JPH1067552A - Solid material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a solid material capable of being utilized for pearl nuclei, accessories, building materials and sea alga growth. SOLUTION: (1) A product is reacted with carbon dioxide in the presence of the mixture of lime water with a biological solution to produce a biological calcium carbonate coating layer. (2) The formation of the biological calcium carbonate coating layer is carried out by reacting the product in the mixture of the lime water with the biological solution, while charging air or carbon dioxide. (3) The formation of the biological calcium carbonate coating layer is carried out in the atmosphere of air or carbon dioxide, while supplying the mixture. (4) Aragonite or shell lime is used for the lime water. (5) A squeezed shellfish meat juice or shellfish meat collagen is used for the biological solution. (6) The aragonite or the shell lime is used for the lime water, and the squeezed shellfish meat juice or the shellfish meat collagen is used for the biological solution. (7) While the solid material is treated with water or a solution capable of reacting with slaked lime, a wiping treatment, a mutually solid material- rubbing or polishing treatment, etc., is utilized to prevent the adhesion of the reaction products or eluted substances to the surface of the solid material.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a pearl nucleus, a ring,
The present invention relates to jewelry such as earrings, necklaces, and bracelets, rosaries, and solid materials that can be used for building materials and for growing seaweed.

[0002]

BACKGROUND ART Pearlite contains aragonite (a type of calcium carbonate), conchiolin (a type of protein), and water.
As the pearl nucleus, a natural pearl nucleus polished shell was used, but recently it has become less and more expensive, and there has been a demand for the development of a pearl nucleus to replace the shell.

[0003]

SUMMARY OF THE INVENTION An object of the present invention is to provide a solid material which can be used not only as a pearl nucleus but also as a building material and for growing seaweeds as well as accessories and beads.

[0004]

Means for Solving the Problems The solid matter of the first invention is a method for forming lime water and biomass into a molded product such as metal, stone, plastic, ceramic, glass, mortar, concrete, calcium carbonate, etc. formed in a desired shape. By applying air or carbon dioxide gas in the presence of a mixture of system solutions to form a biological / calcium carbonate-based coating layer, or further polishing / polishing / rubbing /
It is characterized by glossy finish. The solid coating layer is a mixture of lime water and a biological solution, that is, a product obtained by reacting and hardening by reacting air or carbon dioxide gas on the solution, so that a dense layer without voids is formed, and water hardly penetrates. In addition, due to the presence of the biological solution, adhesion to the molded article is also good. If a dye is added to the mixture, the coating layer is colored. Solids tend to have a deep gloss on the surface, and when the solids are mixed with paddy and agitated, or the surface is polished or rubbed by spraying fine plastic particles, the surface becomes even more glossy with depth Is formed. The molded product is a mixture of fresh mortar or ready-mixed concrete or slaked lime and water,
Molding with metal, plastic, ceramic, wood, etc., centrifugal molding, extrusion molding, press molding, press dehydration molding, vibration press molding, spherical molding by rolling method It is possible to form stones such as limestone, hard sandstone, and aragonite into spherical shapes by means of grinding. Further, commercially available glass spheres, metal spheres, plastic spheres, ceramic spheres and the like can be used as molded products. The solid can be used for pearl nuclei, rosaries, imitation pearls, building materials, seaweed fixing materials, and the like.

[0005] The solid matter of the second invention is characterized in that the formation of the biological / calcium carbonate-based coating layer of the first invention is performed by sending air or carbon dioxide gas to a molded product in a mixture of lime water and a biological solution. It is characterized by being formed by reaction. When the molded product was suspended with a string or wire so that the molded product did not touch the container or other molded products in the mixed solution, and air or carbon dioxide gas was sent through a tube to make the molded product touch the molded product, the molded product was suspended. Except for parts, a biological / calcium carbonate coating layer is formed. If the solid is a pearl nucleus or imitation pearl, make a hole in the molded product,
It may be fixed in the mixed solution through a string or a wire, and may be touched by sending air or carbon dioxide gas. In addition, air or carbon dioxide gas may be sent by submerging in a tank containing a mixed solution, including the case of building materials. In this case, if the moldings are moved at regular intervals, the moldings do not adhere to each other.

The solid matter of the third invention is characterized in that the formation of the biological / calcium carbonate-based coating layer of the first invention is carried out by supplying a mixture of lime water and a biological solution in an atmosphere of air or carbon dioxide gas. It is characterized by being formed by reaction. The above-mentioned solid material may be supplied by opening a hole in the molded product, hanging it from the ceiling of the curing room through a string or the like, spraying the mixed solution, or spraying the mixed solution on the floor. It may be supplied by doing. If the mixture has accumulated on the floor, collect and reuse. In this case, the lime water and the biological solution can be supplied at an increased concentration. The supply of the mixture may be performed intermittently to such an extent that the surface of the molded product is constantly covered with the mixture. The molded product is placed in a tank filled with air or carbon dioxide gas, and the mixed solution is taken out and put in a circulation system or the like. Alternatively, contact with carbon dioxide may be repeated.

[0007] The solid matter of the fourth invention is characterized in that the lime water of the first to third inventions is obtained by adding water to quicklime produced by heating aragonite or shells or slaked lime produced therefrom. And The solid material is suitable as a pearl nucleus because aragonite or shells are used for lime water.

[0008] A fifth aspect of the present invention is characterized in that the biological solution according to the first to third aspects is a juice extracted from shellfish or collagen obtained from shellfish. The solid material is suitable as a pearl nucleus, since the biological solution uses shellfish juice or collagen obtained from shellfish.

[0009] The solid matter of the sixth invention is the lime water of the first to third inventions, which is obtained by adding water to quicklime or slaked lime produced by heating aragonite or shells, The biological solution according to the third aspect of the present invention is characterized in that the biological solution is shell juice or collagen obtained from shell meat.
The solid material is more suitable as a pearl nucleus because the coating is substantially the same as the pearl component.

The solid according to the seventh aspect of the present invention uses wiping and friction, rubbing and polishing between the solids while applying the solid according to the first to sixth aspects to water or a solution which reacts with slaked lime. It is characterized in that reactants and elutes are prevented from adhering to the surface. When slaked lime elutes due to insufficient reaction due to carbonation of lime water, etc., the solid matter loses gloss even if the reactants and eluted substances adhere to the surface and become glossy, but these do not adhere. Gloss is not lost or hardly lost. In addition, since the surface is smooth without unevenness, when a paint is applied or used as a pearl nucleus, a smooth surface layer similar to the base can be obtained even if the coating film or the pearl layer is thin.

[0011]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS First, terms used in the present invention will be described. The biological solution refers to a protein solution and / or a starchy solution. A protein solution is a gelatin solution prepared by adding water and hot-melt, a glue solution prepared by adding water and hot-melt solution, a collagen solution, milk (processing of liquids such as gum arabic that occurs when other plants in the animal are damaged or skim milk, etc.) Milk is also included.)-Casein solution-Egg white or its solution-Soymilk or its solution. Starch solutions are starch, starch, sweet potato starch,
Water is added to starch such as potato starch, rice flour, wheat flour, tapioca flour, corn flour, nata de coco flour, and then hot-melted starch solution, starch sugar solution, konjac solution, cellulose solution, nitrocellulose solution, viscose solution, silk fibroin A solution containing water and hot-melted agar solution, a hot-melted tocorotene solution, a hot-melted funnel solution with added water, and the like include natural juices. Coloring agents include pigments and dyes (animal dyes such as squid and octopus ink, till purple and cochineal, and vegetable dyes obtained from eye leaves, purple roots, safflower flowers, gardenia fruits, etc.). )), Fish scale foil, synthetic pearl foil,
Fish scale foil and / or synthetic pearl foil pearl essence and the like are used.

A: A molded article such as metal, stone, plastic, ceramic, glass, mortar, concrete, calcium carbonate or the like formed in a desired shape is air or carbon dioxide gas in the presence of a mixture of lime water and protein solution. Let
A biological / calcium carbonate coating layer was formed, or further polished, polished, rubbed, polished, etc. Water was added to slaked lime and / or quicklime to lime water, and the supernatant (saturated aqueous solution) was used. To this, 340 parts of egg white solution mixed with 300 parts of water to 60 parts of egg white and 400 parts of water to 400 parts of oyster were mixed and mixed, and 340 parts of oyster juice and 340 parts of low fat milk were strained with a cloth. -340 parts of a heated aqueous solution having a gelatin content of 5/70-380 parts of soymilk 380 parts of different protein solutions are added and mixed to form five types of mixed solutions, and air or carbon dioxide gas is acted on in the presence of the mixed solutions. A solid having a biological / calcium carbonate coating layer was obtained. After 7 days, polishing and polishing were performed to obtain a biological / calcium carbonate solid having a smooth surface. B ‥‥ Metal, stone, plastic, formed into desired shape
Air or carbon dioxide gas is applied to a molded product such as ceramic, glass, mortar, concrete, calcium carbonate, etc. in the presence of a mixture of lime water and a starch solution to form a biological / calcium carbonate coating layer, or In addition, polishing, polishing, rubbing, polishing, etc. were performed. In the mixed solution, 340 parts of a heated solution of funori having a funnel content of 1/12 in lime water, 340 parts of a heated solution of tocorotene obtained by heating 500 parts of tocorotene to 400 parts, or a heated aqueous solution having agar content of 1/60 3
Using three types of mixed solutions to which 50 parts of different starchy solutions were added, air or carbon dioxide gas was allowed to act in the presence of the mixed solutions to obtain a solid having a biological / calcium carbonate-based coating layer. After 7 days, polishing and polishing were performed to obtain a biological / calcium carbonate solid having a smooth surface.

[0013] The biological / calcium carbonate-based coating layer of the embodiment is formed by reacting a molded product in a mixture of lime water and a biological solution while sending air or carbon dioxide gas to contact the molded product. . (4) The biological / calcium carbonate-based coating layer of the embodiment was formed by reacting a mixture of lime water and a biological solution in an atmosphere of air or carbon dioxide gas. (4) As the lime water used for forming the biological / calcium carbonate coating layer of the embodiment, aragonite or calcined lime produced by heating a shell or slaked lime produced from the lime water was used. (4) Shellfish juice or collagen obtained from shellfish was used as the biological solution used for forming the biological / calcium carbonate coating layer of the embodiment.に To the lime water used for forming the biological / calcium carbonate-based coating layer of the embodiment, use lime water formed by adding water to quick lime produced by heating aragonite or shells or slaked lime made therefrom, For the biological solution, a juice extracted from shell meat or collagen taken from shell meat was used.固 形 While applying the solid material of the embodiment to a solution that reacts with water or slaked lime, use wiping or friction / rubbing / polishing between solid materials to prevent reactants and elutes from adhering to the surface. Thus, a glossy solid having a smooth surface was obtained.

[0014]

EXAMPLE ６００ To 300 parts of egg white, 600 parts of water and 30 parts of sodium bicarbonate were added and stirred to prepare a solution, and 800 parts of the solution were added to slaked lime 1
Add 800 parts to make a mixture, make a ball about 1 cm in diameter and a plate about 1 cm thick, soak in hot water at a temperature of 80 ° C. three days later, take it out one day later, and after 7 days polishing and polishing,
A molded product that can be used in the present invention was obtained. (4) The solid of the present invention was obtained using the mixed solution to which the coloring agent was added.球 Using a ball-making machine consisting of a cylindrical side wall and a bottom rotating plate, supply one or more powders of slaked lime, quicklime and cement onto the rotating plate and rotate the rotating plate, A ball was formed while spraying a biological solution to obtain a molded product usable in the present invention. In the above-mentioned rolling method, the powder is attached or impregnated to the droplets of the biological solution, and the droplets of the biological solution and the powder are further adhered or adhered and impregnated while rolling the droplets to form a mixture sphere. However, a solid may be used as a nucleus, and a biological solution and a powder may be adhered or impregnated on the outside of the solid to form a multi-layer.を Eluate and reactant in the presence of 0.5% salt water (any kind of aqueous solution of potassium stearate and silica sol if it reacts with slaked lime) or water With a pan-type mixer, rotating drum, or rotating plate, so as not to adhere to the surface of the spherical solid,
After 24 hours of rubbing while rolling, the gloss did not disappear even when immersed in water for 48 hours. Also,
Similar results were obtained when rolling not only spherical solids but also other balls such as ceramics. In the case where the solid material was a plate having a surface gloss, the plate surface was rubbed or wiped with a rotating brush or a rotating mop for 24 hours in the presence of an aqueous solution of a substance that reacts with an elute such as water or salt water. . This was also soaked in water for 48 hours and the gloss did not disappear. If water or salt water is contaminated with elutes or reactants, it is preferable to replace and work. For polishing or polishing, pressure blowing of abrasive powder, pressure spraying of abrasive powder slurry, pressure water spraying, spraying of plastic fine particles, stirring with paddy or the like can be used.

[0015]

The solid material of the present invention is constituted as described in detail, and includes pearl nuclei, various accessories, rosaries, various shaped objects and building materials.
It can also be used for seaweed growth, etc., and can be used as a favorite accessory or building material by applying nail polish or pearl essence. In addition, it is possible to cultivate nucleated pearls by transplanting small pieces of the mantle of the pearl shell and solid matter together into the gonads of the pearl shell, and also to use pearl clams and oysters such as mussels, mabe, ezo abalone, and pearl oysters. Solids can also be inserted between the mantle and shell to create half-shaped pearls and half-shaped pearl-like accessories.

Claims (7)

[Claims] 1. A metal, stone, plastic, ceramic, glass, mortar, concrete,
In the presence of a mixture of lime water and a biological solution, air or carbon dioxide is allowed to act on a molded product such as calcium carbonate.
A solid material having a calcium carbonate-based coating layer formed thereon or further polished, polished, rubbed or polished. 2. The biological / calcium carbonate-based coating layer according to claim 1 is formed by reacting a molded product in a mixture of lime water and a biological solution while sending air or carbon dioxide gas. A solid material characterized by being. 3. The biological / calcium carbonate-based coating layer according to claim 1 is formed by reacting in an atmosphere of air or carbon dioxide gas while supplying a mixture of lime water and a biological solution. A solid material characterized by being. 4. The solid matter according to claim 1, wherein the lime water according to any one of claims 1 to 3 is obtained by adding water to lime or lime produced by heating shells and slaked lime produced therefrom. 5. A solid material, wherein the biological solution according to claim 1 is collagen extracted from shellfish juice or shellfish. 6. The biological system according to claim 1, wherein the lime water according to any one of claims 1 to 3 is obtained by adding water to calcined lime obtained by heating aragonite or shells or slaked lime produced therefrom. A solid substance, wherein the solution is a juice of shellfish or collagen obtained from shellfish. 7. While reacting the solid substance according to claim 1 with water or a solution that reacts with slaked lime, the reactant or the effluent is removed by utilizing wiping or friction, rubbing or polishing between the solid substances. Solid material characterized by being made not to adhere to the surface.