JPH11188253A - Composition for emulsified matter and emulsified matter - Google Patents
Composition for emulsified matter and emulsified matterInfo
- Publication number
- JPH11188253A JPH11188253A JP10009226A JP922698A JPH11188253A JP H11188253 A JPH11188253 A JP H11188253A JP 10009226 A JP10009226 A JP 10009226A JP 922698 A JP922698 A JP 922698A JP H11188253 A JPH11188253 A JP H11188253A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- composition
- water
- acid
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Colloid Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、化粧品および洗剤
等に用いられる界面活性剤を含まない乳化物用組成物お
よびこの組成物を撹拌して得られる乳化物に関する。The present invention relates to a surfactant-free emulsion composition used for cosmetics and detergents, and an emulsion obtained by stirring this composition.
【０００２】[0002]
【従来の技術および発明が解決しようとする課題】一般
に、洗剤、化粧品等の乳化物においては、水と油とを結
合させて乳化物を作るために界面活性剤が添加されてお
り、この界面活性剤は手荒れ、肌荒れあるいは皮膚アレ
ルギー等の原因となっていた。2. Description of the Related Art Generally, surfactants are added to emulsions such as detergents and cosmetics in order to combine water and oil to form emulsions. The activator has been a cause of rough hands, rough skin or skin allergies.
【０００３】また、これら界面活性剤を用いる乳化物は
高温殺菌すると水と油が分離してしまうので、高温殺菌
処理の代わりに防腐剤を添加する必要があった。ところ
が、この防腐剤は界面活性剤と同様に手荒れ、肌荒れお
よび皮膚アレルギーの原因ともなっていた。[0003] In addition, when emulsions using these surfactants are pasteurized at high temperature, water and oil are separated, so that it was necessary to add a preservative in place of the pasteurization treatment. However, this preservative, like the surfactant, caused rough hands, rough skin and skin allergies.
【０００４】また、最近では、粘土鉱物が化粧品の分野
で感触に非常に優れている素材として多くの製品に利用
されており、特に雲母やタルクは、ファンデーションな
どの粉末化粧品の主要の原料として用いられ、粘土の層
間に界面活性剤を包接させて疎水性の高い油性ゲルに水
を徐々に添加して強い撹拌を加えることによりｗａｔｅ
ｒ−ｉｎ−ｏｉｌ型のエマルジョンを得、これを化粧品
として用いることが知られている。[0004] Recently, clay minerals have been used in many cosmetic products in the field of cosmetics as a material having a very good feel. In particular, mica and talc are used as main raw materials of powder cosmetics such as foundations. A surfactant is included between the layers of the clay, water is gradually added to the highly hydrophobic oily gel, and strong stirring is applied to the water.
It is known that an r-in-oil type emulsion is obtained and used as a cosmetic.
【０００５】しかしながら、このような粘土鉱物を用い
た乳化物も界面活性剤を使用している。また、化粧品の
開発動向として現在肌に優しいマイルド性を追求してお
り、そのためによりよい界面活性剤の選択を主眼とし、
これでは界面活性剤の使用による欠点を完全に解消でき
ない。[0005] However, such emulsions using clay minerals also use surfactants. In addition, we are currently pursuing mildness that is gentle on the skin as a development trend of cosmetics, and for that purpose we focused on selecting better surfactants,
This cannot completely eliminate the disadvantages caused by the use of surfactants.
【０００６】そこで、本発明は、界面活性剤を用いず、
手荒れ、肌荒れ等をおこさない化粧品、洗剤等のための
乳化物用組成物および乳化物を提供することを目的とす
る。[0006] Therefore, the present invention provides a method using no surfactant.
An object of the present invention is to provide an emulsion composition and an emulsion for cosmetics, detergents, and the like, which do not cause rough hands and rough skin.
【０００７】[0007]
【課題を解決するための手段】そこで、本発明は、水と
粘土と親水性ポリマーとで乳化物用組成物を構成した。
この粘土を、水に分散させた後に凍結乾燥させたものと
することが好ましく、高速撹拌によって安定した乳化物
が得られる。また、この乳化物用組成物は、油を含んで
もよく、油を含んだ場合でも界面活性剤を用いることな
く高速撹拌によって安定した乳化物が得られる。Accordingly, the present invention provides an emulsion composition comprising water, clay and a hydrophilic polymer.
This clay is preferably dispersed in water and then freeze-dried, and a high-speed stirring provides a stable emulsion. Further, the composition for an emulsion may contain an oil. Even when the composition contains an oil, a stable emulsion can be obtained by high-speed stirring without using a surfactant.
【０００８】[0008]
【実施の形態】以下、実施の形態について説明する。Embodiments will be described below.
【０００９】本発明の乳化物用組成物は水、油、粘土お
よび親水性ポリマーからなっている。好ましくは、水６
０〜９９．９８重量％、油０〜３９．９重量％、粘土
０．０１〜２０重量％および親水性ポリマー０．０１〜
２０重量％であり、より好ましくは、水７０〜９９．７
重量％、油０．１〜１９．９重量％、粘土０．１〜２重
量％および親水性ポリマー０．１〜５重量％である。[0009] The emulsion composition of the present invention comprises water, oil, clay and a hydrophilic polymer. Preferably, water 6
0 to 99.98% by weight, oil 0 to 39.9% by weight, clay 0.01 to 20% by weight and hydrophilic polymer 0.01 to
20% by weight, more preferably 70 to 99.7 of water.
% By weight, 0.1-19.9% by weight of oil, 0.1-2% by weight of clay and 0.1-5% by weight of hydrophilic polymer.
【００１０】実用上、油汚れをとる洗剤のような用途に
は油を比較的多く添加せしめ、化粧品としての乳液向け
には、比較的油の少ない配合が選択される。In practice, a relatively large amount of oil is added to applications such as detergents for removing oily stains, and a relatively low amount of oil is selected for emulsions as cosmetics.
【００１１】上述の油は必ずしも必要でなく、油を全く
添加しない場合でも油汚れをとる作用は有している。な
お、油は４０％以上添加すると水と油が分離するという
欠点があり、粘土が全くないと乳化液は作ることができ
ず、２０％以上になると粘度が高くなりすぎ、均一な乳
化ができないという欠点がある。親水性ポリマーが全く
含まないと乳化液を作ることができず、２０％以上にな
ると粘度が高くなりすぎ、均一な乳化ができないという
欠点がある。The above-mentioned oil is not always necessary, and has an effect of removing oil stains even when no oil is added. When oil is added in an amount of 40% or more, there is a drawback that water and oil are separated, and an emulsion cannot be produced without clay at all, and when it is 20% or more, the viscosity becomes too high and uniform emulsification cannot be performed. There is a disadvantage that. If no hydrophilic polymer is contained, an emulsion cannot be prepared, and if it is 20% or more, the viscosity becomes too high and uniform emulsification cannot be performed.
【００１２】次に、各組成分について詳細に説明する。Next, each component will be described in detail.
【００１３】１．油 油としては、脂肪酸のグリセリンエステルから成る油
脂、長鎖脂肪酸、疎水性炭化水素等の油と総称されるも
のが全て使用できる。合成油、鉱物油、動物油、植物油
のいずれも用いられる。1. Oils All oils such as fats and oils composed of glycerin esters of fatty acids, long-chain fatty acids, and hydrophobic hydrocarbons can be used. Any of synthetic oil, mineral oil, animal oil, and vegetable oil is used.
【００１４】特に人間の肌に害の少ない、椿オイル、オ
リーブオイル、スクワランオイル、なたね油、大豆油、
ごま油、ひまわり油、コーン油、ひまし油、サフラワー
オイル等の天然油が好ましい。In particular, camellia oil, olive oil, squalane oil, rapeseed oil, soybean oil, which have little harm to human skin,
Natural oils such as sesame oil, sunflower oil, corn oil, castor oil and safflower oil are preferred.
【００１５】２．粘土 粘土としては、フィロシリケートに属する層状結晶を主
成分とする無機化合物が用いられ、例えばスメクタイ
ト、バーミキュライト、マイカ、クロライト、カオリナ
イト、ハロイサイト、クリソタイル、タルクなどが使用
される。中でも結晶層間に交換性陽イオンと水分子層を
有するスメクタイト、バーミキュライトが好ましく、実
用上はスメクタイトに属するモンモリロナイトを主成分
とするベントナイトが好ましい。そして、安全衛生性が
重視される用途向けには、日本薬局方基準に合格したベ
ントナイトを用いることが好ましい。2. Clay As the clay, an inorganic compound mainly composed of layered crystals belonging to phyllosilicate is used. For example, smectite, vermiculite, mica, chlorite, kaolinite, halloysite, chrysotile, talc and the like are used. Above all, smectite and vermiculite having an exchangeable cation and a water molecule layer between crystal layers are preferable, and in practical use, bentonite mainly composed of montmorillonite belonging to smectite is preferable. And, for uses where safety and health are important, it is preferable to use bentonite that has passed the Japanese Pharmacopoeia standards.
【００１６】これらの粘土を、いったん水に分散させた
後に凍結乾燥させたものとすると、油の保持力に優れ、
長期間経過後であっても水と油が分離しない乳化物を得
るのに適している。特に、０．１〜５重量％の粘土を水
に分散させた後に１０００Ｇ〜１５０００Ｇで遠心分離
し、沈殿せずに上清に分散している粘土を凍結乾燥して
得たものを用いると、長期の安定性に極めて優れ、また
色相の良好な乳化物が得られる。If these clays are once dispersed in water and then freeze-dried, they have excellent oil retaining power,
It is suitable for obtaining an emulsion in which water and oil do not separate even after a long period of time. In particular, when a clay obtained by dispersing 0.1 to 5% by weight of clay in water and then centrifuging at 1000 G to 15000 G and freeze-drying the clay dispersed in the supernatant without precipitation is used, An emulsion having excellent long-term stability and good hue can be obtained.
【００１７】粘土粒子の平均粒子径は０．０１μｍ〜５
ｍｍであり、好ましくは０．１〜５００μｍである。こ
れらの粘土を水、油、親水性ポリマーと混合して高速回
転で強撹拌すると、粘土は、通常は数μｍ以下の粒子径
に微細化される。The average particle diameter of the clay particles is 0.01 μm to 5 μm.
mm, and preferably 0.1 to 500 μm. When these clays are mixed with water, oil, and a hydrophilic polymer and vigorously stirred at high speed, the clays are usually finely divided to a particle size of several μm or less.
【００１８】更に、粘土としては上述の粘土にシリカ、
炭酸カルシウム、石英、長石、クリストバライト、酸化
チタン、酸化亜鉛、アパタイト等を０．１〜４０重量％
の範囲で含有した混合粘土であってもよい。Further, as the clay, silica is added to the above-mentioned clay,
0.1 to 40% by weight of calcium carbonate, quartz, feldspar, cristobalite, titanium oxide, zinc oxide, apatite, etc.
May be mixed clay contained in the range.
【００１９】３．親水性ポリマー 親水性ポリマーとして、天然物由来のデンプン、ヒドロ
キシエチルセルロース、カルボキシメチルセルロース、
アルギン酸、ヒアルロン酸、ポリグルタミン酸、キトサ
ン、リグニン、ポリリジン、絹フィブロイン、カルゲナ
ン、カゼイン、繊維素グリコール酸、コラーゲン、ゼラ
チンおよびこれらの金属塩、エステルのうちのいずれか
一つまたはそれらを組み合わせたものが用いられ、化学
合成によるポリビニルアルコール、ポリアクリルアミ
ド、ポリビニルピロリドン、ポリヒドロキシエチルアク
リレート、ポリビニルメチルエーテル、ポリアクリル
酸、ポリ（イソブチレン−マイレン酸）、ポリ（２−ア
クリルアミド−２−メチルプロパン−スルホン酸）、ポ
リ（アクロキシプロパンスルホン酸）、ポリビニルホス
ホン酸、ポリ（メタクリロイロキシエチル四級化アンモ
ニウムクロリド、ポリビニルピリジン、Ｎ−Ｎ−ジメチ
ル−Ｎ−（３−アクリルアミドプロピル）−Ｎ−（カル
ボキシメチル）アンモニウム、ポリエチレングリコー
ル、ポリジオキシソラン、ポリエチレンイミン、ポリ
（Ｎ−ビニルアセトアミド）およびこれらの金属塩、エ
ステルのうちのいずれか一つまたはそれらを組み合わせ
たものを用いることができる。3. Hydrophilic polymer As a hydrophilic polymer, starch derived from natural products, hydroxyethyl cellulose, carboxymethyl cellulose,
Alginic acid, hyaluronic acid, polyglutamic acid, chitosan, lignin, polylysine, silk fibroin, cargenan, casein, cellulose glycolic acid, collagen, gelatin and their metal salts, any one of these or a combination thereof Used, polyvinyl alcohol, polyacrylamide, polyvinylpyrrolidone, polyhydroxyethyl acrylate, polyvinyl methyl ether, polyacrylic acid, poly (isobutylene-malenic acid), poly (2-acrylamido-2-methylpropane-sulfonic acid) by chemical synthesis , Poly (acryloxypropanesulfonic acid), polyvinylphosphonic acid, poly (methacryloyloxyethyl quaternary ammonium chloride, polyvinylpyridine, N-N-dimethyl-N- (3-acrylic acid) Amidopropyl) -N- (carboxymethyl) ammonium, polyethylene glycol, polydioxysolane, polyethyleneimine, poly (N-vinylacetamide) and any one of these metal salts and esters, or a combination thereof. Can be used.
【００２０】特に、アルギン酸ナトリウム、ポリアクリ
ル酸系吸水性ポリマーなどの吸水能力を有するものが好
ましく、更に、天然物由来のアルギン酸ナトリウム等
は、安全衛生上および使用後の生分解性の点で特に好ま
しい。In particular, those having a water absorbing ability such as sodium alginate and a polyacrylic acid-based water-absorbing polymer are preferable. Further, sodium alginate derived from a natural product is particularly preferable in terms of safety and hygiene and biodegradability after use. preferable.
【００２１】また、プロナーゼ等のタンパク質分解酵素
で処理することにより精製したアルギン酸ナトリウム
は、色相が良好でカビが生えにくい乳化物を得るのに特
に適している。Further, sodium alginate purified by treating it with a proteolytic enzyme such as pronase is particularly suitable for obtaining an emulsion having a good hue and hardly producing mold.
【００２２】４．水 水としては、天然水、蒸留水、イオン交換水など各種の
ものを使用することができ、特に限定されない。特殊な
ケースとして海水を用いると、プリン状の乳化物が得ら
れる。4. Water As the water, various waters such as natural water, distilled water and ion-exchanged water can be used, and there is no particular limitation. When seawater is used as a special case, a purine-like emulsion is obtained.
【００２３】本発明の乳化用組成物には、上記の成分に
加えて、通常化粧品、食品、医薬品等で使用されている
他の成分、例えば、ビタミンＡ類、ビタミンＢ2 類、ビ
タミンＢ6 類、ビタミンＣ類、ビタミンＤ類、ビタミン
Ｅ類、ビタミンＰ、グリセリン等の保湿剤、パラジメチ
ルアミノ安息香酸アミル、２−ヒドロキシ−４−メトキ
シベンゾフェノン−５−スルホン酸ナトリウム等の紫外
線吸収剤、パラヒドロキシアニソール等の酸化防止剤、
エチルパラベン、ブチルパラベン等の防腐剤、グリチル
リチン酸誘導体、サリチル酸誘導体、ヒノキチオール、
アラントイン等の消炎剤、グルタチオン、ユキノシタ抽
出物等の美白剤、チタンイエロー、カーサミン、ベニバ
ナ赤等の色材、ポリエチレン、ナイロン等の樹脂粉末、
香料等を必要に応じて適宜配合することができる。The emulsion composition of the present invention, in addition to the above components, typically cosmetics, food, other ingredients used in pharmaceuticals, etc., for example, vitamin A, vitamin B 2, vitamin B 6 , Humectants such as vitamin Cs, vitamin Ds, vitamin Es, vitamin P, glycerin, ultraviolet absorbers such as amyl paradimethylaminobenzoate, sodium 2-hydroxy-4-methoxybenzophenone-5-sulfonate, Antioxidants such as parahydroxyanisole,
Preservatives such as ethylparaben and butylparaben, glycyrrhizic acid derivatives, salicylic acid derivatives, hinokitiol,
Anti-inflammatory agents such as allantoin, whitening agents such as glutathione, saxifrage extract, coloring materials such as titanium yellow, carsamine, safflower red, resin powders such as polyethylene and nylon,
Flavors and the like can be appropriately compounded as needed.
【００２４】次に、これら乳化物用組成物を乳化した乳
化物について説明する。Next, an emulsion obtained by emulsifying the composition for an emulsion will be described.
【００２５】前述の乳化物用組成物を容器内に注入し、
ミキサー撹拌、ポリトロン撹拌などの手段で配合物を高
速で強制撹拌すると容易に乳化し、そのまま放置しても
水と油等が分離することなく安定した乳化物を得ること
ができ、この乳化物に香料等を僅かに加えれば、化粧水
となるし、そのままでも液体洗剤となり得る。The above-mentioned composition for an emulsion is poured into a container,
The composition is easily emulsified by forcibly stirring the mixture at a high speed by means of mixer stirring, polytron stirring, etc., and a stable emulsion can be obtained without leaving water and oil etc. even if left as it is. If a small amount of fragrance or the like is added, it becomes a lotion, or even a liquid detergent as it is.
【００２６】[0026]
【実施例】次に、実施例について説明する。Next, an embodiment will be described.
【００２７】 （実施例１） 水 ３００ｇ スクワランオイル ０．９ｇ ベントナイト（日本薬局方基準合格品） ０．６ｇ アルギン酸 ３ｇ をミキサーで３分間撹拌後、ポリトロンで５分間撹拌し
て水と油が分離していない乳化物を得た。(Example 1) Water 300 g Squalane oil 0.9 g Bentonite (Japanese Pharmacopoeia standard approved product) 0.6 g Alginate 3 g was stirred for 3 minutes with a mixer, and then stirred for 5 minutes with a polytron to separate water and oil. A non-emulsified product was obtained.
【００２８】この乳化物を手の肌に塗ったところ、ベタ
ツキがなく、伸びがよく、浸透感がよく、臭いもなく、
保湿性があった。又、界面活性剤を含まないために、肌
が弱いアレルギー体質の人の肌に塗ってもアレルギーが
起こらなかった。When this emulsion was applied to the skin of hands, there was no stickiness, good elongation, good penetration, no odor,
There was moisture retention. In addition, allergy did not occur even when applied to the skin of a person with a weak allergic constitution, because it did not contain a surfactant.
【００２９】この乳化物を１１０℃、０．２ＭＰａの加
圧のオートクレーブで２５分間殺菌処理したが水と油の
分離は認められなかった。This emulsion was sterilized in an autoclave at 110 ° C. and a pressure of 0.2 MPa for 25 minutes, but no separation of water and oil was observed.
【００３０】この乳化物は全成分が天然物で構成され、
界面活性剤、防腐剤を含まず、化粧品などの乳液に極め
て適している。また、紫外線吸収効果もあり化粧水とし
て極めて有益である。In this emulsion, all components are composed of natural products,
Contains no surfactants or preservatives and is extremely suitable for emulsions such as cosmetics. It also has an ultraviolet absorbing effect and is extremely useful as a lotion.
【００３１】 （実施例２） 水 ３００ｇ 椿油 ０．９ｇ ベントナイト（日本薬局方基準合格品） ０．６ｇ アクリル酸系吸水性ポリマー（三菱化学（株）製アクアパールＩ２５０Ｈ） ０．６ｇ をミキサーで３分間撹拌後、ポリトロンで５分間撹拌し
て水と油が分離していない乳化物を得た。(Example 2) Water 300 g Camellia oil 0.9 g Bentonite (a product conforming to the Japanese Pharmacopoeia standard) 0.6 g Acrylic acid-based water-absorbing polymer (Aquapearl I250H manufactured by Mitsubishi Chemical Corporation) 0.6 g with a mixer 3 After stirring for 5 minutes, the mixture was stirred for 5 minutes with a polytron to obtain an emulsion in which water and oil were not separated.
【００３２】この乳化物を手の肌に塗ったところ、ベタ
ツキがなく、伸びがよく、浸透感がよく、臭いもなく、
保湿性があった。また、界面活性剤を含まないために肌
が弱いアレルギー体質の人の肌に塗ってもアレルギーが
起こらなかった。When this emulsion was applied to the skin of the hand, there was no stickiness, good elongation, good penetration, no odor,
There was moisture retention. In addition, no allergy occurred even when applied to the skin of a person with a weak allergic constitution because the skin did not contain a surfactant.
【００３３】この乳化物を１１０℃、０．２ＭＰａの加
圧のオートクレーブで２５分間殺菌処理したが水と油の
分離は認められなかった。This emulsion was sterilized in an autoclave at 110 ° C. and a pressure of 0.2 MPa for 25 minutes, but no separation of water and oil was observed.
【００３４】この乳化物は界面活性剤、防腐剤を含ま
ず、紫外線吸収効果もあり、化粧品などの乳液に極めて
適している。This emulsion does not contain surfactants and preservatives, has an ultraviolet absorbing effect, and is extremely suitable for emulsions such as cosmetics.
【００３５】 （実施例３） 蒸留水 １００ｇ プロナーゼ処理精製アルギン酸ナトリウム ０．５ｇ 日本薬局方基準合格のベントナイトを蒸留水に１重量％分散させた後に、１ ００００Ｇで遠心分離し、沈殿を除いた上清を凍結乾燥して得たベントナイト ０．５ｇ スクワランオイル １ｇ 保湿剤としてのグリセリン １ｇ をミキサーで３分間撹拌後、ポリトロンで５分間撹拌し
て水と油が分離していない乳化物を得た。(Example 3) Distilled water 100 g Pronase-treated purified sodium alginate 0.5 g Bentonite that passed the Japanese Pharmacopoeia standards was dispersed in distilled water at 1% by weight, and then centrifuged at 10,000 G to remove precipitates. 0.5 g of bentonite obtained by freeze-drying the syrup 0.5 g of squalane oil 1 g of glycerin 1 g as a humectant was stirred for 3 minutes with a mixer, and then stirred for 5 minutes with a polytron to obtain an emulsion in which water and oil were not separated.
【００３６】この乳化物は、４０℃で２ヶ月間放置して
も水と油が分離せず、化粧品などの乳液に極めて適して
いる。This emulsion does not separate water and oil even when left at 40 ° C. for 2 months, and is very suitable for emulsions such as cosmetics.
【００３７】この乳化物を手の肌に塗ったところ、ベタ
ツキがなく、伸びがよく、浸透感がよく、臭いもなく、
保湿性があった。又、界面活性剤を含まないために、肌
が弱いアレルギー体質の人の肌に塗ってもアレルギーが
起こらなかった。When this emulsion was applied to the skin of the hand, there was no stickiness, good elongation, good penetration, no odor,
There was moisture retention. In addition, allergy did not occur even when applied to the skin of a person with a weak allergic constitution, because it did not contain a surfactant.
【００３８】次に比較例について説明する。Next, a comparative example will be described.
【００３９】（比較例１）実施例１の配合からベントナ
イトを抜いた配合で実施例１と同じ条件で撹拌したが、
水と油が分離して均一な乳化物が得られなかった。 （比較例２）実施例１の配合からアルギン酸を抜いた配
合で実施例１と同じ条件で撹拌したが、水と油が分離し
て均一な乳化物が得られなかった。 （比較例３）ベントナイトを抜いた配合で実施例２と同
じ条件で撹拌したが水と油が分離して均一な乳化物が得
られなかった。(Comparative Example 1) A mixture obtained by removing bentonite from the mixture of Example 1 was stirred under the same conditions as in Example 1.
Water and oil separated and a uniform emulsion could not be obtained. (Comparative Example 2) Agitation was performed under the same conditions as in Example 1 except that alginic acid was omitted from the formulation of Example 1, but water and oil separated and a uniform emulsion could not be obtained. (Comparative Example 3) The mixture was stirred under the same conditions as in Example 2 except that bentonite was removed, but water and oil separated and a uniform emulsion could not be obtained.
【００４０】[0040]
【発明の効果】本発明は、以上のように構成したので、
界面活性剤を全く使用しない乳化用組成物および安定し
た乳化物が得られ、化粧品あるいは洗剤として使用した
ときに、肌荒れ、アレルギー等を全く起こさないという
効果を奏する。The present invention is configured as described above.
An emulsifying composition containing no surfactant and a stable emulsified product can be obtained, and when used as a cosmetic or a detergent, there is an effect that no roughening of the skin, no allergy or the like is caused.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｃ１１Ｄ 7/22 Ｃ１１Ｄ 7/22 ──────────────────────────────────────────────────続 き Continued on front page (51) Int.Cl. 6 Identification code FI C11D 7/22 C11D 7/22
Claims (11)
とを特徴とする乳化用組成物。1. An emulsifying composition comprising water, clay and a hydrophilic polymer.
燥させたものであることを特徴とする請求項１に記載の
乳化用組成物。2. The emulsifying composition according to claim 1, wherein the clay is dispersed in water and then freeze-dried.
または請求項２に記載の乳化用組成物。3. The method according to claim 1, wherein oil is added.
Or the composition for emulsification according to claim 2.
油は０〜３９．９重量％、前記粘土は０．０１〜２０重
量％、前記親水性ポリマーは０．０１〜２０重量％であ
ることを特徴とする請求項１乃至請求項３の何れかに記
載の乳化用組成物。4. The water is 60 to 99.98% by weight, the oil is 0 to 39.9% by weight, the clay is 0.01 to 20% by weight, and the hydrophilic polymer is 0.01 to 20% by weight. The composition for emulsification according to any one of claims 1 to 3, wherein
ランオイル、オリーブオイル、なたね油、大豆油、ごま
油、ひまし油、ひまわり油、コーン油、サフラワーオイ
ルであり、前記粘土はモンモリロナイトを主成分とする
ベントナイトであり、前記親水性ポリマーは、天然物由
来のデンプン、ヒドロキシエチルセルロース、カルボキ
シメチルセルロース、アルギン酸、ヒアルロン酸、ポリ
グルタミン酸、キトサン、リグニン、ポリリジン、絹フ
ィブロイン、カルゲナン、カゼイン、繊維素グリコール
酸、コラーゲン、ゼラチンおよびこれらの金属塩、エス
テルのうちいずれか一つ又はその組み合せであり、ある
いは化学合成によるポリビニルアルコール、ポリアクリ
ルアミド、ポリビニルピロリドン、ポリヒドロキシエチ
ルアクリレート、ポリビニルメチルエーテル、ポリアク
リル酸、ポリ（イソブチレン−マイレン酸）、ポリ（２
−アクリルアミド−２−メチルプロパン−スルホン
酸）、ポリ（アクロキシプロパンスルホン酸）、ポリビ
ニルホスホン酸、ポリ（メタクリロイロキシエチル四級
化アンモニウムクロリド、ポリビニルピリジン、Ｎ−Ｎ
−ジメチル−Ｎ−（３−アクリルアミドプロピル）−Ｎ
−（カルボキシメチル）アンモニウム、ポリエチレング
リコール、ポリジオキシソラン、ポリエチレンイミン、
ポリ（Ｎ−ビニルアセトアミド）およびこれらの金属
塩、エステルのうちいずれか一つ又はその組み合せであ
ることを特徴とする請求項１乃至請求項４の何れかに記
載の乳化用組成物。5. The oil is a natural oil such as camellia oil, squalane oil, olive oil, rapeseed oil, soybean oil, sesame oil, castor oil, sunflower oil, corn oil, and safflower oil, and the clay contains montmorillonite as a main component. And the hydrophilic polymer is starch, hydroxyethylcellulose, carboxymethylcellulose, alginic acid, hyaluronic acid, polyglutamic acid, chitosan, lignin, polylysine, silk fibroin, cargenan, casein, cellulose glycolic acid, collagen derived from natural products. , Gelatin and their metal salts and esters, or any combination thereof, or chemically synthesized polyvinyl alcohol, polyacrylamide, polyvinylpyrrolidone, polyhydroxyethyl acrylate, polyhydroxyethyl acrylate, Rivinyl methyl ether, polyacrylic acid, poly (isobutylene-maleic acid), poly (2
-Acrylamide-2-methylpropane-sulfonic acid), poly (acryloxypropanesulfonic acid), polyvinylphosphonic acid, poly (methacryloyloxyethyl quaternary ammonium chloride, polyvinylpyridine, N-N
-Dimethyl-N- (3-acrylamidopropyl) -N
-(Carboxymethyl) ammonium, polyethylene glycol, polydioxisolan, polyethylene imine,
The emulsifying composition according to any one of claims 1 to 4, wherein the composition is any one of poly (N-vinylacetamide), a metal salt thereof, and an ester thereof, or a combination thereof.
るアルギン酸ナトリウム、ポリアクリル酸系吸水性ポリ
マーであることを特徴とする請求項１乃至請求項５の何
れかに記載の乳化用組成物。6. The emulsifying composition according to claim 1, wherein the hydrophilic polymer is a sodium alginate or a polyacrylic acid-based water-absorbing polymer having a water absorbing ability.
撹拌して生成したことを特徴とする乳化物。7. An emulsion obtained by stirring the composition for emulsification of claim 1 in a container at a high speed.
撹拌して生成したことを特徴とする乳化物。8. An emulsion produced by stirring the composition for emulsification according to claim 2 in a container at a high speed.
撹拌して生成したことを特徴とする乳化物。9. An emulsion produced by stirring the composition for emulsification according to claim 3 in a container at a high speed.
速撹拌して生成したことを特徴とする乳化物。10. An emulsion produced by stirring the composition for emulsification according to claim 4 in a container at a high speed.
速撹拌して生成したことを特徴とする乳化物。11. An emulsion produced by stirring the composition for emulsification according to claim 5 in a container at a high speed.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10009226A JPH11188253A (en) | 1997-10-22 | 1998-01-21 | Composition for emulsified matter and emulsified matter |
| PCT/JP1998/004771 WO1999020386A1 (en) | 1997-10-22 | 1998-10-21 | Emulsifying composition and emulsions |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9-290037 | 1997-10-22 | ||
| JP29003797 | 1997-10-22 | ||
| JP10009226A JPH11188253A (en) | 1997-10-22 | 1998-01-21 | Composition for emulsified matter and emulsified matter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11188253A true JPH11188253A (en) | 1999-07-13 |
Family
ID=26343905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10009226A Pending JPH11188253A (en) | 1997-10-22 | 1998-01-21 | Composition for emulsified matter and emulsified matter |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH11188253A (en) |
| WO (1) | WO1999020386A1 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000016941A (en) * | 1998-06-26 | 2000-01-18 | Lion Corp | Prophylatic against pollinosis |
| JP2001206816A (en) * | 1999-11-19 | 2001-07-31 | Frontier:Kk | Milky lotion having skin-softening property and antimicrobial activity, cosmetic preparation and skin- cleansing article |
| JP2003146865A (en) * | 2001-09-07 | 2003-05-21 | Basf Ag | Oil/water-type system containing stabilizer and amino- substituted hydroxybenzophenone and containing little or no emulsifier |
| KR101167494B1 (en) | 2010-08-20 | 2012-07-20 | 곽한무 | A method of an emulsifier by a sunflower |
| US8608991B2 (en) | 2009-06-11 | 2013-12-17 | Case Western Reserve University | Porous material having controlled voids and method of making the same |
| US8822558B2 (en) | 2009-06-11 | 2014-09-02 | Case Western Reserve University | Low density hydrophobic material and method of making the same |
| US8916638B2 (en) * | 2006-03-02 | 2014-12-23 | Case Western Reserve University | Clay aerogel-based polymer composites, materials and methods |
| CN110559210A (en) * | 2019-10-23 | 2019-12-13 | 江南大学 | Preparation method of montmorillonite and sodium alginate synergistically stabilized emulsion |
| KR102484509B1 (en) * | 2022-06-23 | 2023-01-04 | (주) 닥터코스텍 | Manufacturing method of water-in-oil cosmetic composition with less skin irritation |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX253435B (en) | 2001-02-05 | 2008-01-16 | Amcol International Corp | Multifunctional particulate additive for personal care and cosmetic compositions, and the process of making the same. |
| CN115414262B (en) * | 2022-07-19 | 2023-09-22 | 江苏诺兴生物科技有限公司 | Epsilon-polylysine Pickering emulsion and preparation method and application thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02169024A (en) * | 1988-12-22 | 1990-06-29 | Tosoh Corp | Emulsifying method for fat/oil |
| JPH0884921A (en) * | 1994-09-16 | 1996-04-02 | Mikimoto Pharmaceut Co Ltd | Raw material for o/w-type emulsion |
| JPH1045532A (en) * | 1996-08-01 | 1998-02-17 | Shiseido Co Ltd | Message cosmetic |
-
1998
- 1998-01-21 JP JP10009226A patent/JPH11188253A/en active Pending
- 1998-10-21 WO PCT/JP1998/004771 patent/WO1999020386A1/en active Application Filing
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000016941A (en) * | 1998-06-26 | 2000-01-18 | Lion Corp | Prophylatic against pollinosis |
| JP2001206816A (en) * | 1999-11-19 | 2001-07-31 | Frontier:Kk | Milky lotion having skin-softening property and antimicrobial activity, cosmetic preparation and skin- cleansing article |
| JP2003146865A (en) * | 2001-09-07 | 2003-05-21 | Basf Ag | Oil/water-type system containing stabilizer and amino- substituted hydroxybenzophenone and containing little or no emulsifier |
| US8916638B2 (en) * | 2006-03-02 | 2014-12-23 | Case Western Reserve University | Clay aerogel-based polymer composites, materials and methods |
| US8608991B2 (en) | 2009-06-11 | 2013-12-17 | Case Western Reserve University | Porous material having controlled voids and method of making the same |
| US8637582B2 (en) | 2009-06-11 | 2014-01-28 | Case Western Reserve University | Crosslinked polymer aerogels, polymer aerogel composites and methods for preparing the same |
| US8822558B2 (en) | 2009-06-11 | 2014-09-02 | Case Western Reserve University | Low density hydrophobic material and method of making the same |
| US8845937B2 (en) | 2009-06-11 | 2014-09-30 | Case Western Reserve University | Porous material having anisotropic structure and method of making the same |
| KR101167494B1 (en) | 2010-08-20 | 2012-07-20 | 곽한무 | A method of an emulsifier by a sunflower |
| CN110559210A (en) * | 2019-10-23 | 2019-12-13 | 江南大学 | Preparation method of montmorillonite and sodium alginate synergistically stabilized emulsion |
| KR102484509B1 (en) * | 2022-06-23 | 2023-01-04 | (주) 닥터코스텍 | Manufacturing method of water-in-oil cosmetic composition with less skin irritation |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999020386A1 (en) | 1999-04-29 |
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