage that it can be obtained at low cost.

【0015】また、本発明の軸受部品及びその製造方法
は、少なくもC:0.4〜0.6wt%,Cr:9.5
〜13.0wt%,Mo:0.3〜1.0wt%を含む
マルテンサイト系クロムステンレス鋼の鋼管の内径の所
定面をプラズマ浸炭焼入れによりHRC55以上の硬さ
に焼入れした後430℃〜570℃で焼戻しして2次硬
化させ、該鋼管の外周をアルミニューム合金鋳造により
鋳ぐるんで形成したことを特徴とするものである。
The bearing component and the method of manufacturing the same according to the present invention are characterized in that at least C is 0.4 to 0.6 wt% and Cr is 9.5.
1313.0 wt%, Mo: 0.3〜1.0 wt%. A predetermined surface of the inner diameter of the steel pipe of martensitic chrome stainless steel is quenched to a hardness of HRC 55 or more by plasma carburizing and 430 ° C. to 570 ° C. And the steel tube is secondarily hardened, and the outer periphery of the steel pipe is formed by casting through an aluminum alloy casting.

【0016】例えばボールねじナットのような軸受部品
は、内径に螺旋溝の転動面を有する円筒の外周部に鋼球
循環路などの複雑な形状を備えている。本発明は、この
鋼球転動面の耐摩耗性が要求される内径部を前記マルテ
ンサイト系クロムステンレス鋼の鋼管で製作することに
より丸棒鋼から削り出す従来方法に比して内径の孔明け
加工が省略でき、その外周をアルミニューム合金鋳造で
鋳ぐるんで形成することにより複雑な形状が安価容易に
形成できる。また、このような構成にすることにより軽
量化されるので、移動体などに使用する場合に慣性を小
さくし動きのレスポンスが早くなる利点がある。従来の
軸受鋼ではこのような鋳ぐるむことは硬さが低下してで
きなかった。
For example, a bearing component such as a ball screw nut has a complicated shape such as a steel ball circulation path on the outer peripheral portion of a cylinder having a spiral groove rolling surface on the inside diameter. According to the present invention, the inner diameter portion where the wear resistance of the steel ball rolling surface is required is made of the above-mentioned martensitic chrome stainless steel steel pipe, and the inner diameter hole is drilled as compared with the conventional method of shaving from a round bar steel. Processing can be omitted, and a complicated shape can be easily formed at low cost by forming the outer periphery by casting with aluminum alloy casting. Further, since the weight is reduced by adopting such a configuration, there is an advantage that when used for a moving body or the like, the inertia is reduced and the response of movement is quick. In conventional bearing steels, such casting was not possible due to reduced hardness.

【0017】上記アルミニューム合金鋳造後の焼入れ面
の硬さは、対摩耗性のためには高いほど望ましく、転が
り軸受などに使用される場合少なくもHRC58以上の
硬さに保持されることが望ましいが、本発明の耐摩耗部
品はこの要請に十分応えられるものである。
The hardness of the quenched surface after casting of the aluminum alloy is preferably as high as possible for the purpose of abrasion resistance. When used for a rolling bearing or the like, the hardness is preferably maintained at least at HRC 58 or more. However, the wear-resistant part of the present invention can sufficiently meet this demand.

【0018】[0018]

【発明の実施の形態】以下、本発明の1実施形態につい
てを具体的に説明する。図1は耐摩耗部材の一つとして
軸受部材の本発明の製造工程と従来工程とを対比した
図、図2は本発明の1実施形態の成品形状の概略を示す
断面図である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, one embodiment of the present invention will be specifically described. FIG. 1 is a diagram comparing a manufacturing process of the present invention with a conventional process of a bearing member as one of the wear-resistant members, and FIG. 2 is a cross-sectional view schematically showing a product shape of an embodiment of the present invention.

【0019】図2に示す成品のボールねじナットは、ね
じ軸1の螺旋溝を転動する鋼球2が外筒3及び4の一端
の鋼球循環孔6及び7を通って他端の鋼球循環孔6´か
ら螺旋溝に帰るようになっている。鋼球循環孔7の外側
ははカバー材5でカバーされている。
In the ball screw nut of the product shown in FIG. 2, a steel ball 2 rolling in a spiral groove of a screw shaft 1 passes through steel ball circulation holes 6 and 7 at one end of outer cylinders 3 and 4 and a steel ball at the other end. The ball circulation hole 6 'returns to the spiral groove. The outside of the steel ball circulation hole 7 is covered with a cover material 5.

【0020】従来は、図2の内筒3及び外筒4は一体の
鋼材から切削加工により成形された。即ち、図1の従来
の製造工程に示すように、まず素材の棒鋼を所定長さに
切断した後孔明けして管状に加工し外周部の形状を機械
加工により成型した。その後、所要部をガス浸炭焼入れ
し内径研削して成品とされた。しかし、外周部は鋼球循
環孔などがあり形状が複雑で機械加工が困難であった。
かつ、全体を鋼材で製作することにより重量が増し、さ
らに軽量化の要請があった。
Conventionally, the inner cylinder 3 and the outer cylinder 4 shown in FIG. 2 are formed by cutting from an integral steel material. That is, as shown in the conventional manufacturing process of FIG. 1, first, a steel bar as a raw material was cut into a predetermined length, drilled, processed into a tubular shape, and the outer peripheral shape was formed by machining. After that, the required parts were gas carburized and quenched and the inner diameter was ground to obtain finished products. However, the outer peripheral portion has a steel ball circulation hole and the like, so that the shape is complicated and machining is difficult.
In addition, there has been a demand for increasing the weight and further reducing the weight by manufacturing the whole from a steel material.

【0021】これに対し、本発明の方法は、図2の内筒
3及び外筒4を分離し、鋼球2が転動する耐摩耗性を要
する内筒3を鋼管で製作し、耐摩耗性を要しない複雑な
形状の外筒4をアルミニュームダイカストにより肉付け
して成形したものである。即ち、本実施形態ではアルミ
ニューム合金鋳造の方法としてダイカストにより、図1
の製造工程に示すように、素材の鋼管の外径を旋削加工
した後、所定長さに切断して所要部をプラズマ浸炭焼入
・焼戻しした後、その外周をアルミニュームダイカスト
により鋳ぐるんで成形した。その後内径研削して成品と
された。これにより、内筒は加工が簡単で高い耐摩耗性
が得られ、外筒部は機械加工部分が大幅に減ると共に、
アルミニューム合金は鋼より加工が容易で軽いため大幅
に加工工数を減してコストを低減するとともに大幅な軽
量化が達成できた。
On the other hand, according to the method of the present invention, the inner cylinder 3 and the outer cylinder 4 shown in FIG. The outer cylinder 4 having a complicated shape that does not require a property is formed by being filled with aluminum die casting. That is, in the present embodiment, as a method for casting an aluminum alloy, die casting is performed as shown in FIG.
As shown in the manufacturing process, after turning the outer diameter of the material steel pipe, cutting it to a predetermined length, plasma carburizing and tempering the required part, then casting the outer periphery with aluminum die casting did. After that, the product was finished by inner diameter grinding. As a result, the inner cylinder is easily machined and high wear resistance is obtained, and the outer cylinder part has significantly reduced machined parts,
Aluminum alloys are easier and lighter to process than steel, so the number of processing steps has been greatly reduced, reducing costs and achieving significant weight savings.

【0022】本実施形態の内筒3の材料の1例として表
1に示すマルテンサイト系ステンレス鋼のプラズマ浸炭
焼入れした焼入層の熱処理特性を図3に示す。
FIG. 3 shows the heat treatment characteristics of a quenched layer obtained by plasma carburizing and quenching martensitic stainless steel as shown in Table 1 as an example of the material of the inner cylinder 3 of the present embodiment.

【0023】[0023]

【表1】 [Table 1]

【0024】図に示すように、上記ステンレス鋼をプラ
ズマ浸炭しないで真空焼入れした場合の焼入層の硬さ
は、焼入れのままでHv700〜750(HRC60〜
62)であるが、焼戻温度が増すと軟化して250℃を
超えるとHv680(HRC54)まで低下する。50
0℃近傍でやや硬さが上昇してようやくHv600(H
RC55)が得られるが、500℃を超えると急激に硬
さは低下して不安定であり所用硬さのHRC58以上の
硬さを得ることはできない。
As shown in the figure, the hardness of the quenched layer when vacuum quenching the above stainless steel without plasma carburizing is Hv700-750 (HRC60-
62), but softens as the tempering temperature increases, and decreases to Hv680 (HRC54) when the temperature exceeds 250 ° C. 50
Hv600 (H
RC55) is obtained, but when the temperature exceeds 500 ° C., the hardness sharply decreases and becomes unstable, so that the required hardness of HRC 58 or more cannot be obtained.

【0025】これに対し、本発明のプラズマ浸炭焼入れ
を行った焼入層の硬さは、焼入れのままでHv760
(HRC62.5)程度になる。焼戻温度が増すとHv
620(HRC56)に軟化するが、430℃を超える
と析出硬化してHv730〜740(HRC61.5程
度)の高い硬さが得られる。焼戻温度が570℃を超え
ると再び硬さが低下するので、430℃〜570℃の焼
戻しが望ましい。即ち、プラズマ浸炭焼入後にこの温度
で焼戻しすれば、430℃以上の高い温度でも長時間使
用に耐える耐摩耗部品が得られる。また、ダイカスト用
アルミニューム合金のダイカスト鋳造温度は通常570
℃より高いが、凝固時間が短時間であるので上記温度で
焼戻ししたステンレス部材はアルミニュームダイカスト
の鋳ぐるみの際に軟化することがない。したがって、本
発明のマルテンサイト系ステンレス鋼をプラズマ浸炭焼
入れしてアルミニュームダイカストにより肉付けすれ
ば、内筒には転がり軸受として使用される所要硬さのH
v650(HRC58)以上の硬さが得られることが分
かった。
On the other hand, the hardness of the quenched layer subjected to the plasma carburizing and quenching according to the present invention is Hv760 as quenched.
(HRC 62.5). When tempering temperature increases, Hv
However, when the temperature exceeds 430 ° C., precipitation hardens and a high hardness of Hv 730 to 740 (about HRC 61.5) is obtained. If the tempering temperature exceeds 570 ° C, the hardness decreases again, so tempering at 430 ° C to 570 ° C is desirable. That is, if tempering is performed at this temperature after plasma carburizing and quenching, a wear-resistant part that can withstand long-term use even at a high temperature of 430 ° C. or higher can be obtained. The die casting temperature of the aluminum alloy for die casting is usually 570.
Although the temperature is higher than ℃, the solidification time is short, so that the stainless member tempered at the above temperature does not soften when the aluminum die-cast is cast. Therefore, if the martensitic stainless steel of the present invention is plasma carburized and quenched and then is thickened by aluminum die casting, the inner cylinder has a required hardness H used as a rolling bearing.
It was found that a hardness of v650 (HRC58) or more was obtained.

【0026】なお、図4には省略したが、プラズマ浸炭
焼入時の硬さが残留オーステナイトのために低くてなっ
てもHv600(HRC55)以上あれば焼戻しにより
残留オーステナイトが相変化してHRC58以上の2次
硬化硬さが得られることが判った。
Although not shown in FIG. 4, even if the hardness at the time of plasma carburizing and quenching is low due to retained austenite, if Hv 600 (HRC 55) or more, the residual austenite undergoes a phase change due to tempering and becomes HRC 58 or more. It was found that the secondary hardening hardness was obtained.

【0027】[0027]

【実施例】実際の部品について下記の試験条件で試験し
た結果を以下に示す。 部品の形状寸法:図2に示す形状 内筒内径d1: 26mmφ 内筒外径d2: 33mmφ 外筒外径D:約 60mmφ異形 長さL: 30mm 内筒の鋼の材質: 表1に成分を示すマルテンサイト系
ステンレス鋼 製造工程: 図1に示すように鋼管を使用して加工
し、アルミニュームダイカストで鋳ぐるんだ。 熱処理条件: 図3に示すプラズマ浸炭焼入後、55
0℃×2Hr焼戻し
EXAMPLES The results of tests on actual parts under the following test conditions are shown below. Part dimensions: Shape shown in FIG. 2 Inner cylinder inner diameter d1: 26 mm φ Inner cylinder outer diameter d2: 33 mm φ Outer cylinder outer diameter D: about 60 mm φ Irregular length L: 30 mm Material of inner cylinder steel: Table 1 shows the components Martensitic stainless steel Manufacturing process: As shown in Fig. 1, it is processed using steel pipe and cast with aluminum die casting. Heat treatment conditions: After plasma carburizing and quenching shown in FIG.
0 ℃ × 2Hr tempering

【0028】上記条件で試験した結果ダイカスト後に下
記のように非常に高い硬さの結果が得られた。 試験結果: 表面硬さ: Hv730(約HRC61.5) Hv650(HRC58)以上の焼入層深さ: 0.7
mm
As a result of the test under the above conditions, a very high hardness was obtained after die casting as follows. Test result: Surface hardness: Hv730 (about HRC61.5) Hardened layer depth higher than Hv650 (HRC58): 0.7
mm

【0029】以上説明したように本発明の耐摩耗部品の
製造方法によれば、少なくもC:0.4〜0.6wt
%,Cr:9.5〜13.0wt%,Mo:0.3〜
1.0wt%を含むマルテンサイト系クロムステンレス
鋼をプラズマ浸炭焼入れした後430℃〜570℃で焼
戻しすると2次硬化して所要のHRC58以上の硬さが
得られるので、かかる熱処理をすることにより従来の軸
受鋼では使用できなかった高温で使用できる耐摩耗部材
が安価に得られる。また、熱処理変形が少なく研削など
の取代が減じて加工工数を低減できる。
As described above, according to the method for producing a wear-resistant part of the present invention, at least C: 0.4 to 0.6 wt.
%, Cr: 9.5 to 13.0 wt%, Mo: 0.3 to
After plasma carburizing and quenching a martensitic chromium stainless steel containing 1.0 wt% and then tempering at 430 ° C to 570 ° C, secondary hardening is achieved and a required HRC of 58 or more can be obtained. A wear-resistant member that can be used at high temperatures, which could not be used with the bearing steel, can be obtained at low cost. In addition, there is little deformation due to heat treatment, so that the machining allowance such as grinding is reduced, and the number of processing steps can be reduced.

【0030】また、上記組成のマルテンサイト系クロム
ステンレス鋼を使用してプラズマ浸炭焼入・焼戻を行
い、その部材をアルミニュームダイカストなどのアルミ
ニューム合金鋳造で肉付け成形することにより、部材の
硬さがHRC58以上を満足しながら複雑な形状で容積
の大きい部分がアルミニューム合金で成品近似形状に成
型されて機械加工工数が減じコストが低減されて軽量化
できる。
Further, plasma carburizing and tempering is performed using martensitic chromium stainless steel having the above composition, and the member is hardened by casting with an aluminum alloy such as aluminum die casting. While the HRC satisfies HRC 58 or more, a complicated and large-volume portion is formed into an approximate product shape with an aluminum alloy, so that the number of machining steps is reduced, the cost is reduced, and the weight can be reduced.

【0031】上記本実施例ではボールねじナットについ
て試験したが、本発明の製造方法はローラが転動したり
平面で摺動する耐摩耗部材にも適用でき、円筒形状の場
合はステンレス鋼管を使用することにより一層コスト低
減できるが、棒鋼材、平鋼材から削り出すことを排除す
るものではない。また、軸受部品としたが軸受部品に限
るものではなく、広く対摩耗部品に使用される。
In the above embodiment, the ball screw nut was tested. However, the manufacturing method of the present invention can be applied to a wear-resistant member in which the roller rolls or slides on a flat surface. In the case of a cylindrical shape, a stainless steel tube is used. By doing so, the cost can be further reduced, but this does not preclude cutting out from bar steel or flat steel. Further, the bearing component is used, but is not limited to the bearing component, and is widely used for wear-resistant parts.

【0032】[0032]

【発明の効果】以上説明したように、本発明の耐摩耗部
品及びその製造方法によれば、所定成分のマルテンサイ
系ステンレス鋼をプラズマ浸炭焼入・焼戻してアルミニ
ューム合金鋳造で肉付けすることにより、所要部に高い
硬さが得られて軽量化でき、かつ複雑な形状の部品でも
機械工数が低減できてコストの削減ができる。
As described above, according to the wear-resistant part and the method of manufacturing the same according to the present invention, a martensitic stainless steel having a predetermined component is plasma-carburized and quenched and tempered, and is then filled with an aluminum alloy casting. A high hardness can be obtained in the required part, so that the weight can be reduced, and even a part having a complicated shape can reduce the number of mechanical steps and cost.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の耐摩耗部品の製造工程と従来の製造工
程を比較した図である。
FIG. 1 is a diagram comparing a manufacturing process of a wear-resistant part of the present invention with a conventional manufacturing process.

【図2】本発明実施形態の耐摩耗部品の形状を示す断面
図である。
FIG. 2 is a sectional view showing a shape of a wear-resistant part according to the embodiment of the present invention.

【図3】本発明の耐摩耗部品のプラズマ浸炭焼入・焼戻
し条件を示す図である。
FIG. 3 is a diagram showing plasma carburizing quenching and tempering conditions of the wear-resistant part of the present invention.

【図4】本発明のマルテンサイト系ステンレス鋼をプラ
ズマ浸炭焼入れした焼入層の熱処理特性を示す図であ
る。
FIG. 4 is a graph showing heat treatment characteristics of a quenched layer obtained by plasma carburizing and quenching the martensitic stainless steel of the present invention.

【符号の説明】[Explanation of symbols]

1 ねじ軸 2 鋼球 3 内筒 4 外筒 5 カバー 6 鋼球循環路 6´ 鋼球循環路 7 鋼球循環路 DESCRIPTION OF SYMBOLS 1 Screw shaft 2 Steel ball 3 Inner cylinder 4 Outer cylinder 5 Cover 6 Steel ball circulation path 6 'Steel ball circulation path 7 Steel ball circulation path

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI C22C 38/22 C22C 38/22 (72)発明者 秋山 正稔 山形県東根市大字東根甲5600 株式会社ネ ツレン甲府内 (72)発明者 笹 勇 山形県東根市大字東根甲5600 株式会社ネ ツレン甲府内 (72)発明者 有島 利治 山口県厚狭郡山陽町山野井工業団地 株式 会社ネツレン甲府内──────────────────────────────────────────────────の Continuation of the front page (51) Int.Cl. 6 Identification symbol FI C22C 38/22 C22C 38/22 (72) Inventor Masatoshi Akiyama 5600 Higashi-Naka, Higashine-shi, Yamagata Pref. Inventor Isamu Sasa 5600 Higashi-Kone Ko, Higashine-shi, Yamagata Prefecture Netulen Kofu Co., Ltd. (72) Inventor Toshiharu Arishima Yamanoi Industrial Park, Sanyo-cho, Asa-gun, Yamaguchi Prefecture Netulen Kofu Co., Ltd.

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 少なくもC:0.4〜0.6wt%,C
r:9.5〜13.0wt%,Mo:0.3〜1.0w
t%を含むマルテンサイト系クロムステンレス鋼からな
る部材をプラズマ浸炭焼入れによりHRC55以上の硬
さに焼入れした後430℃〜570℃で焼戻しして2次
硬化させてなることを特徴とする耐摩耗部品。
1. At least C: 0.4-0.6 wt%, C
r: 9.5 to 13.0 wt%, Mo: 0.3 to 1.0 w
A wear-resistant part characterized in that a member made of martensitic chromium stainless steel containing t% is hardened to a hardness of HRC 55 or more by plasma carburizing and quenching, and then tempered at 430 ° C to 570 ° C and secondarily hardened. .
【請求項2】 少なくもC:0.4〜0.6wt%,C
r:9.5〜13.0wt%,Mo:0.3〜1.0w
t%を含むマルテンサイト系クロムステンレス鋼からな
る部材の所定面をプラズマ浸炭焼入れによりHRC55
以上の硬さに焼入れした後430℃〜570℃で焼戻し
して2次硬化させ、該部材をアルミニューム合金鋳造に
より肉付けして形成したことを特徴とする耐摩耗部品。
2. At least C: 0.4 to 0.6 wt%, C
r: 9.5 to 13.0 wt%, Mo: 0.3 to 1.0 w
A predetermined surface of a member made of martensitic chromium stainless steel containing t% is subjected to HRC 55 by plasma carburizing and quenching.
A wear-resistant part formed by quenching to the above hardness, tempering at 430 ° C. to 570 ° C., secondary hardening, and forming the member by casting with an aluminum alloy.
【請求項3】 少なくもC:0.4〜0.6wt%,C
r:9.5〜13.0wt%,Mo:0.3〜1.0w
t%を含むマルテンサイト系クロムステンレス鋼の鋼管
の内径の所定面をプラズマ浸炭焼入れによりHRC55
以上の硬さに焼入れした後430℃〜570℃で焼戻し
して2次硬化させ、該鋼管の外周をアルミニューム合金
鋳造により鋳ぐるんで形成したことを特徴とする軸受部
品。
3. At least C: 0.4 to 0.6 wt%, C
r: 9.5 to 13.0 wt%, Mo: 0.3 to 1.0 w
A predetermined surface of the inner diameter of a martensitic chrome stainless steel pipe containing t% is subjected to HRC 55 by plasma carburizing and quenching.
A bearing part characterized by being quenched to the above hardness, then tempered at 430 ° C. to 570 ° C. and secondarily hardened, and the outer periphery of the steel pipe is formed by casting an aluminum alloy.
【請求項4】 前記アルミニューム合金鋳造後の焼入れ
面は少なくもHRC58以上の硬さに保持されたことを
特徴とする請求項1から3のいずれかに記載の耐摩耗部
品。
4. The wear-resistant part according to claim 1, wherein the quenched surface after the casting of the aluminum alloy is maintained at a hardness of at least HRC 58 or more.
【請求項5】 少なくもC:0.4〜0.6wt%,C
r:9.5〜13.0wt%,Mo:0.3〜1.0w
t%を含むマルテンサイト系クロムステンレス鋼からな
る部材をプラズマ浸炭焼入れによりHRC55以上の硬
さに焼入れした後430℃〜570℃で焼戻しして2次
硬化させてなることを特徴とする耐摩耗部品の製造方
法。
5. At least C: 0.4 to 0.6 wt%, C
r: 9.5 to 13.0 wt%, Mo: 0.3 to 1.0 w
A wear-resistant part obtained by quenching a member made of martensitic chromium stainless steel containing t% to a hardness of HRC 55 or more by plasma carburizing and quenching at 430 ° C. to 570 ° C. and secondary hardening. Manufacturing method.
【請求項6】 少なくもC:0.4〜0.6wt%,C
r:9.5〜13.0wt%,Mo:0.3〜1.0w
t%を含むマルテンサイト系クロムステンレス鋼からな
る部材の所定面をプラズマ浸炭焼入れによりHRC55
以上の硬さに焼入れした後430℃〜570℃で焼戻し
して2次硬化させ、該部材をアルミニューム合金鋳造に
より肉付けして形成したことを特徴とする耐摩耗部品の
製造方法。
6. At least C: 0.4-0.6 wt%, C
r: 9.5 to 13.0 wt%, Mo: 0.3 to 1.0 w
A predetermined surface of a member made of martensitic chromium stainless steel containing t% is subjected to HRC 55 by plasma carburizing and quenching.
A method for producing a wear-resistant part, comprising: quenching to the above hardness, tempering at 430 ° C. to 570 ° C., secondarily hardening, and forming the member by casting with an aluminum alloy.
【請求項7】 少なくもC:0.4〜0.6wt%,C
r:9.5〜13.0wt%,Mo:0.3〜1.0w
t%を含むマルテンサイト系クロムステンレス鋼の鋼管
の内径の所定面をプラズマ浸炭焼入れによりHRC55
以上の硬さに焼入れした後430℃〜570℃で焼戻し
して2次硬化させ、該鋼管の外周をアルミニューム合金
鋳造により鋳ぐるんで形成したことを特徴とする軸受部
品の製造方法。
7. At least C: 0.4 to 0.6 wt%, C
r: 9.5 to 13.0 wt%, Mo: 0.3 to 1.0 w
A predetermined surface of the inner diameter of a martensitic chrome stainless steel pipe containing t% is subjected to HRC 55 by plasma carburizing and quenching.
A method for producing a bearing component, comprising: quenching to the above hardness, tempering at 430 ° C. to 570 ° C., secondary hardening, and forming an outer periphery of the steel pipe by casting aluminum alloy by casting.
JP36685797A 1997-12-26 1997-12-26 Bearing parts and manufacturing method thereof Expired - Fee Related JP3844867B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP36685797A JP3844867B2 (en) 1997-12-26 1997-12-26 Bearing parts and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP36685797A JP3844867B2 (en) 1997-12-26 1997-12-26 Bearing parts and manufacturing method thereof

Publications (2)

Publication Number Publication Date
JPH11193454A true JPH11193454A (en) 1999-07-21
JP3844867B2 JP3844867B2 (en) 2006-11-15

Family

ID=18487858

Family Applications (1)

Application Number Title Priority Date Filing Date
JP36685797A Expired - Fee Related JP3844867B2 (en) 1997-12-26 1997-12-26 Bearing parts and manufacturing method thereof

Country Status (1)

Country Link
JP (1) JP3844867B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010105644A1 (en) * 2009-03-19 2010-09-23 Ab Skf Method of manufacturing a bearing ring
GB2519048B (en) * 2012-08-15 2016-11-02 Timken Co Steel article having improved contact fatigue resistance and a method of making
CN114231701A (en) * 2021-12-10 2022-03-25 吉林省齐智科技有限公司 Non-standard hardness heat treatment method for XW-42 die steel

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010105644A1 (en) * 2009-03-19 2010-09-23 Ab Skf Method of manufacturing a bearing ring
CN102356168A (en) * 2009-03-19 2012-02-15 Skf公司 Method of manufacturing bearing ring
US9540705B2 (en) 2009-03-19 2017-01-10 Aktiebolaget Skf Method of manufacturing a bearing ring
GB2519048B (en) * 2012-08-15 2016-11-02 Timken Co Steel article having improved contact fatigue resistance and a method of making
US10087512B2 (en) 2012-08-15 2018-10-02 The Timken Company Steel article having improved contact fatigue resistance and a method of making
CN114231701A (en) * 2021-12-10 2022-03-25 吉林省齐智科技有限公司 Non-standard hardness heat treatment method for XW-42 die steel

Also Published As

Publication number Publication date
JP3844867B2 (en) 2006-11-15

Similar Documents

Publication Publication Date Title
JP5611828B2 (en) Rotating elements or rotating rings formed from bearing steel
KR100738849B1 (en) Rolling bearing component
JP5535922B2 (en) Heat treatment process for steel
JP4632931B2 (en) Induction hardening steel excellent in cold workability and its manufacturing method
JPH09176740A (en) Production of bearing ring for ball bearing
JPH11343520A (en) Bevel gear and production of gear having many gear teeth
JP3278262B2 (en) Manufacturing method of sintered gear
JP4676993B2 (en) Bush making
US5468308A (en) Surface treated cast iron bearing element
JP3372219B2 (en) Manufacturing method of steel parts
JPH0255487B2 (en)
US20080095657A1 (en) Optimization Of Steel Metallurgy To Improve Broach Tool Life
JP2006328465A (en) Method for manufacturing bearing ring for rolling bearing, bearing ring for rolling bearing, and rolling bearing
JPH11193454A (en) Wear resistant part and its production
KR20000010768A (en) Metal mold manufacturing method
JP2006291239A (en) Method for producing high-carbon chromium bearing steel-forged rough-shaped material for inner and outer rings of general purpose small type bearing
JP4533613B2 (en) Nut manufacturing method for roll barrel screw drive
JP2019514699A (en) Method for producing a shaped body
JPH09242763A (en) Manufacture of rolling bearing
JPH1053811A (en) Manufacture of steel member
JPH06264147A (en) Manufacture of steering rack shaft
JP2000145964A (en) Martensitic stainless steel part and manufacture therefor
JP4855369B2 (en) Outer joint member for constant velocity universal joint and fixed constant velocity universal joint
JPH0873929A (en) Machine element part and manufacture thereof
JPH0416538B2 (en)

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20041210

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20051226

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20060110

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060227

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20060418

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060515

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20060626

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060815

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060817

R150 Certificate of patent (=grant) or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100825

Year of fee payment: 4

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110825

Year of fee payment: 5

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120825

Year of fee payment: 6

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120825

Year of fee payment: 6

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130825

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees