KR102484509B1 - Manufacturing method of water-in-oil cosmetic composition with less skin irritation - Google Patents
Manufacturing method of water-in-oil cosmetic composition with less skin irritation Download PDFInfo
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- KR102484509B1 KR102484509B1 KR1020220077117A KR20220077117A KR102484509B1 KR 102484509 B1 KR102484509 B1 KR 102484509B1 KR 1020220077117 A KR1020220077117 A KR 1020220077117A KR 20220077117 A KR20220077117 A KR 20220077117A KR 102484509 B1 KR102484509 B1 KR 102484509B1
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- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 43
- 239000002537 cosmetic Substances 0.000 title claims abstract description 40
- 206010040880 Skin irritation Diseases 0.000 title claims abstract description 29
- 230000036556 skin irritation Effects 0.000 title claims abstract description 29
- 231100000475 skin irritation Toxicity 0.000 title claims abstract description 29
- 239000012071 phase Substances 0.000 claims abstract description 62
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000049 pigment Substances 0.000 claims abstract description 27
- 239000008346 aqueous phase Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims description 35
- 150000001875 compounds Chemical class 0.000 claims description 31
- 239000001993 wax Substances 0.000 claims description 18
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 9
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 claims description 8
- 239000000440 bentonite Substances 0.000 claims description 8
- 229910000278 bentonite Inorganic materials 0.000 claims description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 230000003020 moisturizing effect Effects 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims description 5
- FGUZFFWTBWJBIL-XWVZOOPGSA-N [(1r)-1-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](O)[C@H]1O FGUZFFWTBWJBIL-XWVZOOPGSA-N 0.000 claims description 4
- XJFGDLJQUJQUEI-UHFFFAOYSA-N dodecyl decanoate dodecyl octanoate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC.CCCCCCCCCCCCOC(=O)CCCCCCCCC XJFGDLJQUJQUEI-UHFFFAOYSA-N 0.000 claims description 4
- 229940032044 quaternium-18 Drugs 0.000 claims description 4
- 229940116351 sebacate Drugs 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims description 4
- -1 sorbitan compound Chemical class 0.000 claims description 4
- 229940057429 sorbitan isostearate Drugs 0.000 claims description 4
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 claims description 3
- FVKRIDSRWFEQME-UHFFFAOYSA-N 3-methylbutyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCC(C)C FVKRIDSRWFEQME-UHFFFAOYSA-N 0.000 claims description 3
- RETXUWFOZKDPPJ-UHFFFAOYSA-N 4-hydroxybutyl octanoate Chemical compound CCCCCCCC(=O)OCCCCO RETXUWFOZKDPPJ-UHFFFAOYSA-N 0.000 claims description 3
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 3
- 235000013871 bee wax Nutrition 0.000 claims description 3
- 239000012166 beeswax Substances 0.000 claims description 3
- 239000004204 candelilla wax Substances 0.000 claims description 3
- 235000013868 candelilla wax Nutrition 0.000 claims description 3
- 229940073532 candelilla wax Drugs 0.000 claims description 3
- 239000004203 carnauba wax Substances 0.000 claims description 3
- 235000013869 carnauba wax Nutrition 0.000 claims description 3
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 3
- 229910000271 hectorite Inorganic materials 0.000 claims description 3
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims description 3
- 229940078565 isoamyl laurate Drugs 0.000 claims description 3
- 239000004200 microcrystalline wax Substances 0.000 claims description 3
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 3
- 229940078812 myristyl myristate Drugs 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229940105297 polyglyceryl-2 diisostearate Drugs 0.000 claims description 3
- 229950004959 sorbitan oleate Drugs 0.000 claims description 3
- 229960005078 sorbitan sesquioleate Drugs 0.000 claims description 3
- 229950011392 sorbitan stearate Drugs 0.000 claims description 3
- 229940070720 stearalkonium Drugs 0.000 claims description 3
- 125000005502 stearalkonium group Chemical group 0.000 claims description 3
- ABTZKZVAJTXGNN-UHFFFAOYSA-N stearyl heptanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCC ABTZKZVAJTXGNN-UHFFFAOYSA-N 0.000 claims description 3
- 229940098758 stearyl heptanoate Drugs 0.000 claims description 3
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229940093528 cetearyl ethylhexanoate Drugs 0.000 claims description 2
- 229940048845 polyglyceryl-3 diisostearate Drugs 0.000 claims description 2
- 229940100518 polyglyceryl-4 isostearate Drugs 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 claims 1
- 229940066675 ricinoleate Drugs 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 abstract description 15
- 230000002776 aggregation Effects 0.000 abstract description 10
- 239000004909 Moisturizer Substances 0.000 abstract description 7
- 230000001333 moisturizer Effects 0.000 abstract description 7
- 230000003993 interaction Effects 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 3
- 238000005054 agglomeration Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 66
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000004220 aggregation Methods 0.000 description 8
- 210000002374 sebum Anatomy 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- 229940101631 quaternium-18 hectorite Drugs 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 229940102552 disteardimonium hectorite Drugs 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 244000062730 Melissa officinalis Species 0.000 description 1
- 229920000426 Microplastic Polymers 0.000 description 1
- 231100000766 Possible carcinogen Toxicity 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 231100000693 bioaccumulation Toxicity 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- 230000007688 immunotoxicity Effects 0.000 description 1
- 231100000386 immunotoxicity Toxicity 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
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- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
본 발명은 피부자극이 적은 유중수형 화장료 조성물의 제조방법에 관한 것으로, 더욱 상세하게는 실리콘이나 피이지 성분이 사용되지 않아 피부자극이 적고 상호작용력이 우수한 유화제 성분이 적용되어 적은 양으로도 안정한 구조를 나타내며 안료의 응집현상이 억제될 뿐만 아니라, 수분을 배출하는 오일성분이 함유되어 끈적임이 적고 매끄러운 사용감을 나타내는 피부자극이 적은 유중수형 화장료 조성물의 제조방법에 관한 것이다.The present invention relates to a method for producing a water-in-oil cosmetic composition with little skin irritation, and more particularly, since silicone or sebum components are not used, an emulsifier component with low skin irritation and excellent interaction power is applied, so that it has a stable structure even in a small amount. It relates to a method for producing a water-in-oil cosmetic composition that not only inhibits pigment aggregation but also contains an oil component that discharges moisture and thus has less stickiness and less skin irritation that exhibits a smooth feeling of use.
유중수형 에멀전은 피이지(PEG)계 계면활성제 또는 소르비탄계 계면활성제를 주로 함유하는데, 피이지계 계면활성제는 끈적임이 적고 적은 양으로도 유화가 가능하기 때문에 많이 사용되어 왔다. 그러나 피이지를 합성하는 과정에서 1,4-다이옥산과 미반응의 에틸렌옥사이드가 잔류하게 된다.Water-in-oil emulsions mainly contain a PEG-based surfactant or a sorbitan-based surfactant, and PEG-based surfactants have been widely used because they are less sticky and can be emulsified with a small amount. However, in the process of synthesizing PEG, 1,4-dioxane and unreacted ethylene oxide remain.
1,4-다이옥산은 화합물상에서 제거하기가 매우 어렵다. 1,4-다이옥산은 스킨딥스코어가 8이고, International Agency for Research on Cancer에서 발암 가능물질로 분류되었다. 또한 이는 알러지나 면역 독성을 일으킬 수 있다.1,4-dioxane is very difficult to remove from the compound phase. 1,4-dioxane has a Skin Deep Score of 8 and has been classified as a possible carcinogen by the International Agency for Research on Cancer. It can also cause allergy or immunotoxicity.
또한, 에틸렌옥사이드(Ethylene Oxide)는 International Agency for Research on Cancer에서 발암물질로 분류하였고, 스킨딥스코어가 가장 높은 수치인 10이다.In addition, ethylene oxide was classified as a carcinogen by the International Agency for Research on Cancer, and the Skin Deep Score was 10, the highest value.
또한 유중수형 에멀전은 종래에 실리콘계 유화제가 주류를 이루고 있었는데, 실리콘은 끈적임이 적고 특히 선제품이나 파운데이션 등에서 발수력이 높아 오래 지속해줄 수 있는 장점이 있고, 적은 유화제 함량(3~6%)로도 안정화 할 수 있기 때문에 많이 사용되었다.In addition, conventionally, silicone-based emulsifiers have been the mainstream of water-in-oil emulsions, but silicones are less sticky and have high water repellency, especially in pre-products and foundations, so they can last for a long time, and are stable even with a small amount of emulsifier (3-6%). It is used a lot because it can be done.
그러나 EU에서는 지난 2020년 2월 1일부터 씻어내는 화장품 내 실리콘 성분의 일종인 D4(Octamethylcyclotetrasiloxane)와 D5(decamethylcyclopentasiloxane)의 사용제한을 발표하였다. 이는 지난 2015년 영국의 법령을 수용한 것으로 지속성, 생물축적성 및 유해성을 고려해 수질환경을 보호하기 위해 그 농도를 0.1%로 제한한다.However, from February 1, 2020, the EU announced restrictions on the use of D4 (Octamethylcyclotetrasiloxane) and D5 (decamethylcyclopentasiloxane), which are types of silicone ingredients in wash-off cosmetics. This was accepted by the British law in 2015, and the concentration is limited to 0.1% to protect the water environment in consideration of sustainability, bioaccumulation and harmfulness.
실리콘 중 일부는 미세플라스틱으로 환경에 잔류하고 생태 독성을 띈다고 한다. 그로 인해 유럽에서는 점차 실리콘의 사용을 배제하는 추세이다. 그러나 그 외에 폴리글리세릴계 유화제는 유화력이 떨어지기 때문에 고농도를 사용했을 때만 안정도를 확보할 수 있어 실리콘계 및 피이지계 유화제와 같은 함량으로도 안정도를 확보하는 것이 필요하며, 또한 실리콘과 같은 사용감을 갖는 유화제 개발이 요구되고 있다.Some of the silicon is said to remain in the environment as microplastics and is ecologically toxic. As a result, Europe is gradually excluding the use of silicone. However, other polyglyceryl-based emulsifiers have poor emulsifying power, so stability can be secured only when high concentrations are used, so it is necessary to secure stability with the same content as silicone-based and sebum-based emulsifiers, and also emulsifiers with a feeling of use like silicone development is required.
따라서, 기존에 사용되었던 피이지계 계면활성제 또는 실리콘계 유용성 계면활성제를 대체할 수 있는 끈적임이 적으면서 자극이 없는 유화제가 함유된 화장료 조성물의 개발이 요구되고 있다.Therefore, there is a demand for the development of a cosmetic composition containing an emulsifier that is less sticky and non-irritating, which can replace previously used sebum-based surfactants or silicone-based oil-soluble surfactants.
본 발명의 목적은 실리콘이나 피이지 성분이 사용되지 않아 피부자극이 적고 상호작용력이 우수한 유화제 성분이 적용되어 적은 양으로도 안정한 구조를 나타내며 안료의 응집현상이 억제될 뿐만 아니라, 수분을 배출하는 오일성분이 함유되어 끈적임이 적고 매끄러운 사용감을 나타내는 피부자극이 적은 유중수형 화장료 조성물의 제조방법을 제공하는 것이다.The purpose of the present invention is to show a stable structure even in a small amount by applying an emulsifier component with low skin irritation and excellent interaction power because silicone or PEG components are not used, suppressing pigment aggregation, and oil that discharges moisture. It is to provide a method for producing a water-in-oil cosmetic composition with less stickiness and less skin irritation that exhibits a smooth feeling of use.
본 발명의 목적은 유화제를 제조하는 유화제제조단계, 상기 유화제제조단계를 통해 제조된 유화제, 안료 및, 왁스를 혼합하여 유상부를 제조하는 유상부제조단계, 물 및 보습제를 혼합하여 수상부를 제조하는 수상부제조단계 및 상기 유상부제조단계를 통해 제조된 유상부에 상기 수상부제조단계를 통해 제조된 수상부를 혼합하는 원료혼합단계로 이루어지며, 상기 유화제는 오가노클레이 화합물, 폴리글리세릴계 화합물, 소르비탄계 화합물 및 극성오일로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.An object of the present invention is to prepare an emulsifier, prepare an oil phase by mixing the emulsifier, pigment, and wax prepared through the emulsifier preparation step, prepare an oil phase, and prepare an aqueous phase by mixing water and a moisturizer to prepare an aqueous phase and a raw material mixing step of mixing the water phase part prepared through the water phase part preparation step with the oil phase part prepared through the oil phase part preparation step, wherein the emulsifier is an organoclay compound, a polyglyceryl compound, a sorbitan compound and a polar It shall consist of one or more selected from the group consisting of oil.
본 발명의 바람직한 특징에 따르면, 상기 유화제는 오가노클레이 화합물 100 중량부, 폴리글리세릴계 화합물 250 내지 300 중량부, 소르비탄계 화합물 35 내지 45 중량부 및 극성오일 100 내지 200 중량부로 이루어지는 것으로 한다.According to a preferred feature of the present invention, the emulsifier is composed of 100 parts by weight of an organoclay compound, 250 to 300 parts by weight of a polyglyceryl compound, 35 to 45 parts by weight of a sorbitan compound, and 100 to 200 parts by weight of a polar oil.
본 발명의 더 바람직한 특징에 따르면, 상기 유화제는 오가노클레이 화합물 100 중량부, 폴리글리세릴계 화합물 280 중량부, 소르비탄계 화합물 40 중량부 및 극성오일 140 중량부로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the emulsifier is composed of 100 parts by weight of an organoclay compound, 280 parts by weight of a polyglyceryl-based compound, 40 parts by weight of a sorbitan-based compound, and 140 parts by weight of a polar oil.
본 발명의 더욱 바람직한 특징에 따르면, 상기 오가노클레이 화합물은 쿼터늄-18 벤토나이트, 쿼터늄-90 벤토나이트 , 스테아랄코늄 벤토라이트, 쿼터늄-90 몬모닐로라이트, 쿼터늄-90 세피올나이트, 다이스테아다이모늄 헥토라이트 및 쿼터늄-18 헥토라이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the organoclay compound is quaternium-18 bentonite, quaternium-90 bentonite, stearalkonium bentolite, quaternium-90 montmonilolite, quaternium-90 sepiolite, It shall consist of at least one selected from the group consisting of disteadymonium hectorite and quaternium-18 hectorite.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 폴리글리세릴계 화합물은 폴리글리세릴-2 아이소스테아레이트, 폴리글리세릴-6 폴리리시놀리에이트, 폴리글리세릴-3 다이아이소스테아레이트, 폴리글리세릴-4 아이소스테아레이트, 폴리글리세릴-3 폴리리시놀리에이트, 폴리글리세릴-2 다이아이소스테아레이트 및 폴리글리세릴-4 다이아이소스테아레이트/폴리하이드록시 스테아레이트/세바케이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the polyglyceryl-based compound is polyglyceryl-2 isostearate, polyglyceryl-6 polyricinoleate, polyglyceryl-3 diisostearate, polyglyceryl-4 at least one selected from the group consisting of isostearate, polyglyceryl-3 polyricinoleate, polyglyceryl-2 diisostearate and polyglyceryl-4 diisostearate/polyhydroxy stearate/sebacate. to be made
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 소르비탄계 화합물은 소르비탄 아이소스테아레이트, 소르비탄 세스퀴올레이트, 소르비탄 올레이트 및 소르비탄 스테아레이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a further preferred feature of the present invention, the sorbitan-based compound is composed of at least one selected from the group consisting of sorbitan isostearate, sorbitan sesquioleate, sorbitan oleate and sorbitan stearate.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 극성오일은 코코-카프릴레이트/카프레이트, 미리스틸미리스테이트, 부틸렌글라이콜 카프릴레이트/카프레이트, 아이소아밀라우레이트, 세테아릴에칠헥사노에이트 및 스테아릴헵타노에이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the polar oil is coco-caprylate/caprate, myristyl myristate, butylene glycol caprylate/caprate, isoamyllaurate, cetearylethylhexane It is made of at least one selected from the group consisting of noate and stearylheptanoate.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 유상부제조단계는 유화제 100 중량부, 안료 100 내지 400 중량부 및 왁스 20 내지 200 중량부를 혼합하여 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the oil phase preparation step is made by mixing 100 parts by weight of an emulsifier, 100 to 400 parts by weight of a pigment, and 20 to 200 parts by weight of a wax.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 안료는 산화철, 티타늄다이옥사이드, 징크옥사이드, 세리사이트, 마이카, 탈크 및 카올린으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the pigment is composed of at least one selected from the group consisting of iron oxide, titanium dioxide, zinc oxide, sericite, mica, talc and kaolin.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 왁스는 오조케라이트, 칸데릴라납, 세레신, 마이크로크리스탈린납, 파라핀, 카나우바왁스, 합성왁스 및 비즈왁스로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the wax is made of at least one selected from the group consisting of ozokerite, candelilla wax, ceresin, microcrystalline wax, paraffin, carnauba wax, synthetic wax, and beeswax.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 원료혼합단계는 상기 유상부제조단계를 통해 제조된 유상부 4 내지 40 중량%에 상기 수상부제조단계를 통해 제조된 수상부 60 내지 96 중량%를 혼합하여 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the raw material mixing step is made by mixing 60 to 96% by weight of the aqueous phase part prepared through the phase part manufacturing step with 4 to 40% by weight of the oil phase part produced through the oil phase part manufacturing step. do.
본 발명에 따른 피부자극이 적은 유중수형 화장료 조성물의 제조방법은 실리콘이나 피이지 성분이 사용되지 않아 피부자극이 적고 상호작용력이 우수한 유화제 성분이 적용되어 적은 양으로도 안정한 구조를 나타내며 안료의 응집현상이 억제될 뿐만 아니라, 수분을 배출하는 오일성분이 함유되어 끈적임이 적고 매끄러운 사용감을 나타내는 유중수형 화장료 조성물을 제공하는 탁월한 효과를 나타낸다.The manufacturing method of the water-in-oil cosmetic composition with little skin irritation according to the present invention does not use silicone or sebum components, so it has a stable structure even with a small amount and the aggregation of pigments by applying emulsifier components with low skin irritation and excellent interaction power In addition to this, it shows an excellent effect of providing a water-in-oil cosmetic composition that contains an oil component that discharges moisture and exhibits a smooth feeling of use with less stickiness.
도 1은 본 발명에 따른 피부자극이 적은 유중수형 화장료 조성물의 제조방법을 나타낸 순서도이다.1 is a flow chart showing a method for producing a water-in-oil cosmetic composition with less skin irritation according to the present invention.
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.Hereinafter, a preferred embodiment of the present invention and the physical properties of each component will be described in detail, but this is to be explained in detail so that a person having ordinary knowledge in the art to which the present invention belongs can easily practice the invention, This is not meant to limit the technical spirit and scope of the present invention.
본 발명에 따른 피부자극이 적은 유중수형 화장료 조성물의 제조방법은 유화제를 제조하는 유화제제조단계(S101), 상기 유화제제조단계(S101)를 통해 제조된 유화제, 안료 및, 왁스를 혼합하여 유상부를 제조하는 유상부제조단계(S103), 물 및 보습제를 혼합하여 수상부를 제조하는 수상부제조단계(S103-1) 및 상기 유상부제조단계(S103)를 통해 제조된 유상부에 상기 수상부제조단계(S103-1)를 통해 제조된 수상부를 혼합하는 원료혼합단계(S105)로 이루어진다.The method for producing a water-in-oil cosmetic composition with less skin irritation according to the present invention comprises an emulsifier preparation step (S101) of preparing an emulsifier, mixing the emulsifier, pigment, and wax prepared through the emulsifier preparation step (S101) to prepare an oil phase part. The oil phase part manufacturing step (S103), the water phase part manufacturing step (S103-1) of preparing the water phase part by mixing water and a moisturizer, and the oil phase part manufacturing step (S103-1) in the oil phase part prepared through the oil phase part manufacturing step (S103) It consists of a raw material mixing step (S105) of mixing the water phase prepared through.
상기 유화제제조단계(S101)는 오가노클레이 화합물, 폴리글리세릴계 화합물, 소르비탄계 화합물 및 극성오일로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는데, 오가노클레이 화합물 100 중량부, 폴리글리세릴계 화합물 250 내지 300 중량부, 소르비탄계 화합물 35 내지 45 중량부 및 극성오일 100 내지 200 중량부로 이루어지는 것이 바람직하며, 오가노클레이 화합물 100 중량부, 폴리글리세릴계 화합물 280 중량부, 소르비탄계 화합물 40 중량부 및 극성오일 140 중량부로 이루어지는 것이 가장 바람직하다.The emulsifier preparation step (S101) is composed of at least one selected from the group consisting of organoclay compounds, polyglyceryl compounds, sorbitan compounds, and polar oils, 100 parts by weight of organoclay compounds, 250 to 250 parts by weight of polyglyceryl compounds 300 parts by weight, preferably composed of 35 to 45 parts by weight of a sorbitan-based compound and 100 to 200 parts by weight of a polar oil, 100 parts by weight of an organoclay compound, 280 parts by weight of a polyglyceryl-based compound, 40 parts by weight of a sorbitan-based compound and It is most preferably composed of 140 parts by weight of polar oil.
상기의 성분으로 이루어지는 유화제는 4급암모늄계 계면활성제로 치환 합성하여 제조된 오가노클레이와 폴리글리세릴계 화합물, 소르비탄계 화합물 및 극성 오일 등이 함유되며, 실리콘과 피이지가 사용되지 않아 저자극성을 나타내면서도 적은 양으로도 높은 유화력을 나타낸다.The emulsifier consisting of the above components contains organoclay prepared by substitution synthesis with a quaternary ammonium-based surfactant, polyglyceryl-based compounds, sorbitan-based compounds, and polar oils, and is hypoallergenic as silicone and sebum are not used. while exhibiting high emulsifying power even with a small amount.
이때, 상기 오가노클레이 화합물은 쿼터늄-18 벤토나이트(Quaternium-18 Bentonite), 쿼터늄-90 벤토나이트(Quaternium-90 Bentonite), 스테아랄코늄 벤토라이트(Stearalkonium Bentonite), 쿼터늄-90 몬모닐로라이트(Quaternium-90 Montmorillonite), 쿼터늄-90 세피올나이트(Quaternium-90 Seplolite) 다이스테아다이모늄 헥토라이트(Disteardimonium Hectorite) 및 쿼터늄-18 헥토라이트(Quaternium-18 Hectorite)로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.At this time, the organoclay compound is Quaternium-18 Bentonite, Quaternium-90 Bentonite, Stearalkonium Bentonite, Quaternium-90 Montmonilolite (Quaternium-90 Montmorillonite), Quaternium-90 Sepolite (Quaternium-90 Seplolite) Disteardimonium Hectorite (Disteardimonium Hectorite) and Quaternium-18 Hectorite (Quaternium-18 Hectorite) It is preferable to consist of the above.
또한, 상기 폴리글리세릴계 화합물은 폴리글리세릴-2 아이소스테아레이트(Polyglyceryl-2 Isostearate)(HLB수치 5.5), 폴리글리세릴-6 폴리리시놀리에이트(Polyglyceryl-6 Polyricinoleate)(HLB수치 7.0), 폴리글리세릴-3 다이아이소스테아레이트(Polyglyceryl-3 Diisostearate)(HLB수치 5.0), 폴리글리세릴-4 아이소스테아레이트(Polyglyceryl-4 Isostearate)(HLB수치 5.0), 폴리글리세릴-3 폴리리시놀리에이트(Polyglyceryl-3 Polyricinoleate)(HLB수치 4.0), 폴리글리세릴-2 다이아이소스테아레이트(Polyglyceryl-2 Diisostearate)(HLB수치 4.0) 및 폴리글리세릴-4 다이아이소스테아레이트/폴리하이드록시 스테아레이트/세바케이트(Polyglyceryl-4 diisostearate / polyhydroxystearate / sebacate)(HLB수치5.0)로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.In addition, the polyglyceryl-based compounds are polyglyceryl-2 isostearate (HLB value 5.5), polyglyceryl-6 polyricinoleate (HLB value 7.0), polyglyceryl-6 polyricinoleate (HLB value 7.0), Glyceryl-3 Diisostearate (HLB value 5.0), Polyglyceryl-4 Isostearate (HLB value 5.0), Polyglyceryl-3 polyricinoleate ( Polyglyceryl-3 Polyricinoleate (HLB value 4.0), Polyglyceryl-2 Diisostearate (HLB value 4.0) and Polyglyceryl-4 Diisostearate/Polyhydroxy Stearate/Sebacate It is preferably composed of at least one selected from the group consisting of (Polyglyceryl-4 diisostearate / polyhydroxystearate / sebacate) (HLB value 5.0).
또한, 상기 소르비탄계 화합물은 소르비탄 아이소스테아레이트(Sorbitan Isostearate)(HLB수치 4.7), 소르비탄 세스퀴올레이트(Sorbitan Sesquioleate)(HLB수치 3.7), 소르비탄 올레이트(Sorbitan Oleate)(HLB수치 4.3) 및 소르비탄 스테아레이트(Sorbitan Stearate)(HLB수치 4.7)로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.In addition, the sorbitan-based compound is sorbitan isostearate (HLB value 4.7), sorbitan sesquioleate (HLB value 3.7), sorbitan oleate (HLB value 4.3) ) and sorbitan stearate (HLB value 4.7) is preferably made of at least one selected from the group consisting of.
또한, 상기 극성오일은 코코-카프릴레이트/카프레이트, 미리스틸미리스테이트, 부틸렌글라이콜 카프릴레이트/카프레이트, 아이소아밀라우레이트, 세테아릴에칠헥사노에이트 및 스테아릴헵타노에이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.In addition, the polar oil is coco-caprylate/caprate, myristyl myristate, butylene glycol caprylate/caprate, isoamyllaurate, cetearylethylhexanoate and stearylheptanoate It is preferably made of one or more selected from the group consisting of.
상기 유상부제조단계(S103)는 상기 유화제제조단계(S101)를 통해 제조된 유화제, 안료 및, 왁스를 혼합하여 유상부를 제조하는 단계로, 상기 유화제제조단계(S101)를 통해 제조된 유화제 100 중량부, 안료 100 내지 400 중량부 및 왁스 20 내지 200 중량부를 혼합하여 이루어지는 것이 바람직하다.The oil phase part preparation step (S103) is a step of preparing an oil phase part by mixing the emulsifier, pigment, and wax prepared through the emulsifier preparation step (S101), 100 parts by weight of the emulsifier prepared through the emulsifier preparation step (S101) , It is preferably formed by mixing 100 to 400 parts by weight of a pigment and 20 to 200 parts by weight of a wax.
이때, 상기 안료는 100 내지 400 중량부가 함유되며 화장료 조성물에 다양한 색상을 부여할 뿐만 아니라 자외선을 차단하는 효과를 나타내는데, 산화철, 티타늄다이옥사이드, 징크옥사이드, 세리사이트, 마이카, 탈크 및 카올린으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.At this time, the pigment is contained in an amount of 100 to 400 parts by weight, and not only imparts various colors to the cosmetic composition, but also shows an effect of blocking ultraviolet rays, in the group consisting of iron oxide, titanium dioxide, zinc oxide, sericite, mica, talc and kaolin. It is preferable to consist of one or more selected ones.
이때, 상기 산화철은 황색산화철, 적색산화철 및 흑색산화철 등이 사용될 수 있으며, 상기 티타늄다이옥사이드 및 징크옥사이드는 백색을 나타내며, 상기 세리사이트, 마이카, 탈크 및 카올린 등은 체질안료의 역할을 한다.At this time, yellow iron oxide, red iron oxide, black iron oxide, etc. may be used as the iron oxide, the titanium dioxide and zinc oxide show a white color, and the sericite, mica, talc, kaolin, etc. serve as an extender pigment.
상기 안료의 함량이 100 중량부 미만이면 상기의 효과가 미미하며, 상기 안료의 함량이 400 중량부를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 화장료 조성물의 효능과 안정성을 저하시킬 수 있다.If the content of the pigment is less than 100 parts by weight, the effect is insignificant, and if the content of the pigment exceeds 400 parts by weight, the effect and stability of the cosmetic composition may be reduced without greatly improving the effect.
상기 왁스는 20 내지 200 중량부가 함유되며 본 발명을 통해 제조되는 화장료 조성물에 보습효과를 부여할 뿐만 아니라, 유연성과 점성을 증가시켜 매끄러운 사용감을 부여하고, 화장료 조성물이 고형상의 파운데이션, 고형상의 선밤 및 선스틱 등으로 제조될 수 있도록 하는 역할을 한다.The wax is contained in an amount of 20 to 200 parts by weight and not only provides a moisturizing effect to the cosmetic composition prepared through the present invention, but also gives a smooth feeling of use by increasing flexibility and viscosity, and the cosmetic composition is a solid foundation, solid It serves to make it into sun balm and sun stick.
이때, 상기 왁스는 오조케라이트, 칸데릴라납, 세레신, 마이크로크리스탈린납, 파라핀, 카나우바왁스, 합성왁스 및 비즈왁스로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.At this time, the wax is preferably made of at least one selected from the group consisting of ozokerite, candelilla wax, ceresin, microcrystalline wax, paraffin, carnauba wax, synthetic wax, and beeswax.
상기 왁스의 함량이 20 중량부 미만이면 상기의 효과가 미미하며, 상기 왁스의 함량이 200 중량부를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 상대적으로 유화제나 안료의 함량이 지나치게 줄어들기 때문에 바람직하지 못하다.If the content of the wax is less than 20 parts by weight, the effect is insignificant, and if the content of the wax exceeds 200 parts by weight, the effect is not greatly improved and the content of the emulsifier or pigment is relatively reduced. can't
상기 수상부제조단계(S103-1)는 물 및 보습제를 혼합하여 수상부를 제조하는 단계로, 물 100 중량부에 보습제 3 내지 5 중량부를 혼합하여 이루어지는데, 상기 보습제는 글리세린으로 이루어지는 것이 바람직하다.The water phase preparation step (S103-1) is a step of preparing an aqueous phase by mixing water and a moisturizer, which is made by mixing 3 to 5 parts by weight of a moisturizer with 100 parts by weight of water. The moisturizer is preferably made of glycerin.
상기 보습제의 함량이 3 중량부 미만이면 본 발명을 통해 제조되는 화장료 조성물의 보습효과가 지나치게 저하되며, 상기 보습제의 함량이 5 중량부를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 본 발명을 통해 제조되는 화장료 조성물의 끊적임이 지나치게 증가되기 때문에 바람직하지 못하다.If the content of the humectant is less than 3 parts by weight, the moisturizing effect of the cosmetic composition prepared through the present invention is excessively reduced, and when the content of the humectant exceeds 5 parts by weight, the effect is not greatly improved and through the present invention This is undesirable because the brittleness of the manufactured cosmetic composition is excessively increased.
상기 원료혼합단계(S105)는 상기 유상부제조단계(S103)를 통해 제조된 유상부에 상기 수상부제조단계(S103-1)를 통해 제조된 수상부를 혼합하는 단계로, 상기 유상부제조단계(S103)를 통해 제조된 유상부 4 내지 40 중량%에 상기 수상부제조단계(S103-1)를 통해 제조된 수상부 60 내지 96 중량%를 혼합하여 이루어지데, 상기의 혼합은 호모믹서기 등을 이용하여 2000 내지 3000rpm의 속도로 5 내지 15분 동안 이루어지는 것이 바람직하다.The raw material mixing step (S105) is a step of mixing the water phase part prepared through the oil phase part manufacturing step (S103-1) with the oil phase part manufactured through the oil phase part manufacturing step (S103), through the oil phase part manufacturing step (S103) It is made by mixing 60 to 96% by weight of the water phase part prepared through the water phase part preparation step (S103-1) with 4 to 40 weight % of the prepared oil phase part, and the mixing is performed at a speed of 2000 to 3000 rpm using a homomixer or the like. It is preferably made for 5 to 15 minutes.
상기 원료혼합단계(S105)에서 상기 유상부의 혼합량이 4 중량% 미만이면 유화제 성분으로 인한 구조적 안정성과 안료의 응집현상이 억제 효과 및 부드러운 사용감 등의 효과가 저하되며, 상기 유상부의 혼합량이 40 중량%를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 피부자극성이나 끈적임이 지나치게 증가하게 된다.In the raw material mixing step (S105), when the mixing amount of the oily phase is less than 4% by weight, the structural stability due to the emulsifier component, the effect of suppressing the aggregation of the pigment, and the soft feeling of use are reduced, and the mixing amount of the oily phase is 40% by weight When it exceeds, the above effect is not greatly improved, but skin irritation or stickiness is excessively increased.
이하에서는, 본 발명에 따른 피부자극이 적은 유중수형 화장료 조성물의 제조방법 및 그 제조방법으로 제조된 유중수형 화장료 조성물의 물성을 실시예를 들어 설명하기로 한다.Hereinafter, the manufacturing method of the water-in-oil cosmetic composition with less skin irritation according to the present invention and the physical properties of the water-in-oil cosmetic composition prepared by the manufacturing method will be described with examples.
<제조예 1> 유화제 혼합물의 제조<Preparation Example 1> Preparation of emulsifier mixture
오가노클레이 화합물(쿼터늄-18 벤토나이트) 100 중량부, 폴리글리세릴계 화합물(폴리글리세릴-2 아이소스테아레이트) 280 중량부, 소르비탄계 화합물(소르비탄 아이소스테아레이트) 40 중량부 및 극성오일(코코-카프릴레이트/카프레이트) 140 중량부를 혼합하여 유화제 혼합물을 제조하였다.Organoclay compound (quaternium-18 bentonite) 100 parts by weight, polyglyceryl compound (polyglyceryl-2 isostearate) 280 parts by weight, sorbitan compound (sorbitan isostearate) 40 parts by weight and polar oil An emulsifier mixture was prepared by mixing 140 parts by weight of (coco-caprylate/caprate).
<제조예 2> 유상부의 제조<Production Example 2> Preparation of oily phase
상기 제조예 1을 통해 제조된 유화제 혼합물 100 중량부, 안료(황색 산화철, 티타늄다이옥사이드, 징크옥사이드, 세리사이트, 마이카, 탈크 및 카올린이 1:1:1:1:1:1:1의 중량부로 혼합) 250 중량부 및 왁스(오조케라이트) 110 중량부를 혼합하여 유상부를 제조하였다.100 parts by weight of the emulsifier mixture prepared in Preparation Example 1, pigments (yellow iron oxide, titanium dioxide, zinc oxide, sericite, mica, talc and kaolin are 1:1:1:1:1:1:1 by weight) mixing) 250 parts by weight and 110 parts by weight of wax (ozokerite) were mixed to prepare an oil phase part.
<제조예 3> 수상부의 제조<Production Example 3> Preparation of water phase part
정제수 100 중량부에 보습제(글리세린) 4 중량부를 혼합하여 수상부를 제조하였다.An aqueous phase was prepared by mixing 4 parts by weight of a moisturizer (glycerin) with 100 parts by weight of purified water.
<실시예 1><Example 1>
상기 제조예 2를 통해 제조된 유상부 4 중량% 및 상기 제조예 3을 통해 제조된 수상수 96 중량%를 호모믹서기에 투입하고 2500rpm의 속도로 10분 동안 혼합하여 피부자극이 적은 유중수형 화장료 조성물을 제조하였다.4% by weight of the oil phase part prepared in Preparation Example 2 and 96% by weight of the aqueous phase water prepared in Preparation Example 3 were put into a homomixer and mixed at a speed of 2500 rpm for 10 minutes to obtain a water-in-oil cosmetic composition with less skin irritation. manufactured.
<실시예 2><Example 2>
상기 실시예 1과 동일하게 진행하되, 상기 제조예 2를 통해 제조된 유상부 22 중량% 및 상기 제조예 3을 통해 제조된 수상수 78 중량%를 혼합하여 피부자극이 적은 유중수형 화장료 조성물을 제조하였다.Proceed in the same manner as in Example 1, but by mixing 22% by weight of the oil phase prepared in Preparation Example 2 and 78% by weight of the aqueous phase water prepared in Preparation Example 3 to prepare a water-in-oil cosmetic composition with less skin irritation. .
<실시예 3><Example 3>
상기 실시예 1과 동일하게 진행하되, 상기 제조예 2를 통해 제조된 유상부 40 중량% 및 상기 제조예 3을 통해 제조된 수상수 60 중량%를 혼합하여 피부자극이 적은 유중수형 화장료 조성물을 제조하였다.Proceed in the same manner as in Example 1, but by mixing 40% by weight of the oil phase prepared in Preparation Example 2 and 60% by weight of the aqueous phase water prepared in Preparation Example 3 to prepare a water-in-oil cosmetic composition with less skin irritation. .
<비교예 1><Comparative Example 1>
상기 실시예 1과 동일하게 진행하되, 상기 제조예 2를 통해 제조된 유상부 1 중량% 및 상기 제조예 3을 통해 제조된 수상수 99 중량%를 혼합하여 유중수형 화장료 조성물을 제조하였다.In the same manner as in Example 1, a water-in-oil cosmetic composition was prepared by mixing 1% by weight of the oil phase prepared in Preparation Example 2 and 99% by weight of the aqueous phase water prepared in Preparation Example 3.
<비교예 2><Comparative Example 2>
상기 실시예 1과 동일하게 진행하되, 상기 제조예 2를 통해 제조된 유상부 60 중량% 및 상기 제조예 3을 통해 제조된 수상수 40 중량%를 혼합하여 유중수형 화장료 조성물을 제조하였다.In the same manner as in Example 1, a water-in-oil cosmetic composition was prepared by mixing 60% by weight of the oil phase prepared in Preparation Example 2 and 40% by weight of the aqueous phase water prepared in Preparation Example 3.
<비교예 3><Comparative Example 3>
실리콘 유화제 100 중량부, 안료(황색 산화철, 티타늄다이옥사이드, 징크옥사이드, 세리사이트, 마이카, 탈크 및 카올린이 1:1:1:1:1:1:1의 중량부로 혼합) 250 중량부 및 왁스(오조케라이트) 110 중량부를 혼합하여 제조된 유상부를 제조하고, 상기 유상부 4 중량% 및 상기 제조예 3을 통해 제조된 수상부 96 중량%를 호모믹서기에 투입하고 2500rpm의 속도로 10분 동안 혼합하여 유중수형 화장료 조성물을 제조하였다.100 parts by weight of silicone emulsifier, 250 parts by weight of pigment (yellow iron oxide, titanium dioxide, zinc oxide, sericite, mica, talc and kaolin mixed in a 1:1:1:1:1:1:1 weight part) and wax ( ozokerite) to prepare an oil phase part prepared by mixing 110 parts by weight, and 4% by weight of the oil phase part and 96% by weight of the water phase part prepared in Preparation Example 3 were put into a homomixer and mixed at a speed of 2500 rpm for 10 minutes A water-in-oil cosmetic composition was prepared.
<비교예 4><Comparative Example 4>
상기 비교예 3과 동일하게 진행하되, 유상부 22% 및 상기 제조예 3을 통해 제조된 수상부 78 중량%를 호모믹서기에 투입하고 2500rpm의 속도로 10분 동안 혼합하여 유중수형 화장료 조성물을 제조하였다.Proceed in the same manner as in Comparative Example 3, but 22% of the oil phase part and 78% by weight of the water phase part prepared in Preparation Example 3 were put into a homomixer and mixed at a speed of 2500 rpm for 10 minutes to prepare a water-in-oil cosmetic composition.
<비교예 5><Comparative Example 5>
상기 비교예 3과 동일하게 진행하되, 유상부 40% 및 상기 제조예 3을 통해 제조된 수상부 60 중량%를 호모믹서기에 투입하고 2500rpm의 속도로 10분 동안 혼합하여 유중수형 화장료 조성물을 제조하였다.Proceed in the same manner as in Comparative Example 3, but 40% of the oil phase part and 60% by weight of the water phase part prepared in Preparation Example 3 were put into a homomixer and mixed at a speed of 2500 rpm for 10 minutes to prepare a water-in-oil cosmetic composition.
상기 실시예 1 내지 3 및 비교예 1 내지 5를 통해 제조된 유중수형 화장료 조성물의 피부자극, 보습력, 끈적임 여부 및 외관(안료 뭉침 여부)을 측정하여 아래 표 1에 나타내었다.The water-in-oil cosmetic compositions prepared in Examples 1 to 3 and Comparative Examples 1 to 5 were measured for skin irritation, moisturizing power, stickiness, and appearance (pigment aggregation) and are shown in Table 1 below.
{단, 유중수형 화장료 조성물의 피부자극, 보습력, 끈적임 여부 및 외관(안료 뭉침 여부)은 피시험자 50명을 대상으로 하여 2g을 하루에 2번씩 14일 동안 세안 후 얼굴에 도포하도록 한 후에, 5점 척도법으로 조사하여 평균값을 나타내는 방법을 이용하였다.{However, skin irritation, moisturizing power, stickiness, and appearance (pigment aggregation) of the water-in-oil cosmetic composition were tested on 50 test subjects by applying 2g twice a day for 14 days after washing their face, then 5 A method of indicating the average value was used by investigating the point scale method.
5점:매우 우수, 4점:우수, 3점:보통, 2점:나쁨, 1점:매우 나쁨} 5 points: very good, 4 points: excellent, 3 points: average, 2 points: poor, 1 point: very bad}
<표 1> <Table 1>
상기 표 1에 나타낸 것처럼, 본 발명의 실시예 1 내지 3을 통해 제조된 화장료 조성물은 피부자극이 낮고, 보습력이 우수하며 끈적임이 없는 것을 알 수 있다.As shown in Table 1, it can be seen that the cosmetic compositions prepared in Examples 1 to 3 of the present invention have low skin irritation, excellent moisturizing power, and no stickiness.
또한 안료의 뭉침현상 등이 발생하지 않는 것을 알 수 있다.In addition, it can be seen that aggregation of pigments does not occur.
반면, 비교예 1의 경우 유상부의 함량이 지나치게 낮아 안료 등의 뭉침현상 등으로 인해 외관품질이 낮고, 비교예 2의 경우는 유상부의 함량이 지나치게 높아 피부 보습력이 저하되며 피부 끈적임이 지나치게 증가하는 것을 알 수 있다.On the other hand, in the case of Comparative Example 1, the content of the oily part is too low, so the appearance quality is low due to agglomeration of pigments, etc., and in the case of Comparative Example 2, the content of the oily part is too high, so the skin moisturizing power is reduced and the skin stickiness is excessively increased. Able to know.
또한, 비교예 3 내지 5는 유상부의 유화제로 실리콘 유화제가 사용되어 피부자극이 높은 것을 알 수 있다.In addition, in Comparative Examples 3 to 5, it can be seen that the silicone emulsifier is used as an emulsifier for the oily part, resulting in high skin irritation.
따라서, 본 발명에 따른 피부자극이 적은 유중수형 화장료 조성물의 제조방법은 실리콘이나 피이지 성분이 사용되지 않아 피부자극이 적고 상호작용력이 우수한 유화제 성분이 적용되어 적은 양으로도 안정한 구조를 나타내며 안료의 응집현상이 억제될 뿐만 아니라, 수분을 배출하는 오일성분이 함유되어 끈적임이 적고 매끄러운 사용감을 나타내는 유중수형 화장료 조성물을 제공한다.Therefore, the manufacturing method of the water-in-oil cosmetic composition with little skin irritation according to the present invention does not use silicone or sebum components, so the emulsifier component with low skin irritation and excellent interaction power is applied, showing a stable structure even with a small amount of pigment It provides a water-in-oil cosmetic composition that not only inhibits aggregation, but also contains an oil component that discharges moisture and exhibits a smooth feeling of use with less stickiness.
S101 ; 유화제제조단계
S103 ; 유상부제조단계
S103-1 ; 수상부제조단계
S105 ; 원료혼합단계S101; Emulsifier manufacturing step
S103; Conflict manufacturing step
S103-1; Water phase manufacturing step
S105; Raw material mixing step
Claims (11)
상기 유화제제조단계를 통해 제조된 유화제, 안료 및, 왁스를 혼합하여 유상부를 제조하는 유상부제조단계;
물 및 보습제를 혼합하여 수상부를 제조하는 수상부제조단계; 및
상기 유상부제조단계를 통해 제조된 유상부에 상기 수상부제조단계를 통해 제조된 수상부를 혼합하는 원료혼합단계;로 이루어지며,
상기 유화제는 오가노클레이 화합물 100 중량부, 폴리글리세릴계 화합물 280 중량부, 소르비탄계 화합물 40 중량부 및 극성오일 140 중량부로 이루어지고,
상기 유상부제조단계는 유화제 100 중량부, 안료 100 내지 400 중량부 및 왁스 20 내지 200 중량부를 혼합하여 이루어지며,
상기 안료는 세리사이트, 마이카, 탈크 및 카올린으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.
An emulsifier preparation step of preparing an emulsifier;
An oil phase part preparation step of preparing an oil phase part by mixing the emulsifier, pigment, and wax prepared through the emulsifier preparation step;
An aqueous phase preparing step of preparing an aqueous phase by mixing water and a moisturizing agent; and
A raw material mixing step of mixing the water phase part prepared through the oil phase part manufacturing step with the oil phase part produced through the oil phase part manufacturing step;
The emulsifier is composed of 100 parts by weight of an organoclay compound, 280 parts by weight of a polyglyceryl compound, 40 parts by weight of a sorbitan compound, and 140 parts by weight of a polar oil,
The oil phase preparation step is made by mixing 100 parts by weight of an emulsifier, 100 to 400 parts by weight of a pigment, and 20 to 200 parts by weight of a wax,
The method for producing a water-in-oil cosmetic composition with low skin irritation, characterized in that the pigment consists of at least one selected from the group consisting of sericite, mica, talc and kaolin.
상기 오가노클레이 화합물은 쿼터늄-18 벤토나이트, 쿼터늄-90 벤토나이트 , 스테아랄코늄 벤토라이트, 쿼터늄-90 몬모닐로라이트, 쿼터늄-90 세피올나이트, 다이스테아다이모늄 헥토라이트 및 쿼터늄-18 헥토라이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.
The method of claim 1,
The organoclay compound is quaternium-18 bentonite, quaternium-90 bentonite, stearalkonium bentolite, quaternium-90 monmonilolite, quaternium-90 sepiolite, disteadymonium hectorite and quaterite. A method for producing a water-in-oil cosmetic composition with less skin irritation, characterized in that it consists of at least one selected from the group consisting of nium-18 hectorite.
상기 폴리글리세릴계 화합물은 폴리글리세릴-2 아이소스테아레이트, 폴리글리세릴-6 폴리리시놀리에이트, 폴리글리세릴-3 다이아이소스테아레이트, 폴리글리세릴-4 아이소스테아레이트, 폴리글리세릴-3 폴리리시놀리에이트, 폴리글리세릴-2 다이아이소스테아레이트 및 폴리글리세릴-4 다이아이소스테아레이트/폴리하이드록시 스테아레이트/세바케이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.
The method of claim 1,
The polyglyceryl-based compound is polyglyceryl-2 isostearate, polyglyceryl-6 polyricinoleate, polyglyceryl-3 diisostearate, polyglyceryl-4 isostearate, polyglyceryl-3 poly An oil with low skin irritation characterized in that it consists of at least one selected from the group consisting of ricinoleate, polyglyceryl-2 diisostearate and polyglyceryl-4 diisostearate/polyhydroxy stearate/sebacate. A method for producing a water-type cosmetic composition.
상기 소르비탄계 화합물은 소르비탄 아이소스테아레이트, 소르비탄 세스퀴올레이트, 소르비탄 올레이트 및 소르비탄 스테아레이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.
The method of claim 1,
The sorbitan-based compound is characterized in that it consists of at least one selected from the group consisting of sorbitan isostearate, sorbitan sesquioleate, sorbitan oleate and sorbitan stearate Preparation of a water-in-oil cosmetic composition with low skin irritation method.
상기 극성오일은 코코-카프릴레이트/카프레이트, 미리스틸미리스테이트, 부틸렌글라이콜 카프릴레이트/카프레이트, 아이소아밀라우레이트, 세테아릴에칠헥사노에이트 및 스테아릴헵타노에이트로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.
The method of claim 1,
The polar oil is composed of coco-caprylate/caprate, myristyl myristate, butylene glycol caprylate/caprate, isoamyllaurate, cetearylethylhexanoate and stearylheptanoate. Method for producing a water-in-oil cosmetic composition with less skin irritation, characterized in that it consists of at least one selected from the group.
상기 왁스는 오조케라이트, 칸데릴라납, 세레신, 마이크로크리스탈린납, 파라핀, 카나우바왁스, 합성왁스 및 비즈왁스로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.
The method of claim 1,
The wax is a water-in-oil cosmetic composition with low skin irritation, characterized in that it consists of at least one selected from the group consisting of ozokerite, candelilla wax, ceresin, microcrystalline wax, paraffin, carnauba wax, synthetic wax and beeswax. manufacturing method.
상기 원료혼합단계는 상기 유상부제조단계를 통해 제조된 유상부 4 내지 40 중량%에 상기 수상부제조단계를 통해 제조된 수상부 60 내지 96 중량%를 혼합하여 이루어지는 것을 특징으로 하는 피부자극이 적은 유중수형 화장료 조성물의 제조방법.The method of claim 1,
The raw material mixing step is a water-in-oil cosmetic with low skin irritation, characterized in that it is made by mixing 60 to 96% by weight of the aqueous phase part prepared through the water phase part manufacturing step with 4 to 40% by weight of the oil phase part produced through the oil phase part manufacturing step Method for preparing the composition.
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| KR20170025647A (en) * | 2015-08-31 | 2017-03-08 | (주)아모레퍼시픽 | Cosmetic composition for lip |
| KR20190098194A (en) * | 2016-12-21 | 2019-08-21 | 로레알 | Water-in-oil emulsions comprising specific emulsification systems, lipophilic clays, and organopolysiloxane elastomer powders coated with silicone resins |
| KR20190057660A (en) * | 2017-11-20 | 2019-05-29 | (주)아모레퍼시픽 | Sun screening cometic composition comprising a polyglyceryl-based emulsifier and a sorbitan-based emulsifier |
| KR102127674B1 (en) * | 2019-01-17 | 2020-06-29 | 한국콜마주식회사 | Water-drop solid type cosmetic composition in the form of water-in-oil emulsion of silicone-free and peg-free, and preparation method of the same |
| KR20210119781A (en) * | 2020-03-25 | 2021-10-06 | 코스맥스 주식회사 | Cosmetic composition of water-in-oil type (W/O) Lamellar liquid crystalline emulsion |
| KR20220042013A (en) * | 2020-09-25 | 2022-04-04 | 주식회사 코스메카코리아 | water-in-oil type cosmetic composition and manufacturing method of the same |
| KR102269866B1 (en) * | 2020-10-30 | 2021-06-28 | 한국콜마주식회사 | Water-in-oil cosmetic composition with maximized moisture |
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